===================== Product Identification =====================
MSDS NAME:SPECIALLY DENATURED ALCOHOL 3A
NIIN:00-577-4889
Status Code:A
MSDS Number: CLHNW
=== Responsible Party ===
Company:PHOENIX INDUSTRIES INC
Address:1519 CHAMBERLAYNE PARKWAY
City:RICHMOND
State:VA
ZIP:23222
Country:US
Info Phone Num:804-264-5183/FAX: 264-5535
Emergency Phone Num:804-264-5183
Chemtrec Ind/Phone:(800)424-9300
CAGE:0YED2
=== Contractor Identification ===
Company:PHOENIX INDUSTRIES INC
Address:1519 CHAMBERLAYNE PARKWAY
Box:City:RICHMOND
State:VA
ZIP:23222
Country:US
Phone:804-264-5183/FAX: 264-5535
Contract Num:SP0450-01-M-ZB07
CAGE:0YED2
============= Composition/Information on Ingredients =============
Name:ETHYL ALCOHOL
CAS:64-17-5
RTECS #:KQ6300000
Minumum % Wt:90.
Maxumum % Wt:95.
OSHA PEL:1900 MG/M3;1000 PPM
ACGIH TLV:1880 MG/M3;1000 PPM
Name:METHYL ALCOHOL
CAS:67-56-1
RTECS #:PC1400000
Minumum % Wt:1.
Maxumum % Wt:5.
OSHA PEL:100 PPM
ACGIH TLV:262 MG/M3;200 PPM
ACGIH STEL:328 MG/M3;250 PPM S
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL, RAT, LD50:7,060 MG/KG (ETHANOL)
Health Hazards Acute and Chronic:INHALATION: CAUSES IRRITATION TO
MUCOUS MEMBRANES OF UPPER RESPIRATORY TRACT. PROLONGED EXPOSURES TO
HIGH CONCENTRATIONS MAY CAUSE DROWSINESS, LOSS OF APPETITE,
INABILITY TO CONCENTRATE. INGESTION: CA USES HEADACHES, GASTRITIS,
INTOXICATION, BLINDNESS AND IN ACUTE CASES, DEATH. SKIN CONTACT:
CAUSES IRRITATION, CRACKING, FLAKING DUE TO DEFATTING. EYE
CONTACT:CAUSES IRRITATION. SPLASHES CAUSE TEMPOR ARY PAIN, BLURRED
VISION. CHRONIC EXPOSURE: PROLONGED CONTACT CAUSES DRYING, CRACKING
OF SKIN. MAY AFFECT NERVOUS SYSTEM, LIVER, BLOOD, REPRODUCTIVE
SYSTEM. CONTINUED INGESTION OF SMALL AMOUNTS COULD CAUSE
BLINDNESS.
Effects of Overexposure:INHALATION: IRRITATION OF MUCOUS MEMBRANES OF
UPPER RESPIRATORY TRACT, DROWSINESS, LOSS OF APPETITE, INABILITY TO
CONCENTRATE. INGESTION: HEADACHES, GASTRITIS, INTOXICATION,
BLINDNESS , DEATH. SKIN CO NTACT: IRRITATION, CRACKING, FLAKING,
DEFATTING. EYE CONTACT: IRRITATION, TEMPORARY PAIN, BLURRED VISION.
CHRONIC: DRYING, CRACKING OF SKIN, NERVOUS SYSTEM EFFECTS, LIVER,
BLOOD, REPRODUCTIVE SYSTEM E FFECTS, BLINDNESS.
Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING SKIN
DISORDERS OR EYE PROBLEMS OR IMPAIRED LIVER OR KIDNEY FUNCTION MAY
BE MORE SUSCEPTIBLE TO THE EFFECTS OF THE SUBSTANCE.
======================= First Aid Measures =======================
First Aid:INHALATION: MOVE TO FRESH AIR. IF NOT BREATHING, GIVE
ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN.
CALL A PHYSICIAN. INGESTION: INDUCE VOMITING IMMEDIATELY AS
DIRECTED BY MEDICAL PE RSONNEL. NEVER GIVE ANYTHING BY MOUTH TO AN
UNCONSCIOUS PERSON. SKIN CONTACT: REMOVE CONTAMINATED CLOTHING.
