===================== Product Identification =====================
MSDS NAME:"SUVA" MP66 (R401B)
NIIN:01-392-0963
Status Code:A
MSDS Number: CJNSC
=== Responsible Party ===
Company:DU PONT E I NEMOURS & CO CHEMICALS & PIGMENTS DEPT
Address:1007 MARKET ST
City:WILMINGTON
State:DE
ZIP:19898
Country:US
Info Phone Num:800-441-7515
Emergency Phone Num:800-441-3637
Resp. Party Other MSDS Num.:DU004507
Chemtrec Ind/Phone:(800)424-9300
CAGE:23037
=== Contractor Identification ===
Company:DU PONT E I NEMOURS & CO CHEMICALS & PIGMENTS DEPT
Address:1007 MARKET ST
Box:City:WILMINGTON
State:DE
ZIP:19898
Country:US
Phone:800-441-7515
CAGE:23037
Company:DU PONT FLUOROPRODUCTS
Address:1007 MARKET STREET
Box:City:WILMINGTON
State:DE
ZIP:19898
Country:US
Phone:1-800-441-7515
Contract Num:SP0450-99-C-5448
CAGE:2S827
============= Composition/Information on Ingredients =============
Name:METHANE, CHLORODIFLUORO- (HCFC-22)
CAS:75-45-6
RTECS #:PA6390000
= Wt:61.
Other REC Limits:NONE RECOMMENDED
ACGIH TLV:3540 MG/M3;1000 PPM
Ozone Depleting Chemical:2
Name:ETHANE, 1,1-DIFLUORO- (HFC-152A)
CAS:75-37-6
RTECS #:KI1410000
= Wt:11.
Other REC Limits:AEL/WEEL 1000 PPM
Name:ETHANE, 2-CHLORO-1,1,1,2-TETRAFLUORO (HCFC-124)
CAS:2837-89-0
= Wt:28.
Other REC Limits:AEL/WEEL 1000 PPM
===================== Hazards Identification =====================
LD50 LC50 Mixture:UNTESTED.
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:TARGET ORGANS: RESPIRATORY SYSTEM,
CNS, CVS, LIVER, KIDNEYS, SPLEEN (HMIS). SKIN CONTACT MAY CAUSE
FROSTBITE FROM EXPOSURE TO LIQUID. INHALATION MAY INCLUDE
NONSPECIFIC DISCOMFORT, SUCH AS NAUSEA, HEA DACHE, OR WEAKNESS; OR
TEMPORARY NERVOUS SYSTEM DEPRESSION WITH ANESTHETIC EFFECTS SUCH AS
DIZZINESS, CONFUSION, INCOORDINATION, UNCONSCIOUSNESS. HIGHER
EXPOSURES MAY LEAD TO COUGH, DIFFICULTY BREATHI NG, OR SHORTNESS OF
BREATH; IRREGULAR PULSE, PALPITATIONS, OR INADEQUATE CIRCULATION;
ABNORMAL KIDNEY FUNCTION AS DETECTED BY LABORATORY TESTS; OR
FATALITY FROM GROSS OVEREXPOSURE.
Explanation of Carcinogenicity:NONE OF THE COMPONENTS IN THIS MATERIAL
AT CONCENTRATIONS EQUAL TO OR GREATER THAN 0.1% ARE LISTED BY IARC,
NTP, OSHA OR ACGIH AS A CARCINOGEN.
Effects of Overexposure:INHALATION OF HIGH CONCENTRATIONS OF VAPOR IS
HARMFUL AND MAY CAUSE HEART IRREGULARITIES, LOSS OF CONSCIOUSNESS,
OR DEATH. SKIN CONTACT MAY CAUSE FROSTBITE. INHALATION MAY CAUSE
NAUSEA, HEADACHE, WEAK NESS, DIZZINESS, CONFUSION, INCOORDINATION,
COUGH, DIFFICULTY BREATHING, OR SHORTNESS OF BREATH; IRREGULAR
PULSE, PALPITATIONS, OR INADEQUATE CIRCULATION.
