===================== Product Identification =====================
MSDS NAME:8000034, 320 CLEANER
Status Code:A
MSDS Number: CLNQB
=== Responsible Party ===
Company:MARKEM CORPORATION
Address:150 CONGRESS STREET
City:KEENE
State:NH
ZIP:03431
Country:US
Info Phone Num:603-352-1130
Emergency Phone Num:(800)424-9300
Chemtrec Ind/Phone:(800)424-9300
CAGE:38360
=== Contractor Identification ===
Company:MARKEM CORPORATION
Address:150 CONGRESS STREET
Box:City:KEENE
State:NH
ZIP:03431
Country:US
Phone:603-352-1130
CAGE:38360
============= Composition/Information on Ingredients =============
Name:ETHYL ACETATE
CAS:141-78-6
RTECS #:AH5425000
Minumum % Wt:30.
Maxumum % Wt:60.
OSHA PEL:1400 MG/M3;400 PPM
ACGIH TLV:1440 MG/M3;400 PPM
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:ISOPROPYL ALCOHOL
CAS:67-63-0
RTECS #:NT8050000
Minumum % Wt:30.
Maxumum % Wt:60.
OSHA PEL:980 MG/M3;400 PPM
ACGIH TLV:983 MG/M3;400 PPM
ACGIH STEL:1230 MG/M3;500 PPM
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYE: CAN CAUSE MINOR IRRITATION,
TEARING AND REDDENING. SKIN: CAN CAUSE MINOR IRRITATION, DEFATTING,
AND DERMATITIS. SKIN ABSORBTION: MINIMAL HAZARD IN NORMAL
INDUSTRIAL USE. INHALATION: CAN CAUSE RES PIRATORY IRRITATION,
DIZZINESS, WEAKNESS, FATIGUE, NAUSEA, HEADACHE AND POSSIBLE
UNCONSCIOUSNESS. INGESTION: IRRITATING TO MOUTH, THROAT, AND
STOMACH. CAN CAUSE ABDOMINAL DISCOMFORT, NAUSEA, VOMITING AND
DIARRHEA.
Explanation of Carcinogenicity:NONE OF THE SUBSTANCES HAVE BEEN SHOWN
TO CAUSE CANCER.
Effects of Overexposure:EYE: CAN CAUSE MINOR IRRITATION, TEARING AND
REDDENING. SKIN: CAN CAUSE MINOR IRRITATION, DEFATTING, AND
DERMATITIS. SKIN ABSORBTION: MINIMAL HAZARD IN NORMAL INDUSTRIAL
USE. INHALATION: CAN CAUSE RES PIRATORY IRRITATION, DIZZINESS,
WEAKNESS, FATIGUE, NAUSEA, HEADACHE AND POSSIBLE UNCONSCIOUSNESS.
INGESTION: IRRITATING TO MOUTH, THROAT, AND STOMACH. CAN CAUSE
ABDOMINAL DISCOMFORT, NAUSEA, VOMITING AND DIARRHEA.
Medical Cond Aggravated by Exposure:NO DATA FOUND.
======================= First Aid Measures =======================
First Aid:EYE: IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST
20 MINUTES RETRACTING EYELIDS OFTEN. GET IMMEDIATE MEDICAL
ATTENTION. SKIN: WASH WITH SOAP AND WATER. REMOVE CONTAMINATED
CLOTHING AND LAU NDER. GET MEDICAL ATTENTION IF IRRITATION DEVELOPS
OR PERSISTS. INHALATION: REMOVE TO FRESH AIR. IF NOT BREATHING,
PERFORM RESCUE BREATHING AND, IF AVAILABLE, HAVE A TRAINED PERSON
ADMINISTER OXYGEN. GET MEDICAL ATTENTION IMMEDIATELY. SEE OTHER
INFORMATION)
===================== Fire Fighting Measures =====================
Flash Point:=-3.3C, 26.F
Autoignition Temp:=398.9C, 750.F
Lower Limits:2.0
Upper Limits:12.0
Extinguishing Media:USE ALCOHOL FOAM, CARBON DIOXIDE (CO2) OR DRY
CHEMICAL. WATER MAY NOT BE EFFECTIVE TO EXTINGUISH FIRE. USE WATER
SPRAY TO COOL FIRE-EXPOSED CONTAINERS AND TO PROTECT PERSONNEL.