WASH SKIN WITH SOAP OR MILD DETERGENT AND WATER FOR 15 MINUTES. GET
MEDICAL ATTENTION IF IRR ITATION DEVELOPS OR PERSISTS. EYE CONTACT:
FLUSH WITH WATER FOR 15 MINUTES, LIFTING LOWER AND UPPER EYELIDS
OCCASIONALLY. GET MEDICAL ATTENTION.
===================== Fire Fighting Measures =====================
Flash Point Method:CC
Flash Point:=12.8C, 55.F
Autoignition Temp:=422.C, 791.6F
Lower Limits:3.3
Upper Limits:19
Extinguishing Media:WATER SPRAY, DRY CHEMICAL, ALCOHOL FOAM, OR CARBON
DIOXIDE. WATER MAY BE INEFFECTIVE.
Fire Fighting Procedures:WEAR FULL PROTECTIVE CLOTHING AND
NIOSH-APPROVED SCBA WITH FULL FACEPIECE OPERATED IN THE PRESSURE
DEMAND OR OTHER POSITIVE PRESSURE MODE. WATER SPRAY CAN BE USED TO
EXTINGUISH FIRES AND COOL FIRE-EXP OSED CONTAINERS. WATER MAY BE
USED TO FLUSH SPILLS AWAY FROM EXPOSURES AND TO DILUTE SPILLS TO
NON-FLAMMABLE MIXTURES.
Unusual Fire/Explosion Hazard:FLAMMABLE LIQUID AND VAPOR! DANGEROUS
FIRE HAZARD WHEN EXPOSED TO HEAT OR FLAME. ABOVE FLASH POINT,
VAPOR-AIR MIXTURES ARE EXPLOSVE WITHIN FLAMMABLE LIMITS NOTED
ABOVE. VAPORS CAN FLOW ALONG SURFACES TO DISTANT IGNITION SOURCES
AND FLASH BACK. SEALED CONTAINERS MAY RUPTURE WHEN HEATED.
SENSITIVE TO STATIC DISCHARGE.
================== Accidental Release Measures ==================
Spill Release Procedures:VENTILATE AREA. REMOVE SOURCES OF IGNITION.
WEAR PERSONAL PROTECTIVE EQUIPMENT. ISOLATE HAZARD AREA. CONTAIN
AND RECOVER LIQUID WHEN POSSIBLE. USE NON-SPARKING TOOLS AND
EQUIPMENT. COLLECT LIQUID IN A N APPROPRIATE CONTAINER OR ABSORB
WITH AN INERT MATERIAL (E.G. VERMICULITE, DRY SAND, EARTH) AND
PLACE IN A WASTE CONTAINER. DO NOT FLUSH TO SEWER! U.S. REGULATIONS
(CERCLA) (CONTD. SEE "FEDERAL REG")
====================== Handling and Storage ======================
Handling and Storage Precautions:PROTECT AGAINST PHYSICAL DAMAGE. STORE
IN A COOL, DRY, WELL-VENTILATED LOCATION, AWAY FROM AREAS WHERE
FIRE HAZARD MAY BE ACUTE. OUTSIDE OR DETACHED STORAGE IS PREFERRED.
SEPARATE FROM INCOMPATIBLES. CONTAINERS SHOULD BE BONDED AND
GROUNDED FOR TRANSFERS TO AVOID STATIC SPARKS.
Other Precautions:STORAGE AND USE AREAS SHOULD BE NO SMOKING AREA. USE
NON-SPARKING TYPE TOOLS AND EQUIPMENT, INCLUDING EXPLOSION PROOF
VENTILATION. CONTAINERS OF THIS MATERIAL MAY BE HAZARDOUS WHEN
EMPTY SINCE THEY RE TAIN PRODUCT RESIDUES (VAPORS, LIQUID); OBSERVE
ALL WARNINGS AND PRECAUSIONS LISTED FOR THE PRODUCT.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:(NIOSH APPROVED): IF THE EXPOSURE LIMIT IS
EXCEEDED, WEAR A SUPPLIED AIR, FULL-FACEPIECE RESPIRATOR, AIRLINED
HOOD, OR FULL-FACEPIECE SELF-CONTAINED BREATHING APPARATUS.
