| MSDS | : | 36632, CLOUD WHITE 66-32 | | CAS | : | 100-42-5
1317-65-3
14807-96-6
14808-60-7 | | NAME | : | ing 9:clsd cntnrs. this prod contains extremely flamm solvs whose vaps
matls to avoid:accelerators. avoid contact w/free radical formers
ing 11:lewis acids).
explan of carcin:monographs, supp, vol 7, pg 341, 1987:grp 2a. ntp 6th
spill proc:recovery/disp. avoid dusting cndtns & use good vent.
ing 14:airborne dust levels down.
other prec:cntnrs of this prod may present fire/explo hazs. do not use
ing 16:follow label warnings.
resp prot:org vap resps w/dust, mist & fume filters. where expos
ing 18:level of protection, use a niosh/msha approved positive pressure
vent:vol & pattern to keep tlv of most haz ings in ings section below
ing 20:welding or flamecutting on surfaces coated w/this product. local
polyester alkyd
styrene (sara iii). vp:4.5
calcium carbonate; (limestone)
talc (powder) containing no asbestos fibers; (talc)
unsaturated polyester resin; (polyester resin unsaturated)
silica, crystalline - quartz; (crystalline silica)
contains trace amounts (<1 ppm, <0.001%) of arsenic, cadmium,
supdat:burning liq may cause violent eruption. if water is used, fog nozz
ing 8:formers such as peroxides may rslt in spont exothermic
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LILLY INDUSTRIES INC -- 36632, CLOUD WHITE 66-32
=======================================================
Material Safety Data Sheet
=======================================================
MSDS Num: BSJMB
MSDS NAME: 36632, CLOUD WHITE 66-32
Responsible Party
Name: LILLY INDUSTRIES INC
Address: 210 E ALONDRA BOULEVARD
City: GARDENA CA 90248
Info Phone: 310-352-3087
Emergency Phone Number: 800-424-9300(CHEMTREC)
Published: Y
=======================================================
Contractor Summary
=======================================================
Name: ELANCO PRODUCTS CO, DIV OF ELI LILY/CO
City: INDIANAPOLIS IL 46285
Phone: (317) 261-2000
Name: LILLY INDUSTRIES INC
Address: 210 E ALONDRA BLVD
City: GARDENA CA 90248
Phone: 213-321-0710
=======================================================
Ingredients
=======================================================
Name: ING 9:CLSD CNTNRS. THIS PROD CONTAINS EXTREMELY FLAMM SOLVS WHOSE VAPS
MAY FORM EXPLO MIXTS W/AIR.
-----------------------------
Name: MATLS TO AVOID:ACCELERATORS. AVOID CONTACT W/FREE RADICAL FORMERS
(PEROXIDES, HYDRAZIDES, ALKALI METALS, STRONG
-----------------------------
Name: ING 11:LEWIS ACIDS).
-----------------------------
Name: EXPLAN OF CARCIN:MONOGRAPHS, SUPP, VOL 7, PG 341, 1987:GRP 2A. NTP 6TH
ANNUAL RPT ON CARCINS, 1991:ANTIC TO BE CARCIN.
-----------------------------
Name: SPILL PROC:RECOVERY/DISP. AVOID DUSTING CNDTNS & USE GOOD VENT.
WETTING SPILL W/WATER SPRAY MAY HELP TO KEEP
-----------------------------
Name: ING 14:AIRBORNE DUST LEVELS DOWN.
-----------------------------
Name: OTHER PREC:CNTNRS OF THIS PROD MAY PRESENT FIRE/EXPLO HAZS. DO NOT USE
WELDING/CUTTING TORCHES ON/NEAR CNTNRS.
-----------------------------
Name: ING 16:FOLLOW LABEL WARNINGS.
-----------------------------
Name: RESP PROT:ORG VAP RESPS W/DUST, MIST & FUME FILTERS. WHERE EXPOS
POTNTL UNDER USE CNDTNS NECESSITATES HIGHER
-----------------------------
Name: ING 18:LEVEL OF PROTECTION, USE A NIOSH/MSHA APPROVED POSITIVE PRESSURE
AIR SUPPLIED RESPIRATOR.
