=====================  Product Identification  =====================

MSDS NAME:SULFURIC ACID 93%
NIIN:00-368-7991
MSDS Number: CBRZC
=== Responsible Party ===
Company:ASHLAND CHEMICAL CO   IC AND S DIV
Address:5200 BLAZER PKY
City:DUBLIN
State:OH
ZIP:43017
Country:US
Info Phone Num:614-889-3844
Emergency Phone Num:614-889-3844
CAGE:5A188
=== Contractor Identification ===
Company:ASHLAND CHEMICAL CO
Address:5200 PAUL BLAZEL MEMORIAL PARKWAY
Box:City:DUBLIN
State:OH
ZIP:43017
Country:US
Phone:614-889-4505
CAGE:5A188

=============  Composition/Information on Ingredients  =============

Name:SULFURIC ACID (SARA 302/313) (CERCLA)
CAS:7664-93-9
RTECS #:WS5600000
Fraction by Wt: 93%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:1 MG/M3
ACGIH TLV:1 MG/M3/3 STEL; 9596
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS

Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Fraction by Wt: 4.8-9%
Other REC Limits:NONE RECOMMENDED

=====================  Hazards Identification  =====================

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES  Skin:YES  Ingestion:NO
Reports of Carcinogenicity:NTP:NO    IARC:YES	 OSHA:NO
Health Hazards Acute and Chronic:INHALATION OF VAPOR/MIST MAY CAUSE
    SEVERE IRRITATION & BURNS TO NOSE,THROAT & RESPIRATORY
    TRACT.INGESTION MAY BE FATAL OR HARMFUL;CAUSES SEVERE STOMACH &
    INTESTINAL IRRITATION.EXPOSURE MAY CAUSE IRREV ERSIBLE DAMAGE TO
    SKIN & EYES.PROLONGEDEXPOSURE TO STRONG-INORGANIC MISTS OF SULFURIC
    ACID MAY CAUSE CANCER.
Explanation of Carcinogenicity:IARC LISTS STRONG-INORGANIC-ACXID MISTS
    CONTAINING SULFURIC ACID AS A SUSPECTED (2A) CARCINOGEN.
Effects of Overexposure:INHALED-SEVERE IRRITATION & BURNS TO
    NOSE,THROAT,RESPIRATORY
    TRACT.EYES-STINGING,TEARING,REDNESS,SWELLING,CORNEAL
    DAMAGE,BLINDNESS.SKIN-REDNESS,SWELLING,BURNS,SEVERE SKIN
    DAMAGE.INGESTED-NAUSEA,VOMITI NG,DIARRHEA,ABDOMINAL PAIN,VOMITING
    OF BLOOD,BURNS/TISSUE DESTRUCTION IN MOUTH/THROAT/DIGESTIVE
    TRACT,LOW BLOOD PRESSURE
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

=======================  First Aid Measures  =======================

First Aid:EYES-IMMEDIATELY FLUSH WITH WATER FOR 15 MINUTES, HOLD LIDS
    APART. SEEK MEDICAL ATTN. SKIN-REMOVE CONTAMINATED CLOTHES. FLUSH
    WITH LOTS OF WATER. SEEK MEDICAL ATTN. INHALED-REMOVE TO FRESH AIR.
    ADMINI STER OXYGEN OR ARTIFICIAL RESPIRATION AS NEEDED. SEEK
    MEDICAL ATTN. INGESTED-DO NOT INDUCE VOMITING! SEEK IMMEDIATE
    MEDICAL ATTN. IF CONSCIOUS, RINSE MOUTH & GIVE WATER OR MILK TO
    DRINK.

=====================  Fire Fighting Measures  =====================

Extinguishing Media:DRY CHEMICAL.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND
    FULL FIRE FIGHTER'S PROTECTIVE GEAR/CHEMICAL PROTECTIVE GEAR. USE
    WATER TO COOL FIRE EXPOSED CONTAINERS.
Unusual Fire/Explosion Hazard:NEVER USE WELDING OR CUTTING TORCH ON OR
    NEAR DRUM (EVEN EMPTY) BECAUSE PRODUCT (EVEN RESIDUE) CAN IGNITE
    EXPLOSIVELY.

