===================== Product Identification =====================
MSDS NAME:AMMONIUM FLUORIDE,40% SOLUTION
NIIN:00K000602
MSDS Number: BCBDQ
=== Responsible Party ===
Company:ALLIED CHEMICAL COMPANY
Address:COLUMBIA RD & PARK AVE
Box:1087R
City:MORRISTOWN
State:NJ
ZIP:07960
Country:US
CAGE:1L168
=== Contractor Identification ===
Company:ALLIED CHEMICAL COMPANY
Box:1087R
CAGE:1L168
Company:ALLIED-SIGNAL INC
Address:Box:2332R
City:MORRISTOWN
State:NJ
ZIP:07962-2332
Country:US
Phone:201-455-4414
CAGE:1L164
============= Composition/Information on Ingredients =============
Name:AMMONIUM FLUORIDE (SARA III)
CAS:12125-01-8
RTECS #:BQ6300000
Fraction by Wt: 40.0%
OSHA PEL:2.5 MG F/M3
ACGIH TLV:2.5 MG F/M3; 9192
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS
===================== Hazards Identification =====================
Effects of Overexposure:INH:CHILLS,LABORED BRTHG FEVER/COUCH;ING:MAY BE
FATAL,GASTROENTERITIS,SEV SHOCK *SEE SUPPL DATA.
======================= First Aid Measures =======================
First Aid:INH:REMOVE TO FRESH AIR IMMED.KEEP WARM/QUIET.GIVE OXYGEN IF
NEEDED.CALL MD;ING:DO NOT INDUCE VOMIT.IMMED GIVE MILK OR MILK OF
MAGNESIA.GET MED ATTN;EYES:FLUSH W/WATER FOR 15-20 MIN.GET MED
HELP;SKIN: WASH W/WATER FOR 15-20 MIN & GET MED ATTN
===================== Fire Fighting Measures =====================
Flash Point:NONE
Extinguishing Media:EXTINGUISH WITH AGENT SUITABLE FOR SURROUNDING FIRE
Fire Fighting Procedures:WEAR SELF-CNTND BRTHG APP.USE WATER TO COOL
EXPOSED CONTNTRS
Unusual Fire/Explosion Hazard:NONE NOTED BY MANUFACTURER.
================== Accidental Release Measures ==================
Spill Release Procedures:MOP OR PUMP INTO PLASTIC CONTNRS,CLOSE &
LABEL,& STORE IN COOL DRY PLACE UNTIL DISPOSAL TIME.WATER MAY BE
USE IAW FED,STATE/LOCAL REGS,TO COMPLETE CLEAN-UP TAKING CARE TO
KEEP OUT OF CONTACT W/EYES,SK IN & CLOTHING.
====================== Handling and Storage ======================
Handling and Storage Precautions:PROTECT FROM PHYSICAL DAMAGE.STORE AT
MOD TEMP IN DRY,WELL VENTLTD AREA.KEEP CAP CLOSED.AVOID CONTACT
W/EYES,SKIN & BRTHG OF MIST.USE W/ADEQ VENTILATI
Other Precautions:MEDICAL SURVEILLANC RECOMMENDED.EMPLOYEE TRNG
PROPOSED TO BE REQD.HANDLE W/THE KNOWLEDGE THAT HYDROFLUORIC ACID
IS PRESENT.DO NOT SPLASH ONTO PERSONNEL.WASH THOROUGHLY AFTER
HANDLING.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:MIST RESP FOR MIST;USE SELF-CNTND RESP
SUPPLD-AIR IF TLV >10X2.5MG/C
Ventilation:LOCAL EXHAUST:FOR MISTY COND;MECH(GEN)W/O MISTY CONDITIONS.
Protective Gloves:RUBBER
Eye Protection:CHEM SAFETY GOGG/FACESHLD
Other Protective Equipment:EYE WASH & QUICK-DRENCH SHOWER FACILITIES.
Supplemental Safety and Health
CARDIAC DISTURB.MAY CAUSE DANG.POISONING;SKIN-MAY CAUSE HF BURN,LIGHT
EXPOS TO LIQ/MIST MAY CAUSE DERMATITIS,EYE-SOLN/MIST MAY CAUSE
IRRIT OR HF BURN.INGEST-MAY CAUSE OSSEOUS FLUOROSIS.
================== Physical/Chemical Properties ==================
HCC:T6
Boiling Pt:B.P. Text:>212F,>100C
Vapor Pres:0.5
Vapor Density:2.21
Spec Gravity:1.12
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR LIQUID,ODORLESS.
Percent Volatiles by Volume:UNK
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDANT,PARTICULARLY KCLO*4 & NANO*2.
Stability Condition to Avoid:NONE KNOWN
Hazardous Decomposition Products:NH*3,H*2,F
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSAL OF 40% AMM FLUORIDE SOLN MAY BE SUBJECT
TO REGULATORY STATUTES.USERS REVIEW THEIR OPERATIONS FOR APPLICABLE
REGS,THEN CONSULT REGULATORY AGENCY BEFORE DISCHARGE/DISPOSAL OF
WASTE.DISPOSER MUS T COMPLY W/FEDERAL,STATE,LOCAL DISPOSALLAWS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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