===================== Product Identification =====================
MSDS NAME:183 8374, KODAK RAP. ACCESS DEN. TWIN PK, P. FIX,(SEE SUPPL)
NIIN:01-352-3883
Status Code:A
Kit Part:Y
MSDS Number: CLHQN
=== Responsible Party ===
Company:EASTMAN KODAK CO GOVERNMENT MARKETS CONTRACTS
Address:343 STATE ST
City:ROCHESTER
State:NY
ZIP:14650-1115
Country:US
Info Phone Num:716-722-5151/(800) 242-2424
Emergency Phone Num:716-722-5151
Preparer's Name:NOT PROVIDED
CAGE:19139
=== Contractor Identification ===
Company:EASTMAN KODAK CO GOVERNMENT MARKETS CONTRACTS
Address:343 STATE ST
Box:City:ROCHESTER
State:NY
ZIP:14650-1115
Country:US
Phone:716-722-5151/(800) 242-2424
CAGE:19139
Company:EASTMAN KODAK CO US CUSTOMER SERVICE/GOVERNMENT SALES
Address:800 LEE RD
Box:City:ROCHESTER
State:NY
ZIP:14650-3129
Country:US
Phone:800-828-6203
CAGE:5K871
============= Composition/Information on Ingredients =============
Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Minumum % Wt:60.
Maxumum % Wt:65.
Name:AMMONIUM THIOCYANATE
CAS:1762-95-4
RTECS #:XK7875000
= Wt:27.
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:AMMONIUM THIOSULFATE
CAS:7783-18-8
RTECS #:XN6465000
= Wt:10.
Name:SODIUM BISULFITE
CAS:7631-90-5
RTECS #:VZ2000000
< Wt:1.
ACGIH TLV:5 MG/M3
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:AMMONIUM BISULFITE
CAS:10192-30-0
RTECS #:WT3595000
< Wt:1.
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:NOT PROVIDED
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:GENERAL: OVEREXPOSURE TO THIOCYANATES
HAS BEEN SHOWN TO CAUSE THYROID ENLARGEMENT, DECREASE IN METABOLIC
RATE, AND SYMPTOMS OF HYPOTHYROIDISM IN HUMANS AND ANIMALS.
INHALATION: EXPECTED LOW HAZARD FOR RECOMMENDED HANDLING. IF
HYDROGEN CYANIDE GAS LIBERATED DUE TO CONTACT WITH STRONG OXIDIZER
OR ACID, MAY CAUSE DIZZINESS, HEADACHE, RAPID RESPIRATION, RAPID
PULSE, UNCONSCIOUSNESS, CONVULSIONS, DEATH . IN CONTACT WITH STRONG
ACIDS OR HEATED, SULFITES LIBERATE SULFUR DIOXIDE GAS. SULFUR
DIOXIDE GAS IRRITATING TO RESPIRATORY TRACT. ASTHMATICS OR
HYPERSENSITIVE INDIVIDUALS MAY EXPERIENCE DIFFICULT B REATHING.
(CONTD. SEE "TOXICOLOGICAL")
Explanation of Carcinogenicity:CARCINOGENICITY CLASSIFICATION
(COMPONENTS PRESENT AT 0.1% OR MORE): INTERNATIONAL AGENCY FOR
RESEARCH ON CANCER (IARC): NONE AMERICAN CONFERENCE OF GOVERNMENTAL
INDUSTRIAL HYGIENISTS (ACGIH): NONE NA TIONAL TOXICOLOGY PROGRAM
(NTP): NONE OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA):
NONE
Effects of Overexposure:INHALATION: DIZZINESS, HEADACHE, RAPID
RESPIRATION, RAPID PULSE, UNCONSCIOUSNESS, CONVULSIONS, DEATH,
RESPIRATORY TRACT IRRITATION. ASTHMATICS OR HYPERSENSITIVE
INDIVIDUALS: DIFFICULT BREATHING. EYES: IRRITATION. SKIN:
IRRITATION, SKIN SENSITIZATION. INGESTION: HARMFUL IF SWALLOWED,
IRRITATION OF GASTROINTESTINAL TRACT, WHEEZING, CHEST TIGHTNESS,
STOMACH UPSET, HIVES, FAINTNESS, WEAKNESS, DIARRHEA ..
