===================== Product Identification =====================
MSDS NAME:GC-MS KIT-625, DECAFLUOROTRIPHENYLPHOSPHINE, 48729
NIIN:00N018095
Kit Part:Y
MSDS Number: CBVRR
=== Responsible Party ===
Company:SUPELCO INC
Address:SUPELCO PARK
City:BELLEFONTE
State:PA
ZIP:16823-0048
Country:US
Info Phone Num:814-359-3441
Emergency Phone Num:814-359-3441
CAGE:54968
=== Contractor Identification ===
Company:SIGMA-ALDRICH INC.
Address:3050 SPRUCE STREET
Box:14508
City:ST. LOUIS
State:MO
ZIP:63103
Country:US
Phone:314-771-5765/414-273-3850X5996
CAGE:54968
============= Composition/Information on Ingredients =============
Name:DECAFLUOROTRIPHENYLPHOSPHINE; (C6F5)2P(C6H5)
CAS:5074-71-5
Fraction by Wt: 2.5%
OSHA PEL:N/K
ACGIH TLV:N/K
Name:METHANE, DICHLORO-; (METHANE, DICHLORO-METHYLENE CHLORIDE
CH2CL2) (SARA 313) (CERCLA)
CAS:75-09-2
RTECS #:PA8050000
Fraction by Wt: 97.5%
OSHA PEL:500 PPM
ACGIH TLV:50 PPM, A2
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:SUP DAT: OF THE MYOCARDIUM TO EPINEPHRINE IN LABORATORY
ANIMALS AND COULD HAVE A SIMILAR EFFECT IN HUMANS. (ING 4)
RTECS #:9999999ZZ
Name:ING 3: ADRENOMIMETICS (E.G., EPINEPHRINE) MAY BE
CONTRAINDICATED EXCEPT FOR LIFE-SUSTAINING USES IN HUMANS (ING 5)
RTECS #:9999999ZZ
Name:ING 4: ACUTELY OR CHRONICALLY EXPOSED TO CHLOROCARBONS .
RTECS #:9999999ZZ
Name:FIRST AID PROC: BY MOUTH TO AN UNCON PERS. NEVER TRY TO
MAKE AN UNCON PERS VOMIT. DO NOT INDUCE VOMIT. IMMED CONT MD.
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50 (ORAL RAT): 2524 MG/KG.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE: MAY BE FATAL IF INHALED.
HARMFUL IF SWALLOWED. LACHRIMATION. IRRITATES SKIN, DERM, HDCH,
DIZZ, NARCOS, LIVER & KIDNEY DMG. SEVERAL CHRONIC INHAL STUDIES
REPORTED BY NIOSH REVEALED THAT TEST ANI MALS EXPOSED TO METHYLENE
CHLORIDE CONCS AS HIGH AS 10,000 PPM SHOWED SLIGHT LIVER & KIDNEY
CHANGES. (EFTS OF OVEREXP)
Explanation of Carcinogenicity:METHYLENE CHLORIDE: IARC MONO, SUPP, VOL
7, PG 194, 1987: GROUP 2B. NTP 7TH ANNUAL RPT ON CARCINS, 1994:
(SUP DAT)
Effects of Overexposure:HLTH HAZ: METHYLENE CHLORIDE HAS BEEN SHOWN TO
INCR RATE OF SPONT OCCURING MALIGNANT TUMORS IN ONE STRAIN OF LAB
MICE & BENIGN TUMORS IN LAB RATS. METHYLENE CHLORIDE IS METABOLIZED
TO CO & CAN STRESS CARDIOVASCULAR SYS DUE TO INCRD
CARBOXYHEMOGLOBIN. IN RATS METHYLENE CHLORIDE HAS BEEN SHOWN TO
PRDCE A (SUP DAT)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
Eyes: FLUSH W/WATER FOR AT LEAST 15 MIN. SKIN: PROMPTLY WASH
W/SOAP & LGE VOL OF WATER. REMOVE CONTAM CLTHG. INHAL: IMMED MOVE
TO FRESH AIR. GIVE OXYGEN IF BRTHG IS LABORED. IF BRTHG STOPS, GIVE
ARTF RESP. CONT MD. NEVER ADMIN ADRENALIN FOLLOWING METHYLENE
CHLORIDE EXPOS. INCRD SENSITIVITY OF HEART TO ADRENALIN MAY BE
CAUSED BY OVEREXP TO METHYLENE CHLORIDE. INGEST: NEVER GIVE
ANYTHING (ING 6)
===================== Fire Fighting Measures =====================
Lower Limits:12.0%
Upper Limits:19.0%
Extinguishing Media:USE WATER, CARBON DIOXIDE, DRY CHEMICAL.
