===================== Product Identification =====================
MSDS NAME:TURCOFORM ETCHANT 9H (PC:11085)
NIIN:01-083-6293
Status Code:A
MSDS Number: CJNRZ
=== Responsible Party ===
Company:ELF ATOCHEM NORTH AMERICA, TURCO PRODUCTS, INC.
Address:2375 STATE ROAD
City:CORNWELLS HEIGHTS
State:PA
ZIP:19020
Country:US
Info Phone Num:215-419-7890
Emergency Phone Num:215-419-7892
Chemtrec Ind/Phone:(800)424-9300
CAGE:TO254
=== Contractor Identification ===
Company:ELF ATOCHEM NORTH AMERICA, TURCO PRODUCTS, INC.
Address:2000 MARKET STREET
Box:City:PHILADELPHIA
State:PA
ZIP:19103
Country:US
Phone:215-419-7890
CAGE:TO254
Company:TURCO PRODUCTS, INC. DIVISON OF ELF ATOCHEM NORTH AMERICA
Address:2000 MARKET ST
Box:City:PHILADELPHIA
State:PA
ZIP:19103-3222
Country:US
Phone:215-419-7890
Contract Num:SP0450-99-M-NH22
CAGE:61102
============= Composition/Information on Ingredients =============
Name:SODIUM HYDROXIDE
CAS:1310-73-2
RTECS #:WB4900000
Minumum % Wt:85.
Maxumum % Wt:95.
OSHA PEL:2 MG/M3
ACGIH STEL:C2 MG/M3
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:SODIUM HYDROSULFIDE
CAS:16721-80-5
RTECS #:WE1900000
Minumum % Wt:1.
Maxumum % Wt:10.
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL-RAT FOR NAOH 340MG/KG.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYE:CORROSIVE.CAUSES RAPID TISSUE
DESTRUCTION,PERM DMG & POSSIBLE BLINDNESS.SKIN CORROSIVE.
SOLIDS/DUST WILL CAUSE IRRIT.PROL EXPO WILL CAUSEIRREVERSIBLE
SCARRING.INGEST MAY CAUSE SEVERE BURNS OF MOUT H/THROAT.INHAL OF
DUSTS CAN CAUSE BURNS TO MUCOUS MEMBRANES.
Explanation of Carcinogenicity:THIS PRODUCT DOES NOT CONTAIN ANY
COMPONENTS LISTED BY IARC/NTP/OSHA AS CARCINOGENS.
Effects of Overexposure:CORROSIVE.RAPID EYE TISSUE DESTRUCTION,PERM DMG
& POSSIBLE BLINDNESS.SKIN IRRIT,IRREVERSIBLE SCARRING.SEVERE BURNS
OF MOUTH/THROAT.BURNS MUCOUS MEMBRANES.
Medical Cond Aggravated by Exposure:INDIVIDUALS W/BREATHING DIFFICULTY
MAY FIND EXPO TO PROD INCR THAT DIFFICULTY.SUCH INDIVIDUALS SHOULD
PAY SPECIAL ATTN TO RECOMMENDED EXPO LIMITS FOR HAZ INGREDS.
======================= First Aid Measures =======================
First Aid:INGEST:DONT INDUCE VOMIT.GIVELOTS OF H2O/MILK.GET IMMED MED
ATTN.NEVER GIVE ANYTHING BY MOUTH IF CONSC.SKIN:WASH W/SOAP/H2O.GET
MED ATTN.REMOVE CONTAM CLOTH.EYE: FLUSH W/LOTS OF H2O @LEAST
15MINS OR TIL MED TREATMENT RECEIVED.IMMED/CONSTANTLY FLUSH (OPN
EYELIDS) W/ LOTS OF H2O.WHILE FLUSH REMOVE CONTAM CLOTH/SHOES.GET
EMERG EMD ATTN. INHAL:MOVE TO FRESH AIR.NOT BREATH GIVE ART
RESP.DR:PROBABLE MU COSAL DMG MAY CONTRAINDICATE USE OF GASTRIC
LAVAGE.MEASURE AGAINST CIRCULATORY SHOCK,RESP DEPRESS,CONVL MAY BE
NEEDED.
===================== Fire Fighting Measures =====================
Extinguishing Media:WATER-SPRAY,WATER-FOG.
Fire Fighting Procedures:WEAR SELF CONTAINED BREATHING APPARATUS. COOL
FIRE EXPOSED CONTAINERS WITH WATER.
