===================== Product Identification =====================
MSDS NAME:SOLUTION S0906 TSC INDICATOR
Status Code:A
MSDS Number: CKTQK
=== Responsible Party ===
Company:NALCO CHEMICAL COMPANY
Address:ONE NALCO CENTER
City:NAPERVILLE
State:IL
ZIP:60563-1198
Country:US
Info Phone Num:630-305-1165
Emergency Phone Num:800 462-5378/800 I-M-ALERT
Preparer's Name:WILLIAM S. UTLEY, PHD.
CAGE:89524
=== Contractor Identification ===
Company:ONDEO NALCO COMPANY
Address:ONDEO NALCO CENTER
Box:City:NAPERVILLE
State:IL
ZIP:60563-1198
Country:US
Phone:(630) 305-1000
CAGE:89524
============= Composition/Information on Ingredients =============
Name:METHANOL
CAS:67-56-1
RTECS #:PC1400000
Minumum % Wt:40.
Maxumum % Wt:70.
OSHA PEL:260 MG/M3;200 PPM
ACGIH TLV:262 MG/M3;200 PPM
ACGIH STEL:328 MG/M3;250 PPM
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:PROPIONIC ACID
CAS:79-09-4
RTECS #:UE5950000
Minumum % Wt:1.
Maxumum % Wt:5.
ACGIH TLV:30 MG/M3;10 PPM
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:SODIUM PROPIONATE
CAS:137-40-6
RTECS #:UF7525000
Minumum % Wt:1.
Maxumum % Wt:5.
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EMERGENCY OVERVIEW: WARNING: CONTAINS
METHANOL; MAY BE HARMFUL IF SWALLOWED. FLAMMABLE. KEEP AWAY FROM
HEAT, SPARKS, FLAME. AVOID CONTACT WITH SKIN, EYES & CLOTHING.
AVOID BREATHING VAPORS. DO NOT TAK E INTERNALLY. PRIMARY ROUTES OF
EXPOSURE: EYE, SKIN, INHALATION. EYE & SKIN CONTACT: CAN CAUSE
MODERATE IRRITATION. INGESTION: CAN CAUSE BLINDNESS FROM METHANOL.
CAN BE HARMFUL OR FATAL. INHALATION: P ROLONGED INHALATION OF MIST
OR VAPOR MAY CAUSE NAUSEA, DIZZINESS, LIGHT-HEADEDNESS, VOMITING OR
UNCONSCIOUSNESS DEPENDING ON LENGTH OF EXPOSURE & 1ST AID ACTION
GIVEN. SYMPTOMS OF EXPOSURE: A REVIEW O F (CARCINOGENICITY)
Explanation of Carcinogenicity:N/P. ACUTE/CHRONIC HEALTH HAZARDS:
-AVAILABLE DATA DOES NOT IDENTIFY ANY SYMPTOMS FROM EXPOSURE NOT
PREVIOUSLY MENTIONED.
Effects of Overexposure:N/P. SARA REGS: EPA HAZARD CATEGORIES:
IMMEDIATE (ACUTE) HEALTH HAZARD. FIRE HAZARD. UNDER SARA 311 & 312,
EPA HAS ESTABLISHED THRESHOLD QUANTITIES FOR REPORTING OF HAZ CHEM.
CURRENT THRESHOLDS: 500 LBS OR THRESHOLD PLANNING QTY (TPQ),
WHICHEVER IS LOWER, FOR EXTREMELY HAZ SUBSTANCES & 10,000 LBS FOR
ALL OTHER HAZ CHEM. SEC 313-LIST OF TOXIC CHEM (40 CFR 372):
PRODUCT CONTAINS FOLLOWING INGREDIEN T WHICH APPEARS ON LIST OF
TOXIC CHEMICALS: METHANOL, CAS #67-56-1, % RANGE 40-70.
Medical Cond Aggravated by Exposure:A REVIEW OF AVAILABLE DATA DOES NOT
IDENTIFY ANY WORSENING OF EXISTING CONDITIONS.
