INTERPLASTIC CORPORATION -- SIL65AA-1015 ORTHO LAMINATING RESIN
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Material Safety Data Sheet
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MSDS Num: CLFMF
MSDS NAME: SIL65AA-1015 ORTHO LAMINATING RESIN
Responsible Party
Name: INTERPLASTIC CORPORATION
Address: 1225 WILLOW LAKE BLVD
City: VADNAIS HEIGHTS MN 55110-5145
Info Phone: 612-331-6850
Emergency Phone Number: 800-424-9300
Resp. Party Other MSDS No.: MSDSLETO
Chemtrec IND/Phone: (800)424-9300
Review Ind: Y
Published: Y
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Contractor Summary
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Name: INTERPLASTIC CORPORATION
Address: 1225 WILLOW LAKE BLVD
City: VADNAIS HEIGHTS MN 55110-5145
Phone: 612-331-6850
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Ingredients
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Name: UNSATURATED POLYESTER BASE RESIN. (BASE RESINS ARE IDENTTIFIED BY ONE OR
MORE CAS NUMBERS - REFER TO "OTHER INFORMATION" SECTION)
% low Wt: 52.
% high Wt: 55.
OSHA PEL: NONE-ESTB.
ACGIH TLV: NONE-EST.
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Cas: 100-42-5
RTECS #: WL3675000
Name: STYRENE
% low Wt: 45.
% high Wt: 48.
Other REC Limits: 100PPM 15 MINCEILING
OSHA PEL: 50 PPM TWA
OSHA STEL: 100 PPM CEILING
ACGIH TLV: 50 PPM
ACGIH STEL: 100 PPM
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
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Health Hazards Data
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Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: YES
OSHA: NO
Effects of Exposure: CANCER HAZARD. CONTAINS STYRENE WHICH IS LISTED AS A LUNG
CARCINOGEN (FP N). EFFECTS OF OVEREXPOSURE: FOR STYRENE: EYES: CAN CAUSE
SEVERE IRRITATION, REDNESS, TEARING, BLURRED VISION. SKIN: PROLONGED OR
REPEATED CONTACT CAN CAUSE MODERATE IRRITATION, DEFATTING, DERMATITIS.
BREATHING: EXCESSIVE INHALATION OF VAPORS CAN CAUSE NASAL IRRITATION,
DIZZINESS, WEAKNESS, FATIGUE, NAUSEA, HEADACHE, POSSIBLE UNCONSCIOUSNESS AND
EVEN ASPHYXIATION. SWALLOWING: CAN CAUSE GASTROINTESTINAL IRRITATION, NAUSEA,
VOMITING, DIARRHEA. ASPIRATION OF MATERIAL INTO THE LUNGS CAN CAUSE CHEMICAL
PNEUMONITIS.
Explanation Of Carcinogenicity: STYRENE: IARC GROUP 2B, VOLUME 60, PAGE 233,
1994. STYRENE HAS BEEN IDENTIFIED AS A POSSIBLE HUMAN CARCINOGEN BY IARC. THE
IARC DETERMINATION IS BASED ON LIMITED EVIDENCE IN ANIMALS & OTHER
"RELEVANT" DATA. IARC CONCEDES THERE IS INADEQUATE EVIDENCE ON HUMANS FOR
ITS FINDINGS. THE SIGNIFICANCE OF THESE RESULTS FOR HUMANS HAS NOT BEEN
(TOXICOLOGICAL INFO)
Signs And Symptions Of Overexposure: REFER TO HEALTH HAZARDS ACUTE AND CHRONIC
(FP N).
First Aid: IF ON SKIN: THOROUGHLY WASH EXPOSED AREA WITH SOAP & WATER.
REMOVE CONTAMINATED CLOTHING. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. IF
IN EYES: FLUSH WITH LARGE AMOUNT OF WATER, LIFTING UPPER & LOWE R LIDS
OCCASIONALLY. GET MEDICAL ATTENTION. IF SWALLOWED: DO NOT INDUCE VOMITING.
KEEP PERSON WARM, QUIET & GET MEDICAL ATTENTION. ASPIRATION OF MATERIAL
INTO LUNGS DUE TO VOMITING CAN CAUSE CHEMICAL PNEUMONITIS WHICH CAN BE
FATAL. IF BREATHED: IF AFFECTED, REMOVE INDIVIDUAL TO FRESH AIR. IF BREATHING
IS DIFFICULT, ADMINISTER OXYGEN. IF BREATHING HAS STOPPED, GIVE ARTIFICIAL
RESPIRATION. KEEP PERS ON WARM QUITE, & GET MEDICAL ATTENTION.
