ATOFINA CHEMICALS, INC. -- M5610, TURCO - HTC
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Material Safety Data Sheet
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NIIN: 01-272-1845
MSDS Num: CLGCG
MSDS NAME: M5610, TURCO - HTC
Responsible Party
Name: ATOFINA CHEMICALS, INC.
Address: 2000 MARKET STREET
City: PHILADELPHIA, PA 19103
Info Phone: 800-848-0085
Emergency Phone Number: 703-527-3887
Chemtrec IND/Phone: (800)424-9300
Proprietary Ind: Y
Review Ind: Y
Published: Y
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Contractor Summary
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Name: ATOFINA CHEMICALS, INC.
Address: 2000 MARKET STREET
City: PHILADELPHIA, PA 19103
Phone: 800-848-0085
Name: SDB CONSULTANTS LTD
Address: 401 WHITNEY AVE SUITE 120
City: GRETNA LA 70056
Phone: 504-366-9105
Contract Number: SP0450-01-M-ZD31
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Item Description Information
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Item Manager: S9G
Item Name: CLEANING COMPOUND,ALKALI,FERROUS SURFACE
Unit of Issue: DR
Quantitative Expression: 00000000125LB
UI Container Qty: 0
Type of Container: DRUM
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Ingredients
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Name: *** PROPRIETARY ***
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Health Hazards Data
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Route Of Entry Inds - Inhalation: YES
Skin: YES
Effects of Exposure: BASED ON ITS COMPOSITION, IT IS ANTICIPATED TO BE
CORROSIVE TO EYES AND SKIN. REPEATED CONTACT MAY CAUSE AN ALLERGIC SKIN
REACTION. DERMATITIS (INFLAMMATION OF THE SKIN) AND SUPERFICIAL SKIN DAMAGE
MA Y RESULT FROM REPEATED OR PROLONGED CONTACT. DUST MAY BE CORROSIVE TO THE
RESPIRATORY TRACT AND MAY CAUSE COUGHLING, SORE THROAT AND SHORTNESS OF
BREATH. PROLONGED EXPOSURE MAY RESULT IN ULCERATION OF THE NASAL PASSAGES.
Medical Cond Aggravated By Exposure: MEDICAL CONDITIONS WHICH MAY BE AGGRAVATED
BY EXPOSURE TO THIS MATERIAL INCLUDE LUNG DISEASE OR LIMITED RESPIRATORY
CAPACITY.
First Aid: IF IN EYES, IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR 15 MINS. GET
MEDICAL ATTENTION IMMEDIATELY. IF ON SKIN, IMMEDIATELY FLUSH WITH PLENTY OF
WATER. REMOVE CONTAMINATED CLOTHING & SHOES. GET MEDICAL ATTENTION. IF
SWALLOWED, DO NOT INDUCE VOMITING. GIVE WATER TO DRINK. GET MEDICAL ATTENTION
IMMEDIATELY. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. IF
INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION.
IF BREATHING IS DIFFICULT, GIVE OXYGEN. GET MEDICAL ATTENTION.
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Handling and Disposal
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Spill Release Procedures: STOP THE LEAK, IF POSSIBLE. VENTILATE THE SPACE
INVOLVED. CONTAIN, SWEEP UP, PLACE IN CONTAINER FOR DISPOSAL. SHUT OFF OR
REMOVE ALL IGNITION SOURCES. PREVENT WATERWAY CONTAMINATION. CONSTRUCT A DIKE
TO PREVENT SPREADING. COLLECT RUN-OFF & TRANSFER TO DRUMS OR TANKS FOR
LATER DISPOSAL. CONSULT A REGULATORY SPECIALIST TO DETERMINE APPROPRIATE
STATE OR LOCAL REPORTING REQUIREMENTS, FOR ASSISTANCE.
Waste Disposal Methods: RECOVER, RECLAIM OR RECYCLE WHEN PRACTICAL. DISPOSE OF
IN ACCORDANCE WITH FEDERAL, STATE & LOCAL REGULATIONS. "SEE OTHER
INFORMATION"
Handling And Storage Precautions: HANDLING: DO NOT GET IN EYES, ON SKIN OR
CLOTHING. AVOID BREATHING DUST. KEEP CONTAINER CLOSED. USE ONLY WITH ADEQUATE
VENTILATION. WASH THOROUGHLY AFTER HANDLING. KEEP CONTAINER TIGHTLY CLOSED.
