===================== Product Identification =====================
MSDS NAME:SULFURIC ACID, 66 DEGREE BE WATER WHITE
NIIN:00-975-0707
Status Code:A
MSDS Number: CJMCR
=== Responsible Party ===
Company:GREAT WESTERN CHEMICAL COMPANY
Address:808 S.W. 15TH AVE
City:PORTLAND
State:OR
ZIP:97205
Country:US
Info Phone Num:503-228-2600
Emergency Phone Num:503-228-2600
Preparer's Name:MIKE HOEFLER
Chemtrec Ind/Phone:(800)424-9300
CAGE:0W4M8
=== Contractor Identification ===
Company:GREAT WESTERN CHEMICAL COMPANY
Address:808 S.W. 15TH AVE
Box:City:PORTLAND
State:OR
ZIP:97205
Country:US
Phone:503-228-2600
CAGE:0W4M8
Company:TELECHEM INTERNATIONAL, INC
Address:524 E WEDDELL DRIVE SUITE 3
Box:City:SUNNYVALE
State:CA
ZIP:94089-2115
Country:US
Phone:916-941-3688
Contract Num:SP0450-99-M-NJ10
CAGE:1KH20
============= Composition/Information on Ingredients =============
Name:SULFURIC ACID
CAS:7664-93-9
RTECS #:WS5600000
= Wt:95.
Other REC Limits:NONE RECOMMENDED
OSHA PEL:1 MG/M3
ACGIH TLV:1 MG/M3
ACGIH STEL:3 MG/M3
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Health Hazards Acute and Chronic:TARGET ORGANS: N/P. EYES, SKIN,
RESPIRATORY SYSTEM, TEETH (HMIS). EYE CONTACT: "DANGER" CORROSIVE.
SKIN CONTACT: "DANGER" CORROSIVE. INHALATION: HARMFUL IF INHALED.
INGESTION: HARMFUL IF SWALLOWED. EFFECTS OF OVEREXPOSURE: CAUSES
SEVERE EYE AND SKIN IRRITATION OR BURNS. HARMFUL IF SWALLOWED.
Explanation of Carcinogenicity:N/P. (HMIS: NOT LISTED.)
======================= First Aid Measures =======================
Eyes: IMMEDIATELY FLUSH EYES WITH PLENTY OF CLEAN RUNNING
WATER FOR AT LEAST 15 MINUTES, LIFTING THE UPPER AND LOWER LIDS
OCCASIONALLY. CALL A PHYSICIAN IMMEDIATELY. EXTERNAL: IN CASE OF
CONTACT, IMME DIATELY FLUSH SKIN WITH PLENTY OF CLEAN RUNNING WATER
FOR AT LEAST 15 MINUTES, WHILE REMOVING CONTAMINATED CLOTHING AND
SHOES. IF BURNS OR IRRITATION OCCURS, CALL A PHYSICIAN. INTERNAL:
IF SWALLOWED, DO NOT INDUCE VOMITING. IMMEDIATELY DRINK A LARGE
QUANTITY OF MILK OR WATER AND CALL A PHYSICIAN. NEVER GIVE ANYTHING
BY MOUTH TO AN UNCONSCIOUS PERSON.
===================== Fire Fighting Measures =====================
Extinguishing Media:WATER, FOAM, CARBON DIOXIDE AND DRY CHEMICALS.
Fire Fighting Procedures:WHEN FIRE FIGHTING, WEAR FULL PROTECTIVE
EQUIPMENT, INCLUDING SELF- CONTAINED BREATHING APPARATUS.
Unusual Fire/Explosion Hazard:MAY PRODUCE HAZARDOUS FUMES OR HAZARDOUS
DECOMPOSITION PRODUCTS. WATER SOLUTIONS ARE CORROSIVE. READILY
ATTACKS SOME METALS (I.E. ALUMINUM, MAGNESIUM AND ZINC) TO LIBERATE
FLAMMABLE/EXPLOSIVE HYDROGEN GAS. DILUTION WITH WATER LIBERATES
LARGE AMOUNTS OF HEAT AND MAY CAUSE VIOLENT BOILING AND SPATTERING.
