DOW AGROSCIENCES LLC -- 46482,DURSBAN PRO INSECTICIDE
=======================================================
Material Safety Data Sheet
=======================================================
NIIN: 01-412-4361
MSDS Num: CKTFR
MSDS NAME: 46482,DURSBAN PRO INSECTICIDE
Responsible Party
Name: DOW AGROSCIENCES LLC
Address: 9330 ZIONSVILLE ROAD
City: INDIANAPOLIS IN 46268-1189
Info Phone: 800-992-5994
Emergency Phone Number: 800-992-5994
Resp. Party Other MSDS No.: 004949
=======================================================
Item Description Information
=======================================================
Item Manager: S9G
Item Name: INSECTICIDE,DURSBAN
Specification Number: NONE
Type/Grade/Class: NONE
Unit of Issue: PT
UI Container Qty: 0
Type of Container: BOTTLE,SQUEEZ
=======================================================
Ingredients
=======================================================
Name: *** PROPRIETARY ***
-----------------------------
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: LD50 (ORAL, MALE RAT) IS 620 MG/KG.
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: EYE: MAY CAUSE SLIGHT EYE IRRITATION. CORNEAL INJURY IS
UNLIKELY. SKIN: PROLONGED EXPSURE NOT LIKELY TO CAUSE SIGNIFICANT SKIN
IRRITATION. A SINGLE PROLONGED EXPOSURE IS NOT LIKELY TO RESULT IN THE MA
TERIAL BEING ABSORBED THROUGH SKIN IN HARMFUL AMOUNTS. INGESTION: SINGLE DOSE
ORAL TOXICITY IS CONSIDERED TO BE LOW. SMALL AMOUNTS SWALLOWED ARE NOT LIKELY
TO CAUSE INJURY; SWALLOWING LARGER AMOUNTS M AY CAUSE INJURY. IF ASPIRATED
MAY CAUSE LUNG DAMAGE OR EVEN DEATH DUE TO CHEMICAL PNEUMONITIS. INHALATION:
AT ROOM TEMPERATURE, VAPORS ARE MINIMAL DUE TO LOW VAPOR PRESSURE. IF HEATED
OR MIST IS PRODU CED, MAY BE HAZARDOUS.
Explanation Of Carcinogenicity: CHLORPYRIFOS AND OTHER TESTED COMPONENTS DID
NOT CAUSE CANCER IN LONG-TERM ANIMAL STUDIES.
Signs And Symptions Of Overexposure: HEADACHE, DIZZINESS, INCOORDINATION,
MUSCLE TWITCHING, TREMORS, NAUSEA, ABDOMINAL CRAMPS, DIARRHEA, SWEATING,
PINPOINT PUPILS, BLURRED VISION, SALIVATION, TEARING, TIGHTNESS IN CHEST,
EXCESSIVE URINAT ION, CONVULSION.
Medical Cond Aggravated By Exposure: NOT PROVIDED
First Aid: EYES: IMMEDIATELY FLUSH WITH WATER FOR 15 MINUTES. CONSULT MEDICAL
PERSONNEL. SKIN: IMMEDIATELY WASH WITH PLENTY OF SOAP AND WATER. CONSULT
MEDICAL PERSONNEL. INGESTION: CALL A PHYSICIAN OR POISON CON TROL CENTER
IMMEDIATELY. DO NOT INDUCE VOMITING. DO NOT PUT ANYTHING INTO THE MOUTH OF AN
UNCONSCIOUS PERSON. INHALATION: REMOVE TO FRESH AIR AND IF NOT BREATHING GIVE
ARTIFICIAL RESPIRATION, PREFERAB LY BY MOUTH TO MOUTH. CONSULT MEDICAL
PERSONNEL.
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: WEAR LONG PANTS, LONG-SLEEVED SHIRT, AND IMPERVIOUS
RUBBER GLOVES WHEN HANDLING CONCENTRATE AND CLEANING UP SPILLS. ABSORB SPILLS
WITH AN INERT ABSORBENT MATERIAL SUCH AS HAZORB, ZORBALL, SAND, OR DIR T.
SCOOP CONTAMINATED ABSORBENT MATERIAL INTO CONTAINER. THOROUGHLY WASH BODY
AREAS THAT COME INTO CONTACT WITH THIS PRODUCT. REPORT LARGE SPILLS TO
CHEMTREC 800-424-9300 AND CONSULT DOW AGROSCIENCES.