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Handling and Disposal
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Spill Release Procedures: SMALL SPILL: ABSORB LIQUID ON PAPER, VERMICULITE,
FLOOR ABSORBENT OR OTHER ABSORBENT MATERIAL AND TRANSFER TO HOOD. LARGE
SPILL: ELIMINATE ALL IGNITION SOURCES (FLARES, FLAMES, INCLUDING PILOT LIGHTS
, ELECTRICAL SPARKS). PERSONS NOT WEARING PROTECTIVE EQUIPMENT SHOULD BE
EXCLUDED FROM AREA OF SPILL UNTIL CLEAN-UP HAS BEEN COMPLETED. STOP SPILL AT
SOURCE, DIKE AREA OF SPILL TO (TRANSPORT INFO)
Neutralizing Agent: N/P.
Waste Disposal Methods: SMALL SPILL: ALLOW VOLATILE PORTION TO EVAPORATE IN
HOOD. ALLOW SUFFICIENT TIME FOR VAPORS TO COMPLETELY CLEAR HOOD DUCT WORK.
DISPOSE OF REMAINING MATERIAL IN ACCORDANCE WITH APPLICABLE REGULATIONS.
LARGE SPILL: DESTROY BY LIQUID INCINERATION IN ACCORDANCE WITH APPLICABLE
REGULATIONS. CONTAMINATED ABSORBENT SHOULD BE DISPOSED (OTHER PRECAUTIONS)
Handling And Storage Precautions: N/P. SPECIAL PRECAUTIONS: CONTAINERS OF
THIS MATERIAL MAY BE HAZARDOUS WHEN EMPTIED. SINCE EMPTIED CONTAINERS RETAIN
PRODUCT RESIDUES (VAPORS, LIQUID, AND/OR SOLID), ALL HAZARD PRECAUTIONS GIVEN
IN THIS DATA SHEET MUST BE OBSERVED.
Other Precautions: NEVER USE WELDING OR CUTTING TORCH ON OR NEAR DRUM (EVEN
EMPTY) BECAUSE PRODUCT (EVEN JUST RESIDUE) CAN IGNITE EXPLOSIVELY.
WASTE DISPOSAL METHOD (CONT): OF IN ACCORDANCE WITHLOCAL, STATE AND F EDERAL
REGULATIONS.
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Fire and Explosion Hazard Information
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Flash Point: =31.1C, 88.F
Flash Point Text: SEE OTHER INFO
Extinguishing Media: REGULAR FOAM OR CARBON DIOXIDE OR DRY CHEMICAL.
Fire Fighting Procedures: WATER OR FOAM MAY CAUSE FROTHING WHICH CAN BE VIOLENT
& POSSIBLY ENDANGER THE LIFE OF THE FIREFIGHTER, ESPECIALLY IF SPRAYED
INTO CONTAINERS OF HOT BURNING LIQUID. WEAR (NIOSH APPROVED - FP N) SCBA WI
TH A FULL FACE-PIECE OPERATED IN PRESSURE DEAMND OR OTHER POSITIVE PRESSURE
MODE WHEN FIGHTING FIRES.
Unusual Fire/Explosion Hazard: VAPORS ARE HEAVIER THAN AIR & MAY TRAVEL
ALONG THE GROUND OR MAY BE MOVED BY VENTILATION & IGNITED BY PILOT
LIGHTS, OTHER FLAMES, SPARKS, HEATERS, SMOKING, ELECTRIC MOTORS, STATIC
DISCHARGE, OR OTHER IGNITION SOURCES AT LOCATIONS DISTANT FROM MATERIAL
HANDLING POINT.
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Control Measures
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Respiratory Protection: IF TLV OF THE PRODUCT OR ANY COMPONENT IS EXCEEDED A
NIOSH APPROVED AIR SUPPLIED RESPIRATOR IS ADVISED IN ABSENCE OF PROPER
ENVIRONMENTAL CONTROL. OSHA REGULATIONS ALSO PERMIT OTHER NIOSH RESPIRATORS
UNDER SPECIFIED CONDITIONS. (SEE YOUR SAFETY EQUPMENT SUPPLIER.) ENGINEERING
OR ADMINISTRATIVE CONTROLS SHOULD BE IMPLEMENTED TO REDUCE EXPOSURE.
Ventilation: PROVIDE SUFFICIENT MECHANICAL (GENERAL AND/OR LOCAL EXHAUST)
VENTILATION TO MAINTAIN EXPOSURE BELOW TLV(S).
