===================== Product Identification =====================
MSDS NAME:SIGMAGUARD BT PRIMER HARDENER, 7404B
NIIN:00N069014
Kit Part:Y
MSDS Number: CBXDS
=== Responsible Party ===
Company:SIGMA COATINGS USA BV
Address:1401 DESTREHAN AVE
City:HARVEY
State:LA
ZIP:70059
Country:US
Info Phone Num:504-347-4321
Emergency Phone Num:800-424-9300 (CHEMTREC)
Preparer's Name:JAY FOLSE
CAGE:JO293
=== Contractor Identification ===
Company:SIGMA COATINGS USA B.V.
Address:1401 DESTREHAN AVE
Box:City:HARVEY
State:LA
ZIP:70059
Country:US
Phone:504-347-4321
CAGE:JO293
Company:SIGMA COATINGS USA BV
Address:1401 DESTREHAN AVE
Box:City:HARVEY
State:LA
ZIP:70058-2436
Country:US
Phone:504-347-4321
CAGE:1K005
============= Composition/Information on Ingredients =============
Name:3,3' DIMETHYL-4,4' DIAMINODICYCLOHEXYLMETHANE LD50:
(ORAL, RAT) 550 MG/KG
CAS:6864-37-5
Fraction by Wt: 30-60%
OSHA PEL:N/K
ACGIH TLV:N/K
Name:BENZYL ALCOHOL. VP: 10 @ 68F. LEL: 1.3%.
CAS:100-51-6
RTECS #:DN3150000
Fraction by Wt: 15-40%
OSHA PEL:N/K
ACGIH TLV:N/K
Name:2-BUTANONE; (METHYL ETHYL KETONE) (SARA 313) (CERCLA). VP:
70 @ 68F. LEL: 2.0%. LD50: (ORAL, RAT) 3.4 G/KG.
CAS:78-93-3
RTECS #:EL6475000
Fraction by Wt: 4.500%
OSHA PEL:200 PPM
ACGIH TLV:200 PPM; 300 STEL
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:PHENOL, 2,4,6-TRIS(DIMETHYLAMINOMETHYL); (TRIS-
2,4,6-(DIMETHYLAMINOMETHYL)PHENOL) LD50: (ORAL, RAT) 2169 MG/KG
CAS:90-72-2
RTECS #:SN3500000
Fraction by Wt: 7-13%
OSHA PEL:N/K
ACGIH TLV:N/K
Name:DIMETHYLAMINO METHYL PHENOL LD50: (ORAL, RAT) 2160 MG/KG
CAS:25338-55-0
Fraction by Wt: 1-5%
OSHA PEL:N/K
ACGIH TLV:N/K
Name:EXPLO HAZ: VAP SOURCE. KEEP WELDING/CUTTING EQUIP AWAY FROM
PROD. KEEP CNTNRS TIGHTLY CLSD. ISOLATE FROM HEAT, (ING 8)
RTECS #:9999999ZZ
Name:ING 7: ELEC EQUIP, SPKS & OPEN FLAME. CLSD CNTNR MAY
EXPLODE WHEN EXPOS TO EXTREME HEAT. DO NOT APPLY TO HOT (ING 9)
RTECS #:9999999ZZ
Name:ING 8: SURFS. NEVER USE WELDING/CUTTING TORCH ON/NEAR CNTNR
(EVEN EMPTY) BECAUSE PROD (EVEN RESIDUE) MAY IGNITE EXPLO.
RTECS #:9999999ZZ
Name:MATL TO AVOID: BASED ON ING 1, THIS RAW MATL IS INCOMPAT
W/STRONG OXIDIZING AGENTS, STRONG MINERAL ACIDS, (ING 11)
RTECS #:9999999ZZ
Name:ING 10: ALKALI METALS AND HALOGENS.