==================  Accidental Release Measures  ==================

Spill Release Procedures:COVER WITH SODIUM BICARBONATE OR SODA
    ASH/FLAKED LIME MIXTURE (50-50). MIX AND ADD WATER IF NEEDED. SCOOP
    UP SLURRY AND WASH SITE WITH SODA ASH SOLUTION. PROPER MIXING
    PROCEDURES ARE ESSENTIAL. ONLY T RAINED PERSONNEL SHOULD PERFORM
    THIS TASK.
Neutralizing Agent:SODIUM BICARBONATE OR SODA ASH/FLAKED LIME MIXTURE.

======================	Handling and Storage  ======================

Handling and Storage Precautions:STORE IN A COOL, DRY PLACE AWAY FROM
    INCOMPATIBLE MATERIALS.
Other Precautions:CONTAINERS OF THIS PRODUCT MAY BE HAZARDOUS WHEN
    EMPTIED. SINCE EMPTYS MAY CONTAIN RESIDUE, ALL HAZARD PRECAUTIONS
    MUST BE OBSERVED. ADDITION OF WATER RELEASES HEAT WHICH CAN CAUSE
    VIOLENT BOILING & S PUTTERING. ADD SLOWLY & IN SMALL AMOUNTS

=============  Exposure Controls/Personal Protection  =============

Respiratory Protection:IF ENGINEERING CONTROLS FAIL OR NON-ROUTINE USE
    OR AN EMERGENCY OCCURS; WEAR AN MSHA/NIOSH APPROVED RESPIRATOR WITH
    ACID MIST CARTRIDGE OR AN AIR-SUPPLIED RESPIRATOR OR SCBA, AS
    REQUIRED. USE IAW 29 C FR 1910.134.
Ventilation:USE ADEQUATE MECHANICAL VENTILATION OR LOCAL EXHAUST TO
    MAINTAIN EXPOSURE BELOW TLV(S).
Protective Gloves:NEOPRENE, PVC.
Eye Protection:SAFETY GLASSES/CHEMICAL SPLASH GOGGLES.
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER. DLA-HMIS:
    EYE WASH STATION & SAFETY SHOWER AVAILABLE.
Work Hygienic Practices:WASH HANDS AFTER HANDLING AND BEFORE EATING,
    DRINKING, OR SMOKING. LAUNDER CONTAMINATED CLOTHES BEFORE REUSE.
Supplemental Safety and Health
MSDS PRESENTED BY CAGE 5A188 FOR CONTRACT NUMBER SP0450-96-ML905.

==================  Physical/Chemical Properties  ==================

HCC:C1
Boiling Pt:B.P. Text:212F,100C
Vapor Pres:17.5
Spec Gravity:1.837
Evaporation Rate & Reference:<1 (ETHYL ETHER=1)
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR & SYRUPY LIQUID.
Percent Volatiles by Volume:5-10

=================  Stability and Reactivity Data  =================

Stability Indicator/Materials to Avoid:YES
STRONG ALKALIS, METALS (RELEASES FLAMMABLE/EXPLOSIVE HYDROGEN GAS).
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:ACID VAPORS.
Conditions to Avoid Polymerization:PRODUCT WILL NOT UNDERGO HAZARDOUS
    POLYMERIZATION.

====================  Disposal Considerations  ====================

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND
    FEDERAL ENVIRONMENTAL REGULATIONS.

 Disclaimer (provided with this information by the compiling agencies):
 This information is formulated for use by elements of the Department
 of Defense.  The United States of America in no manner whatsoever,
 expressly or implied, warrants this information to be accurate and
 disclaims all liability for its use.  Any person utilizing this
 document should seek competent professional advice to verify and
 assume responsibility for the suitability of this information to their
 particular situation.

*** END OF RECORD ***