LILLY INDUSTRIES, INC. -- WB LACQUER FINISH
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Material Safety Data Sheet
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MSDS Num: CKTQQ
MSDS NAME: WB LACQUER FINISH
Responsible Party
Name: LILLY INDUSTRIES, INC.
Address: 901 WEST UNION STREET
City: MONTEBELLO CA 90640
Info Phone: (213) 722-7511
Emergency Phone Number: 213-722-7511/NITE:800-424-9300
Resp. Party Other MSDS No.: 607-0005-00
Preparer's Name: ROBERT VANDERHOEK
Chemtrec IND/Phone: (800)424-9300
Review Ind: Y
Published: Y
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Contractor Summary
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Name: LILLY INDUSTRIES, INC.
Address: 901 WEST UNION STREET
City: MONTEBELLO CA 90640
Phone: (213) 722-7511
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Ingredients
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Cas: 111-76-2
RTECS #: KJ8575000
Name: 2-BUTOXYETHANOL (GLYCOL ETHER). (% BY WT: 3.688, VAPOR PRESSURE: .60 MMHG
@ 20C, SKIN NOTATION: YES)
Percent by Wt: 3.69
OSHA PEL: 50.00 PPM
ACGIH TLV: 25.00 PPM
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Cas: 34590-94-8
RTECS #: JM1575000
Name: DIPROPYLENE GLYCOL MONOMETHYL ETHER. (% BY WT: 3.759, VAPOR PRESSURE: .40
MMHG @ 20C)
Percent by Wt: 3.76
OSHA PEL: 100.00 PPM
ACGIH TLV: 100.00 PPM
ACGIH STEL: 150.00 PPM
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Cas: 5131-66-8
RTECS #: UA7700000
Name: PROPYLENE GLYCOL N-BUTYL ETHER. (% BY WT: 3.483, VAPOR PRESSURE: .60
MMHG @ 20C, SKIN NOTATION: YES)
Percent by Wt: 3.48
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Health Hazards Data
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Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: ANIMAL STUDIES CLEARLY DEMONSTRATED DOSE-RELATED ADVERSE
EFFECTS ON THE CNS, HEMATOPOEITIC TISSUES, BLOOD, KIDNEYS AND LIVER
ASSOCIATED WITH THE ADMINISTRATION OF 2-BUTOXYETHANOL (FP N). REPORTS HAVE
ASSOCIATED REPEATED AND PROLONGED OCCUPATIONAL OVEREXPOSURE TO SOLVENTS WITH
PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE. INTENIONAL MISUSE BY DELIBERATELY
CONCENTRATING AND INHALING THE CONTENTS MAY BE HARMFUL OR FATAL. DO NOT
BREATHE VAPORS OR SPRAY MIST. WEAR AN APPROPRIATE, PROPERLY FITTED RESPIRATOR
(NIOSH APPROVED) DURING AND AFTER APPLICATION UNLESS AIR MONITORING
DEMONSTRATES VAPOR/MIST LEVE LS (SIGNS AND SYMPTOMS OF OVEREXPOSURE)
Signs And Symptions Of Overexposure: HEALTH HAZARDS (CONT): ARE BELOW
APPLICABLE LIMITS. FOLLOW RESPIRATOR MANUFACTURER'S DIRECTIONS FOR USE.
PRODUCT CONTAINS ORGANIC SOLVENTS WHICH MAY CAUSE EYE, SKIN AND RESPIRATORY
TRACT IRRITATION. SYMPTOMS OF EXPOSURE ARE: TEARING EYES, REDNESS,
DRYING/CRACKING OF SKIN, DIZZINESS, NAUSEA & FATIGUE FROM INHALATION, AND
VOMITING FROM INGESTION. BASED ON PRESENCE OF 2-BUTOXYETHANOL, INGESTION OF
THIS PRODUCT WILL CAUSE IRRITATION OF GASTROINTESTINAL TRACT AND MAY CAUSE
EFFECTS RESEMBLING THOSE FROM INHALATION OF VAPOR. INGESTION MAY CAUSE
POSSIBLE KIDNEY AND LIVER DAMAGE.