Neutralizing Agent: NOT RELEVANT
Waste Disposal Methods: DO NOT CONTAMINATE FOOD, FEED OR WATER BY STORAGE OR
DISPOSAL. EXCESS PESTICIDE RESULTING FROM THE USE OF THIS PRODUCT MAY BE
DISPOSED OF ON SITE ACCORDING TO LABEL DIRECTIONS OR AT AN APPROVED WASTE
DISPOSAL FACITITY. FOLLOW ALL LOCAL, STATE AND FEDERAL REQUIREMENTS FOR
DISPOSAL.
Handling And Storage Precautions: SEE LABEL. STORE AWAY FROM INCOMPATIBLES,
FOOD AND FEED. PREVENT CROSS-CONTAMINATION WITH OTHER PESTICIDES OR
FERTILIZERS. KEEP OUT OF REACH OF CHILDREN. DO NOT SWALLOW. HANDLE
CONCENTRATE IN VENTILAT ED AREA.
Other Precautions: AVOID CONTACT WITH EYES, SKIN AND CLOTHING. AVOID BREATHING
VAPORS OR MISTS. WASH THOROUGHLY AFTER HANDLING MATERIAL AND BEFORE EATING,
CHEWING GUM, USING TOBACCO, USING THE TOILET OR SMOKING. KEEP AW AY FROM
FOOD, FEEDSTUFFS, AND WATER SUPPLIES.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Flash Point Method: SCC
Flash Point: =115.C, 239.F
Lower Limits: N/D
Upper Limits: N/D
Extinguishing Media: FOAM, CARBON DIOXIDE (CO2), DRY CHEMICAL. FOAM IS
PREFERRED AS UNCONTROLLED WATER CAN SPREAD POSSIBLE CONTAMINATION.
Fire Fighting Procedures: FOAM IS PREFERRED AS UNCONTROLLED WATER CAN SPREAD
POSSIBLE CONTAMINATION.FIRE FIGHTERS SHOULD USE POSITIVE-PRESURE., SELF
CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE EQUIPMENT.
Unusual Fire/Explosion Hazard: TOXIC, IRRITATING GASES MAY BE FORMED UNDER FIRE
CONDITIONS.
=======================================================
Control Measures
=======================================================
Respiratory Protection: ATMOSPHERIC LEVELS SHOULD BE MAINTAINED BELOW THE
EXPOSURE GUIDELINES. WHEN RESPIRATORY PROTECTION IS REQUIRED, USE AN
APPROVED AIR-PURIFYING OR POSITIVE-PRESSURE SUPPLIED-AIR RESPIRATOR DEPENDING
ON THE POTENTIAL AIRBORNE CONCENTRATION.
Ventilation: PROVIDE GENERAL AND/OR LOCAL EXHAUST VENTILATION TO CONTROL
AIRBORNE LEVELS BELOW THE EXPOSURE GUIDELINES.
Protective Gloves: NO PRECAUTIONS OTHER THAN CLEAN BODY-COVERING SHOULD BE
NEEDED.
Eye Protection: USE SAFETY GLASSES.
Other Protective Equipment: NOT PROVIDED
Work Hygienic Practices: NOT PROVIDED
Supplemental Safety and Health: NONE
=======================================================
Physical/Chemical Properties
=======================================================
HCC: T4
NRC/State LIC No: NOT RELEVANT
B.P. Text: NOT DETERMINED
M.P/F.P Text: NOT DETERMINED
Decomp Temp: =130.C, 266.F
Vapor Pres: NOT DETERMINED
Vapor Density: N/D
Spec Gravity: 1.0271G/ML
PH: 4.52 (10.5%)
Viscosity: NOT PROVIDED
Evaporation Rate & Reference: NOT PROVIDED
Solubility in Water: EMULSIFIABLE
Appearance and Odor: LIGHT YELLOW, CLOUDY LIQUID; PETROLEUM ODOR
Corrosion Rate: NOT PROVIDED
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: AVOID HEATING >122F (50C). CHLORPYRIFOS
DECOMPOSES EXOTHERMICALLY AT 266F WHICH CAN LEAD TO HIGHER TEMPERATURES AND
VIOLENT DECOMPOSITION IF GENERATED HEAT IS NOT REMOVED..
Materials To Avoid: OXIDIZING MATERIALS, STRONG ACIDS. IF IN CONTACT WITH
ORGANIC MATERIALS AND FINELY DIVIDED INORGANIC MATERIALS SUCH AS CLAY, ROCK
WOOL INSULATION, RAGS, PAPER, ETC., THIS PRODUCT MAY UNDERGO SPONTANEOUS
COMBUSTION.
