===================== Product Identification =====================
MSDS NAME:SODA BLEACH SOLUTION
NIIN:01-029-5565
Status Code:A
MSDS Number: CJNQQ
=== Responsible Party ===
Company:KREVIT H CO INC
Address:73 WELTON STREET
Box:9433
City:NEW HAVEN
State:CT
ZIP:06534
Country:US
Info Phone Num:203-772-3350
Emergency Phone Num:800-922-6626
Resp. Party Other MSDS Num.:0236
CAGE:66894
=== Contractor Identification ===
Company:INDUSTRIAL CHEMICAL COMMODITIES INC
Address:15944 DERWOOD RD
Box:City:ROCKVILLE
State:MD
ZIP:20855
Country:US
Phone:800-284-5279
Contract Num:SP0450-99-M-NB61
CAGE:1ELU0
Company:KREVIT H CO INC
Address:73 WELTON STREET
Box:9433
City:NEW HAVEN
State:CT
ZIP:06534
Country:US
Phone:203-772-3350
CAGE:66894
============= Composition/Information on Ingredients =============
Name:SODIUM HYPOCHLORITE (CERCLA) (AS AVAILABLE CHLORINE)
CAS:7681-52-9
RTECS #:NH3486300
Minumum % Wt:5.
Maxumum % Wt:15.
Other REC Limits:NONE RECOMMENDED
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS
Name:SODIUM HYDROXIDE (CERCLA)
CAS:1310-73-2
RTECS #:WB4900000
= Wt:1.
Other REC Limits:NONE RECOMMENDED
OSHA PEL:2 MG/M3
ACGIH TLV:C 2 MG/M3; 9596
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Fraction by Wt: BALANCE
Other REC Limits:NONE RECOMMENDED
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50 (ORAL, RAT) 8.91 MG/KG (12% SOLN)
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:TARGET ORGANS: EYES, SKIN, RESPIRATORY
SYSTEM (HMIS). ACUTE: CORROSIVE. INHALATION:. MIST OR FUMES CAN
CAUSE BRONCHIAL IRRITATION, COUGH, DIFFICULT BREATHING,
INFLAMMATION OF MOUTH, NAUSEA, AND PULMO NARY EDEMA. EYE/SKIN:
LIQUEFIED CONTACTCAN PRODUCE IRRITATION OF SKIN WITH BLISTERING AND
ECZEMA. DIRECT CONTACT WITH EYES MAY CAUSE REDNESS, PAIN, PERMANENT
DAMAGE. INGESTION: FEW OUNCES CAN CAUSE CO RROSION OF MUCOUS
MEMBRANES, SWELLING OF THROAT, PERFORATION OF ESOPHAGUS AND
STOMACH, VOMITING, COLITIC HYPOTENSION, CIRCULATORY COLLAPSE,
CONVULSIONS, COMA OR DEATH. AT 15%, AS LITTLE AS 1 OZ MAY BE
LETHAL. CHRONIC: NOT CARCINOGENIC.
Effects of Overexposure:CORROSIVE. MIST OR FUMES CAN CAUSE BRONCHIAL
IRRITATION, COUGH, DIFFICULT BREATHING, INFLAMMATION OF MOUTH,
NAUSEA, AND PULMONARY EDEMA. CONTACT CAN PRODUCE IRRITATION OF SKIN
WITH BLISTERING AND ECZE MA. DIRECT CONTACT WITH EYES MAY CAUSE
REDNESS, PAIN, PERMANENT DAMAGE. INGESTION OF FEW OUNCES CAN CAUSE
CORROSION OF MUCOUS MEMBRANES, SWELLING OF THROAT, PERFORATION OF
ESOPHAGUS AND STOMACH, VOMIT ING, COLITIC HYPOTENSION, CIRCULATORY
COLLAPSE, CONVULSIONS, COMA OR DEATH. AT 15% CONCENTRATION, AS
LITTLE AS 1 OZ MAY BE LETHAL.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:INHALATION: REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE
ARTIFICIAL RESPIRATION, PREFERABLY MOUTH-TO-MOUTH. IF BREATHING IS
DIFFICULT, GIVE OXYGEN. CALL A PHYSICIAN. EYE OR SKIN CONTACT:
FLUSH EYES AN D SKIN WITH PLENTY OF WATER FOR AT LEAST15 MINUTES
WHILE REMOVING CONTAMINATED CLOTHING AND SHOES. IF IRRITATION
OCCURS, CONSULT A PHYSICIAN. THOROUGHLY CLEAN CLOTHING AND SHOES
BEFORE REUSE OR DISCAR D. INGESTION: IF CONSCIOUS, DRINK LARGE
QUANTITIES OF WATER. DO NOT INDUCE VOMITING. TAKE IMMEDIATELY TO A
HOSPITAL OR PHYSICIAN. DO NOT GIVE ANYTHING BY MOUTH TO AN
UNCONSCIOUS PERSON.
