===================== Product Identification =====================
MSDS NAME:106 SAFETY WASH
NIIN:00N002598
MSDS Number: BCJDT
=== Responsible Party ===
Company:HURST GRAPHICS INC
Address:2500 SAN FERNANDO RD
City:LOS ANGELES
State:CA
ZIP:90065-1324
Country:US
Info Phone Num:213-223-4121 / FAX 213-222-1137
Emergency Phone Num:213-223-4121
Preparer's Name:A. KORKIN/W. LOGAN
CAGE:54627
=== Contractor Identification ===
Company:HURST GRAPHICS INC
Address:2500 SAN FERNANDO RD
Box:City:LOS ANGELES
State:CA
ZIP:90065-1324
Country:US
Phone:213-223-4121
CAGE:54627
============= Composition/Information on Ingredients =============
Name:VM & P NAPHTHA
CAS:64742-48-9
Other REC Limits:300 PPM (MFR)
Name:METHANE, DICHLORO-; (METHYLENE DICHLORIDE)
CAS:75-09-2
RTECS #:PA8050000
OSHA PEL:350 PPM; 450 STEL
ACGIH TLV:350 PPM; 450 STEL
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:VOLATILE ORGANIC COMPOUNDS: 606 GM/L OR 5.05 LB/GAL
RTECS #:9999999VO
Name:SUPP DATA:FORM CARBON MONOXIDE IN THE BODY & MAY INTERFERE
W/NORM BLOOD FUNCTION UNDER HIGH EXPOS CNDTNS. (ING 5)
RTECS #:9999999ZZ
Name:ING 4:INTENTIONAL MISUSE BY INHALING PROD MAY CAUSE LIVER,
KIDNEY &/OR BRAIN DAM & OTHER HARMFUL EFTS OR MAY BE (ING 6)
RTECS #:9999999ZZ
Name:ING 5:FATAL. RPTS HAVE ASSOC RPTD/PRLNGD OCCUP OVEREXPOS TO
SOLV W/PERM BRAIN & NERV SYS DAM (SOMETIMES REFERRED (ING 7)
RTECS #:9999999ZZ
Name:ING 6:TO AS SOLVENT OR PAINTER'S SYNDROME.
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:CHLOROCARBON MATLS HAVE PRDCED SENSIT
OF MYOCARDIUM TO EPINEPHRINE IN LAB ANIMALS & COULD HAVE SIMILAR
EFT IN HUMANS. ADRENOMIMETICS (E.G. EPINEPHRINE) MAY BE
CONTRAINDICATED EXCEPT FOR LIFE-SUSTAININ G USES IN HUMANS
ACUTELY/CHRONICALLY EXPOSED TO CHLOROCARBONS . ACUTE:SLEEPINESS;
SKIN/EYE/RESP (EFTS OF OVEREXP)
Explanation of Carcinogenicity:DICHLOROMETHANE: GRP 2B IARC, VOL 7,
P.194, 1987; ANTIC TO BE CARCIN, NTP 6TH ANNUAL RPT ON CARCINOGENS,
1991.
Effects of Overexposure:HLTH HAZ:TRACT IRRIT; DEFATTING OF TISS ON
PRLNGD CONT; MILD CNS DEPRESS. CHRONIC: CUMULATIVE EXPOS TARGET
ORGANS ARE LIVER/KIDNEYS/RESP SYS. SIGNS/SYMPS OF OVEREXPOS:
INHAL:UNUSUAL FATIGUE/LT HEAD/IR RIT OF NOSE & THROAT.
SKIN/EYES:IRRIT. NUMBNESS/TINGLING OF LIMBS & IRRIT IF ABSORBED
THRU SKIN. INGEST:NAUS. (SUP DAT)
Medical Cond Aggravated by Exposure:PRE-EXISTING LIVER &/OR KIDNEY
DISORDERS MAY BE AGGRAVATED BY EXPOSURE TO THIS MATERIAL. PRIOR
HISTORY OF CHRONIC RESPIRATORY & SKIN DISEASE.
======================= First Aid Measures =======================
Eyes:FLUSH IMMEDIATELY W/WATER FOR AT LEAST 15 MINS.
SKIN:WASH PROMPTLY W/SOAP & WATER. INHAL:REMOVE FROM EXPOSURE TO
FRESH AIR. APPLY ARTIFICIAL RESPIRATION IF NECESSARY. INGEST:SEEK
MEDICAL ADVICE. DO NOT GIVE COUNTER AGENTS OR INDUCE VOMITING.
