===================== Product Identification =====================
MSDS NAME:196-008090,GENESOLV DTA AZEOTROPE
NIIN:00K000578
MSDS Number: BCBCM
=== Responsible Party ===
Company:ALLIED CHEMICAL COMPANY
Address:COLUMBIA RD & PARK AVE
Box:1087R
City:MORRISTOWN
State:NJ
ZIP:07960
Country:US
CAGE:1L168
=== Contractor Identification ===
Company:ALLIED CHEMICAL COMPANY
Box:1087R
CAGE:1L168
Company:ALLIED-SIGNAL INC
Address:Box:2332R
City:MORRISTOWN
State:NJ
ZIP:07962-2332
Country:US
Phone:201-455-4414
CAGE:1L164
============= Composition/Information on Ingredients =============
Name:METHYLENE CHLORIDE (SARA III)
CAS:75-09-2
RTECS #:PA8050000
Fraction by Wt: 41.7%
OSHA PEL:500 PPM/C,1000; Z2
ACGIH TLV:50 PPM, A2; 9192
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:1,1,2-TRICHLORO-1,2,2-TRIFLUOROETHANE (FREON 113) (SARA
III)
CAS:76-13-1
RTECS #:KJ4000000
Fraction by Wt: 55.0%
OSHA PEL:1000PPM/1250STEL
ACGIH TLV:1000PPM/1250STEL9192
Ozone Depleting Chemical:1
Name:METHYL ALCOHOL (METHANOL) (SARA III)
CAS:67-56-1
RTECS #:PC1400000
Fraction by Wt: 3.2%
OSHA PEL:S,200PPM/250STEL
ACGIH TLV:S,200PPM/250STEL; 93
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
===================== Hazards Identification =====================
Effects of Overexposure:INH:DROWS,HEAD HEAVINESS,LOSS OF
CONCENTRATION;ING:DIZZ,DROWS,IN LG DOSES FATAL RESP*SEE SUPPL DATA
======================= First Aid Measures =======================
First Aid:INH:REMOVE TO FRESH AIR.GIVE OXY/CPR IF REQD.DO NOT GIVE
EDRENALIN;EYES:FLUSH W/LG AMT OF WATER;SKIN:WASH W/WATER;ING:DO NOT
INDUCE VOMIT UNLESS DIRECTED BY MD.KEEP PATIENT QUIET/WARM;GET MED
ATTN FOR ANY OF ABOVE PROBLEM
===================== Fire Fighting Measures =====================
Flash Point:NONE
Lower Limits:UNK
Upper Limits:UNK
Extinguishing Media:WATER SPRAY
Fire Fighting Procedures:USE SELF-CNTND BRTHG APP APPRVD BY NIOSH.COOL
CONTNR W/SPRAY
Unusual Fire/Explosion Hazard:THERMAL DECOMPOSITION WILL PRODUCE
HALOGENS/CARBONYL HALIDES,PHOSGENE,CO & CO*2.
================== Accidental Release Measures ==================
Spill Release Procedures:EVACUATE AREA.USE PROTECTIVE EQUIP.ELIMINATE
SOURCE OF IGN/HEAT.STOP LEAK W/O RISK.ABSORB W/ABSORBENT MATL(SUCH
AS VERMICULITE) & SHOVEL INTO METAL DRUMS & CLOSE.FOR LG SPILL,DIKE
W/ABSORBENT/SAND,PUM P INTO DRUMS & CLOSE.STORE IN COOL LOC UNTIL
DISPO
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE IN COOL,DRY,VENTILATED
AREA.PROTECT FROM PHYSICAL DAMAGE.KEEP AWAY FM HEAT.AVOID SKIN/EYE
CONTACT.USE ONLY W/ADEQUATE VENTILATION.
Other Precautions:VENTILATE INDOOR TANK OUTDOOR.VENTILATE TRUCK HAVING
DRUMS BEFORE ENTERING.USE ONLY FORMAL TANK ENTRY.DO NOT USE HOSE OF
RUBBER/PLASTIC.PERSONNEL SHOULD HAVE TRAING & MED SURVEILLANCE.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:SELF-CNTND BRTHG APP OR SUPPLIED-AIR RESP,EITHER
W/FULL FACE-PIECE
Ventilation:MECH(GEN)FOR STORAGE LOC & LOCAL EXH FOR FILLING/DRAWING
LOC
Protective Gloves:LEATHER/IMPERVI
Eye Protection:CHEM SAFETY GOGGLES
Other Protective Equipment:NOT GENERALLY REQD.
Supplemental Safety and Health
*FAILURE MAY OCCUR;SKIN:IRRIT,DEFATTING,MAY BE ABSORBED TOXIC
AMTS;EYES:IRRIT,POSS W/SEV PAIN.SEV INJURY IS UNLIKELY.
================== Physical/Chemical Properties ==================
HCC:T4
Boiling Pt:B.P. Text:93F,34C
Vapor Pres:460
Vapor Density:5.0
Spec Gravity:1.40
Evaporation Rate & Reference:1.0 (ETHER)
Solubility in Water:SLIGHT
Appearance and Odor:COLORLESS LIQ,ETHEREAL ODOR
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRON OXIDANTS,HOT REACTV METLS AL,BA & LI SHVGS. POWDRD AL
Stability Condition to Avoid:SOURCE OF HEAT.WILL BE DECOMPOSED ABOVE
250F
Hazardous Decomposition Products:HALOGENS/CARBONYL HALIDES,PHOSGENE,CO
& CO*2.
==================== Disposal Considerations ====================
Waste Disposal Methods:PRODUCT CONTAINS HALOCARBON &
HYDROCARBON.DISPOSAL/TREATMENT OF WASTE DEPENDS ON NATURE OF WASTE
GENERATED BY USERS.REVIEW ALL FED,STATE,LOCAL REGS FOR
DISPOSAL/TREATMENT OF WASTE.DISPOSER MUST COMPLY W/FED STATE &
LOCAL DISPOSAL/DISCHARGELAWS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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