===================== Product Identification =====================
MSDS NAME:A33 R 85 TILE RED POLYURETHANE FLOOR ENAMEL;(SUPDAT)
NIIN:00N035014
Status Code:A
MSDS Number: CHSGR
=== Responsible Party ===
Company:SHERWIN-WILLIAMS CO
Address:101 PROSPECT AV NW
City:CLEVELAND
State:OH
ZIP:44115
Country:US
Info Phone Num:216-566-2902
Emergency Phone Num:216-599-2917
CAGE:54636
=== Contractor Identification ===
Company:SHERWIN-WILLIAMS CO THE
Address:101 PROSPECT AVE NW
Box:City:CLEVELAND
State:OH
ZIP:44115-1042
Country:US
Phone:800-251-2486/216-566-2242
CAGE:54636
============= Composition/Information on Ingredients =============
Name:ING 15: HAZ LEVELS ONLY DURING SANDING/ABRADING OF THE
DRIED FILM. IF NO SPECIFIC DUSTS ARE LISTED IN (ING 17)
RTECS #:9999999ZZ
Name:ING 16: SECTION 2, THE APPLICABLE LIMITS FOR NUISANCE DUSTS
ARE ACGIH TLV 10MG/M3 (TOTAL DUST) OSHA PEL (ING 18)
RTECS #:9999999ZZ
Name:ING 17: 15 MG/M3 (TOTAL DUST), 5 MG/M3 (RESPIRABLE
FRACTION).
RTECS #:9999999ZZ
Name:ETHYLENE GLYCOL (SARA 313) (CERCLA)
CAS:107-21-1
RTECS #:KW2975000
Fraction by Wt: <5%
OSHA PEL:N/K
ACGIH TLV:C 50 PPM,VAPOR; 9495
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Name:SOLVENT NAPHTHA PETROLEUM MEDIUM ALIPHATIC; (MINERAL
SPIRITS). VP: 2.0
CAS:64742-88-7
RTECS #:WF3450000
Fraction by Wt: 29-48%
OSHA PEL:N/K
ACGIH TLV:N/K
Name:TALC
CAS:14807-96-6
RTECS #:WW2710000
Fraction by Wt: 0-27%
OSHA PEL:20 MPPCF Z-3
ACGIH TLV:2 MG/M3 RDUST; 9495
Name:CALCIUM CARBONATE (1:1)
CAS:471-34-1
RTECS #:FF9335000
Fraction by Wt: 2-10%
OSHA PEL:15[5] MG/M3 (MFR)
ACGIH TLV:10 MG/M3 (MFR)
Name:TITANIUM OXIDE; (TITANIUM DIOXIDE)
CAS:13463-67-7
RTECS #:XR2275000
Fraction by Wt: 0-18%
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:10 MG/M3 TDUST; 9495
Name:VOLATILE ORGANIC COMPOUNDS (VOC-LBS/GAL): 3.91-3.94
RTECS #:9999999VO
OSHA PEL:N/K
ACGIH TLV:N/K
Name:SUPDAT: IMMEDIATELY APPARENT. OBTAIN MEDICAL ATTENTION.
RTECS #:9999999ZZ
Name:EFTS OF OVEREXP: OVEREXPOSURE TO SOLVENTS WITH PERMANENT
BRAIN AND NERVOUS SYSTEM DAMAGE.
RTECS #:9999999ZZ
Name:WASTE DISP METH: INCINERATE IN AN APPROVED FACILITY. DO NOT
INCINERATE CLOSED CONTAINER. DISPOSE OF IN (ING 10)
RTECS #:9999999ZZ
Name:ING 9: ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS
REGARDING POLLUTION.
RTECS #:9999999ZZ
Name:RESP PROT: NIOSH FOR PROT AGAINST MATLS IN SECTION II. WHEN
SANDING/ABRADING DRIED FILM, WEAR A DUST/MIST RESP (ING 12)
RTECS #:9999999ZZ
Name:ING 11: APPROVED BY NIOSH FOR DUST WHICH MAY BE GENERATED
FROM THIS PRODUCT, UNDERLYING PAINT, OR THE ABRASIVE.
RTECS #:9999999ZZ
Name:VENT: REFER TO OSHA STANDARDS 1910.94. 1910.107, 1910.108.
RTECS #:9999999ZZ
Name:OTHER PREC: ADEQUATE VENT. AVOID BRTHG VAP & SPRAY MIST.
AVOID CNTCT W/SKIN & EYES. THESE COATINGS MAY CONTAIN (ING 15)
RTECS #:9999999ZZ
Name:ING 14: MATERIALS CLASSIFIED AS NUISANCE PARTICULATES
(LISTED "AS DUST" IN SECTION 2) WHICH MAY BE PRESENT AT (ING 16)
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: IRRIT OF EYES, SKIN & RESP SYS.