First Aid: EYES CONTACT: FLUSH WITH LUKE WARM WATER FOR 15 MINUTES. CONTACT
PHYSICIAN IMMEDIATELY. SKIN CONTACT: FLUSH WASH WITH COPIOUS AMOUNTS OF LUKE
WARM WATER. REMOVE CONTAMINATED CLOTHING PROMPTLY. CONTACT PHYSICIAN
IMMEDIATELY. INHALATION: REMOVE EXPOSED INDIVIDUAL TO FRESH AIR. RESTORE
BREATHING IF REQUIRED. CONTACT A PHYSICIAN IMMEDIATELY. INGESTION: RINSE OUT
MOUTH IMMEDIATELY. GIVE EXPOSED INDIVID UAL 6 TO 8 OUNCES OF LIQUID (NEVER
GIVE ANYTHING BY MOUTH TO AN UNCONCIOUS PERSON). DO NOT INDUCE VOMITING
UNLESS ADVISED BY A PHYSICIAN. CONTACT A PHYSICIAN IMMEDIATELY.
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Handling and Disposal
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Spill Release Procedures: STAY UPWIND AND AWAY FROM SPILL UNLESS WEARING
APPROPRIATE PROTECTIVE EQUIPMENT. STOP AND/OR CONTAIN DISCHARGE IF IT MAY BE
DONE SAFELY. KEEP ALL SOURCES OF IGNITION AWAY. VENTILATE AREA OF SPILL. USE
NON-SPARKING TOOLS FOR CLEANUP. COVER WITH INERT MATERIAL TO REDUCE FUMES.
KEEP OUT OF DRAINS, SEWERS, OR WATERWAYS. CONTACT FIRE AUTHORITIES. NOTIFY
LOCAL HEALTH AND POLLUTION (NEUTRALIZING AGENT)
Neutralizing Agent: N/P. SPILL RELEASE PROCEDURES (CONT): POLLUTION CONTROL
AGENCIES. CALL SPILL RESPONSE TEAMS IF LARGE SPILL.
Waste Disposal Methods: DO NOT FLUSH TO SEWER, WATERSHED OR WATERWAY. DISPOSE
OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS. DO NOT INCINERATE
CLOSED CONTAINERS.
Handling And Storage Precautions: KEEP PRODUCT CONTAINERS COOL, DRY AND AWAY
FROM SOURCES OF IGNITION. USE AND STORE THIS PRODUCT WITH ADEQUATE
VENTILATION. DO NOT SMOKE IN STORAGE AREAS. PERSONNEL SHOULD AVOID INHALATION
OF VAPORS. P ERSONAL CONTACT WITH THE PRODUCT SHOULD BE AVOIDED. SHOULD
CONTACT BE MADE, (OTHER PRECAUTIONS)
Other Precautions: N/P. HANDLING AND STORAGE (CONT): REMOVE SATURATED CLOTHING
AND FLUSH AFFECTED SKIN AREAS WITH WATER. CONTAINERS OF THIS MATERIAL MAY BE
HAZARDOUS WHEN EMPTIED. SINCE EMPTIED CONTAINERS RETAIN PRO DUCT RESIDUES
(VAPOR, LIQUID AND/OR SOLID), ALL HAZARD PRECAUTIONS GIVEN HERE MUST BE
OBSERVED.
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Fire and Explosion Hazard Information
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Flash Point Method: TCC
Flash Point: =65.6C, 150.F
Lower Limits: 1.1
Upper Limits: 14.4
Extinguishing Media: USE CO2, DRY CHEMICAL, OR FOAM EXTINGUISHER. NAT'L FIRE
PROT ASSOC CLASS B EXTINGUISHER IS DESIGNED TO EXTING FIRES ORIGINATING FROM
BURNING LIQUIDS. FLAMMABILITY CLASSIFICATION: 3A.
Fire Fighting Procedures: WATER SPRAY MAY BE INEFFECTIVE. WATER MAY BE USED TO
COOL CLOSED CONTAINERS TO PREVENT PRESSURE BUILDUP AND POSSIBLE AUTOIGNITION
OR EXPLOSION WHEN EXPOSED TO EXTREME HEAT. IF WATER IS USED, FOG NOZZL ES ARE
PREFERABLE. USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT (FP N).