================== Accidental Release Measures ==================
Spill Release Procedures:CONTAIN SPILL (UNLESS SMALL SPILL). WEARING
RECOMMENDED PROTECTIVE EQUIPMENT, CAREFULLY ADD LIME OR SODIUM
CARBONATE TO NEUTRALIZE ACID. PICK UP AND CONTAINERIZE RESIDUES FOR
DISPOSAL. FLUSH SPILL ARE A WITH WATER; COLLECT RINSATES FOR
DISPOSAL OR SEWER, AS APPROPRIATE. DISPOSE OF NEUTRALIZED ACID IN
AN APPROVED LANDFILL IN ACCORDANCE WITH LOCAL AND STATE
REGULATIONS.
Neutralizing Agent:LIME OR SODIUM CARBONATE
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE IN A COOL, DRY, WELL-VENTILATED
AREA. DO NOT ADD (SULFURIC ACID, 66 BE) TO HYPOCHLORITE BLEACHES,
CHLORINE SANITIZERS/CHLORINATED CLEANERS AS THIS LIBERATES TOXIC,
CORROSIVE CHLORINE GAS. ADD SU LFURIC ACID SLOWLY TO COOL WATER
WITH ADEQUATE AGITATION TO PREVENT BOILING AND VIOLENT SPATTERING.
Other Precautions:FOR INDUSTRIAL USE ONLY. KEEP OUT OF REACH OF
CHILDREN. DO NOT GET PRODUCT IN EYES, ON SKIN OR ON CLOTHING. KEEP
CONTAINER TIGHTLY CLOSED WHEN NOT IN USE. WASH THOROUGHLY AFTER
HANDLING.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF AN OSHA-PEL IS EXCEEDED, THEN A
NIOSH-APPROVED RESPIRATOR WITH AN ACID GAS CARTRIDGE OR SUPPLIED
AIR IS REQUIRED.
Ventilation:LOCAL EXHAUST; PREFERABLE. MECHANICAL; OK
Protective Gloves:RUBBER OR SYNTHETIC RUBBER
Eye Protection:CHEMICAL GOGGLES AND FULL FACE SHIELD
Other Protective Equipment:RUBBER APRON, RUBBER BOOTS, EYEWASH, SAFETY
SHOWER.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
HCC:C1
Boiling Pt:=279.C, 534.2F
Melt/Freeze Pt:M.P/F.P Text:NDA
Spec Gravity:1.835 @ 20C
pH:<1.0
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR, COLORLESS TO PALE YELLOW LIQUID WITH A
SLIGHT ACIDIC ODOR.
Percent Volatiles by Volume:NDA
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
CAUSTIC, ALKALI, ORGANIC MATERIALS, ALUMINUM, MAGNESIUM AND ZINC.
Stability Condition to Avoid:NONE.
Hazardous Decomposition Products:WHEN HEATED TO DECOMPOSITION, IT EMITS
TOXIC OXIDES OF SULFUR AND SULFURIC ACID FUMES.
=================== Toxicological Information ===================
Toxicological Information:EYE CONTACT: RABBIT: 5 MG/30 SECONDS
(RINSED): SEVERE. ORAL RAT LD50: 2.140 MG/KG. INHALATION RAT LC50:
510 MG/M3/2 HOURS. HUMAN DATA: INHALATION TCLO: 3 MG/M3/24 WEEKS.
OTHER TOXICCOLOGICAL DATA: INH ALATION MOUSE LC50: 320
MG/KG/2HOURS. TERATOGENICITY: INHALATION RABBIT TCLO: 20 MG/M3/7
HOURS (6-18 DAYS PREGNANT). MUTAGENICITY: CYTOGENETIC
ANALYSIS-HAMSTER OVARY: 4 MMOL/L. TARGET ORGANS: EYES, SK IN,
LUNGS.
