VAN WATERS & ROGERS INC -- TOLUENE
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Material Safety Data Sheet
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NIIN: 00-840-6318
MSDS Num: CKNYQ
MSDS NAME: TOLUENE
Responsible Party
Name: VAN WATERS & ROGERS INC
Address: 6100 CARILLON POINT
City: KIRKLAND WA 98033
Info Phone: 425-889-3400
Emergency Phone Number: 425-889-3400
Resp. Party Other MSDS No.: EQ931650
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Item Description Information
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Item Manager: S9G
Item Name: TOLUENE,ACS
Specification Number: O-C-265
Unit of Issue: CN
Quantitative Expression: 00000000005GL
UI Container Qty: 1
Type of Container: CAN
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Ingredients
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Name: *** PROPRIETARY ***
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Health Hazards Data
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LD50 LC50 Mixture: ORAL (RAT) NOT PROVIDED
Effects of Exposure: EYE/SKIN: IRRITATON. INHALATION: HIGH VAPOR/AEROSOL
CONCENTRATIONS (>1000 PPM) ARE IRRITATING TO THE EYES AND THE RESPIRATORY
TRACT, MAY CAUSE HEADACHES, DIZZINESS, ANESTHESIA, DROWSINESS, UNCONSCIOUS
NESS, CENTRAL NERVOUS SYSTEM EFFECTS, BRAIN DAMAGE AND POSSIBLY DEATH.
INGESTION: SMALL AMOUNTS OF THIS PRODUCT ASPIRATED INTO THE RESPIRATORY
SYSTEM DURING INGESTION/VOMITING MAY CAUSE PULMONARY DAMA GE LEADING TO
DEATH. CHRONIC: DERMATITIS, BRAIN AND NERVOUS SYSTEM DAMAGE. CONCENTRATIONS
>1500 PPM HAS CAUSED FETAL DEVELOPMENTAL EFFECTS IN ANIMALS.
Explanation Of Carcinogenicity: NONE SPECIFIED BY MANUFACTURER.
Signs And Symptions Of Overexposure: IRRITATION, DERMATITIS, HEADACHES,
DIZZINESS, ANESTHESIA, DROWSINESS, UNCONSCIOUSNESS, CENTRAL NERVOUS SYSTEM
EFFECTS, BRAIN DAMAGE, POSSIBLY DEATH, PULMONARY INJURY, FETAL DEVELOPMENT
EFFECTS.
Medical Cond Aggravated By Exposure: SKIN CONTACT MAY AGGRAVATE AN EXISTING
DERMATITIS CONDITION.
First Aid: EYES: FLUSH WITH LARGE AMOUNTS OF WATER UNTIL IRRITATION SUBSIDES.
IF IRRITATION PERSISTS, GET MEDICAL ATTENTION. SKIN: FLUSH WITH LARGE AMOUNTS
OF WATER; USE SOAP IF AVAILABLE. REMOVE GROSSLY CONTAMI NATED CLOTHING,
INCLUDING SHOES, AND LAUNDER BEFORE REUSE. INHALATION: USING PROPER
RESPIRATORY PROTECTION, IMMEDIATELY REMOVE THE AFFECTED VICTIM FROM EXPOSURE.
ADMINISTER ARTIFICIAL RESPIRATION IF B REATHING IS STOPPED. KEEP AT REST.
CALL FOR PROMPT MEDICAL ATTENTION. INGESTION: IF SWALLOWED, DO NOT INDUCE
VOMITING. KEEP AT REST. GET PROMPT MEDICAL ATTENTION.
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Handling and Disposal
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Spill Release Procedures: LAND SPILL: ELIMINATE SOURCES OF IGNITION. PREVENT
ADDITIONAL DISCHARGE OF MATERIAL. IF POSSIBLE TO DO SO WITHOUT HAZARD.ABSORB
LIQUID IN INERT MATERIALS LIKE VERMICULITE OR SAND AND SAVE FOR DISPOSAL IN
A COVERED DRUM. IMPLEMENT CLEANUP PROCEDURES. IF IN PUBLIC AREA, KEEP PUBLIC
AWAY AND ADVISE AUTHORITIES.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: CONSULT AN EXPERT ON DISPOSAL OF RECOVERED MATERIAL AND
ENSURE CONFORMITY TO LOCAL , STATE AND FEDERAL DISPOSAL REGULATIONS.