EMPTY CONTAINER MAY CONTAIN HAZARDOUS RESIDUES.
Other Precautions: STORAGE: STORE IN A COOL, DRY PLACE. AVOID EXCESSIVE HEAT.
STORE OUT OF DIRECT SUNLIGHT IN A COOL, WELL-VENTILATED PLACE.
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Fire and Explosion Hazard Information
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Extinguishing Media: USE WATER FOG OR WATER SPRAY.
Fire Fighting Procedures: FIRE FIGHTERS AND OTHERS WHO MAY BE EXPOSED TO
PRODUCTS OF COMBUSTION SHOULD WEAR FULL FIRE FIGHTING TURN OUT GEAR (FULL
BUNKER GEAR) AND SELF-CONTAINED BREATHING APPARATUS (PRESSURE DEMAND NIOSH
APPR OVED OR EQUIVALENT). FIRE FIGHTING EQUIPMENT SHOULD BE THOROUGHLY
DECONTAMINATED AFTER USE.
Unusual Fire/Explosion Hazard: DUST CLOUDS GENERATED DURING HANDLING AND/OR
STORAGE CAN FORM EXPLOSIVE MIXTURES WITH AIR. NOTE: FOR ANY OPERATION
INVOLVING THIS MATERIAL, USE ONLY CLASS 1 ELECTRICAL EQUIPMENT. ENSURE THAT
ALL EQUIP MENT IS ADEQUATELY GROUNDED.
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Control Measures
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Respiratory Protection: AVOID BREATHING DUST. WHEN AIRBORNE EXPOSURE LIMITS ARE
EXCEEDED (SEE BELOW), USE NIOSH APPROVED RESPIRATORY PROTECTION EQUIPMENT
APPROPRIATE TO THE MATERIAL AND/OR ITS COMPONENTS. CONSULT RESPIRATOR
MANUFACTURER TO DETERMINE APPROPRIATE TYPE EQUIPMENT FOR GIVEN APPLICATION.
OBSERVE RESPIRATOR USE LIMITATIONS SPECIFIED BY NIOSH OR THE MANUFACTURER.
FOR
Ventilation: INVESTIGATE ENGINEERING TECHNIQUES TO REDUCE EXPOSURES BELOW
AIRBORNE EXPOSURE LIMITS. PROVIDE VENTILATION IF NECESSARY TO CONTROL
EXPOSURE LEVELS BELOW
Protective Gloves: PROTECTIVE GLOVES, CONSULT GLOVE MANUFACTURER.
Eye Protection: WEAR A FACE SHIELD, CHEMICAL GOGGLES.
Other Protective Equipment: PROVIDE A SAFETY SHOWER. EYE FLUSHING EQUIPMENT.
APPROPRIATE CHEMICAL RESISTANT PROTECTIVE CLOTHING
Work Hygienic Practices: RINSE IMMEDIATELY IF SKIN IS CONTAMINATED. WASH
CONTAMINATED CLOTHING AND CLEAN PROTECTIVE EQUIPMENT BEFORE REUSE. WASH SKIN
THOROUGHLY AFTER HANDLING. DESTROY CONTAMINATED SHOES.
Supplemental Safety and Health: PRODUCT NAME: TURCO-HTC. CHEMICAL FAMILY:
STRONG ALKALI. CHEMICAL FORMULA: MIXTURE. PRODUCT USE: ALKALINE CLEANER.
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Physical/Chemical Properties
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HCC: B2
PH: (5%SOLUTION)>12
Solubility in Water: SOLUBLE
Appearance and Odor: TAN, GRANULAR MIXTURE
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: AVOID EXCESSIVE HEAT. STORE OUT OF DIRECT
SUNLIGHT IN A COOL, WELL-VENTILATED PLACE.
Materials To Avoid: STRONG ACIDS.
