===================== Product Identification =====================
MSDS NAME:LEAD/ACID BATTERY
NIIN:00-538-9986
MSDS Number: CBRZS
=== Responsible Party ===
Company:STANDARD INDUSTRIES
Address:NELSON RD AT RELIABLE DR
Box:27500
City:SAN ANTONIO
State:TX
ZIP:78227-0500
Country:US
Preparer's Name:H.P. BLANK
CAGE:32571
=== Contractor Identification ===
Company:STANDARD INDUSTRIES
Address:NELSON RD AT RELIABLE DR
Box:27500
City:SAN ANTONIO
State:TX
ZIP:78227-0500
Country:US
CAGE:32571
============= Composition/Information on Ingredients =============
Name:LEAD (SARA 313) (CERCLA) (GRID SPONGE LEAD)
CAS:7439-92-1
RTECS #:OF7525000
Fraction by Wt: NA
Other REC Limits:NONE RECOMMENDED
OSHA PEL:SEE 1910.1025
ACGIH TLV:0.05MG/M3, A3; 9596
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Name:LEAD SULFATE (SARA 313) (CERCLA) (ANGLISTE)
CAS:7446-14-2
RTECS #:OG4375000
Fraction by Wt: NA
Other REC Limits:NONE RECOMMENDED
OSHA PEL:SEE 1910.1025
ACGIH TLV:0.15 MG(PB)/M3; 9596
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS
Name:SULFURIC ACID (SARA 302/313) (CERCLA) (10-30%) (BATTERY
ACID)
CAS:7664-93-9
RTECS #:WS5600000
Fraction by Wt: NA
Other REC Limits:NONE RECOMMENDED
OSHA PEL:1 MG/M3
ACGIH TLV:1 MG/M3/3 STEL; 9596
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:LEAD OXIDE (LEAD PEROXIDE)
CAS:1309-60-0
RTECS #:OG0700000
Fraction by Wt: NA
Other REC Limits:NONE RECOMMENDED
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACID SPILLAGE FROM BATT IN CONFINED
AREAS MAY LEAD TO OVEREXPO FROM SULFURIC ACID MIST INHAL.SULFURIC
ACID MAY CAUSE IRRITATIVE CONTACT DERM.SKIN ABSORPTION NOT
SIGNIFICANT ROUTE OF ENTRY.SULFURIC ACI D MIST/LIQ CAN IRRIT
EYES.HANDS CONTAMIN BY CONTACT W/INTERNAL BATT COMPONENETS CAN
CAUSE INGEST OF LEAD/LEAD (SUPPLE)
Explanation of Carcinogenicity:PER MSDS:MATL/COMPO HAVE BEEN TESTED FOR
ABILITY TO CAUSE CANCER;RESULTS LISTED BY IARC.THERE'S INSUFF
EVIDENCE TO (SUP)
Effects of Overexposure:ACUTE:GI UPSET-LOSS OF APPETITE,DIARR &/OR
CONSTIPATION W/CRAMPING,DIFFI IN SLEEPING,FTG.ACID:SKIN
IRRIT,CORNEAL DMG OF EYE,MUC MEMB OF EYE/UPPER RESP SYS INCLUDING
LUNGS IRRIT.CHRONIC:PB/PB CMPDS:ANE MIA,KIDNEY/CNS DMG,REPRODUCT
SYS DMG,AFFECT DEVELOPING FETUSES,SCARRING OF CORNEA,CHRONIC
BRONCHITIS,TOOTH EROSION.
Medical Cond Aggravated by Exposure:INORGANIC LEAD & ITS CMPDS CAN
AGGRAVATE CHRONIC FORMS OF KIDNEY, LIVER, & NEUROLOGIC DISEASES.
CONTACT OF SULFURIC ACID W/SKIN MAY AGGRAVATE SKIN DISEASES SUCH AS
ECZEMA & CONTACT DERMATITS.
======================= First Aid Measures =======================
First Aid:INHAL:REMOVE FROM EXPO.CONSULT PHYSICIAN IF ANY OF ACUTE
EFFECTS LISTED ABOVE DEVELOP.SKIN:WASH THOROUGHLY W/SOAP/WATER.ACID
SPLASHED ON CLOTH REMOVE;ON SHOES REMOVE IMMED.EYE:IMMED RINSE
W/COOL RUNNI NG WATER FOR @LEASAT 15MINS.SEEK MED ATTN AFT
RINSING.INGEST:LEAD/LEAD CMPDS:CONSULT PHYSICIAN.SULFURIC ACID:DO
NTO INDUCE VOMIT.REFER TO PHYSICIAN IMMED.
===================== Fire Fighting Measures =====================
Flash Point:NA
Autoignition Temp:Autoignition Temp Text:NP
Lower Limits:NA
Upper Limits:NA
Extinguishing Media:DRY CHEMICAL, FOAM, CO2.