Handling And Storage Precautions: KEEP CONTAINER CLOSED. HANDLE AND OPEN
CONTAINERS WITH CARE. STORE IN A COOL, WELL VENTILATED PLACE AWAY FROM
INCOMPATIBLE MATERIALS. DO NO HANDLE OR STORE NEAR AN OPEN FLAME, HEAT OR
OTHER SOURCES OF IGNITION. PROTECT MATERIAL FROM DIRECT SUNLIGHT.
Other Precautions: MATERIAL WILL ACCUMULATE STATIC CHARGES WHICH MAY CAUSE AN
ELECTRICAL SPARK. USE PROPER BONDING AND/OR GROUNDING PROCEDURES. DO NOT
PRESSURIZE, CUT, HEAT, OR WELD CONTAINERS. EMPTY PRODUCT CONTAINERS MAY
CONTAIN PRODUCT RESIDUE. DO NOT REUSE EMPTY CONTAINERS. WITHOUT COMMERCIAL
CLEANING OR RECONDITI ONING.
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Fire and Explosion Hazard Information
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Flash Point: =7.2C, 45.F
Autoignition Temp: =552.2C, 1026.F
Autoignition Temp Text: APPROX
Lower Limits: 1.4
Upper Limits: 7.4
Extinguishing Media: EITHER ALLOW FIRE TO BURN UNDER CONTROLLED CONDITIONS OR
EXTINGUISH WITH FOAM OR DRY CHEMICAL. TRY TO COVER LIQUID SPILLS WITH FOAM.
Fire Fighting Procedures: USE WATER SPRAY TO COOL FIRE EXPOSED SURFACES AND TO
PROTECT PERSONNEL. SHUT OFF "FUEL" TO FIRE. IF A LEAK OR SPILL HAS NOT
IGNITED USE WATER SPRAY TO DISPERSE THE VAPORS. RESPIRATORY AND EYE PROTECTI
ON REQUIRED FOR FIRE FIGHTING PERSONNEL. AVOID SPRAYING WATER DIRECTLY INTO
STORAGE CONTAINERS DUE TO DANGER OF BOILOVER
Unusual Fire/Explosion Hazard: FLAMMABLE LIQUID, CAN RELEASE VAPORS THAT FORM
FLAMMABLE MIXTURES AT TEMPERATURES AT OR ABOVE THE FLASHPOINT. TOXIC GASES
WILL FORM UPON COMBUSTION. STATIC DISCHARGE, MATERIAL CAN ACCUMULATE STATIC
CH ARGES WHICH CAN CAUSE AN INCENDIARY ELECTRICAL DISCHARGE.
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Control Measures
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Respiratory Protection: WHERE CONCENTRATIONS IN AIR MAY EXCEED THE LIMITS AND
ENGINEERING, WORK PRACTICE, OR OTHER MEANS OF EXPOSURE REDUCTION ARE NOT
ADEQUATE, NIOSH/MSHA APPROVED RESPIRATORS MAY BE NECESSARY TO PREVENT OVE
REXPOSURE BY INHALATION.
Ventilation: THE USE OF LOCAL EXHAUST VENTILATION IS RECOMMENDED TO CONTROL
PROCES EMISSIONS NEAR THE SOURCE. PROVIDE MECHAICAL VENTILATION OF CONFINED
SPACES.
Protective Gloves: CHEMICAL RESISTANT GLOVES.
Eye Protection: SAFETY GLASSES WITH SIDE SHEILDS
Other Protective Equipment: LONG SLEEVES. LABORATORY SAMPLES SHOULD BE HANDLED
IN A LAB HOOD.
Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health: USE EXPLOSION PROOF VENTILATION EQUIPMENT. THIS
LIQUID IS VOLATILE AND GIVES OFF INVISIBLE VAPORS. EITHER THE LIQUID OR VAPOR
MAY SETTLE IN LOW AREAS OR TRAVEL SOME DISTANCE ALONG THE GROUND OR SURFAC E
TO IGNITION SOURCES WHERE THEY MAY IGNITE OR EXPLODE.
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Physical/Chemical Properties
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HCC: F2
Boiling Point: =110.C, 230.F
B.P. Text: 230-232F
Melt/Freeze Pt: <-60.C, -76.F
Vapor Pres: 22 @ 68F (APPROX)
Spec Gravity: 3.20 CALCULATED
Viscosity: 0.7 @ 77F (APPROX)
Evaporation Rate & Reference: 2.4 (APPROX)
Solubility in Water: 0.05 @ 77F CALCULATED
Appearance and Odor: NONE SPECIFIED BY MANUFACTURER. ( LIQUID WITH AROMATIC
HYDROCARBON ODOR).