======================= First Aid Measures =======================
Eyes: FLUSH W/WATER FOR 15 MIN. CALL A PHYSICIAN. SKIN: WASH
THOROUGHLY WITH SOAP & RINSE WITH WATER. CALL A PHYSICIAN.
INGESTION: INDUCE VOMITING. GIVE WATER. CALL A PHYSICIAN.
INHALATION: REMOVE TO FRESH AIR. TREAT SYMPTOMS; CALL PHYSICIAN.
NOTE TO PHYSICIAN: BASED ON INDIVIDUAL REACTIONS OF PATIENT,
PHYSICIAN'S JUDGEMENT SHOULD BE USED TO CONTROL SYMPTOMS & CLINICAL
CONDITION. CAUTION: IF UNCON SCIOUS, HAVING TROUBLE BREATHING OR IN
CONVULSIONS, DO NOT INDUCE VOMITING OR GIVE WATER.
===================== Fire Fighting Measures =====================
Flash Point Method:PMCC
Flash Point:=24.4C, 76.F
ASTM D-93
Extinguishing Media:BASED ON NFPA GUIDE, USE DRY CHEMICAL, FOAM, CARBON
DIOXIDE OR OTHER EXTING AGENT SUITABLE FOR CLASS B FIRES. USE WATER
TO COOL CONTAINERS EXPOSED TO FIRE. FOR (SEE FIRE FIGHTING)
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT . EXTINGUISHING MEDIA: LARGE FIRES, USE WATER SPRAY OR
FOG, THOROUGHLY DRENCHING THE BURNING MATERIAL.
================== Accidental Release Measures ==================
Spill Release Procedures:TRANSPORTATION ACCIDENTS-CALL (24 HRS) (800)
462-5378. SMALL LIQUID SPILLS: CONTAIN WITH ABSORBENT MATERIAL,
SUCH AS CLAY, SOIL OR ANY COMMERCIALLY AVAILABLE ABSORBENT. COMBINE
WITH IGNITABLE PLANT WA STES. KEEP THE SPILL AWAY FROM HEAT,
SPARKS, FLAMES AND WELDING OPERATIONS.
====================== Handling and Storage ======================
Handling and Storage Precautions:HANDLING: AVOID CONTACT WITH SKIN,
EYES AND CLOTHING. STORAGE: KEEP CONTAINER CLOSED WHEN NOT IN USE.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH APPROVED RESPIRATOR APPROPRIATE FOR THE
EXPOSURE OF CONCERN . RESPIRATORY PROTECTION IS NOT NORMALLY NEEDED
(MFR).
Ventilation:GENERAL VENT IS RECOMMENDED. ADDITIONALLY, LOCAL EXHAUST
VENT IS RECOMMENDED WHERE VAPORS, MISTS OR AEROSOLS MAY BE
RELEASED.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPROVED CHEMICAL SAFETY GOGGLES .
Other Protective Equipment:EYEWASH AND DELUGE SHOWER MEETING ANSI
DESIGN CRITERIA .
Work Hygienic Practices:WEAR GLOVES AND SAFETY GLASSES. RESPIRATORY
PROTECTION IS NOT NORMALLY NEEDED.
Supplemental Safety and Health
HUMAN EXPOSURE CHARACTERIZATION: BASED ON NALCO'S RECOMMENDED PRODUCT
APPLICATION AND OUR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT, THE
POTENTIAL HUMAN EXPOSURE IS: LOW. PHYSICAL/CHEMICAL DATA: DENSI TY:
7.2 LBS/GAL. VALUES LISTED UNDER PHYSICAL/CHEMICAL PROPERTIES ARE
TYPICAL VALUES FOR THIS PRODUCT.