===================== Ecological Information =====================
Ecological:THIS PRODUCT WILL AFFECT THE PH OF WATER. NO SPECIFIC
ENVIRONMENTAL FATE DATA IS AVAILABLE. NO AQUATIC TOXICITY IS
AVAILABLE FOR SULFURIC ACID SOLUTIONS. THIS PRODUCT WILL AFFECT THE
PH OF THE WATER W HICH DOES AFFECT AQUATIC LIFE. RAINBOW TROUT LC50
PH=4.0 FOR A 7 DAY BIOASSAY. OTHER SPECIES MAY VARY ON PH
SUSCEPTIBILITY.
==================== Disposal Considerations ====================
Waste Disposal Methods:THIS PRODUCT, IF DISPOSED AS SHIPPED, MEETS EPA
CRITERIA OF A HAZARDOUS WASTE AS SPECIFIED IN 40 CFR 261 ON THE
BASIS OF ITS CORROSIVITY. DISPOSE OF PRODUCT IN A LICENSED
HAZARDOUS WASTE DISPOSAL FACI LITY IN ACCORDANCE WITH ALL
APPLICABLE LAWS. WHEN EMPTY, THOROUGHLY RINSE CONTAINER WITH WATER
BEFOR E DISPOSAL OR RETURN TO MANUFACTURER.
=================== MSDS Transport Information ===================
Transport Information:DOT PROPER SHIPPING NAME: SULFURIC ACID, HAZARD
CLASS 8, UN1830, PKG II, PRIMARY LABEL: CORROSIVE. SUBSIDIARY
LABEL: NONE REQUIRED. PRIMARY /SUBSIDIARY PLACARDS: CORROSIVE. DOT
REPORTABLE QUANTITY (RQ ): 1000 LBS (H2SO4). RQ FOR PRODUCT: 1,075
LBS (70.6 GALLONS). MARINE POLLUTANT: NO. DOT 1996 NORTH AMERICAN
EMERGENCY RESPONSE GUIDEBOOK NO.: 157. TDG PROPER SHIPPING NAME:
SULFURIC ACID, HAZARD CLAS S: 8(9.2), UN1830, PKG II, PRIMARY
LABEL: CORROSIVE. SUBSIDIARY LABEL: NONE REQUIRED.
PRIMARY/SUBSIDIARY PLACARDS: CORROSIVE. TDG REPORTABLE QUANTITY
(RQ): 5 LITERS OR KG. REGULATED LIMIT (RL): 50KG H 2SO4). RL FOR
PRODUCT: 53.8KG(29.4 L).
===================== Regulatory Information =====================
SARA Title III Information:SECTION 302 & 303 (40 CFR 355): LISTED
SUBSTANCE: YES, REPORTABLE QUANTITY: 1,000 POUNDS. PLANNING
THRESHOLD 1,000 POUNDS. SECTION 311 &312 (40 CFR 370): HAZARD
CATGORIES (PRODUCT): REACTIVE, ACUTE HE ALTH, CHRONIC HEALTH.
PLANNING THRESHOLD: 1,000 POUNDS. SECTION 313 (40 CFR 372): LISTED
TOXIC CHEMICAL: YES (STRONG ACID MIST). REPORTING THRESHOLD: 10,000
POUNDS.
Federal Regulatory Information:US EPA REQUIREMENTS: RELEASE REPORTING;
CERCLA (40 CFR 302), LISTED SUBSTANCE: YES. REPORTABLE QUANTITY:
1,000 POUNDS, CATEGORY: C. U.S. TSCA STATUS: LISTED (40 CFR 710):
YES.
State Regulatory Information:STATE RIGHT TO KNOW LAWS: MA, NJ, PA.
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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