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: NONE
Materials To Avoid: OXIDIZING AGENTS.
Hazardous Decomposition Products: OXIDES OF CARBON.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: WILL NOT OCCUR.
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Toxicological Information
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Ecological Information
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MSDS Transport Information
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Transport Information: DOT PSN: TOLUENE, 3, UN1294, II.
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Regulatory Information
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Sara Title III Information: RQ = 1,000 LBS (454 KG).SEC 311/312 HAZARDOUS
CATEGORIES: IMMEDIATE AND DELAYED HEALTH HAZARDS. FIRE HAZARD. LISTED ON THE
COMMUNITY RIGHT TO KNOW ACT.
Federal Regulatory Information: THIS PRODUCT IS LISTED ON THE TSCA INVENTORY.
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Other Information
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Transportation Information
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Trans ID NO: 153612
MSDS NAME: TOLUENE
MSDS Prepared Date: 05/08/2000
Review Date: 06/17/2000
Net Unit Weight: 36.2 LB/5GL
Multiple KIT Number: 0
Unit Of Issue: CN
Container QTY: 1
Type Of Container: CAN
Additional Data: CARGO AIRCRAFT ONLY LABEL REQUIRED. ( QUANTITY = 19 LITERS)
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Detail DOT Information
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DOT PSN Code: OJY
DOT Proper Shipping Name: TOLUENE
Hazard Class: 3
UN ID Num: UN1294
DOT Packaging Group: II
Label: FLAMMABLE LIQUID
Special Provision: T1
Packaging Exception: 150
Non Bulk Pack: 202
Bulk Pack: 242
Max Qty Pass: 5 L
Max Qty Cargo: 60 L
Vessel Stow Req: B
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Detail IMO Information
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IMO PSN Code: OSR
IMO Proper Shipping Name: TOLUENE
IMDG Page Number: 3285
UN Number: 1294
UN Hazard Class: 3.2
IMO Packaging Group: II
Subsidiary Risk Label: -
EMS Number: 3-07
MED First Aid Guide NUM: 310
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Detail IATA Information
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IATA PSN Code: YEL
IATA UN ID Num: 1294
IATA Proper Shipping Name: TOLUENE
IATA UN Class: 3
IATA Label: FLAMMABLE LIQUID
UN Packing Group: II
Packing Note Passenger: 305
Max Quant Pass: 5L
Max Quant Cargo: 60L
Packaging Note Cargo: 307
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Detail AFI Information
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AFI PSN Code: YEL
AFI Proper Shipping Name: TOLUENE
AFI Hazard Class: 3
AFI UN ID NUM: UN1294
AFI Packing Group: II
Special Provisions: P5
Back Pack Reference: A7.3
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HAZCOM Label
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MSDS NAME: TOLUENE
Assigned IND: Y
Company: VAN WATERS & ROGERS INC
Street: 6100 CARILLON POINT
City: KIRKLAND WA
Zipcode: 98033
Health Emergency Phone: 425-889-3400
Label Required IND: Y
Date Of Label Review: 06/17/2000
Status Code: A
Year Procured: 2000
Origination Code: F
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Slight
Fire Hazard: Moderate
Reactivity Hazard: None
Hazard And Precautions: EYE/SKIN: IRRITATON. INHALATION:HIGH VAPOR
CONCENTRATIONS (>1000 PPM) ARE IRRITATING TO THE EYES AND THE RESPIRATORY
TRACT, MAY CAUSE HEADACHES, DIZZINESS, DROWSINESS, UNCONSCIOUSNESS, CNS
EFFECTS & P OSSIBLY DEATH. INGESTION: ASPIRATION HAZARD. CHRONIC:
DERMATITIS, BRAIN AND NERVOUS SYSTEM DAMAGE. FIRST AID:EYES: FLUSH WITH
WATER. GET MEDICAL HELP. SKIN: FLUSH & WASH W/SOAP & WATER. REMOVE
CONTAMI NATED CLOTHING/ SHOES, AND LAUNDER BEFORE REUSE. INHALATION:REMOVE
THE VICTIM FROM EXPOSURE. ADMINISTER ARTIFICIAL RESPIRATION IF BREATHING IS
STOPPED.CALL FOR MEDICAL HELP. INGESTION: IF SWALLOWED, D O NOT INDUCE
VOMITING. GET PROMPT MEDICAL HELP.
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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