===================== Fire Fighting Measures =====================
Flash Point:NONFLAMMABLE
Fire Fighting Procedures:FIREFIGHTERS SHOULD WEAR NIOSH/MSHA APPROVED
PRESSURE-DEMAND SELF CONTAINED BREATHING APPARATUS. USE WATER SPRAY
TO COOL FIRE-EXPOSED CONTAINERS.
Unusual Fire/Explosion Hazard:CAN DECOMPOSE TO FORM IRRITATING CHLORINE
GAS AND OXYGEN.
================== Accidental Release Measures ==================
Spill Release Procedures:IMMEDIATELY EVACUATE AREA. PROVIDE MAXIMUM
VENTILATION. WEAR PROTECTIVE EQUIPMENT. LARGE SPILLS: RECOVER
SPILLED MATERIAL ON ADSORBENTS SUCH AS VERMICULITE. SWEEP INTO
CLOSED CONTAINERS FOR DISPOSAL. DO NOT USE COMBUSTIBLE SUCH AS
SAWDUST.THOROUGHLY WET VACUUM AREA. DO NOT FLUSH TO SEWER. SMALL
SPILLS (LESS THAN 10 GALLONS): DILUTE WITH LARGE AMOUNT OF WATER
AND THEN FLUSH TO SANITARY SEWER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:WHEN HANDLING, WEAR GLOVES, SAFETY
GOGGLES AND RESPIRATORY PROTECTION. STORE IN A COOL, DRY,
WELL-VENTILATED AREA. AVOID EXCESSIVE STORAGE TEMPERATURES AND
DIRECT SUNLIGHT. STORE AWAY FROM ACIDS AND O RGANICS. STORE ONLY IN
CLOSED, PROPERLYLABELED CONTAINERS.
Other Precautions:AVOID CONTACT WITH EYES AND SKIN. MAY CAUSE BURNS TO
EYES AND SKIN. AVOID INHALAION OF VAPORS, MISTS AND FUMES. USE WITH
ADEQUATE VENTILATION. VENTILATION MUST BE SUFFICIENT TO MINIMIZE
EMPLOYEE EXPOS URE TO SODIUM HYPOCHLORITE. WASH THOROUGHLY AFTER
HANDLING. DO NOT SWALLOW. DO NOT EAT, DRINK OR SMO KE IN WORK AREA.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE A HALF OR FULL FACEPIECE ACID GAS CHEMICAL
CARTRIDGE RESPIRATOR WHEN EXPOSURES TO SODIUM HYPOCHLORITE ARE
LIKELY. AN APPROPRIATE PARTICULATE PRE-FILTER IS ALSO REQUIRED WHEN
MISTS ARE PRESENT. SIM ILAR PROTECTION SHOULD BE WORN WHILE
CLEANING UP SPILLS OR LEAKS IF IRRITATION OCCURS. RESPIRATORS MUST
BE APPROVED BY NIOSH/MSHA.
Ventilation:USE LOCAL OR GENERAL VENTILATION TO MINIMIZE EMPLOYEE
EXPOSURES AS NECESSARY.
