===================== Product Identification =====================
MSDS NAME:GENESOLV DE AZEOTROPE
NIIN:00K000565
MSDS Number: BCBBW
=== Responsible Party ===
Company:ALLIED CHEMICAL CORP
Emergency Phone Num:201-455-2000
CAGE:1L168
=== Contractor Identification ===
Company:ALLIED CHEMICAL COMPANY
Box:1087R
CAGE:1L168
Company:ALLIED-SIGNAL INC
Address:Box:2332R
City:MORRISTOWN
State:NJ
ZIP:07962-2332
Country:US
Phone:201-455-4414
CAGE:1L164
============= Composition/Information on Ingredients =============
Name:1,1,2-TRICHLORO-1,2,2-TRIFLUOROETHANE (FREON 113) (SARA
III)
CAS:76-13-1
RTECS #:KJ4000000
Fraction by Wt: 95.5%
OSHA PEL:1000PPM/1250STEL
ACGIH TLV:1000PPM/1250STEL9192
Ozone Depleting Chemical:1
Name:ETHYL ALCOHOL (ETHANOL)
CAS:64-17-5
RTECS #:KQ6300000
Fraction by Wt: 4.5%
OSHA PEL:1000 PPM
ACGIH TLV:1000 PPM; 9192
Name:METHYL ALCOHOL (METHANOL) (SARA III)
CAS:67-56-1
RTECS #:PC1400000
Fraction by Wt: <0.5%
OSHA PEL:S,200PPM/250STEL
ACGIH TLV:S,200PPM/250STEL; 93
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
===================== Hazards Identification =====================
Effects of Overexposure:EYES,SKIN:IRRITNT,MAY DEFAT
SKIN;INHALE,INGEST:DROWSINESS,DIZZINESS,NAUSEA,VOMIT;MAY CAUSE
ASPHYX.
======================= First Aid Measures =======================
First Aid:INHALE:REMOVE TO FRESH AIR,GIVE CPR/O*2 IF NEED.DO NOT GIVE
ADRENALINE (EPINEPHRINE);SKIN/EYES:FLUSH W/LG AMTS H*2O (FLUSH EYES
15 MIN-LIFT EYELIDS);INGEST:GIVE H*2O & INDUCE VOMITING
IMMEDIATELY.FOR INHALE,INGEST OR EYES:CALL PHYSICIAN.
===================== Fire Fighting Measures =====================
Extinguishing Media:N/R-NON-FLAMMABLE;USE H*2O SPRAY TO DIVERT FROM
FIRE & HEAT.
Fire Fighting Procedures:NIOSH/MSHA APPROV SCBA.H*2O SPRAY TO COOL
CONT,DIVERT SPILL.
Unusual Fire/Explosion Hazard:CONTACT W MOLTEN ALUMINUM,BARIUM,&
LITHIUM SHAVINGS PRODUCES RAPID EXOTHERMIC REACTIONS.
================== Accidental Release Measures ==================
Spill Release Procedures:EVACUATE UNPROTECTED PERSONS.ELIMINATE
IGNITION SOURCES.STOP LEAK.USE H*2O SPRAY TO COOL CONTAINERS/FLUSH
SPILL AWAY FROM FIRE & HEAT.PROVIDE VENTILATION. ABSORB W
COMMERCIAL ABSORBENT.SHOVEL INTO COV ERED METAL DRUMS, PENDING
DISPOSAL.
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE IN COOL,DRY,WELL VENTILATED.LOW
FIRE RISK AREA.PROTECT FROM PHYSICAL DAMAGE.AVOID ANY PHYSICAL
CONTACT.KEEP CONTAINERS TIGHTLY CLOSED.
Other Precautions:AVOID PROLONGED OR REPEATED CONTACT WITH LIQUID OR
VAPOR.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF EXPOSED > 500PPM,NIOSH/MSHA APP SCBA OR AIR
LINE RESPIR.
Ventilation:MECHANICAL(GEN./LOCAL EXHAUST)
Protective Gloves:IMPERVIOUS
Eye Protection:SAFETY/CHEM GOGGLES
Other Protective Equipment:NORMAL FULL WORK CLOTHING COVERING
ARMS,LEGS.NO CONTACT LENS
Supplemental Safety and Health
ALLIED CHEMICAL PRODUCT CODE NO.196-008040.BLEND OF
TRICHLOROTRIFLUOROETHANE,C*2CL*3F*3,95.5WT%,ETHANOL,C*2H*5OH,4.5%,A
ND METHANOL,CH*3OH,0.5% MAX WITHIN ETHANOL COMPONENT.
================== Physical/Chemical Properties ==================
HCC:N1
Boiling Pt:B.P. Text:111F,44C
Vapor Pres:365
Vapor Density:6.0
Spec Gravity:1.49
Evaporation Rate & Reference:2 (ETHER=1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:COLORLESS LIQUID GAS; FAINT ETHERAL ODOR.
Percent Volatiles by Volume:100
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDANTS,REACTIVE METALS,POWDERED AL,ZN,MG
Stability Condition to Avoid:DECOMPOSES ABOVE 250F;THERMAL
DECOMP.INCREASES TOXICITY.
Hazardous Decomposition Products:HALOGENS,CARBONYL HALIDES,INCLUDING
PHOSGENE,CO, & CO*2.
==================== Disposal Considerations ====================
Waste Disposal Methods:PRODUCT IS PRIMARILY A FLUOROCARBON, CONTAINING
NITRATED ORGANIC & KETONE. CONTACT SUPPLIER FOR DISPOSAL METHODS.
DISPOSE IN FULL REGULATORY COMPLIANCE.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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