===================== Product Identification =====================
MSDS NAME:SODIUM NITROFERRICYANIDE
NIIN:00N008686
MSDS Number: CBVPT
=== Responsible Party ===
Company:MALLINCKRODT
Box:M
City:PARIS
State:KY
ZIP:40361
Country:US
Info Phone Num:314-982-5000
Emergency Phone Num:314-982-5000
CAGE:ZA916
=== Contractor Identification ===
Company:MALLINCKRODT MEDICAL, INC
Address:2703 WAGNER PLACE
Box:M
City:MARYLAND HEIGHTS
State:MO
ZIP:63043
Country:US
Phone:314-770-7800
CAGE:ZA916
Company:MALLINCKRODT SPECIALTY CHEMICALS CO
Address:222 RED SCHOOL LANE
Box:City:PHILLIPSBURG
State:NJ
ZIP:08865
Country:US
Phone:908-859-2151
CAGE:62910
============= Composition/Information on Ingredients =============
Name:FERRATE(2-),PENTACYANONITROSYL-,DISODIUM,DIHYDRATE; (SODIUM
NITROFERRICYANIDE,DIHYDRATE)
CAS:13755-38-9
RTECS #:LJ8925000
OSHA PEL:N/K
ACGIH TLV:N/K
Name:FERRATE (2-), PENTACYANONITROSYL-, DISODIUM; (SODIUM
NITROFERRICYANIDE (ANHYDROUS))
CAS:14402-89-2
RTECS #:LJ8750000
OSHA PEL:5 MG/M3 (CYANIDES)
ACGIH TLV:S, 5 MG/M3 CYANIDES
Name:SUPDAT:INTO THE GENERAL WORK AREA. PLEASE REFER TO ACGIH
DOCUMENT "INDUST VENT, A MANUAL OF RECOMMENDED (ING 4)
RTECS #:9999999ZZ
Fraction by Wt: 5%
Name:ING 3:PRACTICES", MOST RECENT EDITION, FOR DETAILS.
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50:(ORAL RABBIT) 34 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE:INHAL:MAY CAUSE IRRIT TO RESP
TRACT & SYSTEMIC POISONING W/SYMPS PARALLELING INGEST.
INGESTION:TOXIC EFTS MAY BE SIMILAR TO NITRITE POISONING; SYMPS MAY
INCL HDCH, FLUSHING OF SKIN, VOMIT, COLIC & DIARR, MUSCULAR WEAK,
DIZZ, COLLAPSE, FALL IN BLOOD PRESS, CYANOSIS, CONVLS, COMA, RESP
PARALYSIS, (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:DEATH DUE TO CIRCULATORY COLLAPSE. IT
HAS BEEN SUGGESTED THIS MATL MAY RELEASE CYANIDE IN SOME CASES.
SKIN:MAY CAUSE IRRIT, REDNESS, & PAIN. MAY BE ABSORBED THRU SKIN,
CAUSING SYSTEMIC POISON ING W/SYMPS PARALLELING INGEST.
EYE:MAYCAUSE IRRIT, REDNESS, & PAIN. CHRONIC:RPTD, PRLNGD EXPOSURE
THRU ANY (SUPDAT)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:INHAL:REMOVE TO FRESH AIR. IF NOT BRTHG, GIVE ARTF RESP. IF
BRTHG IS DFCLT, GIVE OXYG. CALL PHYS. INGEST:INDUCE VOMIT IMMED BY
GIVING 2 GLASSES OF WATER & STICKING FINGER DOWN THROAT. NEVER GIVE
ANYTH ING BY MOUTH TO UNCON PERSON. CALL PHYSIMMED. SKIN:IMMED
FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MINS WHILE REMOVING CONTAMD
CLTHG & SHOES. CALL PHYS. EYE:WASH W/PLENTY OF WATER FOR AT LEAST
(SUPDAT)
===================== Fire Fighting Measures =====================
Extinguishing Media:USE ANY MEANS SUITABLE FOR EXTINGUISHING
SURROUNDING FIRE.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:NOT CONSIDERED TO BE A FIRE OR EXPLOSION
HAZARD.
================== Accidental Release Measures ==================
Spill Release Procedures:VENTILATE AREA OF LEAK OR SPILL. CLEAN-UP
PERSONNEL MAY REQUIRE RESPIRATORY PROT FROM DUST. SPILLS:SWEEP UP &
CONTAINERIZE FOR RECLAMATION OR DISPOSAL. VACUUMING OR WET SWEEPING
MAY BE USED TO AVOID D UST DISPERSAL.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:KEEP IN TIGHTLY CLSD CNTNR, STORED IN
COOL, DRY, VENTILATED AREA. PROTECT AGAINST PHYSICAL DMG.
Other Precautions:WARNING! HARMFUL IF SWALLOWED, INHALED/ABSORBED THRU
SKIN. AVOID BRTHG DUST. AVOID CONT W/EYES, SKIN & CLTHG. KEEP CNTNR
CLSD. USE WITH ADEQUATE VENTILATION.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF TLV IS EXCEEDED, NIOSH APPRVD DUST/MIST RESP
W/CHEM GOGGS MAY BE WORN, IN GENERAL, UP TO 10 TIMES TLV. CONSULT
RESP SUPPLIER FOR LIMITATIONS. ALTERNATIVELY, A NIOSH APPRVD
SUPPLIED AIR FULL FACE RE SP/AIRLINED HOOD MAY BE WORN.
Ventilation:SYS OF LOCAL &/OR GEN EXHAUST IS REC TO KEEP EMPLOYEE EXPOS
BELOW AIRBORNE EXPOS LIMS. LOC EXHAUST VENT IS (SUPDAT)
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:IMPERVIOUS CLTHG, INCLUDING BOOTS, GLOVES,
LAB COAT, APRON/COVERALLS. ANSI APPRVD EYE WASH & DELUGE SHOWER .
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. CONTACT LENSES
SHOULD NOT BE WORN WHEN WORKING WITH THIS MATERIAL.
Supplemental Safety and Health
SOL IN H*2O:40 G/100 CC WATER @ 16C(16F). EFTS OF OVEREXP:ROUTE MAY
CAUSE SYMPTOMS SIMILAR TO ACUTE TOXICITY. FIRST AID PROC:15 MINS,
LIFTING LOWER & UPPER EYELIDS OCCASNLY. GET MED ATTN IMMED. VENT:G
ENERALLY PREFERRED BECAUSE IT CAN CONTROL EMISSIONS OF CONTAMINANT
@ ITS SOURCE, PREVENTING DISPERSION OF IT (ING 3)
================== Physical/Chemical Properties ==================
Spec Gravity:1.72
Evaporation Rate & Reference:NOT KNOWN
Solubility in Water:SUPP DATA
Appearance and Odor:RED TRANSPARENT CRYSTALS, ODORLESS.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NO DATA FOUND.
Stability Condition to Avoid:STABLE UNDER ORDINARY CONDITIONS OF USE
AND STORAGE.
Hazardous Decomposition Products:EMITS TOXIC FUMES OF NITROGEN OXIDES,
CYANIDE AND SODIUM OXIDE WHEN HEATED TO DECOMPOSITION.
==================== Disposal Considerations ====================
Waste Disposal Methods:WHATEVER CANNOT BE SAVED FOR RECLAMATION MAY BE
DELIVERED TO AN APPROVED WASTE DISPOSAL FACILITY. ENSURE COMPLIANCE
WITH LOCAL, STATE AND FEDERAL REGULATIONS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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