Hazardous Decomposition Products: HYDROGEN CHLORIDE, NITROGEN OXIDES AND OTHER
TOXIC, IRRITATING VAPORS MAY BE FORMED IF PRODUCT IS INVOLVED IN FIRE.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NONE
=======================================================
Toxicological Information
=======================================================
Toxicological Information: TERATOLOGY (BIRTH DEFECTS): CHLOPYRIFOS DID NOT
CAUSE BIRTH DEFECTS IN LABORATORY ANIMALS. REPRODUCTIVE EFFECTS:CHLORPYRIFOS
DID NOT INTERFERE WITH FERTILITY IN REPRODUCTIVE STUDIES IN LABORATORY ANIM
ALS. SOME EVIDENCE OF TOXICITY TO THE OFFSPRING OCCURRED BUT ONLY AT DOSES
HIGH ENOUGH TO PRODUCE SIGNIFIGANT TOXICITY IN THE PARENT ANIMALS.
MUTAGENICITY: BASED ON A MAJORITY OF NEGATIVE DATA AND SOM E EQUIVOCAL OR
MARGINALLY POSITIVE RESULTS, CHLORPYRIFOS IS CONSIDERED TO HAVE MINIMAL
MUTAGENIC POTENTIAL.
=======================================================
Ecological Information
=======================================================
Ecological: BIOCONCENTRATION POTENTIAL IS MODERATE. LOG OCTANOL/WATER PARTITION
COEFFICIENT (LOG POW) IS 4.96. BIOCONCENTRATION FACTOR (BCF) IN FISH IS
100-1673. BIOCONCENTRATION FACTOR (BCF) IN INVERTEBRATES IS 180. THE
PHOTOLYSIS HALF-LIFE IN WATER IS THREE TO FOUR WEEKS. THE ATMOSPHERIC HALF
LIFE IS 1.4 HOURS. DEGRADATION IS EXPECTED IN THE SOIL ENVIRONMENT WITHIN
DAYS TO WEEKS. ECOTOXICOLOY: MATERIAL IS V ERY HIGHLY TOXIC TO AQUATIC
ORGANISMS ON AN ACUTE BASIS (LC50 <0.1 MG/L IN MOST SENSITIVE SPECIES).
=======================================================
MSDS Transport Information
=======================================================
Transport Information: FOR DOT REGULATORY INFORMATION, IF REQUIRED, CONSULT
TRANSPORTATION REGULATIONS, PRODUCT SHIPPING PAPERS OR CONTACT YOUR DOW
AGROSCIENCES REPRESENTATIVE,
=======================================================
Regulatory Information
=======================================================
Sara Title III Information: SARA 313 INFORMATION: TO THE BEST OF OUR KNOWLEDGE,
THE PRODUCT CONTAINS NO CHEMICAL SUBJECT TO TO SARA TITLE III SECTION 313
SUPPLIER NOTIFICATION REQUIREMENTS. SARA SECTION 311/312 HAZARD CATEGORY:
IMMEDIATE HEALTH HAZARD, DELAYED HEALTH HAZARD.
Federal Regulatory Information: TOXIC SUBSTANCES CONTROL ACT (TSCA): ALL
INGREDIENTS ARE ON THE TSCA INVENTORY OR ARE NOT REQUIRED TO BE LISTED ON THE
TSCA INVENTORY. OSHA HAZARD COMMUNICATION STANDARD: THIS PRODUCT IS A
"HAZARDOUS CHEMICAL" AS DEFINED BY THE OSHA HAZARD COMMUNICATION STANDARD,
29 CFR 1910.1200. COMPREHENSIVE ENVIRONMENTAL RESPONSE COMPENSATION AND
LIABILITY ACT (CERCLA OR SUPERFUND): THIS PRODUCT CONTAINS THE F OLLOWING
SUBSTANCE(S) LISTED AS "HAZARDOUS SUBSTANCES" UNDER CERCLA WHICH MAY REQUIRE
REPORTING OF R ELEASES: CHLORPYRIFOS, CAS# 2921-88-2, RQ=1 LB, 23.5%. EPA
REGISTRATION NUMBER 62719-166.