Protective Gloves:NEOPRENEE OR NITRILE GLOVES
Eye Protection:SPLASH-PROOF CHEMICAL GOGGLES.
Other Protective Equipment:USE RUBBER/PLASTIC BOOTS, APRON OR CHEMICAL
SUITS WHEN NECESSARY TO PREVENT SKIN CONTACT.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.AVOID CONTACT
WITH EYES AND SKIN,INHILATION OF VAPORS/MISTS/FUMES.DO NOT
EAT,DRINK OR SMOKE IN WORK AREA.
Supplemental Safety and Health
NOTES TO PHYSICIAN: DO NOT ADMINISTER ACIDIC ANTIDOTES OR SODIUM
BICARBONATE FOLLOWING SODIUM HYPOCHLORITE OVEREXPOSURE. AN OUNCE OF
1% SODIUM THIOSULFATE OR MILK OF MAGNESIA IS HELPFUL.
================== Physical/Chemical Properties ==================
HCC:B1
Boiling Pt:B.P. Text:DECOMPOSES
Melt/Freeze Pt:=-14.C, 6.8F
Decomp Temp:Decomp Text:@760MMHG
Vapor Pres:17.5MMHG@20C
Spec Gravity:1.21@ 20C(H20=1)
pH:APPROX 13
Evaporation Rate & Reference:1 (WATER = 1)
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR, PALE YELLOW OR GREENISH LIQUID WITH A
CHLORINE ODOR
Percent Volatiles by Volume:100%
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
AVOID MIXING WITH ACIDS(LIBERATES CHLORINE), AMMONIA, UREA, OXIDIZING
MATERIALS, METALS SUCH AS NICKEL, COPPER, TIN, MANGANESE, IRON
(WHICH CAUSE LIBERATION OF OXYGEN).
Stability Condition to Avoid:NONE
Hazardous Decomposition Products:IN A FIRE SODIUM HYPOCHLORITE MAY
DECOMPOSE PRODUCING IRRITATING CHLORINE GAS, OXYGEN.
=================== Toxicological Information ===================
Toxicological Information:TOXICITY DATA: LC50 INHALATION: NOT
ESTABLISHED. LD50 DERMAL: NOT ESTABLISHED. SKIN/EYE IRRITATION:
(RAT) 8.91 MG/KG (12% SOLUTION). FISH, LC50 (LETAHL CONCENTRATION):
UNKNOWN.
==================== Disposal Considerations ====================
Waste Disposal Methods:THE MANUFACTURER RECOMMENDES DISPOSAL IN AN
APPROVED HAZARDOUS WASTE MANAGEMENT FACILITY. CARE MUST BE TAKEN
WHEN USING OR DISPOSING OF CHEMICAL, MATERIALS AND/OR THEIR
CONTAINERS TO PREVENT ENVIRONME NTAL CONTAMINATION. IT IS YOUR DUTY
TO DISPOSE OF THE CHEMICAL MATERIALS AND/OR THEIR CONTAINERS IN
ACCORDANCE WITH ALL REGULATIONS REGARDING DISPOSAL
===================== Regulatory Information =====================
SARA Title III Information:A. 311/312 CATEGORIES - ACUTE AND
REACTIVITY, B. NOT LISTED IN SECTION 313, C. NOT LISTED AS AN
"EXTREMELY HAZARDOUS SUBSTANCE" IN SECTION 302. CERCLA: LISTED IN
TABLE 302.4 OF 40 CFR PART 302 AS A H AZARDOUS SUBSTANCE WITH A
REPORTABLE QUANTITY OF 100 POUNDS. RELEASES TO AIR, LAND OR WATER
WHICH EXCEED THE R.Q. MUST BE REPORTED TO THE NATIONAL RESPONSE
CENTER, 1-800-424-8801.
Federal Regulatory Information:TSCA: SODIUM HYPOCHLORITE IS ON THE TSCA
INVENTORY UNDER CAS # 7681-52-9.
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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