MAY CAUSE NERVOUS SYS DEPRESS. EXTREME OVEREXP MAY RSLT IN
UNCONSCIOUSNESS & POSSIBY DEATH. SIGNS & SYMPS OF OVEREXP: HDCH,
DIZZ, NAUS; & LOSS OF COORDINATION AR E INDICATIONS OF EXCESSIVE
EXPOS TO VAPS/SPRAY MIST. REDNESS & ITCHING/BURNING SENSATION MAY
INDICATE (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: EYE/EXCESSIVE SKIN EXPOS. CHRONIC:
PRLNG OVEREXP TO SOLV INGREDS IN SECTION 2 MAY CAUSE ADVERSE EFTS
TO LIVER, URINARY, & REPROD SYS. RATS EXPOSED TO TITANIUM DIOXIDE
DUST AT 250 MG/M3 DEVEL OPED LUNG CANCER, HOWEVER, SUCH EXPOS
LEVELS ARE NOT ATTAINABLE IN WORKPLACE. RPTS HAVE ASSOCD RPTD &
PRLNGD (ING 8)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:INHAL: IF AFFECTED, REMOVE FROM EXPOSURE. RESTORE BREATHING.
KEEP WARM AND QUIET. SKIN: WASH AFFECTED AREA THOROUGHLY WITH SOAP
AND WATER. REMOVE CONTAMINATED CLOTHING AND LAUNDER BEFORE RE-USE.
EYES: FLUSH WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES.
GET MEDICAL ATTENTION. INGEST: GET MEDICAL ATTENTION.
===================== Fire Fighting Measures =====================
Flash Point:100F,38C
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROT EQUIP .
WATER SPRAY MAY BE INEFT. IF H*2O IS USED, FOG NOZZLES ARE PREF.
H*2O MAY BE USED TO COOL CLSD CNTNRS (SUPDAT)
Unusual Fire/Explosion Hazard:KEEP CNTNRS TIGHTLY CLSD. ISOLATE FROM
HEAT, ELEC EQUIP, SPARKS, & OPEN FLAME. CLSD CNTNRS MAY EXPLODE
WHEN EXPOSED TO EXTREME HEAT. APPLICATION TO (SUPDAT)
================== Accidental Release Measures ==================
Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND
REMOVE WITH INERT ABSORBENT.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:KEEP AWAY FROM HEAT & OPEN FLAME.
CONSULT NFPA CODE. USE APPROVED BONDING AND GROUNDING PROCEDURES.
KEEP CONTAINER CLOSED WHEN NOT IN USE.
Other Precautions:TRANSFER ONLY TO APPROVED CNTNRS W/COMPLETE & APPROP
LABELING. DO NOT TAKE INTERNALLY. KEEP OUT OF REACH OF CHILDREN.
INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING & INHALING THE
CONTENTS CAN BE HA RMFUL/FATAL. USE ONLY WITH (ING 14)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF PERS EXPOS CANNOT BE CONTROLLED BELOW APPLIC
LIMS BY VENT, WEAR A PROPERLY FITTED ORG VAP/PARTICULATE RESP
APPRVD BY NIOSH FOR PROT AGAINST MATLS IN SECTION 2. WHEN
SANDING/ABRADING DRIED FILM, WEA R A DUST/MIST RESP APPRVD BY (ING
11)
Ventilation:LOC EXHST PREF. GEN EXHST ACCEPTABLE IF EXPOS TO MATLS IN
SECTION 2 IS MAINTAINED BELOW APPLICABLE EXPOS LIMS. (ING 13)
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS .
Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET
ANSI DESIGN CRITERIA .
Work Hygienic Practices:WASH HANDS AFTER HANDLING.
Supplemental Safety and Health
MFR'S TRADE NAME/PART #: ALKYD SPECIAL PURPOSE COATINGS. MP: 1.0-1.02 .
FIRE FIGHT PROC: TO PVNT PRESS BUILD-UP & POSS
AUTOIGNITION/EXPLOSION WHEN EXPOSED TO EXTREME HEAT. EXPLO HAZ: HOT
SURFS R EQS SPECIAL PRECS. DURING EMER CNDTNS OVEREXP TO DECOMP
PRODS MAY CAUSE A HLTH HAZ. SYMPS MAY NOT BE (ING 7)
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:>200F,>93C
Melt/Freeze Pt:M.P/F.P Text:SUPDAT
Vapor Pres:SEE INGS
Vapor Density:HVR/AIR
Spec Gravity:0.87-1.39
Evaporation Rate & Reference:SLOWER THAN ETHER
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
Percent Volatiles by Volume:45-85
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE KNOWN.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:BY FIRE: CARBON DIOXIDE, CARBON
MONOXIDE.
==================== Disposal Considerations ====================
Waste Disposal Methods:WASTE FROM THESE PRODS MAY BE HAZS AS DEFINED
UNDER RCRA 40 CFR 261. WASTE MUST BE TESTED FOR IGNITABILITY TO
DETERM APPLIC EPA HAZ WASTE NUMBERS. WASTE CONTAINING CHROMIUM
OXIDE (A33G110) MUST ALSO B E TESTED FOR EXTRACTABILITY. (ING 9)
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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