Medical Cond Aggravated by Exposure:SOME ASTHMATICS, HYPERSENSITIVE OR
SULFITE-SENSITIVE INDIVIDUALS MAY EXPERIENCE DIFFICULT BREATHING,
WHEEZING, CHEST TIGHTNESS, STOMACH UPSET, HIVES, FAINTNESS,
WEAKNESS AND DIARRHEA.
======================= First Aid Measures =======================
First Aid:INHALATION: MOVE TO FRESH AIR. TREAT SYMPTOMATICALLY. GET
MEDICAL ATTENTION IF SYMPTOMS OCCUR. EYES: FLUSH WITH WATER FOR 15
MINUTES. GET MEDICAL ATTENTION IF SYMPTOMS OCCUR. SKIN: FLUSH WITH
WATER FOR 15 MINUTES WHILE, REMOVING CONTAMINATED CLOTHING AND
SHOES. GET MEDICAL ATTENTION IF SYMPTOMS OCCUR. WASH CONTAMINATED
CLOTHING BEFORE REUSE. DESTROY OR CLEAN CONTAMINATED SHOES.
INGESTION: INDUCE VOMITING AS DIRECTED BY MEDICAL PERSONNEL. NEVER
GIVE ANYTHING BY MOUTH TO UNCONSCIOUS PERSON. (CONTD. SEE "FEDERAL
REGULATORY")
===================== Fire Fighting Measures =====================
Flash Point:NONE
Extinguishing Media:WATER SPRAY, CARBON DIOXIDE (CO2), DRY CHEMICAL,
ALCOHOL FOAM.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND
PROTECTIVE CLOTHING. FIRE OR EXCESSIVE HEAT MAY PRODUCE HAZARDOUS
DECOMPOSITION PRODUCTS.
Unusual Fire/Explosion Hazard:SOLUTION CONTAINS A STRONG REDUCING
AGENT. DRIED PRODUCT RESIDUE CAN ACT AS A REDUCING AGENT.
================== Accidental Release Measures ==================
Spill Release Procedures:FLUSH TO SEWER WITH LARGE AMOUNTS OF WATER.
OTHERWISE, ABSORB SPILL WITH VERMICULITE OR OTHER INERT MATERIAL,
THEN PLACE IN A CONTAINER FOR CHEMICAL WASTE. CLEAN SURFACE
THOROUGHLY TO REMOVE RESIDUAL CONTAMINATION.
Neutralizing Agent:NOT PROVIDED
====================== Handling and Storage ======================
Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED TO
PREVENT THE LOSS OF WATER. KEEP AWAY FROM INCOMPATIBLE SUBSTANCES.
KEEP FROM CONTACT WITH OXIDIZING AGENTS, COMBUSTIBLE MATERIAL,
HALOGENATED MATERIALS, SODIUM HYPOCHL ORITE (BLEACH), STRONG ACIDS
(E.G. SULFURIC ACID), BASES.
Other Precautions:AVOID BREATHING MIST OR VAPOR. AVOID CONTACT WITH
EYES, SKIN, AND CLOTHING. USE WITH ADEQUATE VENTILATION. WASH
THOROUGHLY AFTER HANDLING. IF ACCIDENTALLY MIXED WITH A STRONG
OXIDIZER OR ACID, DO NOT BREATHE GAS. WARNING! CONTACT WITH A
STRONG OXIDIZER OR ACID MAY LIBERATE HYDROGEN CYANIDE GAS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE SHOULD BE NEEDED UNDER NORMAL CONDITIONS OF
USE. HOWEVER IN THE UNLIKELY EVENT THAT HAZARDOUS DECOMPOSITION
PRODUCTS ARE RELEASED, EMERGENCY RESPONSE PERSONNEL MUST WEAR A
FULL-FACE POSITIVE-PRES SURE AIR SUPPLIED RESPIRATOR. IF
RESPIRATORS ARE USED, A PROGRAM SHOULD BE INSTITUTED TO ASSURE
COMPLIANCE WITH OSHA STANDARD 29 CFR 1910.134.