Ventilation:A SYSTEM OF LOCAL AND/OR GENERAL EXHAUST IS RECOMMENDED TO
KEEP EMPLOYEE EXPOSURES BELOW THE AIRBORNE EXPOSURE LIMITS.
Protective Gloves:WEAR IMPERVIOUS GLOVES.
Eye Protection:USE CHEMICAL SAFETY GOGGLES AND/OR FULL FACE SHIELD
WHERE SPLASHING IS POSSIBLE
Other Protective Equipment:MAINTAIN EYE WASH FOUNTAIN AND QUICK-DRENCH
FACILITIED IN WORK AREA. WEAR IMPERVIOUS PROTECTIVE CLOTHING,
INCLUDING BOOTS, LAB COAT, APRON OR COVERALLS, AS APPROPRIATE TO
PREVENT SKIN CONTACT.
Supplemental Safety and Health
LOCAL EXHAUST VENTILATION IS GENERALLY PREFERRED BECAUSE IT CAN CONTROL
THE EMISSIONS OF THE CONTAMINANT AT ITS SOURCE, PREVENTING
DISPERSION OF IT INTO THE GENERAL WORK AREA. PLEASE REFER TO THE
ACGI H DOCUMENT, "INDUSTRIAL VENTILATION, A MANUAL OF RECOMMENDED
PRACTICES", MOST RECENT EDITION, FOR DETAILS.
================== Physical/Chemical Properties ==================
HCC:F2
Boiling Pt:=78.C, 172.4F
B.P. Text:(ETHANOL)
Melt/Freeze Pt:=-114.C, -173.2F
M.P/F.P Text:(ETHANOL)
Vapor Pres:40 MM HG @ (66F)(ETHANOL)
Spec Gravity:0.79 @ 20C/4C
pH:NO INFORMATION
Solubility in Water:MISCIBLE IN WATER.
Appearance and Odor:CLEAR, COLORLESS LIQUID; MILD PLEASANT WHISKEY-LIKE
ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDANTS, SILVER SALTS, ACID CHLORIDES, ALKALI METALS, METAL
HYDRIDES, HYDRAZINE, AND MANY OTHER SUBSTANCES.
Stability Condition to Avoid:STABLE UNDER ORDINARY CONDITIONS OF USE
AND STORAGE. HEAT, FLAMES, IGNITION SOURCES AND INCOMPATIBLES.
Hazardous Decomposition Products:CARBON DIOXIDE AND CARBON MONOXIDE MAY
FORM WHEN HEATED TO DECOMPOSITION.
Conditions to Avoid Polymerization:WILL NOT OCCUR.
=================== Toxicological Information ===================
Toxicological Information:ETHYL ALCOHOL: ORAL, RAT, LD50: 7,060 MG/KG;
INHALATION, RAT, LC50: 20,000 PPM/ 10 H; IRRITATION DATA, EYE,
RABBIT: 500 MG/24H SEVERE; INVESTIGATED AS A TUMORIGEN, MUTAGEN,
REPRODUCTIVE EFFECTOR. METH YL ALCOHOL: ORAL, RAT, LD50:5,628
MG/KG; INHALATION, RAT, LC50: 64,000 PPM/4H; SKIN, RABBIT, LD50:
15,800 MG/KG; IRRITATION DATA, SKIN, RABBIT: 20 MG/24H, MODERATE;
INVESTIGATED AS A TUMORIGEN, MUTAGE N, REPRODUCTIVE EFFECTOR.
