===================== Product Identification =====================
MSDS NAME:VANADIUM (V) OXIDE, 99.6+%, AC206420000, AC206422500
Status Code:A
MSDS Number: CLNQP
=== Responsible Party ===
Company:ACROS ORGANICS N.V.
Address:ONE REAGENT LANE
City:FAIRLAWN
State:NJ
ZIP:07410
Country:US
Info Phone Num:800-227-6701;800-ACROS-01
Emergency Phone Num:800-424-9300
CAGE:TO107
=== Contractor Identification ===
Company:ACROS ORGANICS N.V.
Address:ONE REAGENT LANE
Box:City:FAIRLAWN
State:NJ
ZIP:07410
Country:US
Phone:800-227-6701;800-ACROS-01
CAGE:TO107
============= Composition/Information on Ingredients =============
Name:VANADIUM (V) OXIDE. (EINECS# 215-239-8)
CAS:1314-62-1
RTECS #:YW2450000
= Wt:99.6
Other REC Limits:SEE OTHER INFO.
OSHA PEL:SEE ABOVE
ACGIH TLV:V205: 0.05 MG/M3
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50 (ORAL, RAT): 10 MG/KG.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EMERGENCY OVERVIEW: APPEARANCE: YELLOW
TO BROWN. DANGER: MAY BE FATAL IF SWALLOWED. MAY CAUSE SEVERE
ALLERGIC RESPIRATORY REACTION. MAY CAUSE ALLERGIC SKIN REACTION.
POISON! MAY CAUSE CENTRAL NERVOUS SYSTEM EFFECTS. MAY CAUSE EYE
AND SKIN IRRITATION. CAUSES DIGESTIVE AND RESPIRATORY TRACT
IRRITATION. TARGET ORGANS: CENTRAL NERVOUS SYSTEM. POTENTIAL HEALTH
EFFECTS: EYE: CAUSES EYE IRRITATION. CAUSE S REDNESS AND PAIN.
SKIN: MAY CAUSE SKIN IRRITATION. MAY CAUSE SKIN SENSITIZATION, AN
ALLERGIC REACTION, WHICH BECOMES EVIDENT UPON RE-EXPOSURE TO THIS
MATERIAL. INGESTION: MAY BE FATAL IF SWALLOWED. MAY CAUSE CENTRAL
(OVEREXPOSURE).
Explanation of Carcinogenicity:VANADIUM (V) OXIDE-ACGIH: A4 - NOT
CLASSIFIABLE AS A HUMAN CARCINOGEN.
Effects of Overexposure:HEALTH HAZARDS (CON'T): NERVOUS SYSTEM
EFFECTS. SYMPTOMS INCLUDE EXCESS SALIVATION, VOMITING AND DIARRHEA.
HIGH CONCENTRATIONS MAY CAUSE DROWSINESS, CONVULSIONS,
UNCONSCIOUSNESS AND CENTRAL NERVOUS S YSTEM DAMAGE. INHALATION: MAY
CAUSE RESPIRATORY TRACT IRRITATION. MAY CAUSE EFFECTS SIMILAR TO
THOSE DESCRIBED FOR INGESTION. MAY CAUSE LUNG DAMAGE. MAY CAUSE
ASTHMA AND SHORTNESS OF BREATH. CHRONIC: NO INFORMATION FOUND.
======================= First Aid Measures =======================
Eyes: FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES
OCCASIONALLY LIFTING UPPER AND LOWER LIDS. GET MEDICAL AID. SKIN:
GET MEDICAL AID. FLUSH SKIN WITH PLENTY OF SOAP AND WATER FOR AT
LEAST 1 5 MINUTES WHILE REMOVING CONTAMINATED CLOTHING AND SHOES.
INGESTION: IF VICTIM IS CONSCIOUS AND ALERT, GIVE 2-4 CUPFULS OF
MILK OR WATER. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS
PERSON. GET MED ICAL AID IMMEDIATELY. WASH MOUTH OUT WITH WATER.
INHALATION: REMOVE FROM EXPOSURE TO FRESH AIR IMMEDIATELY. IF NOT
BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT
(SPILL RELEASE)
===================== Fire Fighting Measures =====================
Flash Point:=1750.C, 3182.F
Lower Limits:NOT AVAIL.
Upper Limits:NOT AVAIL.
Extinguishing Media:USE EXTINGUISHING MEDIA MOST APPROPRIATE FOR THE
SURROUNDING FIRE.
Fire Fighting Procedures:AS IN ANY FIRE, WEAR A SELF-CONTAINED
BREATHING APPARATUS IN PRESSURE-DEMAND, NIOSH APPROVED OR
EQUIVALENT, AND FULL PROTECTIVE GEAR. SUBSTANCE IS NONCOMBUSTIBLE.
NFPA RATING: NOT PUBLISHED.