-----------------------------
Name: VENT:VOL & PATTERN TO KEEP TLV OF MOST HAZ INGS IN INGS SECTION BELOW
ACCEPT LIM & TO REMOVE DECOMP PRODS DURING
-----------------------------
Name: ING 20:WELDING OR FLAMECUTTING ON SURFACES COATED W/THIS PRODUCT. LOCAL
VENTILATION SHOULD BE SUFFICIENT.
-----------------------------
Name: POLYESTER ALKYD
% Wt: 20-30
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
-----------------------------
Cas: 100-42-5
RTECS #: WL3675000
Name: STYRENE (SARA III). VP:4.5
% Wt: 37.43
OSHA PEL: 50 PPM;100 PPM STEL
ACGIH TLV: 50 PPM;100 STEL, S
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
------------------------------
Cas: 1317-65-3
RTECS #: EV9580000
Name: CALCIUM CARBONATE; (LIMESTONE)
% Wt: 5-10
Other REC Limits: 5 MG/M3
OSHA PEL: 15 MG/M3 TDUST
ACGIH TLV: 10 MG/M3 TDUST
------------------------------
Cas: 14807-96-6
RTECS #: WW2710000
Name: TALC (POWDER) CONTAINING NO ASBESTOS FIBERS; (TALC)
% Wt: 5-10
Other REC Limits: 10 PPM (MFR)
OSHA PEL: 2 MG/M3
ACGIH TLV: 2 MG/M3
------------------------------
Name: UNSATURATED POLYESTER RESIN; (POLYESTER RESIN UNSATURATED)
% Wt: 1-5
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
-----------------------------
Cas: 14808-60-7
RTECS #: VV7330000
Name: SILICA, CRYSTALLINE - QUARTZ; (CRYSTALLINE SILICA)
% Wt: <1
OSHA PEL: 0.1 MG/M3 RDUST
ACGIH TLV: 0.1 MG/M3 RDUST
------------------------------
Name: CONTAINS TRACE AMOUNTS (<1 PPM, <0.001%) OF ARSENIC, CADMIUM,
CHROMIUM VI, & LEAD.
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
-----------------------------
Name: SUPDAT:BURNING LIQ MAY CAUSE VIOLENT ERUPTION. IF WATER IS USED, FOG NOZZ
ARE PREFERABLE. CONT W/FREE RADICAL
-----------------------------
Name: ING 8:FORMERS SUCH AS PEROXIDES MAY RSLT IN SPONT EXOTHERMIC
POLYMERIZATION. EXPOS TO HEAT BUILDS UP PRESS IN
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
Route Of Entry Inds - Inhalation: YES
Skin: NO
Ingestion: NO
Carcinogenicity Inds - NTP: YES
IARC: YES
OSHA: NO
Effects of Exposure: REPORTS HAVE ASSOC RPTD & PRLNG OVEREXP TO SOLVS
W/BRAIN & NERV SYS DMG. INTENTIONAL MISUSE, BY DELIB INHALING CONTENTS,
MAY BE HARMFUL/FATAL. AVOID BRTHG VAPS/SPRAY MIST. SKIN CONT:MAY CAUSE
IRRIT/BL ISTERING. EYE:MAY CAUSE MOD IRRIT, TEARING, BURNING/REDNESS.
INHAL:OVEREXP MAY CAUSE RESP IRRIT/NAUS. (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: STYRENE:IARC MONOGRAPHS, SUPP, VOL 7, PG 345,
1987:GRP 2B. ANIMAL:NERV SYS. SILICA, CRYSTALLINE-QUARTZ:IARC
Signs And Symptions Of Overexposure: HLTH HAZ:EVEN UNCON/DEATH. LONG TERM EXPOS
MAY CAUSE PULM FIBROSIS LEADING TO PERM LUNG DMG. PROD NOT CLASSIFIED AS
CARCIN BUT CONTAINS <0.001% OF ARSENIC, CADMIUM, CHROMIUM, LEAD -
SUBSTANCES LISTED AS CARCINOGENS.