REPRODUCTIVE TOXICITY: ETHANOL HAS BEEN LINKED TO BIRTH DEFECTS IN
HUMANS. CARCINOGENICITY: ETHANOL HAS BEEN LINKED TO CANCER IN
HUMANS. CHRONIC ETHANOL INGESTION IS ASSOCIAT ED WITH .(CONTD. SEE
"SARA I I I")
===================== Ecological Information =====================
Ecological:ENVIRONMENTAL FATE: ETHANOL: WHEN RELEASED IN SOIL, MATERIAL
EXPECTED TO READILY BIODEGRADE; EXPECTED TO LEACH INTO GROUNDWATER;
EXPECTED TO QUICKLY EVAPORATE. WHEN RELEASED IN WATER, THIS
MATERIAL MA Y EVAPORATE TO A MODERATE EXTENT; NOT EXPECTED TO
SIGNIFICANTLY BIOACCUMULATE. WHEN RELEASED IN AIR: THIS MATERIAL IS
EXPECTED TO BE READILY DEGRADED BY REACTION WITH PHOTOCHEMICALLY
PRODUCED HYDROXYL RADICALS.; EXPECTED TO BE READILY REMOVED FROM
THE ATMOSPHERE BY DRY AND WET DEPOSITION; EXPECTED TO HAVE A
HALF-LIFE OF 1 T0 10 DAYS. PRODUCT IS NOT EXPECTED TO BE TOXIC TO
AQUATIC LIFE. LC50/96-HOU R VALUES FOR FISH ARE OVER 100 MG/L.
==================== Disposal Considerations ====================
Waste Disposal Methods:SPILLS NOT RECOVERED SHOULD BE SENT AS WASTE TO
RCRA APPROVED INCINERATOR OR WASTE FACILITY. PROCESSING, USE,
CONTAMINATION OF PRODUCT MAY CHANGE WASTE MANAGEMENT OPTION. STATE
AND LOCAL DISPOSAL REG ULATIONS MAY DIFFER FROM FEDERAL
REGULATIONS. DISPOSE OF CONTAINER AND UNUSED CONTENTS IN ACCORDANCE
WITH FEDERAL, STATE, AND LOCAL REQUIREMENTS.
=================== MSDS Transport Information ===================
Transport Information:DOMESTIC (LAND, D.O.T.): PROPER SHIPPING NAME:
ETHANOL SOLUTION (SD31 ALCOHOL); HAZARD CLASS: 3; UN 1170; PKG: I
I. ICAO (AIR): PROPER SHIPPIG NAME: ETHANOL SOLUTION (SD3A
ALCOHOL); HAZARD CLASS: 3; UN 1170; PKG: I I.
===================== Regulatory Information =====================
SARA Title III Information:SARA 302: ETHYL ALCOHOL(64-17-5) AND METHYL
ALCOHOL(67-56-1): NO RQ AND TPQ REGULATIONS. SARA 313: ETHYL
ALCOHOL: LIST - NO ANDCHEMICAL CATG.: NO; METHYL ALCOHOL: LIST -
YES; CHEMICAL CATG. - NO. (CONTD. FROM TOXICOLOGICAL) LIVER
CANCER. MOST INDUSTRIAL ETHANOL CONTAINS DENATURANTS THAT RENDER IT
UNDESIRABLE TO DRINK. CANCER LISTS: INGREDIENT: ETHYL ALCOHOL
(64-17-5): NTP CARCINOGEN: KNOWN - N O; ANTICIPATED - NO; IARC
CATEGORY - NONE. METHYL ALCOHOL (67-56-1): NTP CARCINOGEN : KNOWN-
NO; NTP ANTICIPATED - NO; IARC CATEGORY - NONE.
Federal Regulatory Information:ETHYL ALCOHOL (64-17-5): RCRA, CERCLA-
NO; TSCA - 261.33 - NO; 8(D) - NO; METHYL ALCOHOL (67-56-1): RCRA,
CERCLA - 5,000; TSCA - 261.33 -U154; 8(D) - NO. (CONTD. FROM
"SPILL RELEASE") REPORTING SPI LLS AND RELEASES TO SOIL, WATER, AND
AIR IN EXCESS OF REPORTABLE QUANTITIES. THE TOLL FREE NUMBER FOR TH
COAST GUARD NATIONAL RESPONSE CENTER IS 800-424-8802.
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
*** END OF RECORD *** |
|