Fire Fighting Procedures:WEAR NIOSH APPROVED PRESSURE DEMAND SCBA &
FULL PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:THE FOLLOWING TOXIC VAPORS ARE FORMED
WHEN THIS MATERIAL IS HEATED TO DECOMPOSITION: HYDROGEN CHLORIDE,
PHOSGENE.
================== Accidental Release Measures ==================
Spill Release Procedures:TAKE UP WITH ABSORBENT MATERIAL. VENTILATE
AREA. METHYLENE CHLORIDE VAPORS ARE HEAVIER THAN AIR AND WILL
COLLECT IN LOW AREAS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE IN SEALED CONTAINER IN COOL, DRY
LOCATION.
Other Precautions:NO SMOKING IN AREA OF USE. DO NOT USE IN THE GENERAL
VICINITY OF ARC WELDING, OPEN FLAMES OR HOT SURFACES. HEAT AND/OR
UV RADIATION MAY CAUSE THE FORMATION OF HCL AND/OR PHOSGENE .
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WEAR NIOSH APPROVED FACE MASK WITH ORGANIC VAPOR
CANISTER. WEAR NIOSH/OSHA APPROVED RESPIRATORY PROTECTION.
Ventilation:USE ONLY IN WELL VENTILATED AREA.
Protective Gloves:WEAR NEOPRENE GLOVES.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGS .
Other Protective Equipment:EMERGENCY EYEWASH & DELUGE SHOWER MEETING
ANSI DESIGN CRITERIA .
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
CNDTNS TO AVOID: FLAMES, HOT GLOWING SURF/ELEC ARCS CAN DECOMPOSE TO
FORM HYDROGEN CHORIDE GAS & TRACES OF PHOSGENE. EXPLAN OF CARCIN:
ANTIC TO BE CARCIN. ANIMAL: LUNG, LIVER, SALIVARY, MAMMARY GLAND
(TUMORS). EFTS OF OVEREXP: SIGNIFICANT INCR IN SALIVARY GLAND
TUMORS. CHLOROCARBON MATLS HAVE PRODUCED SENSIT (ING 3)
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:104F,40C
Melt/Freeze Pt:M.P/F.P Text:-143F,-97C
Vapor Pres:349
Vapor Density:2.93
Spec Gravity:1.320
Evaporation Rate & Reference:0.71 (ETHER=1)
Solubility in Water:1.6
Appearance and Odor:CLEAR COLORLESS LIQUID, WITH ETHER-LIKE ODOR
Percent Volatiles by Volume:100
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG BASES, OXIDIZING AGENTS.
Stability Condition to Avoid:LIQ OXYGEN/OTHER STRONG OXIDANTS MAY FORM
EXPLO MIX W/METHYLENE CHLORIDE. THIS MATL/ITS VAPS WHEN IN CONT
WITH (SUP DAT)
Hazardous Decomposition Products:HYDROGEN CHLORIDE, PHOSGENE.
==================== Disposal Considerations ====================
Waste Disposal Methods:COMPLY WITH ALL APPLICABLE FEDERAL, STATE, OR
LOCAL REGULATIONS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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