Hazardous Decomposition Products: NONE KNOWN
Hazardous Polymerization Indicator: NO
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Toxicological Information
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Toxicological Information: SODIUM METASILICATE: SINGLE EXPOSURE (ACUTE) STUDIES
INDICATE THAT THIS MATERIAL IS SLIGHTLY TOXIC TO RATS IF SWALLOWED (LD50
800-1,349 MG/KG; CORROSIVE TO MUCOUS MEMBRANES OF THE GASTROINTESTINAL TRA CT
CAUSING VOMITING & BLEEDING) & CORROSIVE TO RABBIT EYES & SKIN
(4-HR & 24-HR EXPOSURE). SODIUM HYDROXIDE: SINGLE EXPOSURE (ACUTE)
STUDIES INDICATE THAT THIS MATERIAL IS SLIGHTLY TOXIC IF ABSORBED T HROUGH
THE SKIN (RAT LD50 1,350 MG/KG; DRY SODIUM HYDROXIDE) & CORROSIVE TO
RABBIT EYES & SKIN. MANY PUBLICATIONS CONFIRM THAT THIS MATERIAL IS
CORROSIVE TO ALL TISSUES.
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Ecological Information
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Ecological: SODIUM HYDROXIDE: DATA FOM SEVERAL SPECIES OF FISH SHOWED A RANGE
OF TOLERANCE (BROOK TROUT>SPOTFIN & LAKE EMERALD
SHINERS>MINNOWS>MOSQUITOFISH>GOLDFISH) THAT WAS MOST LIKELY RELATED
TO CHANGES IN THE PH PRODUCED BY ADDITION OF SODIUM HYDROXIDE TO THE WATER.
THE MINIMUM LETHAL CONCENTRATION FOR MINNOW. MAYFLY LARVAE & DAPHINIA WAS
100PPM & FOR CHIRONOMUS LARVAE, 700 PPM. TRISODIUM PHOSPHATE: THIS
MATERIAL IS PRACTICALLY NON-TOXIC TO MOSQUITO FISH (LC50 151 MG/L), AFRICAN
CATFISH (LC50 748 MG/L) & DAPHINA MAGNA (LC50>52 MG/L). SURFACTANT:
THIS MATERIAL I S SLIGHTLY TOXIC O DAPHNIA MAGNA (48-HR LC50 52-99 MG/L).
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MSDS Transport Information
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Transport Information: DOT NAME: CORROSIVE SOLID, BASIC, INORGANIC, NOS. DOT
TECHNICAL NAME: (SODIUM HYDROXIDE, SODIUM METASILICATE). DOT HAZARD CLASS: 8.
UN NUMBER: 3262. DOT PACKING GROUP: PG II. RQ: 1000 LBS. (SODIUM HYD ROXIDE).
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Regulatory Information
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Sara Title III Information: HAZARD CATEGORIES UNDER CRITERIA OF SARA TITLE III
RULES (40 CFR PART 370)" IMMEDIATE (ACUTE) HEALTH-Y; DELAYED (CHRONIC)
HEALTH-N; FIRE-N; REACTIVE-N, SUDDEN RELEASE OF PRESSURE-N. SARA REPORTABLE
QU ANTITIES: SODIUM HYDROXIDE-1000 LBS. TRISODIUM ORTHOPHOSPAHTE-5000 LBS.
Federal Regulatory Information: SODIUM METASILICATE, SODIUM HYDROXIDE,
TRISODIUM ORTHOPHOSPHATE AND PROPRIETARY SURFACTANT: ARE IDENTIFIED AS
HAZARDOUS CHEMICALS ACCORDING TO THE CRITERIA OF THE OSHA COMMUNICATION
STANDARD (29 CFR 1 910.1200). THIS MATERIAL IS CLASSIFIED AS HAZARDOUS UNDER
FEDERAL OSHA REGULATIONS. THE COMPONENTS OF THIS PRODUCT ARE ALL ON THE TSCA
INVENTORY LIST.