Medical Cond Aggravated by Exposure:INDIVIDUALS WITH PREEXISTING
DISEASES OF THE CENTRAL NERVOUS SYSTEM, CARDIOVASCULAR SYSTEM,
LUNGS OR KIDNEYS MAY HAVE INCREASED SUSCEPTIVITY TO THE TOXICITY OF
EXCESSIVE EXPOSURES.
======================= First Aid Measures =======================
First Aid:INHALATION: IF HIGH CONCENTRATIONS ARE INHALED, IMMEDIATELY
REMOVE TO FRESH AIR. KEEP PERSON CALM. IF NOT BREATHING, GIVE
ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN.
CALL A PHYSICI AN. SKIN CONTACT: FLUSH SKIN WITH WATERFOR AT LEAST
15 MINUTES AFTER EXCESSIVE CONTACT. SEEK MEDICAL ASSISTANCE IF
IRRITATION IS PRESENT. TREAT FOR FROSTBITE IF NECESSARY BY GENTLY
WARMING AFFECTED AR EA. WASH CONTAMINATED CLOTHING BEFORE REUSE.
EYE CONTACT: IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES WITH PLENTY
OF WATER FOR AT LEAST 15 MINUTES. CALL A PHYSICIAN. INGESTION:
INGESTION IS NOT CONSIDE RED A POTENTIAL ROUTE OF EXPOSURE.
===================== Fire Fighting Measures =====================
Flash Point:WILL NOT BURN
Autoignition Temp:>685.C, 1265.F
Lower Limits:NA
Upper Limits:NA
Extinguishing Media:USE MEDIA APPROPRIATE FOR SURROUNDING MATERIAL.
Fire Fighting Procedures:COOL TANK/CONTAINER WITH WATER SPRAY.
SELF-CONTAINED BREATHING APPARATUS (SCBA) MAY BE REQUIRED IF
CYLINDERS RUPTURE OR RELEASE UNDER FIRE CONDITIONS.
Unusual Fire/Explosion Hazard:CYLINDERS MAY RUPTURE UNDER FIRE
CONDITIONS. DECOMPOSITION MAY OCCUR. THIS PRODUCT IS NOT FLAMMABLE
AT TEMPERATURES UP TO 100 DEG C (212 DEG F). HOWEVER, MIXTURE OF
THIS PRODUCT WITH HIGH CONCENTRATIO NS OF AIR AT ELEVATED PRESSURE
CAN BECOME COMBUSTIBLE AT AMBIENT TEMPERATURE.
================== Accidental Release Measures ==================
Spill Release Procedures:REVIEW FIRE FIGHTING MEASURES AND HANDLING
SECTIONS BEFORE CLEAN-UP. USE APPROPRIATE PERSONAL PROTECTIVE
EQUIPMENT DURING CLEAN-UP. VENTILATE AREA, ESPECIALLY LOW OR
ENCLOSED PLACES WHERE HEAVY VAPORS MIGHT COLLECT. REMVOE OPEN
FLAMES. USE SELF-CONTAINED BREATHING APPARATUS (SCBA) IF LARGE
SPILL/LEAK OCCURS. SPILL CLEAN UP: COMPLY WITH FEDERAL, STATE, AND
LOCAL REGULATIONS FOR REPORTING RELEASES.
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE IN A CLEAN, DRY PLACE. DO NOT
HEAT ABOVE 52 C (126 F).
Other Precautions:AVOID BREATHING VAPORS OR MIST. AVOID CONTACT WITH
EYES OR SKIN. USE WITH SUFFICIENT VENTILATION TO KEEP EMPLOYEE
EXPOSURE BELOW RECOMMENDED LIMITS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:UNDER NORMAL MANUFACTURING CONDITIONS, NO
RESPIRATORY PROTECTION IS REQUIRED WHEN USING THIS PRODUCT.
SELF-CONTAINED BREATHING APPARATUS (SCBA) IS REQUIRED IF A LARGE
RELEASE OCCURS.
Ventilation:LOCAL EXHAUST SHOULD BE USED WHEN LARGE AMOUNTS ARE
RELEASED. MECHANICAL VENTILATION SHOULD BE USED IN LOW OR ENCLOSED
PLACES.
