PROMEGA CORPORATION -- PHENOL: CHLOROFORM: ISOAMYL ALCOHOL, Z566
=======================================================
Material Safety Data Sheet
=======================================================
MSDS Num: CJVRH
MSDS NAME: PHENOL: CHLOROFORM: ISOAMYL ALCOHOL, Z566
Responsible Party
Name: PROMEGA CORPORATION
Address: 2800 WOODS HOLLOW ROAD
City: MADISON WI 53711
Info Phone: 800-356-9526; 608-274-4330
Emergency Phone Number: 800-424-9300 (CHEMTREC)
Chemtrec IND/Phone: (800)424-9300
Review Ind: Y
Published: Y
=======================================================
Contractor Summary
=======================================================
Name: PROMEGA CORPORATION
Address: 2800 WOODS HOLLOW ROAD
City: MADISON WI 53711
Phone: 800-356-9526; 608-274-4330
=======================================================
Item Description Information
=======================================================
=======================================================
Ingredients
=======================================================
Cas: 108-95-2
RTECS #: SJ3325000
Name: PHENOL; (PHENOL, PURE)
% low Wt: 75.
% high Wt: 100.
Other REC Limits: N/K (FP N)
OSHA PEL: 19 MG/M3;5 PPM
OSHA STEL: N/K (FP N)
ACGIH TLV: 19 MG/M3;5 PPM
ACGIH STEL: N/K (FP N)
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
------------------------------
Cas: 67-66-3
RTECS #: FS9100000
Name: TRICHLOROMETHANE
% low Wt: 15.
% high Wt: 20.
Other REC Limits: N/K (FP N)
OSHA PEL: C240 MG/M3;C50 PPM
OSHA STEL: N/K (FP N)
ACGIH TLV: 49 MG/M3;10 PPM
ACGIH STEL: N/K (FP N)
EPA Rpt Qty: 10 LBS
DOT Rpt Qty: 10 LBS
------------------------------
Name: NONHAZARDOUS INGREDIENTS
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: SEE TOXICOLOGICAL INFORMATION.
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: YES
IARC: YES
OSHA: NO
Effects of Exposure: ACUTE: SKIN: CAUSTIC EFFECT ON SKIN AND MUCOUS MEMBRANES.
EYES: STRONG CAUSTIC EFFECT. SENSITIZATION: NO SENSITIZING EFFECTS KNOWN. THE
PRODUCT SHOWED THE FOLLOWING DANGERS ACCORDING TO THE CALCULATIO N METHOD OF
THE GENERAL EU CLASSIFICATION GUIDELINES FOR PREPARATIONS AS ISSUED IN THE
LATEST VERSION: POISONOUS, CORROSIVE. SWALLOWING WILL LEAD TO A STRONG
CAUSTIC EFFECT ON MOUTH AND THROAT AND TO THE DANGER OF PERFORATION OF
ESOPHAGUS AND STOMACH.
Explanation Of Carcinogenicity: TRICHLOROMETHANE: IARC MONOGRAPHS, SUPPLEMENT,
VOLUME 7, PAGE 152, 1987: GROUP 2B. NTP 8TH ANNUAL REPORT ON CARCINOGENS,
1998: REASONABLY ANTICIPATED TO BE HUMAN CARCINOGEN.
Signs And Symptions Of Overexposure: SEE HEALTH HAZARDS.
First Aid: IMMEDIATELY REMOVE ANY CLOTHING SOILED BY THE PRODUCT. IN CASE OF
IRREGULAR BREATHING OR RESPIRATORY ARREST PROVIDE ARTIFICIAL RESPIRATION.
INHALATION: IN CASE OF UNCONSCIOUSNESS, PLACE PATIENT STABLY IN SIDE
POSITION FOR TRANSPORTATION. SKIN: IMMEDIATELY WASH WITH WATER AND SOAP AND
RINSE THOROUGHLY. EYES: RINSE OPENED EYE FOR AT LEAST 15 MINUTES UNDER
RUNNING WATER. THEN CONSULT A DOCTOR. INGEST ION: DO NOT INDUCE VOMITING;
IMMEDIATELY CALL FOR MEDICAL HELP. DRINK COPIOUS AMOUNTS OF WATER AND PROVIDE
FRESH AIR. IMMEDIATELY CALL A DOCTOR.
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: WEAR PROTECTIVE EQUIPMENT. KEEP UNPROTECTED PERSONS
AWAY. PREVENT SEEPAGE INTO SEWAGE SYSTEM, WORKPITS AND CELLARS. DO NOT ALLOW
TO ENTER SEWERS/SURFACE OR GROUND WATER. ABSORB WITH LIQUID-BINDING MAT ERIAL
(SAND, DIATOMITE, ACID BINDERS, UNIVERSAL BINDERS, SAWDUST). USE NEUTRALIZING
AGENT. DISPOSE CONTAMINATED MATERIAL AS WASTE ACCORDING TO DISPOSAL
REGULATIONS. ENSURE ADEQUATE VENTILATION.