Protective Gloves: WEAR CHEMICAL RESISTANT GLOVES THAT AFFORDS PROPER (OTHER
PROTECTIVE EQUIPMENT)
Eye Protection: CHEMICAL SPLASH GOGGLES IN COMPLIANCE WITH OSHA REGULATIONS
(WORK HYGENIC PRAC)
Other Protective Equipment: NORMAL WORK CLOTHING COVERING ARMS AND LEGS.
EYEWASH AND DELUGE SHOWER MEETING ANSI DESIGN CRITERIA (FP N). GLOVES
(CONT): PROTECTION TO THE HANDS, SUCH AS: NEOPRENE, RUBBER, LATEX, ETC.
Work Hygienic Practices: N/P. EYE PROTECTION (CONT): ARE ADVISED; HOWEVER,
OSHA REGULATIONS ALSO PERMIT OTHER TYPE SAFETY GLASSES (CONSULT YOUR SAFETY
EQUIPMENT SUPPLIER).
Supplemental Safety and Health: PERMISSIBLE EXPOSURE LEVEL: NOT ESTABLISHED FOR
PRODUCT. OSHA CEILING VALUE IS 100PPM & ACGIH SHORT TERM EXPOSURE LIMIT
(STEL) IS 100PPM. NIOSH RECOMMENDS A LIMIT OF 50PPM, 8HR TWA; 100PPM 15
MINUTES CEILING. GENERAL OR GENERIC ID: UNSATURATED POLYESTER RESIN.
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Physical/Chemical Properties
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Boiling Point: =145.2C, 293.4F
B.P. Text: @760.00MM HG FOR STYRENE
Vapor Pres: 4.3 MMHG(20 DEG C)STYRENE
Vapor Density: AIR=1 3.6
Spec Gravity: 1.0-1.2@77DEG F(25 DEG C)
Evaporation Rate & Reference: SLOWER THAN ETHER
Appearance and Odor: FLAMMABLE LIQUID. ODOR: NOT SPECIFIED BY MANUFACTURER (FP
N).
Percent Volatiles by Volume: 52 - 55
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: EXPOSURE TO EXCESSIVE HEAT OR OPEN FLAME; STORAGE
IN OPEN CONTAINERS; PROLONGED STORAGE (6 MONTHS), STORAGE ABOVE 38 DEG C (100
DEG F). CONTAMINATION WITH OXIDIZING AGENTS.
Materials To Avoid: AVOID CONTACT WITH STRONG ALKALIES, STRONG MINERAL ACIDS
AND OXIDIZING AGENTS.
Hazardous Decomposition Products: MAY FORM TOXIC MATERIALS: CARBON MONOXIDE,
CARBON DIOXIDE, VARIOUS/LOW MOLECULAR WEIGHT HYROCARBONS, ORGANIC ACIDS.
Hazardous Polymerization Indicator: YES
Conditions To Avoid Polymerization: CAN OCCUR.
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Toxicological Information
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Toxicological Information: OVEREXPOSURE TO STYRENE HAS APPARENTLY BEEN FOUND TO
CAUSE THE FOLLOWING EFFECTS IN LABORATORY ANIMALS: LIVER ABNORMALITIES,
KIDNEY DAMAGE, AND LUNG DAMAGE. EXPLANATION OF CARCINOGENICITY (CONT): E
STABLISHED. STYRENE IS NOT EXPECTED TO CAUSE CANCER IN HUMANS AT
CONCENTRATIONS BELOW THE RECOMMENDED EXPOSURE STANDARD OR WHEN APPROPRIATE
INDUSTRIAL HYGIENE PROCEDURES ARE FOLLOWED. MOREOVER, STUDIE S IN HUMANS
EXPOSED FOR LONG PERIODS OF TIME TO STYRENE HAVE NOT DEMONSTRATED ANY
CARCINOGENIC EFFECTS. AT THE CONCLUSION OF A MAJOR NOTICE AND COMMENT
RULEMAKING REVISING ITS AIR CONTAMINANTS REGULAT IONS, OSHA CONCLUDED
(ECOLOGICAL INFO)
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Ecological Information
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Ecological: N/P. TOXICOLOGICAL INFO (CONT): THAT THE "CURRENT EVIDENCE ON
STYRENE'S CARCINOGENICITY DOES NOT SUPPORT ITS CLASSIFICATION IN THE FINAL
RULE AS A CARCINOGEN." IN THE SAME RULEMAKING, THE NATIONA L INSTITUTE FOR
OCCUPATIONAL SAFETY AND HEALTH (NIOSH) COMMENTED THAT THERE "SEEMS TO BE
LITTLE BASIS FROM EXPERIMENTAL ANIMAL INVESTIGATIONS OR EPIDEMIOLOGIC STUDIES
TO CONCLUDE AT THIS TIME THAT STY RENE IS CARCINOGENIC." THE NATIONAL
TOXICOLOGY PROGRAM DOES NOT INCLUDE STYRENE ON ITS LIST OF CHEMICALS EXPECTED
TO BE CARCINOGENIC.