Fire Fighting Procedures:DO NOT ENTER FIRE AREA WITHOUT PROPER
PROTECTION INCLUDING SLF-CONTAINED BREATHING APPARATUS AND FULL
PROTECTIVE EQUIPMENT. FIGHT FIRE FROM A SAFE DISTANCE AND A
PROTECTED LOCATION. USE WATER SPRAY/FO G FOR COOLING. EVEN IF
MATERIAL IS WATER SOLUBLE, IT MAY NOT BE PRACTICAL TO EXTINGUISH
FIRE BY WATER DILUTION.
Unusual Fire/Explosion Hazard:HEAT MAY BUILD PRESSURE&RUPTURE CLOSED
CONTAINERS, SPREADING FIRE&INCREASING RISK OF BURNS OR INJURIES.
WATER MAY BE INEFFECTIVE IN FIREFIGHTING DUE TO LOW FLASH PINT AND
LIMITED MISCIBILITY WITH WATE R. FLAMMABLE/COMBUSTIBLE COMPONENTS
OF THIS MATERIAL MAY BE LIGHTER THAN WATER AND BURN WHILE FLOATING
ON THE SURFACE
================== Accidental Release Measures ==================
Spill Release Procedures:SHUT OFF IGNITION SOURCES:SMOKING,FLAMES OR
OTHER SOURCES OF IGNITION MUST NOT BE PERMITTED IN THE AREA.SMALL
SPILLS:TAKE UPW/ SAND OR OTHER NONCOMBUSTIBLE ABSORBENT MATERIAL
AND PUT INTO PROPERLY LAB ELED CONTAINERS FOR DISPOSAL.LARGE
SPILLS:DIKE AHEAD OF LIQUID SPILL AREA TO MINIMIZE MIGRATION AND
VAPOR GENERATION.VENTILATE AREA.GET PROFESSIONAL HELP FROM THE FIRE
DEPARTMENT OR OUTSIDE CONTRACTOR
====================== Handling and Storage ======================
Handling and Storage Precautions:AVOID CONTACT WITH MATERIAL, AVOID
BREATHING VAPORS, USE ONLY IN A WELL VENTILATED AREA, USE BONDING
AND GROUNDING WHEN TRANSFERRING THIS MATERIAL. STORE IN A COOL DRY
VENTILATED LOCATION, AWAY FROM O XIDIZERS, HEAT, FLAME OR OTHER
INCOMPATIBLE CONDITIONS. KEEP CONTAINER(S) CLOSED IF POSSIBLE.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF AIR MONITORING INDICATES AIRBORNE
CONCENTATIONS AT OR ABOVE THE LIMITS, OR SYMPTOMS OF INHALATION
OVER-EXPOSURE OCCUR, A RESPIRATORY PROTECTION PROGRAM MAY BE
REQUIRED. ENGINEERING CONTROLS TO REDU CE THE EXPOSURE BELOW
ACCEPTABLELIMITS ARE USUALLY PREFERABLE TO A RESPIRATOR PROGRAM.
Ventilation:LOCAL EXHAUST OR OTHER ENGINEERING CONTROLS TO KEEP
EXPOSURE TO AIRBORNE CONTAMINANTS BELOW THE TLV, PEL. EXPLOSION
PROOF WHEN EXHAUSTING FLAMMABLE VAPORS.
Protective Gloves:NITRILE, NEOPRENE, NATURAL RUBBER.
Eye Protection:CHEMICALLY RESISTANT SAFETY GLASSES WITH SIDE SHIELDS,
CHEMICAL SPLASH GOGGLES.
Other Protective Equipment:EYE WASH STATION SHOUD BE AVAILABLE.
Work Hygienic Practices:CONTACT LENSES SHOULD NOT BE WORN. CLEAN
EQUIPMENT THOROUGHLY AFTER EACH USE.
Supplemental Safety and Health
VAPORS ARE HEAVIER THAN AIR AND MAY TRAVEL TO A SOURCE OF IGNITION AND
FLASH BACK.CONTAINER MAY EXPLODE IN HEAT OR FIRE.VAPORS MAY BE
IGNITED BY HEAT,SPARKS,FLAME OR OTHER SOURCE OF IGNITION GIVING RI
SE TO A CLASS B FIRE.HEAT MAY BUILD UP PRESSURE AND RUPTURE CLOSED
CONTAINERS,SPREADING FIRE AND INCREASING RISK OF BURN
================== Physical/Chemical Properties ==================
HCC:F2
Boiling Pt:=75.6C, 168.F
Melt/Freeze Pt:M.P/F.P Text:ND
Vapor Pres:10-100
Vapor Density:>AIR
Spec Gravity:0.83
pH:ND
Viscosity:ND
Evaporation Rate & Reference:2-10 (N-BUTYL ACETATE=1)
Appearance and Odor:COLORLESS TO SLIGHTLY PALE LIQUID, STRONG SOLVENT
ODOR.