HEAT PROTECTION PROCEDURES: (STATE REG)
Unusual Fire/Explosion Hazard: KEEP CONTAINERS TIGHTLY CLOSED. ISOLATE FROM
HEAT, ELECTRICAL EQUIPMENT, SPARKS AND OPEN FLAME. CLOSED CONTAINER MAY
EXPLODE WHEN EXPOSED TO EXTREME HEAT. DO NOT APPLY TO HOT SURFACES. NEVER
USE WELD ING OR CUTTING TORCH ON OR NEAR CONTAINER (EVEN EMPTY) BECAUSE
PRODUCT (OR RESIDUE) MAY IGNITE EXPLOSIVELY.
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Control Measures
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Respiratory Protection: IN OUTDOOR OR OPEN AREAS USE (NIOSH APPROVED)
MECHANICAL FILTER RESPIRATOR TO REMOVE SOLID AIRBORNE PARTICLES OF OVERSPRAY
DURING SPRAY APPLICATION. IN RESTRICTED VENTILATION AREAS, USE (NIOSH APPROV
ED) CHEMICAL-MECHANICAL FILTERS DESIGNED TO REMOVE A COMBINATION OF
PARTICULATE AND GAS AND VAPOR. IN CONFINED AREAS (SUPPLEMENTAL SAFETY/HEALTH)
Ventilation: USE VENTILATION AS REQUIRED TO CONTROL VAPOR CONCENTRATIONS. AVOID
PROLONGED OR REPEATED BREATHING OF VAPORS. IF EXPOSURE EXCEEDS TLV,
(ECOLOGICAL)
Protective Gloves: WEAR RESISTANT GLOVES SUCH AS NATURAL RUBBER, NEOPRENE, BUNA
N, OR NITRILE.
Eye Protection: WEAR GOGGLES (ANSI APPROVED-FPN) IF THERE IS A LIKELIHOOD OF
CONTACT WITH EYES.
Other Protective Equipment: PROTECTIVE GLOVES REQUIRED FOR PROLONGED OR
REPEATED CONTACT. AN APRON SHOULD BE WORN TO PERVENT SKIN CONTACT. EYEWASH
STATIONS AND SAFETY SHOWERS SHOULD BE READILY AVAILABLE IN HANDLING AREAS.
Work Hygienic Practices: AVOID CONTACT WITH EYES. WASH HANDS THOROUGHLY BEFORE
EATING AND USING WASHROOM. REMOVE CONTAMINATED CLOTHING IMMEDIATELY AND DO
NOT WEAR AGAIN UNTIL IT HAS BEEN PROPERLY LAUNDERED.
Supplemental Safety and Health: RESP PROTECTION (CONT): USE (NIOSH APPROVED)
AIR LINE TYPE RESPIRATORS OR HOODS. RESPIRATORY PROTECTION MAY ALSO BE
NECESSARY IN ANY LATER MANUFACTURING OPERATIONS IN WHICH THE PRODUCT MAY
BECOME AIRB ORNE IN THE FORM OF VAPOR OR DUST.
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Physical/Chemical Properties
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Boiling Point: =168.9C, 336.F
B.P. Text: HIGH-379.0 F; LOW 336.0 F
Vapor Pres: SEE INGREDIENTS SECTION
Vapor Density: > AIR
Evaporation Rate & Reference: SLOWER THAN BUTYL ACETATE
Appearance and Odor: N/A (NONE SPECIFIED BY MANUFACTURER, FP N)
Percent Volatiles by Volume: 71.96 BY WT
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Reactivity Data
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Stability Indicator: YES PRESENCE OF (OTHER INFO)
Stability Condition To Avoid: AVOID EXPOSURE TO SPARKS, OPEN FLAME, HOT
SURFACES, AND ALL SOURCES OF HEAT AND IGNITION.
Materials To Avoid: THIS PRODUCT IS INCOMPATIBLE WITH STRONG ACIDS. BASED ON
THE PRESENCE OF DIPROPYLENE GLYCOL MONOMETHYL ETHER, THIS PRODUCT IS
INCOMPATIBLE WITH STRONG OXIDIZING AGENTS; CONTACT WITH MAY CAUSE FIRE OR
EXPLOSION. BASED ON TH
Hazardous Decomposition Products: MAY PRODUCE HAZARDOUS FUMES WHEN HEATED TO
DECOMPOSITION AS IN WELDING. FUMES MAY CONTAIN CARBON MONOXIDE, CARBON
DIOXIDE, OXIDES OF NITROGEN.