RTECS #:9999999ZZ
Name:EFTS OF OVEREXP: ING 4, EYE CNTCT MAY RSLT IN LOSS OF
VISION W/SEV BURNS. PROD, IF INGESTED, MAY CAUSE IRRIT TO (ING 13)
RTECS #:9999999ZZ
Name:ING 12: MEMBS OF MOUTH, THROAT & GI TRACT WHICH MATL
CONTACTS. NOTICE-REPORTS HAVE ASSOC RPTD & PRLNGD OCCUP (ING 14)
RTECS #:9999999ZZ
Name:ING 13: OVEREXP TO SOLVS W/PERM BRAIN & NERVS SYS DMG.
INTENTIONAL MISUSE BY DELIB CONC & INHAL CONTENTS MAY BE (ING 15)
RTECS #:9999999ZZ
Name:ING 14: HARMFUL/FATAL. WARNING: THIS PROD CNTNS CHEM(S)
KNOWN TO CA TO CAUSE CANCER & BIRTH DEFECTS/OTHER REPRO HARM.
RTECS #:9999999ZZ
Name:SPILL PROC: OUT OF DRAINS, SEWERS OR WATERWAYS. CONTACT
FIRE AUTHS. NOTIFY LOCAL HLTH & POLLUTION CONTROL (ING 17)
RTECS #:9999999ZZ
Name:ING 16: AGENCIES. CALL SPILL RESPONSE TEAMS IF LARGE SPILL.
RTECS #:9999999ZZ
Name:RESP PROT:OF PARTICULATE & GAS & VAP. IN CONFINED AREAS USE
NIOSH/MSHA APPRVD AIR LINE TYPE RESPS/HOODS. NIOSH/ (ING 19)
RTECS #:9999999ZZ
Name:ING 18: MSHA APPRVD RESP PROT MAY ALSO BE NEC IN ANY LATER
MFG OPERATIONS IN WHICH PROD MAY BECOME AIRBORNE IN (ING 20)
RTECS #:9999999ZZ
Name:ING 19: FORM OF VAP OR DUST.
RTECS #:9999999ZZ
Name:EYE PROT: & FULL LENGTH FACESHIELD .
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:SEE INGREDIENTS
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:BASED ON ING 4, PROD CAN IRRIT & DMG
ALL BODY TISS IT CNTCTS & CAN CAUSE ALLERGIC SENSIT. BASED ON INGS
2 & 3, PROD MAY CAUSE IRRIT TO UPPER RESP TRACT. BASED ON ING 2,
PROD IS SEV IRRIT TO EYES. EXPO S MAY CAUSE EXTENSIVE CORNEAL
INJURY. BASED ON ING 4, CNTCT W/EYES MAY CAUSE TRANSIENT CORNEAL
DMG, (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: CONJ IRRIT & BURNS IF NOT PROMPTLY
REMOVED. BASED ON INGS 2 & 3, PROD MAY CAUSE SKIN IRRIT &
DRYING/DEFAT OR CRACKING & DERM ON RPTD/PRLNGD EXPOS TO SKIN. BASED
IN ING 4, PROD MAY CAUSE DRYI NG & DERM ON RPTD/PRLNGD SKIN EXPOS.
BASED ON INGS 1,4 & 5, PROD IS CORR TO EYE, SKIN, NOSE & THROAT.
BASED ON (ING 12)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:EYE: FLUSH W/WATER FOR AT LEAST 15 MIN. SEEK MD IMMED. SKIN:
FLUSH WASH W/COPIOUS AMTS OF WATER. REMOVE CONTAMD CLTHG PROMPTLY.
CONTACT MD IMMED. INHAL: REMOVE TO FRESH AIR. RESTORE BRTHNG IF
REQD. CO NTACT MD IMMED. INGEST: RINSE MOUTH IMMED. GIVE 6 TO 8 OZ
OF LIQ. (NEVER GIVE ANYTHING BY MOUTH TO UNCON PERSON.) DO NOT
INDUCE VOMIT UNLESS ADVISED BY MD. CONTACT MD IMMED.
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:23.0F,-5.0C
Lower Limits:1.3%
Upper Limits:13%
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM, ALCOHOL FOAM OR
WATER FOG.