Waste Disposal Methods: MUST NOT BE DISPOSED OF TOGETHER WITH HOUSEHOLD
GARBAGE. DO NOT ALLOW PRODUCT TO REACH SEWAGE SYSTEM. DISPOSAL MUST BE MADE
ACCORDING TO OFFICIAL REGULATIONS. DISPOSE OF IN ACCORDANCE WITH LOCAL, STAT
E, AND FEDERAL REGULATIONS (FP N).
Handling And Storage Precautions: STORE IN COOL, DRY PLACE IN TIGHTLY CLOSED
RECEPTACLES. OPEN AND HANDLE RECEPTACLE WITH CARE. NO SPECIAL MEASURES
REQUIRED FOR PROTECTION AGAINST EXPLOSIONS & FIRES. NO SPECIAL
REQUIREMENTS TO BE MET BY STOREROOMS AND RECEPTACLES. NO INFORMATION
REQUIRED ABOUT STORAGE IN ONE COMMON STORAGE FACILITY.
Other Precautions: KEEP RECEPTACLE TIGHTLY SEALED. CLASS ACCORDING TO
REGULATION ON FLAMMABLE LIQUIDS: A III.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Flash Point: >55.C, 131.F
Autoignition Temp: =595.C, 1103.F
Lower Limits: 1.3%
Upper Limits: 9.5%
Extinguishing Media: CARBON DIOXIDE, EXTINGUISHING POWDER OR WATER SPRAY. FIGHT
LARGE FIRES WITH WATER SPRAY OR ALCOHOL RESISTANT FOAM.
Fire Fighting Procedures: NO SPECIAL MEASURES REQUIRED. WEAR NIOSH APPROVED
SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE EQUIPMENT (FP N).
Unusual Fire/Explosion Hazard: PRODUCT IS NOT SELF-IGNITING. PRODUCT DOES NOT
PRESENT AN EXPLOSION HAZARD.
=======================================================
Control Measures
=======================================================
Respiratory Protection: NOT REQUIRED. USE NIOSH APPROVED RESPIRATOR APPROPRIATE
FOR EXPOSURE OF CONCERN (FP N).
Protective Gloves: PROTECTIVE GLOVES. WEAR IMPERVIOUS GLOVES (FP N).
Eye Protection: ANSI APPROVED CHEMICAL WORKERS GOGGLES AND FULL LENGTH
FACESHIELD (FP N).
Other Protective Equipment: EYEWASH AND DELUGE SHOWER MEETING ANSI DESIGN
CRITERIA (FP N).
Work Hygienic Practices: KEEP AWAY FROM FOODSTUFFS, BEVERAGES & FEED. IMMED
REMOVE ALL SOILED & CONTAMINATED CLOTHING. WASH HANDS BEFORE BREAKS & AT END
OF WORK. STORE PROT CLOTHING SEPARATELY. AVOID CONT W/EYES & SKIN.
Supplemental Safety and Health: PHYSICAL/CHEM PROPERTIES: DENSITY: 1.135 G/CM3
@ 20C; SOL IN WATER: NOT MISCIBLE/DFCLT TO MIX; ORG SOLVS: 0.6%; SOLIDS
CONTENT: 83.4%. FED REGS: 45 - IN CASE OF ACCIDENT/IF YOU FEEL UNWELL, SEEK
MED A DVICE IMMED. WATER HAZ CLASS: WATER DANGER 3 (SELF-ASSESSMENT):
EXTREMELY HAZ FOR WATER.
=======================================================
Physical/Chemical Properties
=======================================================
Boiling Point: =62.C, 143.6F
Vapor Pres: 210.0 HPA @ 20C
PH: 0.0 @ 20C
Solubility in Water: SEE SUP DAT
Appearance and Odor: COLORLESS FLUID WITH CHARACTERISTIC ODOR.
=======================================================
Reactivity Data
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Stability Condition To Avoid: NO DECOMPOSITION IF USED ACCORDING TO
SPECIFICATIONS.
Materials To Avoid: NO DANGEROUS REACTIONS KNOWN.
Hazardous Decomposition Products: NO DANGEROUS DECOMPOSITION PRODUCTS KNOWN.
=======================================================
Toxicological Information
=======================================================
Toxicological Information: ACUTE TOXICITY: LD/LC50 VALUES THAT ARE RELEVANT FOR
CLASSIFICATION: 108-95-2 PHENOL, PURE: ORAL: LD50: 300 MG/KG (MUS); DERMAL:
LD50: 670 MG/KG (RAT); INHALATIVE: LC50/4 H: 316 MG/L (RAT). 67-66-3 TR
ICHLOROMETHANE: ORAL: LD50: 908 MG/KG (RAT); DERMAL: LD50: 75 MG/KG (RAT).