Medical Cond Aggravated By Exposure: CONJUNCTIVITIS OF EYE, DERMATITIS, ASTHMA,
PREEXISTING RESPIRATORY DISEASES. PREEXISTING LUNG DISEASE, BY EXPOSURE TO
DUST.
First Aid: EYES:FLUSH W/LUKE WARM WATER FOR AT LEAST 15 MINUTES & OBTAIN
PROMPT MEDICAL ATTENTION. SKIN:WASH W/SOAP & WATER. IF IRRITATION OCCURS,
GET MEDICAL ATTENTION. INGEST:DO NOT INDUCE VOMITING. OBTAIN EME RGENCY
MEDICAL HELP. VOMITING MAY LEAD TO CHEMICAL PNEUMONITIS, WHICH CAN BE FATAL.
INHAL:REMOVE TO FRESH AIR.
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: REMOVE SOURCES OF IGNIT. PVNT FLOW INTO
SEWERS/WATERWAYS. CLEAN UP W/INERT ABSORB USING NON-SPARKING TOOLS. THOSE
INVOLVED IN CLEANUP OF SPILLS SHOULD USE NIOSH/MSHA APPRVD RESP PROT FOR
AIRBORNE DUST . VACUUM/SCOOP UP SPILLED MATL FOR (ING14)
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: DISPOSAL MUST BE I/A/W FEDERAL, STATE & LOCAL
REGULATIONS (FP N). FOLLOW APPLICABLE REGULATIONS ON DISPOSAL OF WASTE.
RESIDUES ARE HAZARDOUS DUE TO THEIR IGNITABILITY.
Handling And Storage Precautions: KEEP PROD CNTNRS COOL, DRY & AWAY FROM
SOURCES OF IGNIT. USE & STORE THIS PROD W/ADEQ VENT. DO NOT SMOKE IN STOR
AREAS. DO NOT TAKE INTERNALLY.
Other Precautions: KEEP AWAY FROM FOOD PRODS. KEEP CNTNRS CLSD WHEN NOT IN USE.
FOR INDUS USE ONLY. THIS PROD CONTAINS PIGMENTS WHICH MAY BECOME DUST
NUISANCE WHEN REMOVED BY ABRASIVE BLASTING, SANDING/GRINDING. KEEP FR OM
OXIDIZERS. EVEN WHEN EMPTY,
=======================================================
Fire and Explosion Hazard Information
=======================================================
Flash Point Text: 88.0F,31.1C
Lower Limits: 1.1%
Upper Limits: 6.1%
Extinguishing Media: DRY CHEMICAL, CARBON DIOXIDE OR FOAM.
Fire Fighting Procedures: USE NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP (FP
N). THIS SHOULD BE USED FOR DUST PROT WHEN FINE PWDR IS AIRBORNE DURING FIRE
SITUATION. PVNT HUMAN (SUPDAT)
Unusual Fire/Explosion Hazard: WATER SPRAY MAY BE INEFT. WATER MAY BE USED TO
COOL CLSD CNTNRS TO PVNT PRESS BUILD UP & POSS AUTOIGNIT/EXPLO WHEN EXPOS
TO EXTREME HEAT. IF WATER IS (SUPDAT)
=======================================================
Control Measures
=======================================================
Respiratory Protection: IF EXPOS EXCEEDS TLV, USE NIOSH/MSHA APPRVD
SUPPLIED-AIR RESP OPERATED IN POS PRESS MODE. IF USE CNDTNS GENERATE AIRBORNE
DUST, MATL SHOULD BE HNDLD IN OPEN/WELL VENTILATED AREA. WHEN ADEQ VENT IS
NOT AVAIL, USE NIOSH/MSHA APPRVD
Ventilation: USE VENT AS REQD TO CONTROL VAP CONCS, AVOID PRLNG/RPTD BRTHG OF
VAPS. PROVIDE GEN DILUTION/LOC EXHST VENT IN
Protective Gloves: NEOPRENE OR RUBBER GLOVES.
Eye Protection: SPLASH GOGGLES OR FACE SHIELD.
