INTEGRA CHEMICAL COMPANY -- SULFURIC ACID, S978.10
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Material Safety Data Sheet
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MSDS Num: CJVRC
MSDS NAME: SULFURIC ACID, S978.10
Responsible Party
Name: INTEGRA CHEMICAL COMPANY
Address: 710 THOMAS AVE SW
City: RENTON WA 98055
Info Phone: 425-277-9244
Emergency Phone Number: 800-451-8346
Resp. Party Other MSDS No.: S978
Review Ind: Y
Published: Y
=======================================================
Contractor Summary
=======================================================
Name: INTEGRA CHEMICAL COMPANY
Address: 710 THOMAS AVE SW
City: RENTON WA 98055
Phone: 425-277-9244
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Item Description Information
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Ingredients
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Cas: 7664-93-9
RTECS #: WS5600000
Name: SULFURIC ACID. LD50:(ORAL,RAT) 2140 MG/KG.
% low Wt: 90.
% high Wt: 98.
OSHA PEL: 1 MG/M3
ACGIH TLV: 1 MG/M3
ACGIH STEL: 3 MG/M3
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
------------------------------
Cas: 7732-18-5
RTECS #: ZC0110000
Name: WATER
% low Wt: 2.
% high Wt: 10.
=======================================================
Health Hazards Data
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LD50 LC50 Mixture: SEE INGREDIENTS AND TOXICOLOGICAL INFO.
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: YES
OSHA: NO
Effects of Exposure: ACUTE: SKIN CONTACT: CORROSIVE MATERIAL. CONTACT MAY CAUSE
SEVERE BURNS. EYE CONTACT: VAPORS, MISTS AND LIQUIDS ARE CORROSIVE. BRIEF
CONTACT WITH VAPORS MAY BE SEVERELY IRRITATING. BRIEF LIQUID CONTAC T MAY
CAUSE SEVERE DAMAGE AND PROLONGED CONTACT MAY RESULT IN PERMANENT INJURY.
INGESTION: HARMFUL IF SWALLOWED. LIQUIDS ARE EXTREMELY CORROSIVE TO THE MOUTH
AND THROAT. SWALLOWING LIQUID BURNS TISSUE , AND CAN CAUSE SEVERE ABDOMINAL
PAIN, NAUSEA, VOMITING AND COLLAPSE. SEVERE OVEREXPOSURE MAY BE FATAL.
INHALATION: HARMFUL IF INHALED. VAPORS AND MISTS ARE CORROSIVE TO MUCOUS
MEMBRANES. SYMPTOMS INC LUDE IRRITATED NOSE, (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: SULFURIC ACID: IARC MONOGRAPHS ON THE
EVALUATION OF CARCINOGENIC RISK OF CHEMICALS TO MAN, VOL 54, PG 41, 1992:
GROUP 1. ANIMAL: PULMONARY IRRIT.
Signs And Symptions Of Overexposure: HLTH HAZ: THROAT AND LABORED BREATHING.
MAY HAVE MINOR INITIAL SYMPTOMS FOLLOWED IN SEVERAL HOURS BY SEVERE SHORTNESS
OF BREATH REQUIRING PROMPT MEDICAL ATTENTION. CHRONIC: LUNG DAMAGE. TARGET
ORGANS: RESPIRATORY SYSTEM, LUNGS, EYES, SKIN, TEETH, KIDNEYS.
Medical Cond Aggravated By Exposure: RESPIRATORY CONDITIONS.
First Aid: SKIN: IMMED REMOVE CONTAM CLTHG. FLUSH SKIN WITH WATER FOR AT LEAST
15 MINUTES. SEEK IMMEDIATE MED ATTN. EYES: IMMED FLUSH WITH LARGE AMTS OF
WATER, HOLDING LIDS APART TO ENSURE RINSING OF ENTIRE SURF ACE. WASHING
WITHIN SEVERAL SECONDS OF CONTACT IS ESSENTIAL TO ACHIEVE MAX EFFECTIVENESS.
GET IMMEDIATE MED ATTN. INHAL: REMOVE VICTIM TO FRESH AIR. IF NOT BREATHING,
GIVE ARTF RESP. IF BREATHING IS D IFFICULT ADMINISTER OXYGEN. SEEK MED ATTN.
INGEST: DO NOT INDUCE VOMITING. IF VICTIM IS CONSCIOUS, GIVE WATER. NEVER
GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. SEEK IMMEDIATE MED ATTN.