=======================================================
Ecological Information
=======================================================
Ecological: GENERAL NOTES: WATER DANGER CLASS 3 (GERMAN REGULATION)
(SELF-ASSESSMENT): EXTREMELY HAZARDOUS FOR WATER. DO NOT ALLOW PRODUCT TO
REACH GROUND WATER, WATER COURSE OR SEWAGE SYSTEM, EVEN IN SMALL QUANT ITIES.
MUST NOT REACH BODIES OF WATER OR DRAINAGE DITCH UNDILUTED OR UNNEUTRALIZED.
DANGER TO DRINKING WATER IF EVEN EXTREMELY SMALL QUANTITIES LEAK INTO THE
GROUND.
=======================================================
MSDS Transport Information
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Transport Information: DOT REGS: HAZ CLASS: 6.1; IDENTIFICATION #: UN2929;
PACKING GROUP: II; PROPER SHIPPING NAME (TECHNICAL NAME): PHENOL, SOLUTION.
LAND TRANSPORT ADR/RID (CROSS-BORDER): ADR/RID CLASS: 6.1 POIS SUBSTANCE S;
ITEM: 26B1; DANGER CODE (KEMLER): 633; UN-#: 2810; DESCRIPTION OF GOODS:
PHENOL, SOLUTION. MARITIME TRANSPORT IMDG: IMDG CLASS: 6.1; PAGE: 6270-3; UN
#: 2929; PACKAGING GROUP: II; EMS NUMBER: 6.1-0 1; MARINE POLLUTANT: YES;
PROPER SHIPPING NAME: PHENOL, SOLUTION. AIR TRANSPORT ICAO-TI & IATA-DGR:
ICAO/IATA CLASS: 6.1; UN/ID #: 2929; PACKAGING GROUP: II; PROPER SHIPPING
NAME: PHENOL, SOLUTION.
=======================================================
Regulatory Information
=======================================================
Federal Regulatory Information: MARKINGS: THE PROD HAS BEEN CLASSIFIED &
MARKED I/A/W EU DIRECTIVES/ORDINANCE ON HAZ MATLS. CODE LETTER & HAZ
DESIGNATION OF PROD: T TOX. HAZ-DETERMINING COMPONENTS OF LABELLING:
TRICHLOROMETHANE PHEN OL, PURE. RISK PHRASES: 24/25 - TOX IN CONT W/SKIN
& IF SWALLOWED; 34 - CAUSES BURNS; 40 - POSS RISK OF IRREVERSIBLE EFTS;
48/20/22 - HARMFUL: DANGER OF SERIOUS DMG TO HLTH BY PRLNG EXPOS THRU INHAL
& IF SWALLOWED. SFTY PHRASES: 1/2 - KEEP LOCKED UP & OUT OF REACH OF
CHILDREN; 26 - IN CASE OF CONT W /EYES, RINSE IMMED W/PLENTY OF WATER &
SEEK MED ADVICE; 36/37/39 - WEAR SUITABLE PROT CLTHG, GLOVES & EYE/FACE
PROT; (SUP DAT)
=======================================================
Other Information
=======================================================
Other Information: HAZARDS IDENTIFICATION: HAZARD DESCRIPTION: T TOXIC.
INFORMATION PERTAINING TO PARTICULAR DANGERS FOR MAN AND ENVIRONMENT: R 24/25
- TOXIC IN CONTACT WITH SKIN AND IF SWALLOWED; R 34 - CAUSES BURNS; R 40:
POSSIBLE RISK OF IRREVERSIBLE EFFECTS; R 48/20/22 - HARMFUL: DANGER OR
SERIOUS DAMAGE TO HEALTH BY PROLONGED EXPOSURE THROUGH INHALATION AND IF
SWALLOWED. NFPA RATINGS (SCALE 0-4): HEALTH = 3; FI RE = 2; REACTIVITY = 0.
=======================================================
HAZCOM Label
=======================================================
MSDS NAME: PHENOL: CHLOROFORM: ISOAMYL ALCOHOL, Z566
Company: PROMEGA CORPORATION
Street: 2800 WOODS HOLLOW ROAD
City: MADISON WI
Zipcode: 53711
Health Emergency Phone: 800-424-9300 (CHEMTREC)
Label Required IND: Y
Date Of Label Review: 11/15/1999
Status Code: A
Origination Code: F
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Severe
Contact Hazard: Severe
Fire Hazard: Moderate
Reactivity Hazard: None
Hazard And Precautions: CORROSIVE. POISON. ACUTE: SKIN: CAUSTIC EFFECT ON SKIN
AND MUCOUS MEMBRANES. EYES: STRONG CAUSTIC EFFECT. SENSITIZATION: NO
SENSITIZING EFFECTS KNOWN. SWALLOWING WILL LEAD TO A STRONG CAUSTIC EFFECT O
N MOUTH AND THROAT AND TO THE DANGER OF PERFORATION OF ESOPHAGUS AND STOMACH.
CHRONIC: CANCER HAZARD. TRICHLOROMETHANE IS LISTED AS AN ANIMAL LUNG
CARCINOGEN (FP N).
=======================================================
Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
*** END OF RECORD *** |
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