===================== Product Identification =====================
MSDS NAME:ROLMARK ROLLER STENCIL INK, ALL COLORS, 014521
NIIN:00N016731
MSDS Number: CBVRC
=== Responsible Party ===
Company:MARSH CO
Address:707 EAST B ST
City:BELLEVILLE
State:IL
ZIP:62222
Country:US
Info Phone Num:618-234-1122
Emergency Phone Num:800-535-5053; 708-918-1900
CAGE:GO822
=== Contractor Identification ===
Company:MARSH CO
Address:707-EAST B STREET
Box:388
City:BELLEVILLE
State:IL
ZIP:62222
Country:US
Phone:618-234-1122
CAGE:GO822
Company:MARSH COMPANY
Address:707 EAST B STREET
Box:388
City:BELLEVILLE
State:IL
ZIP:62222
Country:US
Phone:618-234-1122
CAGE:0MBZ9
============= Composition/Information on Ingredients =============
Name:2-PENTANONE, 4-HYDROXY-4-METHYL-;
(4-HYDROXY-4-METHYL-2-PENTANONE). LD50: 4000 MG/KG.
CAS:123-42-2
RTECS #:SA9100000
Fraction by Wt: 40-70%
OSHA PEL:50 PPM
ACGIH TLV:50 PPM
Name:PROPANOL, OXYBIS-; (DIPROPYLENE GLYCOL). LD50: 15 G/KG.
CAS:110-98-5
RTECS #:UB8785000
Fraction by Wt: 1-5%
OSHA PEL:N/K
ACGIH TLV:N/K
Name:DIETHYLENE GLYCOL. LD50: 14.8 G/KG.
CAS:111-46-6
RTECS #:ID5950000
Fraction by Wt: 1-5%
OSHA PEL:N/K
ACGIH TLV:N/K
Name:ETHANOL, 2-(2-ETHOXYETHOXY)-; (DIETHYLENE GLYCOL MONOETHYL
ETHER). LD50: 8.6 G/KG.
CAS:111-90-0
RTECS #:KK8750000
Fraction by Wt: 7-13%
OSHA PEL:N/K
ACGIH TLV:N/K
Name:GLYCOL ETHER
OSHA PEL:N/K
ACGIH TLV:N/K
Name:BARIUM COMPOUNDS. %: GREEN <0.7%; ORANGE <1.2%; RED <0.08%;
YELLOW <1.5%.
Fraction by Wt: <1.5%
OSHA PEL:N/K
ACGIH TLV:N/K
Name:BISMUTH; (BI)
CAS:7440-69-9
RTECS #:EB2600000
OSHA PEL:N/K
ACGIH TLV:N/K
Name:GALLIUM; (GA)
CAS:7440-55-3
RTECS #:LW8600000
OSHA PEL:N/K
ACGIH TLV:N/K
Name:INDIUM; (IN)
CAS:7440-74-6
RTECS #:NL1050000
OSHA PEL:0.1 MG/M3
ACGIH TLV:0.1 MG/M3
Name:TIN; (SN)
CAS:7440-31-5
RTECS #:XP7320000
OSHA PEL:2 MG/M3
ACGIH TLV:2 MG/M3
Name:COPPER; (CU) (SARA 313) (CERCLA). %: BRIGHT BLUE & GREEN
<0.3%.
CAS:7440-50-8
RTECS #:GL5325000
Fraction by Wt: <0.3%
OSHA PEL:0.1MG/M3 FUME;1 DUST
ACGIH TLV:0.2 MG/M3 FUME
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:BARIUM; (BA) (SARA 313). %: GREEN & ORANGE <0.04%; RED
<0.004%; YELLOW <0.08%.
CAS:7440-39-3
RTECS #:CQ8370000
Fraction by Wt: <0.08%
OSHA PEL:0.5 MG/M3
ACGIH TLV:N/K
Name:INGREDIENTS 14 -17 HAVE NOT BEEN INTENTIONALLY INTRODUCED &
THE SUM OF ANY INCIDENTAL PRESENCE IS <100 PPM BY WEIGHT.
RTECS #:9999999ZZ
OSHA PEL:N/K
ACGIH TLV:N/K
Name:CADMIUM; (CD) (SARA 313) (CERCLA). %: <100 PPM BY WT.
CAS:7440-43-9
RTECS #:EU9800000
Fraction by Wt: <0.1%
OSHA PEL:0.2 MG/M3 DUST
ACGIH TLV:0.01 MG/M3 DUST
EPA Rpt Qty:10 LBS
DOT Rpt Qty:10 LBS
Name:CHROMIUM; (CR) (SARA 313) (CERCLA). %: <100 PPM BY WT.
CAS:7440-47-3
RTECS #:GB4200000
Fraction by Wt: <0.1%
OSHA PEL:1 MG/M3
ACGIH TLV:0.5 MG/M3
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Name:LEAD; (PB) (SARA 313) (CERCLA). %: <100 PPM BY WT.
