===================== Product Identification =====================
MSDS NAME:CARBON DIOXIDE,DRY ICE (SOLID ONLY)
NIIN:00-288-7219
MSDS Number: CBRYQ
=== Responsible Party ===
Company:AIR PRODUCTS AND CHEMICALS INC.
Address:7201 HAMILTON BLVD
Box:538
City:ALLENTOWN
State:PA
ZIP:18195-1501
Country:US
Info Phone Num:215-481-4911
Emergency Phone Num:800-623-9374
CAGE:00742
=== Contractor Identification ===
Company:AIR PRODUCTS AND CHEMICALS INC
Address:7201 HAMILTON BLVD
Box:City:ALLENTOWN
State:PA
ZIP:18195-1501
Country:US
Phone:800-345-3148/ 800-752-1597
CAGE:00742
Company:BADGER FIRE PROTECTION INC
Address:4261 SEMINOLE TRAIL
Box:City:CHARLOTTESVILLE
State:VA
ZIP:22901
Country:US
Phone:804-973-4361
CAGE:6L214
Company:BADGER POWHATAN
Address:ROUTE 29 NORTH
Box:7146
City:CHARLOTTESVILLE
State:VA
ZIP:22906
Country:US
Phone:804-973-4361
CAGE:0FYK7
============= Composition/Information on Ingredients =============
Name:CARBON DIOXIDE
CAS:124-38-9
RTECS #:FF6400000
Other REC Limits:NONE RECOMMENDED
OSHA PEL:5000 PPM
ACGIH TLV:5000PPM/30000STEL;96
===================== Hazards Identification =====================
LD50 LC50 Mixture:TLV=5000PPM(TLV-STEL)-15000PPM,1.5%BYVOL
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:CARBON DIOXIDE DOESN'T SUPPORT
LIFE.MAY PRODUCE IMMED HAZ ATMS.@CONC >1.5% MAY PRODUCE
HYPERVENTILLATION,HEAD,VISUAL DISTURB,TREMOR,LOSS OF
CONSC,DEATH.CONC >10% UNCONSC CAN OCCUR W/O WARNING,PREVENTI NG
SELF-RESCUE.@MUCH HIGHER CONC DISPLACES OXY IN AIR BELOW LEVELS
NECESSARY TO SUPPORT LIFE.CO2 MINOR BUT (SUPPLEMENTA)
Effects of Overexposure:CONC 3-6%-HEADACHES, DYSPNEA,
PERSPIRATION.6-10%-HEADACHES, DYSPNEA, PERSPIRATION, TREMORS,
VISUAL DISTRUBANCE, UNCONSC. OVER 10%-UNCONSC.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:PERSONS SUFFERING FROM TOXIC EFFECT OF CO2 SHOULD BE MOVED TO
AREAS W/NORMAL ATM.SCBA MAY BE NECESSARY TO PREVENT TOXIC
EXPO/ASPHYXIATION OF RESCUE WORKERS.ASSISTED RESP/SUPPLEMEN OXY
SHOULD BE GIVEN IF NOT BREATHING.FROZEN TISSUES SHOULD BE
FLOODED/SOAKED W/TEPID WATER(105-115F).DON'T USE HOT
WATER.CRYOGENIC BURNS RESULT IN BLISTER/DEEPER TISSUE FREEZING
SHOULD BE SEEN PROMPTLY BY PHYSICIAN.
===================== Fire Fighting Measures =====================
Flash Point:NA
Autoignition Temp:Autoignition Temp Text:NA
Lower Limits:NA
Upper Limits:NA
Extinguishing Media:CARBON DIOXIDE IS AN EXTINGUISHING AGENT FOR CLASS
B & C FIRES.