================== Physical/Chemical Properties ==================
Spec Gravity:0.86 GM/ML
Appearance and Odor:YELLOW/AMBER LIQUID; ALCOHOL ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS (E.G., CHLORINE, PEROXIDES, CHROMATES, NITRIC ACID,
PERCHLORATES, CONCENTRATED OXYGEN, PERMANGANATES) WHICH CAN
GENERATE HEAT, FIRES, EXPLOSIONS & RELEASE OF TOXIC FUMES.
Hazardous Decomposition Products:THERMAL DECOMPOSITION PRODUCTS: IN
EVENT OF COMBUSTION, CO, CO2 MAY BE FORMED. DO NOT BREATHE SMOKE OR
FUMES. WEAR SUITABLE PROTECTIVE EQUIPMENT.
=================== Toxicological Information ===================
Toxicological Information:TOXICITY STUDIES HAVE NOT BEEN CONDUCTED ON
THIS PRODUCT, BUT TOX STUDIES OF INGREDIENTS HAVE BEEN REVIEWED.
ACUTE ORAL TOXICITY (ALBINO RATS): METHANOL LD50=5,628 MG/KG. ACUTE
DERMAL TOX (ALBINO RATS ): METHANOL LD50=20 GM/KG. ACUTE INHALATION
TOX (ALBINO RATS): METHANOL LC50=64,000 PPM (8 HOURS). PRIMARY SKIN
IRRITATION TEST (ALBINO RABBITS): COMMENTS: 24 HR CONTACT W/500 MG
METHANOL PRODUCED MOD ERATE IRRITATION. PRIMARY EYE IRRITATION TEST
(ALBINO RABBITS): COMMENTS: 40 MG METHANOL PRODUCED MODERATE
IRRITATION. HUMAN HAZARD CHARACTERIZATION: BASED ON OUR HAZARD
CHARACTERIZATION, THE POTENTIA L HUMAN HAZARD IS: HIGH.
===================== Ecological Information =====================
Ecological:IF RELEASED INTO ENVIRONMENT, SEE CERCLA (SARA/FED REG).
ENVIRONMENTAL HAZARD AND EXPOSURE CHARACTERIZATION: BASED ON OUR
HAZARD CHARACTERIZATION, THE POTENTIAL ENVIRONMENTAL HAZARD IS:
MODERATE. BASE D ON NALCO'S RECOMMENDED PRODUCT APPLICATION AND THE
PRODUCT'S CHARACTERISTICS, THE POTENTIAL ENVIRONMENTAL EXPOSURE IS:
LOW. RISK CHARACTERIZATION: EVALUATION OF HUMAN/ENVIRONMENTAL
HAZARDS & EXPOSUR ES OF PRODUCT: HUMAN-LOW; ENVIRONMENTAL-LOW. ANY
USE INCONSISTENT WITH NALCO'S RECOMMENDATIONS MAY AFFECT RISK
CHARACTERIZATION.
==================== Disposal Considerations ====================
Waste Disposal Methods:IF PRODUCT BECOMES A WASTE, IT MEETS CRITERIA
OF A HAZARDOUS WASTE AS DEFINED UNDER RCRA 40 CFR 261. HAZARDOUS
WASTE D001. COMBINE WITH OTHER PLANT IGNITABLE WASTES FOR DISPOSAL.
CAN BE INCINERATED IAW LOCAL, STATE AND FEDERAL REGULATIONS. EMPTY
PRODUCT CONTAINERS SHOULD BE PUNCTURED, IF PLASTIC, AND PLACED IN
GARBAGE COLLECTION CONTAINERS.
=================== MSDS Transport Information ===================
Transport Information:PROPER SHIPPING NAME/HAZARD CLASS MAY VARY BY
PACKAGING, PROPERTIES, AND MODE OF TRANSPORTATION. TYPICAL PROPER
SHIPPING NAMES FOR PRODUCT ARE: ALL TRANSP. MODES: FLAMMABLE
LIQUID, N.O.S. UN/ID NO.: U N 1993. HAZARD CLASS, PRIMARY:
3-FLAMMABLE LIQUID. PACKING GROUP: III. IMDG PAGE NO.: 3345. IATA
PACKING INSTRUCTION: CARGO: 310. IATA CARGO AIRCRAFT LIMIT: 220L
(MAX NET QUANTITY PER PACKAGE). FLASH POINT: 76F; 24.4 C.