Protective Gloves:LINED BUTYL GLOVES
Eye Protection:CHEMICAL SPLASH GOGGLES
Supplemental Safety and Health
REFRIGERANT CONCENTRATION MONITORS MAY BE NECESSARY TO DETERMINE VAPOR
CONCENTRATIONS IN WORK AREAS PRIOR TO USE OF TORCHES OR OTHER OPEN
FLAMES, OR IF EMPLOYEES ARE ENTERING ENCLOSED AREAS.
================== Physical/Chemical Properties ==================
HCC:G3
Melt/Freeze Pt:=-34.6C, -30.2F
Vapor Pres:6142 @ 77F
Vapor Density:3.2
Spec Gravity:1.193
Evaporation Rate & Reference:>1 (CC14=1.0)
Solubility in Water:0.1 WT% @ 25C
Appearance and Odor:CLEAR, COLORLESS LIQUIFIED GAS, SLIGHT ETHER ODOR
Percent Volatiles by Volume:100
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
INCOMPATIBLE WITH ALKALI OR ALKALINE EARTH METALS - POWDERED AL, ZN,
BE, ETC.
Stability Condition to Avoid:AVOID OPEN FLAMES AND HIGH TEMPERATURES.
Hazardous Decomposition Products:THIS MATERIAL CAN BE DECOMPOSED BY
HIGH TEMPERATURES (OPEN FLAMES, GLOWING METAL SURFACES, ETC)
FORMING HAZARDOUS.HYDROCHLORIC AND HYDROFLOURIC ACIDS, AND POSSIBLY
CARBONYL HALIDES.
Conditions to Avoid Polymerization:WILL NOT OCCUR.
=================== Toxicological Information ===================
Toxicological Information:THE BLEND IS UNTESTED. CHLORODIFLUOROMETHANE
INHALATION 4-HOUR LC50: 220,000 PPM IN RATS. CARDIAC SENSITIZATION
OCCURRED IN DOGS AT 50,000 PPM OR GREATER. DIFLUOROETHANE
INHALATION 4-HOUR ALC: 383,00 0 PPM IN RATS; ORAL ALD: >1,500 MG/KG
IN RATS. CHLOROTETRAFLUOROETHANE INHALATION 4-HOUR ALC: >230,000
PPM IN RATS.
===================== Ecological Information =====================
Ecological:AQUATIC TOXCITY: HCFC-22 48 HOUR EC50 - DAPHNIA MAGNA: 433
MG/L
==================== Disposal Considerations ====================
Waste Disposal Methods:TREATMENT, STORAGE, TRANSPORTATION AND DISPOSAL
MUST BE IN ACCORDANCE WITH APPLICABLE FEDERAL, STATE/PROVINCIAL,
AND LOCAL REGULATIONS. RECOVER BY DISTILLATION OR REMOVE TO A
PERMITTED WASTE DISPOSAL FACILITY.
=================== MSDS Transport Information ===================
Transport Information:DOT/IMO PROPER SHIPPING NAME: LIQUIFIED GAS,
N.O.S. (PENTAFLUOROETHANE AND TETRAFLUOROETHANE); HAZARD CLASS:
2.2; UN NO.: 3163; DOT/IMO LABEL: NONFLAMMABLE GAS. SHIPPING
CONTAINERS: TANK CARS, CYLINDE RS, TON TANKS.
===================== Regulatory Information =====================
SARA Title III Information:TITLE III HAZARD CLASSIFICATIONS SECTIONS
311, 312 ACUTE AND PRESSURE: YES. THIS PRODUCT CONTAINS THE
FOLLOWING CHEMICALS SUBJECT TO THE REPORTING REQUIREMENTS OF
SECTION 313 OF TITLE III OF THE SU PERFUND AMENDMENTS AND
REAUTHORIZATION ACT (SARA) OF 1986 AND 40 CFR PART 372: METHANE,
CHLORODIFLUORO- (HCFC-22) 75-45-6 53% AND ETHANE,
2-CHLORO-1,1,1,2-TETRAFLUORO (HCFC-124) 2837-89-0 34%.
Federal Regulatory Information:TSCA INVENTORY STATUS:
REPORTED/INCLUDED.
State Regulatory Information:
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
*** END OF RECORD *** |
|