HOECHST CELANESE CORP -- HYDRANAL COULOMAT CG-34840
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Material Safety Data Sheet
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MSDS Num: BWNWD
MSDS NAME: HYDRANAL COULOMAT CG-34840
Responsible Party
Name: HOECHST CELANESE CORP
Box: 1026
City: CHARLOTTE NC 28201-1026
Info Phone: 804-484-5000
Emergency Phone Number: 800-424-9300 (CHEMTREC)
Published: Y
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Contractor Summary
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Name: CRESCENT CHEMICAL CO., INC.
Address: 1324 MOTOR PARKWAY
City: HAUPPAUGE NY 11788
Phone: (516) 348-0333
Name: HOECHST CELANESE CORP
Address: UNKNOWN
Box: 1026
City: CHARLOTTE NC 28201-1026
Phone: 800-253-2637
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Ingredients
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Cas: 67-56-1
RTECS #: PC1400000
Name: METHANOL; (METHYL ALCOHOL)(SARA 313) (CERCLA). LD50:(ORAL,RAT)5628 MG/KG
% Wt: 40
OSHA PEL: S, 200 PPM
ACGIH TLV: S,200 PPM/250 STEL
EPA Rpt Qty: 5000 LBS
DOT Rpt Qty: 5000 LBS
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Cas: 111-42-2
RTECS #: KL2975000
Name: ETHANOL, 2,2'-IMINODI-; (DIETHANOLAMINE) (SARA 313) (CERCLA)
% Wt: 1
OSHA PEL: 3 PPM
ACGIH TLV: 0.46 PPM
EPA Rpt Qty: 1 LB
DOT Rpt Qty: 1 LB
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Cas: 10034-85-2
RTECS #: MW3760000
Name: HYDRIODIC ACID
% Wt: 1
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
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Health Hazards Data
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LD50 LC50 Mixture: SEE ING 1
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: THIS PRODUCT CONTAINS METHANOL. WHEN INGESTED METHANOL
CAUSES CENTRAL NERVOUS SYSTEM EFFECTS RESEMBLING ALCOHOLIC INTOXICATION;
AFTER 6-30 HRS. VOMITING, ABDOMINAL PAIN, VISUAL DISTURBANCES, SHORTNESS OF
BREATH, DELIRIUM, UNCONSCIOUSNESS, COMA AND DEATH RESULT; INHALATION AND SKIN
ABSORPTION ARE (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: NOT RELEVANT.
Signs And Symptions Of Overexposure: HLTH HAZ:ALSO ROUTES OF EXPOSURE. SYMPTOMS
ARE SIMILAR TO ABOVE; LIVER AND IN PARTICULAR EYE DAMAGE RESULTING IN
TEMPORARY OR PERMANENT BLINDNESS ALSO OCCURS; 100 TO 100 ML OF METHANOL IS
FATAL TO HUM ANS, AS LITTLE AS 10 ML CAUSES PERMANENT BLINDNESS. CONTAINS
DIETHANOLAMINE WHICH IS MILD IRRITANT WHEN TESTED (SUPDAT)
Medical Cond Aggravated By Exposure: SKIN AND EYE CONDITIONS; LIVER AND KIDNEY
CONDITIONS, RESPIRATORY CONDITIONS.
First Aid: INHAL:CONSULT PHYS IF IRRIT OF RESP PASSAGES OCCURS. EYE:HOLD EYES
OPEN & FLUSH FOR @ LEAST 15 MINS W/LG QTYS OF WATER. SEEK MED ATTN.
SKIN:REMOVE CONTAMD CLTHG. FLUSH AFFECTED AREA W/PLENTY OF WATER. SEEK MED
ATTN. INGEST:IF PERSON IS CONSCIOUS, GIVE WATER/MILK TO DILUTE STOMACH
CONTENTS. CONSULT PHYS.
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Handling and Disposal
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Spill Release Procedures: WEARING APPROP PERSONAL PROT EQUIP, CONTAIN SPILL,
COLLECT ONTO INERT ABSORBENT. PLACE IN SUITABLE CONTAINER.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL
REGULATIONS.
Handling And Storage Precautions: OBSERVE ALL NEC PRECAUT FOR HNDLG FLAM LIQS.
KEEP AWAY FROM SOURCES OF HEAT & IGNIT. SMOKING SHOULD BE PROHIBITED
WHERE MATL IS BEING HANDLED.
