===================== Product Identification =====================
MSDS NAME:196-008030,GENESOLV DE-35 SOLVENT
NIIN:00K000568
MSDS Number: BCBBZ
=== Responsible Party ===
Company:ALLIED CHEMICAL CO.
Address:COLUMBIA RD & PARK AVE
Box:1087R
City:MORRISTOWN
State:NJ
ZIP:07960
Country:US
CAGE:1L168
=== Contractor Identification ===
Company:ALLIED CHEMICAL COMPANY
Box:1087R
CAGE:1L168
Company:ALLIED-SIGNAL INC
Address:Box:2332R
City:MORRISTOWN
State:NJ
ZIP:07962-2332
Country:US
Phone:201-455-4414
CAGE:1L164
============= Composition/Information on Ingredients =============
Name:1,1,2-TRICHLORO-1,2,2-TRIFLUOROETHANE (FREON 113) (SARA
III)
CAS:76-13-1
RTECS #:KJ4000000
Fraction by Wt: 65.0%
OSHA PEL:1000PPM/1250STEL
ACGIH TLV:1000PPM/1250STEL9192
Ozone Depleting Chemical:1
Name:METHYL ALCOHOL (METHANOL) (SARA III)
CAS:67-56-1
RTECS #:PC1400000
Fraction by Wt: 1.35%
OSHA PEL:S,200PPM/250STEL
ACGIH TLV:S,200PPM/250STEL; 93
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:ETHYL ALCOHOL (ETHANOL)
CAS:64-17-5
RTECS #:KQ6300000
Fraction by Wt: 35.0%
OSHA PEL:1000 PPM
ACGIH TLV:1000 PPM; 9192
===================== Hazards Identification =====================
Effects of Overexposure:INH:HEAD,DIZZ,NAUSE,VOMIT;SKIN:IRRIT,MAY
DEFAT;EYES*IRRITANT,VAP MAY HAVE MILD IRRIT,POSS DAMAGE
======================= First Aid Measures =======================
First Aid:INH:REMOVE TO FRESH AIR.GIVE OXY/CPR IF REQD.DO NOT GIVE
EDRENALIN;EYES:FLUSH W/LG AMT OF WATER;SKIN:WASH W/WATER;ING:INDUCE
VOMIT BY GIVING 2-4 GLASSES OF WATER.NEVER GIVE ANYTHING BY MOUTH
TO UNCON PERSON:GET MED ATTN FOR ANY ABOVE PROBLEM.
===================== Fire Fighting Measures =====================
Flash Point:142F-147F,OC
Autoignition Temp:Autoignition Temp Text:366C
Lower Limits:3.3
Upper Limits:19.0
Extinguishing Media:CO*2,CHEM(ALCOHOL)FOAM,DRY CHEM.
Fire Fighting Procedures:SELF-CNTND BRTHG APP APPRVD BY NIOSH.COOL
CNTNR BY WATERSPRA
Unusual Fire/Explosion Hazard:PROLONG EXP TO WHITE METLS CAUSE
CORR.CONTACT W/MOLTEN AL,BA & LI SHAVINGS REACT EXOTHERMALLY
================== Accidental Release Measures ==================
Spill Release Procedures:EVACUATE AREA.USE PROTECTVE EQUIP.ELIMINATE
SOURCE OF IGN/HEAT.STOP LEAK W/O RISK.ABSORB W/ABSROBENT MATL(SUCH
AS VERMICULITE) & SHOVEL INTO METAL DRUMS & CLOSE.FOR LG SPILL,DIKE
W/ABSORB/SAND,PUMP IN TO DRUMS & CLOSE.DELAYD CLEANUP INCREASFIRE
HAZ.
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE IN COOL WELL-VENTILATED AREA OF
LOW FIRE RISK.PROTECT CONTNRS FROM PHYSICAL DAMAGE & KEEP
CLOSED.AVOID BREATNG VAP,EYE/SKIN CONTACT.KEEP FM HEAT
Other Precautions:MEDICAL SURVEILLANCE/EMPLOYEE TRAING PROPOSED.TANKS
CANNOT BE EFFECTIVLY FLUSHED OF VAP IN SUMPS CONTNG LIQ.FOLLOW TANK
ENTRY PROCEDURES IF CLEANING REQD.SEE LABEL IN PROD CONTNR.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:SELF-CNTND BRTHG APP OR SUPPLIED-AIR RESPIR
EFFECTVE TO 4500 PPM
Ventilation:MECH(GEN)FOR STORAGE LOC & LOCAL EXHAUST FOR FILLING ZONES.
Protective Gloves:PROTEC GLOVE
Eye Protection:CHEM SAFETY GOGGLES
Other Protective Equipment:COMPLETE PROTEC CLOTHING & BOOTS EYE-WASH
FACILITY
Supplemental Safety and Health
FORMULA:C*2H*50H/C*2CL*3F*3/CH*3OH.BASED IN ASSUMPTION THAT FLASH POINT
BY CLOSED CUP WILL BE LOWERED THAN OPEN CUP METHOD,THE STORAGE
COMPATIBILITY CODE F4 IS ASSIGNED.
================== Physical/Chemical Properties ==================
HCC:F4
Boiling Pt:B.P. Text:44.8C,113F
Vapor Pres:360
Vapor Density:3.0
Spec Gravity:1.16
Evaporation Rate & Reference:15 (ETHER=1)
Solubility in Water:SLIGHT
Appearance and Odor:COLORLESS LIQ W/ETHEREAL & FAINT ALCOHOL ODOR.
Percent Volatiles by Volume:100
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDANTS,REACTIVE METLS,CA,POWD AL,ZN,MG,ETC.
Stability Condition to Avoid:WILL DECOMPOSE AT TEMP ABOVE 250F.DO NOT
BOIL ABOVE 140F.
Hazardous Decomposition Products:HALOGENS,CARBONYL HALIDES,PHOSGENE,CO
& CO*2.
==================== Disposal Considerations ====================
Waste Disposal Methods:SPILL OR LEAK MATL COLLECT SHOULD BE DILUTED
W/WATER.USERS.SHOULD REVIEW FED,STATE,LOCAL REGS BEFORE
DISCHARGING/DISPOSING WASTE MATL.DISPOSER MUST COMPLY
W/FEDERAL,STATE & LOCAL REGS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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