Fire Fighting Procedures:NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP WATER
SPRAY MAY BE INEFTIVE. WATER MAY BE USED TO COOL CLSD CNTNRS TO
PVNT PRESS BUILDUP & POSS AUTOIGNIT(SUPDAT)
Unusual Fire/Explosion Hazard:KEEP CNTNRS TIGHTLY CLSD. ISOLATE FROM
HEAT, ELEC EQUIP, SPKS & OPEN FLAME. VAPS MAY BE HVR/AIR & MAY
TRAVEL ALONG GROUND BEFORE IGNIT/FLASHING BACK TO (ING 7)
================== Accidental Release Measures ==================
Spill Release Procedures:STAY UPWIND & AWAY FROM SPILL UNLESS WEARING
APPROP PROT EQUIP. STOP &/OR CNTN DISCHARGE IF IT MAY BE DONE
SAFELY. KEEP ALL SOURCES OF IGNIT AWAY. VENT AREA OF SPILL. USE
NON-SPK TOOLS FOR CLEANUP. CO VER W/INERT MATL TO REDUCE FUMES.
KEEP (ING 16)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:AVOID INHAL OF VAPS. PERSONAL CNTCT
W/PROD SHOULD BE AVOIDED. SHOULD CNTCT BE MADE, REMOVE SATURATED
CLTHG & FLUSH AFFECTED SKIN AREAS W/WATER.
Other Precautions:CONTAINERS OF THIS MATERIAL MAY BE HAZARDOUS WHEN
EMPTIED. SINCE EMPTIED CONTAINERS RETAIN PRODUCT RESIDUES (VAPOR,
LIQUID AND/OR SOLID), ALL HAZARD PRECAUTIONS GIVEN MUST BE
OBSERVED.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IN OUTDOOR/OPEN AREAS USE NIOSH/MSHA APPRVD MECH
FILTER RESP TO REMOVE SOLID AIRBORNE PARTICLES OF OVERSPRAY DURING
SPRAY APPLICATION. IN RESTRICTED VENT AREAS USE NIOSH/MSHA APPRVD
CHEM-MECH FILTERS DESIGNED TO REMOVE COMBINATION (ING 18)
Ventilation:VENT AS REQD TO CONTROL VAP CONCS. AVOID PRLNGD/RPTD BRTHG
OF VAPS. IF EXPOS EXCEEDS TLV, USE NIOSH/MSHA APPRVD RESP.
Protective Gloves:NATRL RUB, NEOPRENE, BUNA N OR NITRILE.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGS (ING 21)
Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER . AN
APRON SHOULD BE WORN TO AVOID SKIN CONTACT.
Work Hygienic Practices:WASH HANDS THOROUGHLY BEFORE EATING AND USING
WASHROOM.
Supplemental Safety and Health
FIRE FIGHT PROC: OR EXPLO WHEN EXPOS TO EXTREME HEAT. IF WATER IS USED,
FOG NOZZS PREF. BASED ON INGS 2 & 3 LIQ & VAP IS DANGEROUS FIRE HAZ
& MOD EXPLO HAZ WHEN EXPOS TO HEAT/FLAME. HVR/AIR VAPS CAN F LOW
ALONG SURFS TO DIST IGNIT SOURCES &FLASH BACK.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:>175F,>79C
Vapor Pres:70 @ 68F
Vapor Density:HVR/AIR
Spec Gravity:1.39
Evaporation Rate & Reference:FASTER THAN BUTYL ACETATE
Appearance and Odor:THICK LIQUID; SLIGHT/NOT IRRITATING ODOR.
Percent Volatiles by Volume:5.37
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
BASED ON INGS 2 & 3, PROD IS INCOMPAT W/STRONG OXIDIZING AGENTS; CNTCT
W/THESE MATLS MAY CAUSE FIRE/EXPLO. (ING 10)
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH FEDERAL,
STATE AND LOCAL REGULATIONS .
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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