Ventilation:GOOD GENERAL VENTILATION (TYPICALLY 10 AIR CHANGES PER
HOUR) SHOULD BE USED. VENTILATION RATES SHOULD BE MATCHED TO
CONDITIONS.
Protective Gloves:WEAR IMPERVIOUS GLOVES.
Eye Protection:WEAR SAFETY GLASSES WITH SIDE SHIELDS (OR GOGGLES).
Other Protective Equipment:PROVIDE EYE BATH, SAFETY SHOWER, WASHING
FACILITIES. WEAR PROTECTIVE CLOTHING APPROPRIATE FOR THE RISK OF
EXPOSURE.
Work Hygienic Practices:SUPPLEMENTARY LOCAL EXHAUST VENTILATION, CLOSED
SYSTEMS, OR RESPIRATORY PROTECTION MAY BE NEEDED IN SPECIAL
CIRCUMSTANCES.
Supplemental Safety and Health
THIS ENTRY DESCRIBES 183 8374, KODAK RAPID ACCESS DENTAL TWIN PACK,
PART FIXER, SERIAL NUMBER "CLHQN" PART OF A TWO PART KIT. SEE THIS
SAME NSN, SERIAL NUMBER "CLHQV" FOR 183 8374, KODAK RAPID ACCESS
DENTAL TWIN PACK, PART DEVELOPER FOR DATA ON SECOND PART OF KIT.
================== Physical/Chemical Properties ==================
HCC:B3
NRC/State Lic Num:NOT RELEVANT
Boiling Pt:>100.C, 212.F
Melt/Freeze Pt:M.P/F.P Text:NOT PROVIDED
Decomp Temp:Decomp Text:NOT PROVIDED
Vapor Pres:22 MBAR (16.7 MM HG) @68F
Vapor Density:0.4(AIR=1)
Spec Gravity:1.12 (H2O=1)
pH:5.4
Viscosity:NOT PROVIDED
Evaporation Rate & Reference:NOT PROVIDED
Solubility in Water:COMPLETE
Appearance and Odor:COLORLESS, ODORLESS LIQUID.
Percent Volatiles by Volume:60-65 ( WT)
Corrosion Rate:NOT PROVIDED
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, COMBUSTIBLE MATERIAL, HALOGENATED MATERIAL,
SODIUM HYPOCHLORITE (BLEACH), STRONG ACIDS, (E.G. SULFURIC ACID ),
BASES.
Stability Condition to Avoid:CONTACT WITH STRONG OXIDIZING AGENTS OR
ACIDS LIBERATES POISONOUS GAS AND FLAMMABLE MATERIAL. CONTACT WITH
BASE LIBERATES FLAMMABLE MATERIAL.
Hazardous Decomposition Products:CARBON DIOXIDE, CARBON MONOXIDE,
OXIDES OF NITROGEN, OXIDES OF SULFUR, AMMONIA, CHLORAMINE,
CYANIDES, CARBONYL SULFIDE.
Conditions to Avoid Polymerization:WILL NOT OCCUR.
=================== Toxicological Information ===================
Toxicological Information:(CONTD. FROM "HEALTH HAZARDS") EYES:
IRRITATION. SKIN: IRRITATION. HARMFUL IF ABSORBED THROUGH SKIN.
