===================== Product Identification =====================
MSDS NAME:D-05367 GRACE NON-SHRINK GROUT
NIIN:00F051646
MSDS Number: CCFLY
=== Responsible Party ===
Company:W R GRACE & CO
Address:62 WHITTEMORE AVE
City:CAMBRIDGE
State:MA
ZIP:02140-1623
Country:US
Info Phone Num:617-876-1400 EXT 3140
Emergency Phone Num:617-876-1400 EXT 3140
CAGE:1BX64
=== Contractor Identification ===
Company:GRACE W R AND CO DEWEY AND ALMY CHEMICAL DIV
Address:62 WHITTEMORE AVE
Box:City:CAMBRIDGE
State:MA
ZIP:02140-1623
Country:US
Phone:617-876-1400
CAGE:17486
Company:W R GRACE & CO
Address:55 HAYDEN AVE
City:LEXINGTON
State:MA
ZIP:02173
Country:US
Phone:713-479-7348
CAGE:1BX64
============= Composition/Information on Ingredients =============
Name:PORTLAND CEMENT, CONTAINS: TRICALCIUM SILICATE, DICALCIUM
SILICATE, TRICALCIUM ALUMINATE, TETRACALCIUM ALUMINOFERRATE
CAS:65997-15-1
RTECS #:VV8770000
Fraction by Wt: 45-55%
Other REC Limits:50 MPPCF (MSHA)
ACGIH TLV:10 MG/CUM (DUST)
Name:CEMENT BINDER *96-3*
CAS:65997-16-2
Fraction by Wt: 45-55%
Name:CALCIUM SULFATE
CAS:7778-18-9
RTECS #:WS6920000
Fraction by Wt: 0-4%
Other REC Limits:5 MG/CUM (DUST)
OSHA PEL:15 MG/CUM
ACGIH TLV:10 MG/CUM
Name:CRYSTALLINE-QUARTZ SILICA, SILICA DUST (SUSPECTED HUMAN
CARCINOGEN BY IARC-GROUP 2A; SUSPECTED CARCINOGEN NTP) *96-3*
CAS:14808-60-7
RTECS #:VV7330000
Fraction by Wt: 45-55%
Other REC Limits:0.05 MG/CUM (NIOSH)
OSHA PEL:10 MG/CUM %RESP SIO2
ACGIH TLV:0.1 MG/CUM RESP DUST
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:INHALATION: IRRITATION & INFLAMMATION
TO THE RESPIRATORY SYSTEM. CRYSTALLINE SILICA (QUARTZ): LONG TERM
EXPOSURE CAN DECREASE LUNG FUNCTION & CREATE SILICOSIS,
PNEUMOCONIOSIS, LUNG CANCER & OTHER LUNG DISEASE. SKIN/EYES:
IRRITATION & BURNS. INGESTION: IRRITATION & BURNS TO THE LININGS OF
THE MOUTH, ESOPHAGUS & STOMACH.
Explanation of Carcinogenicity:SEE INGREDIENTS.
Effects of Overexposure:IRRITATION, INFLAMMATION, COUGHING, SNEEZING,
SHORTNESS OF BREATH, WHEEZING, BURNS.
Medical Cond Aggravated by Exposure:RESPIRATORY CONDITIONS SUCH AS
ASTHMA, EMPHYSEMA, BRONCHITIS & ALLERGIC DERMATITIS (CEMENT
DERMATITIS).
======================= First Aid Measures =======================
Eyes: FLUSH W/PLENTY OF WATER FOR 15 MINS. SKIN: FLUSH
W/PLENTY OF WATER & DRY THOROUGHLY. AFTER WORK SHIFT, SHOWER W/SOAP
& WATER. INHALATION: REMOVE TO FRESH AIR. INGESTION: GIVE LARGE
VOLUMES OF WA TER/MILK TO DRINK FOR DILUTION EFFECT &INDUCE
VOMITING BY STICKING FINGER DOWN THROAT. NEVER GIVE ANYTHING BY
MOUTH TO AN UNCONSCIOUS PERSON. OBTAIN MEDICAL ATTENTION IN ALL
CASES.
===================== Fire Fighting Measures =====================
Fire Fighting Procedures:NONE
================== Accidental Release Measures ==================
Spill Release Procedures:SWEEP/SHOVEL MATERIAL & PLACE IN SUITABLE
CONTAINERS FOR RECYCLE/DISPOSAL.
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE IN A COOL, DRY AREA. USE BAG
OPENING & DISPOSAL PROCEDURES WHICH MINIMIZE DUST RELEASE. EQUIP
MIXERS W/DUST COVERS WHEN NECESSARY.
Other Precautions:AVOID CREATING & INHALING DUST. AVOID CONTACT W/SKIN
& EYES.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WEAR NIOSH APPROVED DUST MASK (TYPE TC-21C-XXX)
TO PREVENT EXPOSURE ABOVE THE LIMITS.
Ventilation:LOCAL EXHAUST/MECHANICAL (GENERAL): EXHAUST FANS MAY BE
NECESSARY WHEN MIXING IN ENCLOSED AREAS.
Protective Gloves:IMPERVIOUS
Eye Protection:SAFETY GLASSES
Other Protective Equipment:BARRIER CREAMS, BOOTS, NORMAL WORK CLOTHES.
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
pH:11-13
Solubility in Water:SLIGHT
Appearance and Odor:COARSE, FREE FLOWING GREY POWDER; ODORLESS
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
Hazardous Decomposition Products:HEAT >2642F, SULFUR DIOXIDE & OXIDES
OF CALCIUM.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF WASTE IAW/FEDERAL, STATE & LOCAL
REGULATIONS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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