ADDNL FIR ST AID & TREATMENT NOTES: NO INFO AVAIL.
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Handling and Disposal
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Spill Release Procedures: PREVENT SPREAD OF SPILL. WEAR FULL PROTECTIVE
EQUIPMENT, INCLUDING A COMPLETE PROTECTIVE SUIT AND AN APPROPRIATE NIOSH
APPROVED RESPIRATOR DEPENDING UPON THE SIZE OF THE SPILL. CAREFULLY
NEUTRALIZE WI TH SODA ASH OR LIME. PLACE MATERIAL INTO CLEAN DISPOSAL
CONTAINER. FLUSH SPILL AREA WITH WATER.
Neutralizing Agent: NEUTRALIZE WITH SODA ASH OR LIME.
Waste Disposal Methods: DISPOSE I/A/W ALL LOCAL, STATE AND FEDERAL REGULATIONS.
EPA WASTE NUMBER: D002, D003 (CORROSIVE, REACTIVE WASTE).
Handling And Storage Precautions: STORE IN A COOL, DRY, CORROSIVE ACIDS STORAGE
AREA OR CABINET. KEEP CONTAINER TIGHTLY CLOSED. MIXING WITH WATER PRODUCES A
STRONGLY EXOTHERMIC REACTION THAT MAY SPRAY ACID SOLUTION IN IMMEDIATE AREA.
WHEN MIXING WITH WATER, ALWAYS ADD ACID SLOWLY TO WATER, NEVER ADD WATER TO
CONCENTRATED ACID.
Other Precautions: DANGER! DO NOT ALLOW CONTACT WITH SKIN, EYES OR CLOTHING.
USE ONLY WITH ADEQUATE PROTECTIVE EQUIPMENT. HARMFUL OR FATAL IF SWALLOWED.
=======================================================
Fire and Explosion Hazard Information
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Extinguishing Media: DRY CHEMICAL OR CO*2. DO NOT USE WATER.
Fire Fighting Procedures: USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT
(FP N). USE WATER TO COOL NEARBY CONTAINERS AND STRUCTURES.
Unusual Fire/Explosion Hazard: REACTS WITH MOST METALS TO PRODUCE FLAMMABLE
HYDROGEN GAS. VIOLENT EXOTHERMIC REACTION WITH WATER. HEAT PRODUCED MAY BE
SUFFICIENT TO IGNITE COMBUSTIBLE MATERIAL. RATING: HEALTH - 3; FLAMMABILITY
- 0; REACTIVITY - 3, NFPA RATING: HEALTH - 3; FLAMMABILITY - 0; REACTIVITY -
2.
=======================================================
Control Measures
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Respiratory Protection: RESPIRATORY PROTECTION REQUIRED IF AIRBORNE
CONCENTRATIONS EXCEED PEL OR TLV. A NIOSH APPROVED CHEMICAL CARTRIDGE
RESPIRATOR WITH AN ACID/ORGANIC CARTRIDGE IS RECOMMENDED. A NIOSH APPROVED
SUPPLIED AI R RESPIRATOR OR SCBA SHOULD BE ON HAND FOR USE IN EMERGENCY
SITUATIONS.
Ventilation: USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET TLV AND PEL
REQUIREMENTS.
Protective Gloves: CHEMICAL-RESISTANT GLOVES.
Eye Protection: ANSI APPROVED CHEMICAL WORKERS GOGGLES & FULL LENGTH FACESHIELD
(FP N).
Other Protective Equipment: EYE WASH & DELUGE SHOWER MEETING ANSI DESIGN
CRITERIA (FP N). PROTECTIVE CLOTHING APPROPRIATE FOR THE RISK OF EXPOSURE.
=======================================================
Physical/Chemical Properties
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Boiling Point: =327.C, 620.6F
Melt/Freeze Pt: =-2.C, 28.4F
Vapor Pres: <0.3 MM HG @ 20C
Vapor Density: 3.4(AIR=1)
Spec Gravity: 1.844 (WATER=1)
Solubility in Water: MISCIBLE
Appearance and Odor: CLEAR TO YELLOWISH OILY LIQUID; SHARP ODOR.
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: MOISTURE.
Materials To Avoid: INCOMPATIBLE WITH STRONG BASES AND STRONG OXIDIZERS. WATER,
ORGANICS, MOST REACTIVE MATERIALS, MOST COMMON METALS, CARBONATES, SULFIDES,
CYANIDES, CARBIDES.