MATERIAL HAS A LOW POTENTIAL TO CAUSE ALLERGIC SKIN REACTIONS;
CASES OF HUMAN SKIN SENSTIIZATION H AVE BEEN REPORTED. INGESTION:
HARMFUL IF SWALLOWED. MAY CAUSE IRRITATION OF GASTROINTESTINAL
TRACT. SOME ASTHMATICS OR SULFITE-SENSITIVE INDIVIDUALS MAY
EXPERIENCE WHEEZING, CHEST TIGHTNESS, STOMACH UPSET, HIVES,
FAINTNESS, WEAKNESS, AND DIARRHEA. WARNING! CONTACT WITH STRONG
OXIDIZER OR ACID LIBERATES POISONOUS AND FLAMMABLE GAS, CAN CAUSE
THYROID DAMAGE, SKIN, AND EYE IRRITATION, AND IS HARMFUL IF
ABSORBED THROUGH SKIN OR SWALLOWED
===================== Ecological Information =====================
Ecological:FOLLOWING PROPERTIES ARE ESTIMATED FROM THE COMPONENTS OF
THE PREPARATIONS. POTENTIQL TOXICITY: FISH, LC50: >100 MG/L;
DAPHNID, EC50: >100 MG/L; ALGAL, IC50: >100 MG/L. ORGANICS READILY
DEGRADABLE (>7 0%): YES (7 DAYS). POTENTIAL BIOACCUMULATION: LOG
POW <1. COD (APPROXIMATE): 150 G/L; BOD5 (APPROXIMATE): 48 G/L.
POTENTIAL TOXICITY WASTE TREATMENT MICROORGANISMS, EC50: > 100
MG/L. AFTER DILUTION WI TH A LARGE AMOUNT OF WATER, FOLLOWED BY
SECONDARY WASTE TREATMENT, THIS MATERIAL IS NOT EXPECTED TO CAUSE
ADVERSE ENVIRONMENTAL EFFECTS.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISCHARGE, TREATMENT, OR DISPOSAL MAY BE SUBJECT
TO NATIONAL, STATE, OR LOCAL LAWS. FLUSH TO SEWER WITH LARGE
AMOUNTS OF WATER. SINCE EMPTIED CONTAINERS RETAIN PRODUCT RESIDUE,
FOLLOW LABEL WARNINGS E VEN AFTER CONTAINER IS EMPTIED.
=================== MSDS Transport Information ===================
Transport Information:TRANSPORTATION DATA FROM KODAK: LAND: NOT
REGULATED;OCEAN: PSN: POTASSIUM HYDROXIDE SOLUTION, CLASS 8, UN
1814, PKG: I I I, LTD. QTY. AIR: PSN: POTASSIUM HYDROXIDE SOLUTION,
CLASS 8, UN 1814, PKG: I I I //-?- X .567 L //821 //ICAO. NOTE:
MUST BE SHIPPED CARGO AIRCRAFT ONLY.
===================== Regulatory Information =====================
SARA Title III Information:CHEMICAL(S) SUBJECT TO THE REPORTING
REQUIREMENTS OF SECTION 313 OR TITLE I I I OF THE SUPERFUND
AMENDMENTS AND REAUTHORIZATION ACT (SARA) OF 1986 AND 40 CFR PART
372: AMMONIUM THIOCYANATE, AMMONIU M THIOSULFATE.
Federal Regulatory Information:NOT PROVIDED. (CONTD. FROM "FIRST AID")
WARNING! CONTACT WITH STRONG OXIDIZER OR ACID MAY LIBERATE HYDROGEN
CYANIDE GAS. IF HYROGEN CYANIDE GAS RELEASED, INFORM LOCAL
EMERGENCY AMBULANCE / RESUCITATIO N SERVICE OR PHYSICIAN THAT
PATIENT MAY HAVE BEEN EXPOSED TO HYDROGEN CYANIDE GAS.
State Regulatory Information:MATERIAL(S) KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE CANCER: NONE ; MATERIAL(S) KNOWN TO THE STATE
OF CALIFORNIA TO CAUSE ADVERSE REPRODUCTIVE EFFECTS: NONE.
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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