NOTE TO MD:IF SIGNS OF CENTRAL NERVOUS SYSTEM DEPRESSION OCCUR,
OBTAIN BLOOD GLUCOSE & COMPLETE NEUROLOGICAL EXAMINATION.
===================== Fire Fighting Measures =====================
Flash Point:>54F,>12C
Extinguishing Media:CARBON DIOXIDE, FOAM OR DRY CHEMICAL.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD PRESS DEMAND SCBA &
FULL PROT EQUIP . USE WATER SPRAY TO KEEP CONTR COOL. SOLV VAPS
EXPOSED TO OPEN FLAMES CAN BECOME (SUP DAT)
Unusual Fire/Explosion Hazard:THERMAL DECOMPOS PRODS MAY INCL HCL &
PHOSGENE . KEEP WORK AREAS FREE OF HOT METAL & OTHER SOURCES OF
IGNIT. BLENDS CONTAINING CHLORINATED PRODS (SUP DAT)
================== Accidental Release Measures ==================
Spill Release Procedures:ELIMINATE IGNITION SOURCES. CONTAIN SPILLS FOR
SALVAGE OR DISPOSAL. MINIMIZE DILUTION WATER TO CONTROL SPILL
VOLUME. AVOID RUN-OFF INTO SEWERS & DITCHES.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE IN ORIGINAL CONTRS IN A COOL
LOCATION, SAFE FROM PHYSICAL DAMAGE, W/CONTRS TIGHTLY CLOSED. DO
NOT REUSE CONTRS.
Other Precautions:NO SMOKING IN AREA OF USE. DO NOT USE IN GEN VICINITY
OF ARC WELDING, OPEN FLAMES OR HOT SURF. HEAT &/OR UV RADIA MAY
CAUSE FORMATION OF HCL &/OR PHOSGENE . TRAIN ALL EMPLOYEES ON SPEC
HNDLNG PR OCEDURES PRIOR TO WORKING W/PROD.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IN WORKING ATMOSPHERE WHERE TLV/PEL LEVELS ARE
EXCEEDED, USE NIOSH/MSHA APPROVED SUPPLIED-AIR RESPIRATOR. DO NOT
EXCEED 50 PPM W/OUT FURTHER ENGINEERING CONTROLS.
Ventilation:VENTILATION IS ESSENTIAL FOR MAINTAINING A SAFE LEVEL OF
VAPOR CONCENTRATION. FLOOR LEVEL VENTILATION IS PREFERRED.
Protective Gloves:VITON OR SOLVENT RESISTANT GLOVES.
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:PRACTICE PERSONAL CLEANLINESS BY PROMPT REMOVAL
OF LIQ IN CONT W/SKIN. REMOVE NON-IMPERVIOUS CLTHG THAT BECOMES
WET.
Supplemental Safety and Health
FIRE FIGHT PROC:COMBUST UNDER CERTAIN CNDTNS-THEN USE FOAM, DRY CHEM OR
CARBON DIOXIDE TO EXTING. EXPLO HAZ:MAY EXHIBIT REDUCED FLASH AS
THE MORE VOLATILE CHLORINATE EVAPORATES. EFTS OF OVEREXP:COMMEN T:
PROD CONTAINS INGREDS WHICH HAVE BEEN ASSOC W/CHROMOSOME
ALTERATIONS & MUTAGENICITY IN LAB TESTS. SOME (ING 4)
================== Physical/Chemical Properties ==================
HCC:F3
Boiling Pt:B.P. Text:103F,39C
Vapor Pres:90 @ 20C
Vapor Density:>1
Spec Gravity:0.86
Evaporation Rate & Reference:4 (BUTYL ACETATE=1)
Solubility in Water:<1%
Appearance and Odor:CLEAR BLUE LIQUID W/MILD, PLEASANT ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:CARBON DIOXIDE & CARBON MONOXIDE
GASES, HYDROGEN CHLORIDE & PHOSGENE GASES.
==================== Disposal Considerations ====================
Waste Disposal Methods:CONSULT FEDERAL, STATE & LOCAL REGULATIONS
CONTROLLING PROPER DISPOSAL OF CHLOROHYDROCARBON CONTAINING
MATERIALS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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