State Regulatory Information: THE FOLLOWING PRODUCT COMPONENTS ARE CITED ON
CERTAIN STATE LISTS AS MENTIONED. NON-LISTED COMPONENTS MAY BE SHOWN IN THE
COMPOSITION SECTION OF THE MSDS: 1,2-PROPANEDIOL, CAS# 57-55-6, PENNSYLVANIA
H AZARDOUS SUBSTANCE (PRESENT AT GREATER THAN OR EQUAL TO 1%); CHLORPYRIFOS,
CAS# 2921-88-2, PENNSYLVANIA HAZARDOUS SUBSTANCE (PRESENT AT GREATER THAN OR
EQUAL TO 0.1%); PENNSYLVANIA HAZARDOUS SUBSTANCE (PRESENT AT GREATER THAN OR
EQUAL TO 1.0%); NEW JERSEY WORKPLACE HAZARDOUS SUBSTANCE (PRESENT AT GR EATER
THAN OR EQUAL TO 1.0%).
=======================================================
Other Information
=======================================================
Other Information: EXCESSIVE EXPOSURE MAY PRODUCE ORGANOPHOSPHATE TYPE
CHOLINESTERASE INHIBITION. NOTE TO PHYSICIAN: THE DECISION OF WHETHER TO
INDUCE VOMITING OR NOT SHOULD BE MADE BY AN ATTENDING PHYSICIAN. IF LAVAGE
IS PERFORMED, ENDOTRACHEAL AND/OR ESOPHAGEAL CONTROL IS SUGGESTED. DANGER
FROM LUNG ASPIRATION MUST BE WEIGHED AGAINST TOXICITY WHEN CONSIDERING
EMPTYING THE STOMACH. CHLORPYRIFOS IS A CHOLINESTERASE INHIBITOR. TREAT
SYMPTOMATICALLY. IF EXPOSED, ATROPINE, ONLY BY INJECTION, IS THE PERERABLE
ANTIDOTE. TREATMENT BASED ON JUDGEMENT OF THE PHYSICIAN IN RESPONSE TO
REACTIONS OF THE PATIENT.
=======================================================
Transportation Information
=======================================================
Trans ID NO: 154720
MSDS NAME: 46482,DURSBAN PRO INSECTICIDE
MSDS Prepared Date: 01/27/1997
Review Date: 09/19/2000
Tech Entry NOS Shipping Nm: CHLORPYRIFOS 23.5%
Net Unit Weight: 1.1 LBS
Multiple KIT Number: 0
Unit Of Issue: PT
Container QTY: 0
Type Of Container: BOTTLE,SQUEEZ
Additional Data: LIMITED QUANTITIES ARE EXEMPT FROM LABELING AND PLACARDING;
UNLESS OFFERED FOR TRANSPORTATION BY AIR . SEE 49 CFR 173.153.
=======================================================
Detail DOT Information
=======================================================
DOT PSN Code: LAX
DOT Proper Shipping Name: ORGANOPHOSPHORUS PESTICIDES, LIQUID, TOXIC
Hazard Class: 6.1
UN ID Num: UN3018
DOT Packaging Group: III
Label: KEEP AWAY FROM FOOD
Special Provision: N76,T14
Non Bulk Pack: 203
Bulk Pack: 241
Max Qty Pass: 60 L
Max Qty Cargo: 220 L
Vessel Stow Req: A
Water/Ship/Other Req: 40
=======================================================
Detail IMO Information
=======================================================
IMO PSN Code: LBE
IMO Proper Shipping Name: ORGANOPHOSPHORUS PESTICIDE, LIQUID, TOXIC o
IMDG Page Number: 6219
UN Number: 3018
UN Hazard Class: 6.1
IMO Packaging Group: I/II/III
Subsidiary Risk Label: -
EMS Number: 6.1-02
MED First Aid Guide NUM: 505
=======================================================
Detail IATA Information
=======================================================
IATA PSN Code: SRE
IATA UN ID Num: 3018
IATA Proper Shipping Name: ORGANOPHOSPHOROUS PESTICIDE, LIQUID, TOXIC *
IATA UN Class: 6.1
IATA Label: TOXIC
UN Packing Group: III
Packing Note Passenger: 611
Max Quant Pass: 60L
Max Quant Cargo: 220L
Packaging Note Cargo: 618
Exceptions: A3,A4,A6
=======================================================
Detail AFI Information
=======================================================
AFI PSN Code: SRE
AFI Symbols: *
AFI Proper Shipping Name: ORGANOPHOSPHORUS PESTICIDES, LIQUID, TOXIC
AFI Hazard Class: 6.1
AFI UN ID NUM: UN3018
AFI Packing Group: III
Special Provisions: P5, N76
Back Pack Reference: A10.5
=======================================================
HAZCOM Label
=======================================================
MSDS NAME: LABEL COVERED UNDER EPA REGS - HAZCOM LABEL NOT AUTHORIZED
=======================================================
Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
*** END OF RECORD *** |
|
|