CAS:7439-92-1
RTECS #:OF7525000
Fraction by Wt: <0.1%
OSHA PEL:N/K
ACGIH TLV:0.15 MG/M3 DUST
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Name:MERCURY; (HG) (SARA 313) (CERCLA). %: <100 PPM BY WT.
CAS:7439-97-6
RTECS #:OV4550000
Fraction by Wt: <0.1%
OSHA PEL:0.1 MG/M3, C
ACGIH TLV:0.025 MG/M3, S
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Name:VOLATILE ORGANIC COMPOUNDS: 680-760 G/L.
RTECS #:9999999VO
===================== Hazards Identification =====================
LD50 LC50 Mixture:SEE INGREDIENTS.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE:MODERATELY TOXIC BY INGESTION &
OTHER ROUTES. IRRITANT TO SKIN, MUCOUS MEMBRANES & A SEVERE EYE
IRRITANT. A SYSTEMIC IRRITANT BY INHALATION. CHRONIC:OVEREXPOSURE
CAN CAUSE ANEMIA & DAMAGE TO LIV ER & KIDNEYS. NARCOTIC IN HIGH
CONCENTRATIONS. NOTE:LEAD & MERCURY APPEAR ON THE NAVY LISTING OF
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:OCCUPATIONAL CHEMICAL REPRODUCTIVE
HAZARDS. SEEK CONSULTATION FROM APPROPRIATE HEALTH PROFESSIONALS
CONCERNING LATEST HAZARD LIST INFO & SAFE HANDLING & EXPOSURE INFO
.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
Eyes:FLUSH W/WATER FOR AT LEAST 15 MINUTES & SEEK MEDICAL
ATTENTION. SKIN:WASH W/SOAP & WATER. REMOVE CONTAMINATED CLOTHING.
INHAL:REMOVE TO FRESH AIR, IF DISCOMFORT PERSISTS, SEEK MEDICAL
ATTENTION. INGEST:DO NOT INDUCE VOMITING, CALL MD IMMEDIATELY.
===================== Fire Fighting Measures =====================
Flash Point:126F,52C
Lower Limits:1.8%
Upper Limits:6.9%
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL OR ALCOHOL FOAM.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:NONE KNOWN.
================== Accidental Release Measures ==================
Spill Release Procedures:AVOID UNCONTROLLED RELEASES OF THIS MATERIAL.
WEAR APPROPRIATE PROTECTIVE CLOTHING, COLLECT SPILLED MATERIAL IS
ABSORBENT MEDIA & TRANSFER TO SECURE DOT APPROVED CONTAINER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:MATERIAL IS CLASSIFIED AS COMBUST -
KEEP AWAY FROM HEAT & OPEN FLAME. HAZ PROD RESIDUE MAY REMAIN AFTER
PROD HAS BEEN REMOVED FROM ITS CNTNR.
Other Precautions:DO NOT REUSE "EMPTY" CNTNR W/OUT COMMERCIAL
CLEANING/RECONDITIONING. THIS PROD DOES NOT HAVE APPROVAL AS FOOD
ADDITIVE, EITHER DIRECT/INDIRECT. WHEN APPLIED TO OUTSIDE SURF OF
FOOD CNTNRS, CNTNR MUST BE FUNCTIONAL BARRIER SO THAT (SUPDAT)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH APPROVED RESPIRATOR WHEN AIRBORNE LEVELS
MAY EXCEED PEL.
Ventilation:LOCAL EXHAUST:PREFERABLE; GENERAL EXHAUST:ACCEPTABLE.
Protective Gloves:CHEMICAL RESISTANT GLOVES.
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS .
Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET
ANSI DESIGN CRITERIA . AS NECESSARY TO AVOID PROLONGED CONTACT.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
SPEC GRAV:0.99-1.32 (H*2O=1). WASTE DISP METH:CLASSIFIED AS A HAZ
WASTE. OTHER PREC:THERE IS NO MIGRATION OF COMPONENTS OF THIS
PRODUCT TO FOOD.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:>275F,>135C
Vapor Pres:0.9
Vapor Density:3.7
Spec Gravity:SUPP DATA
Evaporation Rate & Reference:<1 (N-BUTYL ACETATE=1)
Solubility in Water:MISCIBLE
Appearance and Odor:VARIOUS COLORS W/KETONE ODOR.
Percent Volatiles by Volume:71-80
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
ISOLATE FROM STRONG OXIDIZERS & ACIDS.
Stability Condition to Avoid:AVOID EXPOSURE TO HEAT, FLAME & SPARKS.
Hazardous Decomposition Products:CARBON MONOXIDE FROM INCOMPLETE
BURNING.
Conditions to Avoid Polymerization:AVOID EXPOSURE TO HEAT & FLAME.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISP MUST BE I/A/W FED, STATE & LOC REGS . ALL
RECOVERED SPILLED MATL SHOULD BE COLLECTED, IDENTIFIED, LABELED,
TRANSPORTED & DISP OF I/A/W APPLIC LAWS & REGS. IT IS UP TO PROD
USER TO DETERM, A T TIME OF DISP, IF MATL SHOULD BE (SUPPDATA)
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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