Other Protective Equipment: EMERGENCY EYE WASH FOUNTAINS SHOULD BE IN VICINITY.
PROTECTIVE CLOTHING SHOULD BE WORN. DELUGE SHOWER (FP N).
Work Hygienic Practices: FOLLOW PRUDENT HYGIENIC PRACTICES. WASH THOROUGHLY
AFTER HANDLING.
Supplemental Safety and Health: FIRE FIGHT PROC:EXPOS TO FIRE, SMOKE, FUMES/
PRODS OF COMBUST. EVACUATE NONESSNTL PERS FROM FIRE AREA. EXPLO HAZ:USED, FOG
NOZZ ARE PREFERABLE. VAPS MAY BE HVR/AIR & MAY TRAVEL ALONG GROUND BEFORE
IGN IT/FLASHING BACK TO VAP SOURCE. CLSD CNTNRS MAY BE COOLED BY WATER SPRAY.
WATER/FOAM SPRAYED INTO CNTNR OF HOT
=======================================================
Physical/Chemical Properties
=======================================================
HCC: F4
B.P. Text: >293F,>145C
Vapor Pres: 4.5 @ 68F
Vapor Density: HVR/AIR
Spec Gravity: 1.31 (FP N)
Evaporation Rate & Reference: SLOWER THAN ETHER
Solubility in Water: SLIGHT
Appearance and Odor: WHITE, THIXOPROPIC LIQUID; MODERATE AROMATIC ODOR.
Percent Volatiles by Volume: 54.15
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: AVOID EXPOS TO SPKS, OPEN FLAMES, HOT SURFS & ALL
SOURCES OF HEAT & IGNIT. DO NOT HEAT >150F.
Materials To Avoid: AVOID STRONG MINERAL ACIDS & OXIDIZING AGENTS. AVOID STRONG
ACIDS, ALKALIES, OXIDIZERS, AMINES, POLYMERIZATION
Hazardous Decomposition Products: MAY PRODUCE HAZ FUMES WHEN HEATED TO DECOMP.
FUMES MAY CONTAIN CARBON MONOXIDE, CARBON DIOXIDE & OXIDES OF NITROGEN.
Hazardous Polymerization Indicator: YES
Conditions To Avoid Polymerization: HAZARDOUS POLYMERIZATION MAY OCCUR W/
CATALYST OR HEAT.
=======================================================
Toxicological Information
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Ecological Information
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MSDS Transport Information
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Regulatory Information
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Other Information
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HAZCOM Label
=======================================================
MSDS NAME: 36632, CLOUD WHITE 66-32
Assigned IND: Y
Company: LILLY INDUSTRIES INC
Street: 210 E ALONDRA BLVD
City: GARDENA CA
Zipcode: 90248
Health Emergency Phone: 800-424-9300(CHEMTREC)
Label Required IND: Y
Date Of Label Review: 11/11/1993
Status Code: C
Label Date: 11/11/1993
Origination Code: G
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Moderate
Fire Hazard: Severe
Reactivity Hazard: None
Hazard And Precautions: EXTREMELY FLAMMABLE. ACUTE:SKIN CONTACT:MAY CAUSE
IRRITATION OR BLISTERING. EYE:MAY CAUSE MODERATE IRRITATION, TEARING, BURNING
OR REDNESS. INHAL:OVEREXPOSURE MAY CAUSE RESPIRATORY IRRITATION OR NAUSE A.
EVEN UNCONSCIOUSNESS OR DEATH. INTENTIONAL MISUSE MAY BE HARMFUL OR FATAL.
AVOID BREATHING VAPORS. CHRONIC:CANCER HAZARD. CONTAINS STYRENE &
CRYSTALLINE SILICA WHICH ARE LISTED AS CARCINOGENS (FP N ). MAY CAUSE
PULMONARY FIBROSIS, PERMANENT LUNG DAMAGE. REPORTS HAVE ASSOCIATEDREPEATED
& PROLONGED OVEREXPOSURE TO SOLVENTS W/BRAIN & NERVOUS SYSTEM DAMAGE.
=======================================================
Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
*** END OF RECORD *** |
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