Other Precautions: PROD IS ANALYTICAL REAGENT & IS COVERED BY TSCA RESEARCH
& DEVEL EXEMPTION. IT IS PROVIDED FOR USE AS ANALYTICAL REAGENT & NOT
FOR INCORPORATION INTO COMMERCIAL PROD & MUST BE USED UNDER SUPERVISION O
F A TECHNICALLY QUALIFIED INDIVIDUAL.
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Fire and Explosion Hazard Information
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Flash Point Text: 57.2F,14.0C
Lower Limits: 5.5%
Upper Limits: 26.5%
Extinguishing Media: CARBON DIOXIDE, WATER SPRAY, FOAM OR DRY CHEMICAL.
Fire Fighting Procedures: USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT (FP N).
Unusual Fire/Explosion Hazard: EMITS TOXIC AND CORROSIVE FUMES UNDER FIRE
CONDITIONS.
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Control Measures
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Respiratory Protection: IF AIRBORNE CONC POSE HLTH HAZ, BECOME IRRITATING, OR
EXCEED RECOMMENDED LIMS, USE NIOSH/MSHA APPRVD RESPIRATOR IN ACCORDANCE WITH
OSHA RESP PROT REQUIREMENTS UNDER 29 CFR 1910.134.
Ventilation: LOCAL EXHAUST VENT OR RESP PROT TO MAINTAIN EMPLOYEE EXPOS BELOW
PEL/TLV.
Protective Gloves: RUBBER GLOVES.
Eye Protection: ANSI APPROVED CHEM SAFETY GOGGLES (FP N)
Other Protective Equipment: CLOTHING SUITABLE TO PREVENT SKIN CONTACT. EYEWASH
FOUNTAIN & DELUGE SHOWER MEETING ANSI DESIGN CRITERIA (FP N).
Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health: EFTS OF OVEREXP:ON RABBIT SKIN AND SEVERE
IRRITANT WHEN TESTED ON RABBIT EYES. DIETHANOLAMINE IS SEVERE MUCOSAL
IRRITANT WHICH MIGHT LEAD TO CORROSIVE LESIONS OF MOUTH AND ESOPHAGUS.
DIETHANOLAMINE IS REPORTED TO HAVE CAUSED KIDNEY AND LIVER DAMAGE IN
ANIMALS. HYDROGEN IODIDE IS AN EYE, SKIN & MUCOUS MEMBRANE IRRITANT.
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Physical/Chemical Properties
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B.P. Text: 145F,63C
Vapor Density: 1.064
PH: 4-7
Evaporation Rate & Reference: NOT KNOWN
Solubility in Water: MISCIBLE
Appearance and Odor: YELLOWISH LIQUID WITH AN AROMATIC ODOR
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: SEE SPECIAL PRECAUTIONS.
Materials To Avoid: NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products: THERMAL DECOMP MAY GENERATE CO*2, CO & OXIDES
OF NITROGEN & SULFUR & HYDROGEN IODIDE & CHLORIDE.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT.
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Toxicological Information
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Ecological Information
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MSDS Transport Information
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Regulatory Information
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Other Information
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HAZCOM Label
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MSDS NAME: HYDRANAL COULOMAT CG-34840
Company: HOECHST CELANESE CORP
Street: UNKNOWN
PO Box: 1026
City: CHARLOTTE NC
Zipcode: 28201-1026
Health Emergency Phone: 800-424-9300 (CHEMTREC)
Label Required IND: Y
Date Of Label Review: 01/27/1995
Status Code: C
Label Date: 01/27/1995
Origination Code: G
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Moderate
Fire Hazard: Severe
Reactivity Hazard: None
Hazard And Precautions: EXTREMELY FLAMMABLE. ACUTE:THIS PRODUCT CONTAINS
METHANOL. WHEN INGESTED , INHALED/ABSORBED THRU SKIN, METHANOL CAUSES CENTRAL
NERVOUS SYSTEM EFFECTS RESEMBLING ALCOHOLIC INTOXICATION; AFTER 6-30 HRS.
VOMITING, ABDOMINAL PAIN, VISUAL DISTURBANCES, SHORTNESS OF BREATH, DELIRIUM,
UNCONSCIOUSNESS, COMA AND DEATH RESULT, LIVER & EYE DAMAGE, CAUSING
TEMPORARY/PERMANENT BLINDNESS. CHRONIC:NONE SPECIFIED BY MANUFACTURER.
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.