TECHNICAL NAME(S): METHANOL. RQ LBS (PER PACKAGE): NONE. RQ
COMPONENT(S): NONE.
===================== Regulatory Information =====================
SARA Title III Information:CERCLA/SUPERFUND, 40 CFR 117, 302: PRODUCT
CONTAINS METHANOL, A REPORTABLE QUANTITY (RQ) SUBSTANCE & IF 6,400
LBS OF PRODUCT ARE RELEASED, REQUIRES NOTIFICATION TO NATIONAL
RESPONSE CENTER, WASHINGTON , D.C. (1-800-424-8802).
SARA/SUPERFUNDAMENDMENTS & REAUTHORIZATION ACT OF 1986 (TITLE
III)-SECTIONS 302, 311, 312 & 313: SEC 302-EXTREMELY HAZ SUBSTANCES
(40 CFR 355): PRODUCT DOES NOT CONTAIN INGRED 'S LISTED IN APPENDIX
A & B AS AN EXTRMLY HAZ SUBSTANCE. SEC'S 311 & 312-MATL SAFETY DATA
SHEETS RQMTS (40 CFR 370): OUR HAZ EVALUATION FOUND THIS PRODUCT
HAZ. PRODUCT SHOULD BE REPORTED UNDER FOLLOWI NG (OVEREXPOSURE)
Federal Regulatory Information:OSHA'S HAZARD COMMUNICATION RULE, 29 CFR
1910.1200: BASED ON HAZ EVALUATION, FOLLOWING INGRED IN PRODUCT IS
HAZ: PROPIONIC ACID, SODIUM PROPIONATE: IRRITANTS. METHANOL:
FLAMMABLE. METHANOL=TWA 200 PPM , STEL 250 PPM (SKIN) ACGIH/TLV,
262 MG/M3, 328 MG/M3 ACGIH/TLV. METHANOL=TWA 200 PPM, STEL 250 PPM
(SKIN) OSHA/PEL, 260 MG/M3, 310 MG/M3 OSHA/PEL. TSCA: PRODUCT
CONTAINS A SUBSTANCE NOT FOUND ON THE 8 (B) INVENTORY LIST & CAN
ONLY BE USED UNDER THE 5 (H) (3) RESEARCH EXEMPTION FOR RESEARCH,
DEVELOP MENT & ANALYSIS. RCRA, 40 CFR 261 SUBPART C & D: CONSULT
SEC 13 FOR RCRA CLASSIFICATION. FEDERAL WATER POLLUTION CONTROL
ACT, (STATE REG)
State Regulatory Information:CA PROPOSITION 65: THIS PRODUCT DOES NOT
CONTAIN ANY CHEMICALS WHICH REQ WARNING UNDER CA PROP 65. MICHIGAN
CRITICAL MATERIALS: PRODUCT DOESN'T CONTAIN INGRED LISTED ON MI
CRITICAL MATLS REGISTER. STA TE RIGHT-TO-KNOW LAWS: REGULATED IN
STATES USING TLV FOR METHANOL AS CRITERIA FOR LISTING. FED REGS:
CLEAN WATER ACT, 40 CFR 401.15 (FORMERLY SEC 307), 40 CFR 116
(FORMERLY SEC 311): NONE OF THE INGRE DS ARE SPECIFICALLY LISTED.
CLEAN AIR ACT, SEC 111 (40 CFR 60), SEC 112 (40 CFR 61, 1990
AMENDMENTS) , SEC 611 (40 CFR 82, CLASS I & II OZONE DEPLETING
SUBSTANCES): PRODUCT CONTAINS FOLLOWING INGRED'S COVERED BY CLEAN
AIR ACT: METHANOL.
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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