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MSDS Transport Information
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Transport Information: UN/NA NUMBER: UN1866. SPILL RELEASE PROCEDURES
(CONT): PREVENT SPREADING, PUMP LIQUID TO SALVAGE TANK. REMAINING LIQUID MAY
BE TAKEN UP ON SAND, CLAY, EARTH, FLOOR ABSORBENT OR OTHER ABSORBENT
MATERIAL AND SHOVELED INTO CONTAINERS.
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Regulatory Information
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Sara Title III Information: THIS PRODUCT CONTAINS TOXIC CHEMICALS SUBJECT TO
THE REPORTING REQUIREMENTS OF SECTION 313 OF THE EMERGENCY PLANNING AND
COMMUNITY RIGHT-TO-KNOW ACT OF 1986 & 40 CFR 372. PLEASE REFER TO
INGREDIENTS S ECTION FOR THE SPECIFIC PRODUCT AND CONCENTRATION.
FEDERAL REGULATORY (CONT): 29350-58-1, 31472-46-5, 54228-09-0,67380-21-6,
67939-40-6, 68647-07-4,155122-62-6, 68492-68-2.
Federal Regulatory Information: N/P. OTHER INFORMATION (CONT): 37339-47-2,
56083-98-8, 67712-08-7, 68299-40-1, 62569-28-2, 149-717-53-3, 32677-47-7,
30946-90-8, 31260-98-7, 32505-78-5, 32762-75-7, 36346-15-3, 36425-15-7,
36425-16- 8, 37347-86-7, 37999-57-8, 52453-94-8, 56083-99-9, 57863-48-6,
61224-63-3, 58182-50-6, 68585-94-4, 25749-46-6, 27837-75-8, 28679-80-3,
30110-00-0, 42133-45-9, 58182-50-6, 67845-68-5, 68585-94-4, 29011 -83-4,
141224-31-9, 64386-66-9, 64386-67-0, 57863-48-6, 67599-39-7, 67939-08-6,
68002-44-8, 68140-84 -1, 68140-88-5, 68171-28-8, 68238-98-2, 68511-26-2,
72259-64-4, 81192-92-9, 135108-89-3, 25101-03-5, 26588-55-6, 28516-30-5,
(SARA III)
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Other Information
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Other Information: RATING: (H= 2, F=3, R=1). HAZARD CLASSIFICATION: FLAMMABLE
LIQUID. WHSE NO: 022. PERCENT NON-VOLATILES: 52-55%. FLAMMABLE LIMITS:
(LOWEST VALUE OF STYRENE) LOWER - 1.1%; (UPPER VALUE OF STYRENE) UPPER -
6.1%. FLASH POINT: 88F FOR VOLATILE COMPONENT. BASE RESIN CAS INDEX: THE BASE
RESINS INDICATED IN INGREDIENTS SECTION ARE IDENTIFIED BY ONE OR MORE OF THE
FOLLOWING CAS NUMBERS: 9065-68-3, 250 37-66-5, 25464-21-5, 25749-49-9,
25987-82-0, 26098-37-3, 26123-45-5, 26265-08-7, 26301-26-8, 26795-76-6,
28472-89-1, 113060-15-4, 2999350-58-1, 28516-30-5, 31472-46-5, 25215-72-9,
27342-37-6, 28572-30 -7, 29403-69-8, (FEDERAL REGULATORY)
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HAZCOM Label
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MSDS NAME: SIL65AA-1015 ORTHO LAMINATING RESIN
Assigned IND: Y
Company: INTERPLASTIC CORPORATION
Street: 1225 WILLOW LAKE BLVD
City: VADNAIS HEIGHTS MN
Zipcode: 55110-5145
Health Emergency Phone: 800-424-9300
Label Required IND: Y
Date Of Label Review: 06/21/2001
Status Code: A
Origination Code: F
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Moderate
Fire Hazard: Severe
Reactivity Hazard: None
Hazard And Precautions: CANCER HAZARD. CONTAINS STYRENE WHICH IS LISTED AS A
LUNG CARCINOGEN (FP N). ACUTE/CHRONIC: FOR STYRENE: EYES: CAN CAUSE SEVERE
IRRITATION, REDNESS, TEARING, BLURRED VISION. SKIN: PROLONGED OR REPEATE D
CONTACT CAN CAUSE MODERATE IRRITATION, DEFATTING, DER
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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