================== Accidental Release Measures ==================
Spill Release Procedures:SM QUANT VAPORIZE LEAVING CO2 SNOW(COMBINATION
OF DRY ICE/WATER ICE WHERE ATM MOISTURE PRESENT).VENTI INDOOR AREAS
WELL.VENTI WELL/AVOID CONTACT W/COLD VAP/DRY ICE.CO2 HEAVY GAS &
WILL REMAIN LOW SPOT S W/O ASSIST VENTI.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:PREVENT SKIN CONTACT/ENTRAPMENT OF LIQ
IN CLSD SYS.STORE/USE LIQ CNTNR/CYL IN WELL VENTI AREA.CYL CONTAIN
GAS/LIQ CO2 @EXTREMELY HI PRESS/HNDL W/CARE.
Other Precautions:NEVER USE DIRECT FLAME TO HEAT CYL.USE CHECK
VAL-PREVENTS BACKFLOW INTO STORAGE CNTNR.AVOID DRAG/ROLL/SLIDE
CYL;USE SUITABLE HAND TRUCK.KEEP AWAY FROM HEAT SOURCES.DON'T STORE
IN HEAVY TRAFFIC AREAS.A VOID EXPO TO SALT/OTHER CORR CHEM.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:SELF-CONTAINED BREATHING APPARATUS IN
OXYGEN-DEFICIENT ATM OR WEHRE CARBON DIOXIDE EXCEEDS
1.5%.CAUTION!RESPIRATORS WILL NOT FUNCTION.USE MAY RESULT IN
ASPHYXIATION.
Ventilation:NAT/MECH:GAS/VAP PRESENT.LOC:@PT SOURCES OF CO2
VAP.MECH(GEN):LOW LYING AREA NOT VENT.VENT SITUATED TO
AVOID(WORKHYGPRA)
Protective Gloves:LOOSE FITTING/IMPERMEABLE(LEATHER)GLOVES
Eye Protection:SAFETY GLASSES.
Other Protective Equipment:NONE.
Work Hygienic Practices:VENTI:HIGHER THAN NORMAL CONC OF CO2 IN
WORKAREA.REF:COMPRESSED GAS ASSOC PAMPHLET P-1 ADDN STORAGE
RECOMMENDATIONS.
Supplemental Safety and Health
APPEARANCE:IF PRESSURE SUDDENLY RELIEVED LIQ RAPIDLY COOLS AS IT
EVAPORATES & SUBLIMES FORMING DRY ICE @-109.3F. HEALTH
HAZ:IMPORTANT CONSTITUENT OF STM AVG ABOUT 0.03% OR 300 PPM BY
VOL.@HIGHER CONC AFFECTS RESP RATE. DISPO:VENT TO ATM SLOWLY
PREVENTING RAPID DEPRESSUREIZATION RESULTING IN SOLID CO2 FORM
LONGER TO VAP
================== Physical/Chemical Properties ==================
HCC:G3
Boiling Pt:B.P. Text:-109F,-78C
Melt/Freeze Pt:M.P/F.P Text:-70F,-57C
Decomp Temp:Decomp Text:NP
Vapor Pres:831PSIA
Vapor Density:0.115
Spec Gravity:1.53 @68F,1ATM
pH:NP
Viscosity:NP
Evaporation Rate & Reference:NP
Solubility in Water:87.8% @1ATM & 68F.
Appearance and Odor:COLORLESS,ODORLESS GAS OR LIQUID.STORED IN CNTNR
UNDER OWN VAP PRESSURE(SUPPLEM
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
IF MOISTURE IS PRESENT MATLS MUST RESIST CARBONIC ACID.
Stability Condition to Avoid:NONE.
Hazardous Decomposition Products:NONE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DON'T ATTEMPT TO DISPO OF RESIDUE IN COMPRESSED
GAS CYL.RETURN TO AIR PROD W/RESIDUAL PRESSURE/CYL VALVE TIGHTLY
CLSD/VALVE CAP ON.DISPO BULK QUANT FROM REFRIG STORAGE TK DISPO
OUTSIDE IN WELL VENTI L OCATION AWAY FROM WORKAREA,VAP CAN
DISPERSE(SUPPL)
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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