Hazardous Polymerization Indicator: NO
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Toxicological Information
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Ecological Information
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Ecological: VENTILATION (CONT): USE A NIOSH-APPROVED RESPIRATOR TO PREVENT
OVEREXPOSURE. PROVIDE GENERAL DILUTION OR LOCAL EXHAUST VENTILATION IN
VOLUME AND PATTERN TO KEEP TLV OF MOST HAZARDOUS INGREDIENT BELOW ACCEPTABLE
LEVEL, LEL BELOW STATED LIMIT, AND TO REMOVE DECOMPOSITION PRODUCTS DURING
WELDINGOR FLAME CUTTING ON SURFACES COATED WITH THIS PRODUCT.
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MSDS Transport Information
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Regulatory Information
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Federal Regulatory Information: PRODUCT CONTAINS FOLLOWING TOXIC CHEMICALS
SUBJECT TO REPORTING REQUIREMENTS OF SECTION 313 OF THE EMERGENCY PLANNING
AND COMMUNITY RIGHT-TO-KNOW ACT OF 1986 AND OF 40 CFR 372. THIS INFORMATION
MUST B E INCLUDED IN ALL MSDSS THAT ARE COPIED AND DISTRIBUTED FOR THIS
MATERIAL. CHEMICAL: 2-BUTOXYETHANOL (GLYCOL ETHER), 111-76-2 (CAS#),
WEIGHT=3.688%. ( * DENOTES PERCENT PARENT METAL CONTAINED IN THE PRECEDING
CHEMICAL COMPOUND : (NONE SHOWN, FP N).
State Regulatory Information: N/P. FIRE FIGHTING PROCEDURES (CONT): HEAT
PROTECTION PROCEDURES: CONTAINERS EXPOSED TO INTENSE HEAT FROM FIRES SHOULD
BE COOLED WITH WATER TO PREVENT VAPOR PRESSURE BUILDUP WHICH COULD RESULT IN
CO NTAINER RUPTURE.
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Other Information
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Other Information: INFORMATION: HEALTH - 2. FLAMMABILITY - 2. REACTIVITY - 0.
PERSONAL PROTECTIVE EQUIPMENT: - X. HAZARD INDEX: 4= SEVERE, 3= SERIOUS, 2=
MODERATE, 1= SLIGHT, 0= LEAST, *= CHRONIC HEALTH HAZARD, X= ASK YOUR
SUPERVISOR FOR SPECIFIC HANDLING DIRECTIONS. PHYSICAL AND CHEMICAL
PROPERTIES (CONT): WEIGHT PER GALLON: 8.39. MATERIALS TO AVOID (CONT):
2-BUTOXYETHANOL (GLYCOL ETHER) THIS PRODUCT IS INC OMPATIBLE WITH STRONG
OXIDIZING AGENTS. FIRE (CONT): LOWER FLAMMABILITY LIMIT: N/A.
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HAZCOM Label
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MSDS NAME: WB LACQUER FINISH
Assigned IND: Y
Company: LILLY INDUSTRIES, INC.
Street: 901 WEST UNION STREET
City: MONTEBELLO CA
Zipcode: 90640
Health Emergency Phone: 213-722-7511/NITE:800-424-9300
Label Required IND: Y
Date Of Label Review: 10/03/2000
Status Code: A
Origination Code: F
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Moderate
Fire Hazard: Moderate
Reactivity Hazard: Slight
Hazard And Precautions: ACUTE: MAY CAUSE EYE, SKIN AND RESPIRATORY TRACT
IRRITATION. SYMPTOMS OF EXPOSURE ARE: TEARING EYES, REDNESS, SKIN
DRYING/CRACKING, DIZZINESS, NAUSEA AND FATIGUE FROM INHALATION, AND VOMITING
FROM IN GESTION. INGEST WILL CAUSE GI TRACT IRRITATION AND MAY CAUSE EFFECTS
SIMILAR TO INHALATION. CHRONIC: INGESTION MAY CAUSE KIDNEY OR LIVER DAMAGE.
REPEATED/PROLONGED OCCUPATIONAL OVEREXPOSURE MAY RESUL T IN PERMANENT BRAIN
AND NERVOUS SYSTEM DAMAGE. 2-BUTOXYETHANOL MAY CAUSE ADVERSE EFFECTS TO THE
CNS, KIDNEYS, LIVER, BOOD AND BLOOD-FORMING TISSUES (FP N).
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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