================== Accidental Release Measures ==================
Spill Release Procedures:USE PROPER PERSONAL PROTECTIVE EQUIPMENT AS
INDICATED IN CONTROL MEASURES SECTION. VACUUM OR SWEEP UP MATERIAL
AND PLACE INTO A SUITABLE DISPOSAL CONTAINER. FIRST AID (CON'T):
GIVE OXYGEN. GET MEDI CAL AID. NOTES TO PHYSICIAN: TREAT
SYMPTOMATICALLY AND SUPPORTIVELY.
====================== Handling and Storage ======================
Handling and Storage Precautions:WASH THOROUGHLY AFTER HANDLING. WASH
HANDS BEFORE EATING. DO NOT BREATHE DUST,VAPOR, MIST OR GAS. DO NOT
GET IN EYES, ON SKIN OR ON CLOTHING. DO NOT INGEST OR INHALE USE
ONLY IN A CHEMICAL FUME HOOD. STORE IN A TIGHTLY CLOSED CONTAINER.
STORE IN A COOL, DRY WELL VENTILATED AREA AWAY (OTHER PREC)
Other Precautions:HANDLING/STORAGE (CON'T): FROM INCOMPATIBLE
SUBSTANCES. POISON ROOM LOCKED.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:FOLLOW OSHA RESPIRATOR REGULATIONS FOUND IN
29CFR 1910.134 OR EUROPEAN STANDARD EN 149. ALWAYS USE A NIOSH OR
EUROPEAN STANDARD EN 149 APPROVED RESPIRATOR WHEN NECESSARY.
Ventilation:USE ADEQUATE VENTILATION TO KEEP AIRBORNE CONCENTRATIONS
LOW.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:WEAR PROTECTIVE EYEGLASSES OR CHEMICAL SAFETY
(SUPPLEMENTAL SAFETY)
Other Protective Equipment:EYEWASH AND DELUGE SHOWER MEETING ANSI
DESIGN CRITERIA . WEAR APPROPRIATE PROTECTIVE CLOTHING TO PREVENT
SKIN EXPOSURE.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. WASH HANDS
BEFORE EATING. DO NOT INGEST OR INHALE.
Supplemental Safety and Health
EYE PROTECTION (CON'T): GOGGLES AS DESCRIBED BY OSHA EYE AND FACE
PROTECTION REGULATIONS IN 29 CFR 1910.133 OR EUROPEAN STANDARD
EN166. PHYSICAL/CHEMICAL DATA (CON'T): MOLECULAR FORMULA: O5V2.
MOLE CULAR WEIGHT: 181.88. SYNONYMS: VANADIUM PENTOXIDE. NFPA
RATING: NOT PUBLISHED.
================== Physical/Chemical Properties ==================
Boiling Pt:=1750.C, 3182.F
B.P. Text:1750 DEGC@760.00MM HG
Melt/Freeze Pt:=690.C, ######F
Decomp Temp:=1750.C, 3182.F
Vapor Pres:NOT AVAILABLE
Vapor Density:NOT AVAIL.
Spec Gravity:3.3570G/CM3
pH:NOT AVAILABLE
Viscosity:NOT AVAILABLE
Evaporation Rate & Reference:NOT AVAILABLE
Solubility in Water:1G/125ML
Appearance and Odor:YELLOW TO BROWN SOLID. ODOR: NONE REPORTED.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG ACIDS.
Stability Condition to Avoid:INCOMPATIBLE MATERIALS, EXPOSURE TO AIR,
COMBUSTIBLE MATERIALS. STABLE UNDER NORMAL TEMPERATURES AND
PRESSURES.
Hazardous Decomposition Products:IRRITATING AND TOXIC FUMES AND GASES,
VANADIUM OXIDE (VOX) GASES.
Conditions to Avoid Polymerization:HAS NOT BEEN REPORTED.
=================== Toxicological Information ===================
Toxicological Information:RTECS#: CAS# 1314-62-1:YW2450000, Y22460000.
LD50/LC50: CAS# 1314-62-1:ORAL, MOUSE: LD50=23 MG/KG; ORAL, RAT:
LD50=10 MG/KG. EPIDEMIOLOGY: NO DATA AVAILABLE. TERATOGENICITY: NO
DATA AVAILABLE. REPRODU CTIVE EFFECTS: NO DATA AVAILABLE.
NEUROTOXICITY: NO DATA AVAILBLE. MUTAGENICITY: LAB REXPERIMENTS
HAVE SHOWN MUTAGENTIC EFFECTS. OTHER STUDIES: NO DATA AVAILABLE.
EXPOSURE LIMITS: VANADIUM (V) OXIDE: ACGIH: RESPIRABLE DUST AND
FUME AS V205: 0.05 MG/M3. NIOSH: AS V: 35 MG/M3 IDLH. OSHA - FINAL
PELS: NONE LISTED. OSHA VACATED PELS: VANADIUM (V) OXIDE:
RESPIRABLE DUST (AS V205): 0.05 MG/M3 TWA; FUME (AS V205): 0.05
MG/M3 TWA.