================== Accidental Release Measures ==================
Spill Release Procedures:FLUSH W/H2O.SWEEP/SCOOP UP & REMOVE.PREVENT
SPREAD OF SPIL.DISPO OF IMMED.CONTAIN SPILL.STOP LEAT @SOURCE IF
DONE SAFELY.BE SURE AREA WELL VENTI.TRANSFER MATL INTO DRUMS FOR
DISPO.WASH AREA W/H2O.RESI DUAL AMTS SHOULD BE FLUSHED TO CHEM
WASTE TREATMENT.
====================== Handling and Storage ======================
Handling and Storage Precautions:KEEP CONTAINER CLOSED.EMPTY CONTAINER
MAY CONTAIN HAZARDOUS RESIDUES. OTHER PRECAU CONTD:OF PROD IN SOLN
BY MORE THAN 5% W/ANY SINGLE ADDN.H2O TEMPS SHOULD NOT EXCEED 160F
DURING ADDITION.
Other Precautions:PROD LIBERATES GREAT DEAL TO HEAT WHEN ADDED TO
H2O.TO AVOID RAPID TEMPS RISE,VIOLENT SPATTERING OR EXPLO RUPTIONS
"ALWAYS"ADD PROD TO H2O."NEVER"ADD H2O TO PROD.MIX PROD SHOULD BE
USED:HEAT H2O 80-10 0F BEF ADDING PROD.ADD SM AMTS OF PROD
SLOWLY/EVENLY WHILE CONSTANTLY MIX SOLN.NEVER INCR CONC(GO TO
HNDLG/STORG PRECAU)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:RESP TYPE:CARTRIDGE.FILTERS:DUST.AVOID BREATH
VAP/MIST/DUST.USE NIOSH APPROV FULL FACE RESP WHEN AIRBORNE EXPO
LIKELY.IF USED FULL FACE PIECE REPLACES NEED FOR CHEM
GOGG/FACESHIELD.IF EXPO CANT BE KEP T TO MIN W/ENGINEER CNTRLS USE
HIOSH APPROV RESP EQPMT AS NOTED.OBSERVE RESP USE LIMITATIONS SPEC
BY NIOSH/MFG.EMERG/OTHER CONDITIONS WHERE(SEE OTHER INFOR)
Ventilation:LOC EXHAU USE W/ADEQUATE VENT.ENGINEERING
CNTRLS:INVESTIGATE ENGIN TECHNIQUES TO REDUCE EXPO BELOW AIRBORNE
EXPO LIMITS.PROVIDE VENTI IF NECESSARY(SEE OTH INFO)
Protective Gloves:ANY NON-PERMEABLE TO PRODUCT
Eye Protection:FACE SHIELD GOGG;CHEM GOGG.
Other Protective Equipment:RUBBER BOOTS, APRON. EYE- PROTECTION:WHERE
THERE IS POTENTIAL FOR EYE CONTACT, WEAR CHEMICAL GOGGLES AND HAVE
EYE FLUSHING EQUIPMENT IMMEDIATELY AVAILABLE.
Work Hygienic Practices:WASH THOROUGHLY AFT HNDLG.DONT GET IN
EYES/SKIN/CLOTH.DONT BREATHE DUST/VAPOR/MIST/ GAS.LAUDNER CONTAM
CLOTH;DESTROY CONTAM SHOES.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
HCC:B1
Vapor Density:NA(AIR=1)
pH:>12.0(5%SOLN)
Solubility in Water:SOLUBLE
Appearance and Odor:CANARY YELLOW BEADS AND FLAKES
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG ACIDS,ACIDIC SOLUTION OF THIS MATERIAL MAY GENERATE HYDROGEN
SULFIDE A TOXIC GAS HAVING THE ODOR OF ROTTEN EGGS.
Stability Condition to Avoid:HIGH TEMPERATURES MAY CAUSE EVOLUTION OF
TOXIC SULFUR DIOXIDE OR HYDROGEN SULFIDE GASES.PROD LIBERATES GREAT
DEAL OF HEAT WHEN ADDED TO H2O.
Hazardous Decomposition Products:HIGH TEMPS MAY CAUSE EVOLUTION OF
TOXIC SULFUR DIOXICE OR HYDROGEN SULFIDE GASES.
==================== Disposal Considerations ====================
Waste Disposal Methods:ABSORB W/NON-COMBUSTIBLE MATL & PLACE IN DOT
APPROVED WASTE CONTAINERS.KEEP OUT OF SEWERS,STROM DRAINS & SURFACE
WATERS.CONSULT FED/STATE/LOC AUTHORITIES FOR PROPER DISPO
PROCEDURES.
=================== MSDS Transport Information ===================
Transport Information:PER MSDS:SHIPPING INFO-CORROSIVE
SOLID,BASIC,INORGANIC,N.O.S(SODIUM HYDROXIDE,SODIUM SULFHYDRATE);8.
UN3262, PGII.
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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