State Regulatory Information: MASSACHUSETTS RIGHT TO KNOWN: SODIUM HYDROXIDE,
TRISODIUM ORTHOPHOSPAHTE. PENNSYLVANIA ENVIRONMENTAL HAZARD: SODIUM
HYDROXIDE, TRISODIUM ORTHOPHOSPHATE. PENNSYLVANIA RIGHT TO KNOWN: SODIUM
HYDROXIDE, TRISODIUM ORTHOPHOSPAHTE.
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Other Information
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Other Information: DISPOSAL: NOTE-CHEMICAL ADDITIONS TO, PROCESSING OF, OR
OTHERWISE ALTERING THIS MATERIAL MAY MAKE THIS WASTE MANAGEMENT INFORMATION
INCOMPLETE, INACCURATE, OR OTHERWISE INAPPROPRIATE. FURTHERMORE, STA TE &
LOCAL WASTE DISPOSAL REQUIREMENTS MAY BE MORE RESTRICTIVE OR OTHERWISE
DIFFERENT FROM FEDERAL LAWS & REGULATIONS. **CLEANUP PROCEDURES: TRANSFER
TO CONTAINERS IN PREPARATION FOR LATER DISPOSAL. A VOID GENERATION OF VAPORS.
PLACE IN NON-SPARKING CONTAINERS FOR RECOVERY OR DISPOSAL. REMOVE FROM SPILL
LOCATION. DECONTAMINATE AREA.
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Transportation Information
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Trans ID NO: 157727
MSDS NAME: M5610, TURCO - HTC
MSDS Prepared Date: 02/27/2001
Review Date: 07/01/2001
Net Unit Weight: 125 LB
Multiple KIT Number: 0
Review IND: Y
Unit Of Issue: DR
Container QTY: 0
Type Of Container: DRUM
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Detail DOT Information
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DOT PSN Code: DYB
Symbols: G
DOT Proper Shipping Name: CORROSIVE SOLID, BASIC, ORGANIC, N.O.S.
Hazard Class: 8
UN ID Num: UN3263
DOT Packaging Group: II
Label: CORROSIVE
Packaging Exception: 154
Non Bulk Pack: 212
Bulk Pack: 240
Max Qty Pass: 15 KG
Max Qty Cargo: 50 KG
Vessel Stow Req: B
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Detail IMO Information
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IMO PSN Code: ETE
IMO Proper Shipping Name: CORROSIVE SOLID, BASIC, ORGANIC, N.O.S. o
IMDG Page Number: 8150-1
UN Number: 3263
UN Hazard Class: 8
IMO Packaging Group: I/II/III
Subsidiary Risk Label: -
EMS Number: 8-15
MED First Aid Guide NUM: 760
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Detail IATA Information
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IATA PSN Code: HMR
IATA UN ID Num: 3263
IATA Proper Shipping Name: CORROSIVE SOLID, BASIC, ORGANIC, N.O.S. *
IATA UN Class: 8
IATA Label: CORROSIVE
UN Packing Group: II
Packing Note Passenger: 814
Max Quant Pass: 15KG
Max Quant Cargo: 50KG
Packaging Note Cargo: 816
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Detail AFI Information
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AFI PSN Code: HNG
AFI Symbols: *
AFI Proper Shipping Name: CORROSIVE SOLID, BASIC, ORGANIC, N.O.S.
AFI Hazard Class: 8
AFI UN ID NUM: UN3263
AFI Packing Group: II
Special Provisions: P5
Back Pack Reference: A12.4
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HAZCOM Label
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MSDS NAME: M5610, TURCO - HTC
Assigned IND: Y
Company: ATOFINA CHEMICALS, INC.
Street: 2000 MARKET STREET
City: PHILADELPHIA, PA
Zipcode: 19103
Health Emergency Phone: 703-527-3887
Label Required IND: Y
Date Of Label Review: 07/01/2001
Status Code: A
Origination Code: F
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Severe
Contact Hazard: Severe
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: TAN, GRANULAR MIXTURE. DANGER! CAUSES EYE & SKIN
BURNS. MAY CAUSE BLINDNESS. CAUSES RESPIRATORY TRACT IRRITATION. MAY CAUSE
ALLERGIC SKIN REACTION.
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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