Hazardous Decomposition Products: OXIDES OF SULFUR. HYDROGEN.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: WILL NOT OCCUR.
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Toxicological Information
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Toxicological Information: TOXICITY DATA: SULFURIC ACID: LC50:(INHAL,MOUSE) 320
MG/M3/2H; LC50:(INHAL,RAT) 510 MG/M3. WATER: NO INFORMATION AVAILABLE.
REPRODUCTIVE EFFECTS: NONE IDENTIFIED.
=======================================================
MSDS Transport Information
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Transport Information: REGULATED MATL DOMESTIC GROUND TRANSPORTATION
(REFERENCE: CFR TITLE 49, TRANSPORTATION) - PROPER SHIPPING NAME: SULFURIC
ACID. UN/NA ID #: UN1830. PACKING GRP: II. HAZ CLASS & LBL: 8 CORR.
SUBSIDIARY RISK & LBL: N/P. REGULATED MATL VIA AIR TRANSPORTATION
(REFERENCE: ICAO TECHNICAL INSTRUCTIONS FOR THE SAFE TRANSPORT OF DANGEROUS
GOODS BY AIR) - PROPER SHIPPING NAME: SULPHURIC ACID. UN ID #: UN1830 .
PACKING GRP: II. HAZ CLASS & LBL: 8 CORR. SUBSIDIARY RISK & LBL: N/P.
PASSENGER AIRCRAFT: PACKING INSTRUCTION - 809/Y809; MAX NET QTY PER PACKAGE -
1/0.5 L. CARGO AIRCRAFT: PACKING INSTRUCTION - 813 ; MAX NET QTY PER PACKAGE
- 30 L.
=======================================================
Regulatory Information
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Sara Title III Information: CERCLA (RQ): SULFURIC ACID: 1000 LBS; WATER: N/P.
SARA EHS (TPQ): SULFURIC ACID: 1000 LBS; WATER: N/P. SARA 313 TOXIC RELEASE
(DE MINIMUS): SULFURIC ACID: 1.0 LBS; WATER: N/P. SARA HAZARD CATEGORIES:
SULFURIC ACID: ACUTE: YES; CHRONIC: YES; FLAMMABILITY: NO; PRESSURE: NO;
REACTIVITY: YES. WATER: ACUTE: NO; CHRONIC: NO; FLAMMABILITY: NO; PRESSURE:
NO; REACTIVITY NO.
Federal Regulatory Information: TSCA INVENTORY: SULFURIC ACID: YES; WATER: N/P.
CLEAN AIR CATEGORIES: SULFURIC ACID AND WATER: SOCMI: NO; HAP: NO; VOLATILE
HAP: NO; ORGANIC HAP: NO; OZONE DEPLETING: NO.
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Other Information
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Other Information: MSDS REVISION HISTORY: 002 - CHANGED HEADER PHONE NUMBER.
=======================================================
HAZCOM Label
=======================================================
MSDS NAME: SULFURIC ACID, S978.10
Company: INTEGRA CHEMICAL COMPANY
Street: 710 THOMAS AVE SW
City: RENTON WA
Zipcode: 98055
Health Emergency Phone: 800-451-8346
Label Required IND: Y
Date Of Label Review: 12/07/1999
Status Code: A
Origination Code: F
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Severe
Contact Hazard: Severe
Fire Hazard: None
Reactivity Hazard: Slight
Hazard And Precautions: CORROSIVE. ACUTE: SKIN CONT: MAY CAUSE SEVERE BURNS.
EYE CONT: VAPS, MISTS & LIQS ARE CORR. PRLNGD CONT MAY RSLT IN PERM
INJURY. INGEST: HARMFUL IF SWALLOWED. LIQS ARE EXTREMELY CORR TO MOUTH &
THROAT . SWALLOWING LIQ BURNS TISS, & CAN CAUSE SEVERE ABDOM PAIN, NAUS,
VOMIT & COLLAPSE. SEVERE OVEREXP MAY BE FATAL. INHAL: HARMFUL. VAPS &
MISTS ARE CORR TO MUC MEMBS. SYMPS INCL IRRITATED NOSE, THROAT & LABORED
BRTHG. MAY HAVE MINOR INITIAL SYMPS FOLLOWED IN SEVERAL HRS BY SEVERE
SHORTNESS OF BRTH. CHRONIC: CANCER HAZ. SULFURIC ACID IS LISTED AS A HUMAN
LUNG CARCIN (FP N). LUNG DAMAGE.
=======================================================
Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
*** END OF RECORD *** |
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