===================== Ecological Information =====================
Ecological:ECOTOXICITY: NOT AVAILABLE. ENVIRONMENTAL FATE: NOT
AVAILABLE. PHYSICAL/CHEMICAL: NOT AVAILABLE. OTHER: NOT
AVAILABLE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN MANNER CONSISTENT W/FEDERAL, STATE
& LOCAL REGULATIONS. RCRA D-SERIES MAXIMUM CONCENTRATION OF
CONTAMINANTS: NONE LISTED. RCRA D-SERIES CHRONIC TOXICITY REFERENCE
LEVELS: NONE LISTED. RC RA F-SERIES: NONE LISTED. RCRA-P SERIES:
CAS# 1314-62-1: WASTE NUMBER P120. E. RCRA U-SERIES: NONE L ISTED.
CAS#1314-62-1 IS BANNED FROM LAND DISPOSAL.
=================== MSDS Transport Information ===================
Transport Information:US DOT SHIPPING NAME: VANADIUM PENTOXIDE. HAZARD
CLASS: 6.1. UN NUMBER: UN2862. PACKING GROUP: II. IMO SHIPPING
NAME: VANADIUM PENTOXIDE. HAZARD CLASS: 6.1. UN NUMBER: 2862.
PACKING GROUP: II. IATA SH IPPING NAME: VANADIUM PENTOXIDE. HAZARD
CLASS: 6.1; UN NUMBER: 2862; PACKING GROUP: II. RID/ADR SHIPPING
NAME: VANADIUM PENTOXIDE; DANGEROUS GOODS CODE: 6.1 (58B); UN
NUMBER: 2862. CANADIAN TDG SHIPPI NG NAME: VANADIUM PENTOXIDE;
HAZARD CLASS: 6.1(9.2); UN NUMBER: UN2862.
===================== Regulatory Information =====================
SARA Title III Information:SECTION 302 (RQ) CAS# 1314-62-1: FINAL RQ =
1000 POUNDS (454 KG). SECTION 302 (TPQ) CAS# 1314-62-1: TPQ
=100/10,000 POUNDS; 1000 POUNDS. SARA CODES CAS#1314-62-1: ACUTE,
CHRONIC, FLAMMABLE. SECTION 31 3 NO CHEMICALS ARE REPORTABLE UNDER
SECTION 313. CLEAN AIR ACT: THIS MATERIAL DOES NOT CONTAIN ANY
HAZARDOUS AIR POLLUTANTS, CLASS 1 OZONE DEPLETORS OR CLASS 2 OZONE
DEPLETORS. CLEAN WATER ACT: CAS#14 14-62-1 IS LISTED AS A HAZARDOUS
SUBSTANCE UNDER THE CWA. NONE OF THE CHEMICALS IN THIS PRODUCT ARE
LISTED AS PRIORITY POLLUTANTS UNDER CWA. NONE OF THE CHEMICALS IN
THIS PRODUCT ARE LISTED AS TOXIC P OLLUTANTS UNDER CWA.
Federal Regulatory Information:TSCA CAS# 1314-62-1 IS LISTED ON TSCA
INVENTORY. HEALTH & SAFETY REPORTING LIST: NONE OF THE CHEMICALS
ARE ON THE HEALTH & SAFETY REPORTING LIST. CHEMICAL TEST RULES:
NONE OF THE CHEMICALS IN THIS PRO DUCT ARE UNDER A TEST RULE.
SECTION 12B: NONE OF THE CHEMICALS ARE LISTED UNDER TSCA SECTION
12B. TSCA SIGNIFICANT NEW USE RULE: NONE OF THE CHEMICALS IN THIS
MATERIAL HAVE A SNUR UNDER TSCA. OSHA: NO NE OF THE CHEMICALS IN
THIS PRODUCT ARE CONSIDERED HIGHLY HAZARDOUS BY OSHA. CLEAN AIR
ACT: THIS MAT ERIAL DOES NOT CONTAIN ANY HAZARDOUS AIR POLLUTANTS.
THIS MATERIAL DOES NOT CONTAIN ANY CLASS 1 OZONE DEPLETORS.
(OTHER INFORMATION)
State Regulatory Information:VANADIUM (V) OXIDE CAN BE FOUND ON THE
FOLLOWING STATE RIGHT TO KNOW LISTS: CALIFORNIA, NEW JERSEY,
FLORIDA, PENNSYLVANIA, MINNESOTA, MASSACHUSETTS. CALIFORNIA NO
SIGNIFICANT RISK LEVEL: NONE OF THE C HEMICALS IN THIS PRODUCT ARE
LISTED. EUROPEAN/INTERNATIONAL REGULATIONS: EUROPEAN LABELING IN
ACCORDANCE WITH EC DIRECTIVES - HAZARD SYMBOLS: XN. RISK PHRASES: R
20 HARMFUL BY INHALATION. SAFETY PHRA SES: S 22 DO NOT INHALE DUST.
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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