Fire Fighting Procedures:USE POSITIVE PRESSURE, SELF-CONTAINED
BREATHING APPARATUS.
Unusual Fire/Explosion Hazard:HYDROGEN/OXY GASES PRODUCED IN CELL
DURING NORMAL BATT OPERATION.THESE GASES ENTER AIR THRU VENT
CAPS.TO AVOID CHANCE OF FIRE/EXPLO KEEP SPARKS/IGN SOURCES AWAY
================== Accidental Release Measures ==================
Spill Release Procedures:REMOVE CONBUST MATL/IGN SOURCES.CONTAIN/DIKE
W/SODA ASH(SODIUM CARBONATE)/QUICKLIME(CALCIUM OXIDE).COVER
W/EITHER CHEM.MIX WELL.MAKE CERTAIN MIX IS NEUTRA.COLLECT
RESIDUE;PLACE IN DR/SUITABLE CNTNR;DI SPO AS HAZ WASTE.WEAR ACID
RESIST BOOT,CHEM (SUPP)
Neutralizing Agent:SODA ASH (SODIUM CARBONATE) OR QUICKLIME (CALCIUM
OXIDE).
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE LEAD/ACID BATT W/ADEQUATE
VENTILATION.MAKE CERTAIN VENT CAPS ARE ON TIGHTLY.PLACE MIN OF
2LAYERS OF CORRUGATED CARDBOARD BETWEEN LAYERS OF BATT.
Other Precautions:STACK IN TRAILER STACK NO MORE THAN 3 LAYERS HIGH.USE
BATT CARRIER TO LIFT BATT/PLACE HANDS @OPPOSITE CORNERS TO AVOID
SPILLING ACID THRU VENTS.AVOID CONTACT W/INTERN BATT COMPO.STORAGE
AREA W/DRAIN-C APTURE CAPACITY/SAF SHOWER/EYEWASH.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE REQUIRED.
Ventilation:NONE SPECIFIED BY MANUFACTURER.
Protective Gloves:VINYL COATED,PVC,GAUNTLET TYP W/ROUGH FI
Eye Protection:CHEM SPLASH GOGG,FCSHIELD W/SAF GLASSES.
Other Protective Equipment:SAF SHOES WORN W/RUBB/NEOPRENE
BOOTS/STEEL-LAD RUBB/NEOPRENE BOOTS WORN OVER SOCKS.EYEWASH
FOUNT,SAF SHOWER.
Work Hygienic Practices:DON'T WEAR CONTAMIN CLOTH AGAIN TIL CLEANED;ON
SHOES DISCARD-ACID CAN'T BE REMOVED FROM LEATHER.
Supplemental Safety and Health
INCOMPAT:MATLS,CHLORATES,NITRATES,PICRATES,FULMINATES. HEALTH HAZ:CMPDS
IF HANDS NOT WASHED PRIOR TO EAT/DRINK/SMOKE. CANC:LEAD CAN/CAN'T
CAUSE CANCER. SPILL:SPLASH GOGG,FCSHIELD,ACID RESIST GLOVES.DO N'T
RELEASE UNNEUTRALIZED ACID.
================== Physical/Chemical Properties ==================
HCC:C1
Boiling Pt:B.P. Text:NA
Melt/Freeze Pt:M.P/F.P Text:NA
Decomp Temp:Decomp Text:NP
Vapor Pres:NA
Vapor Density:NA
Spec Gravity:NA
pH:NP
Viscosity:NP
Evaporation Rate & Reference:NA
Solubility in Water:NA
Appearance and Odor:OBJ-TRANSPARENT-OPAQUE CASE,SEALED COVER W/SIDE/TOP
TERMINALS,VENT CAP,ODORLESS
Percent Volatiles by Volume:NA
Corrosion Rate:NP
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
PB/PB CMPDS:K,CARBIDES,SULFIDES,PEROXIDES,P,S.SULFURIC ACID:COMBUST
MATLS,STRONG REDUCING AGENTS,MOST METALS,ORG (SUPPL)
Stability Condition to Avoid:SPARKS & OTHER SOURCES OF IGNITION.
Hazardous Decomposition Products:PB/PB CMPDS:OXIDES OF LEAD & SULFUR.
SUFLURIC ACID:HYDROGEN, SULFER DIOXIDES, SULFUR TRIOXIDE.
==================== Disposal Considerations ====================
Waste Disposal Methods:ACID:NEUTRALIZE AS ABOVE FOR SPILL;COLLECT
RESIDUE;PLACE IN DRM/SUITABLE CNTNR.DISPO OF HAZ WASTE.DO NTO FLUSH
LEAD CONTAMIN ACID TO SEWER.BATT:SEND TO LEAD SMELTER FOR
RECLAMATION FOLLOWING APPLICABL E FED/STATE/LOC REGS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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