Percent Volatiles by Volume:100
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:ELEVATED TEMPERATURES IN COMBINATION WITH
SPARKS, OPEN FLAMES, OR OTHER SOURCES OF IGNITION.
Hazardous Decomposition Products:CARBON DIOXIDE; CARBON MONOXIDE.
=================== Toxicological Information ===================
Toxicological Information:ETHYL ACETATE:LC50(RAT):16000 PPM(6-HOUR
EXPOSURE).LC50(MOUSE):44000 MG/M3(12200 PPM)(3HOUR
EXPOSURE).LD50(ORAL,RAT):11.3 ML/KG(10200
MG/KG).LD50(ORAL,RAT):5600 MG/KG.LD50(ORAL,MOUSE):4100 MG/KG.LD50(
ORAL,RABBIT):4900 MG/KG.LD50(ORAL,GUINEA PIG):5500
MG/KG.LD50(DERMAL,RABBIT): GREATER THAN 20 ML/KG(1800
MG/KG).ISOPROPYL ALCOHOL:LD50(RAT,ORAL):4.42-5.84
G/KG.LD50(MOUSE,ORAL):4.8 G/KG.LD50(RABBIT,OR AL):7.9
G/KG.LD50(RABBIT,DERMAL):13 G/KG
===================== Ecological Information =====================
Ecological:ETHYL ACETATE;LC50 PIMEPHALES PROMELAS(FATHEAD MINNOW) 230
MG/L/96 HR. IF RELEASED INTO WATER ETHYL ACETATE WILL BE LOST
PRIMARILY BY EVAPORATION AND BIODEGRADATION.2-PROPANOL; LC50
PIMEPHALES PROMELA S(FATHEAD MINNOW) 11830 MH/L/1HR,11160 MG/L/24
HR 11130 MG/L/48 HR,72 HR,96 HR. WHEN RELEASED INTO
WATER,ISOPROPANOL WILL VOLATILIZE AND BIODEGRADE.IN THE ATMOSPHERE
IT WILL PHOTODEGRADE PRIMARLY BY R EACTION WITH HYDROXYL RADICALS
WITH A HALF-LIFE OF ONE TO SEVERAL DAYS. IN THE ATMOSPHERE ETHYL
ACETATE WILL REACR WITH PHOTCHEMICALLY PRODUCED HYROXYL RADICALS. A
FEW PERCENT AN HOUR WILL DISAPPEAR U NDER PHOTOCHEMICAL SMOG
SITUATIONS.
==================== Disposal Considerations ====================
Waste Disposal Methods:POTENTIAL EPA WASTE CODE (S): D001: F003.
DISPOSE OF BY INCINERATION OR WASTE WATER TREATMENT FOLLOWING
FEDERAL, STATE, LOCAL OR PROVINCIAL REGULATIONS.
=================== MSDS Transport Information ===================
Transport Information:DOT AND IATA;FLAMMABLE LIQUID N.O.S (ISOPROPANOL,
ETHYL ACETATE,3,UN1993,PGII. LABEL REQUIRED: FLAMMABLE LIQUID.
===================== Regulatory Information =====================
SARA Title III Information:THE FOLLOWING COMPONENTS ARE LISTED UNDER
SECTION 313.ISOPROAPL ALCOHOL(67-63-0).WHMIS: THE FOLLOWING
COMPONENTS ARE WHMIS WORKPLACE HAZARDOUS MATERIALS:ETHYL
ACETAT(141-78-6),ISOPROPYL ALCOHOL(67-63- 0)
Federal Regulatory Information:TSCA:ALL CHEMICALS IN THIS PRODUCT ARE
ON THE USEPA TSCA 8(B) INVENTORY,ETHYL ACETATE(141-78-6),ISOPROPYL
ALCOHOL(67-63-0).RCRA THE FOLLOWING COMPONENTS ARE SUBJECT TO RCRA
LAND DISPOSAL RESTRICTIONS: ETHYL ACETATE(141-78-6).THE FOLLOWING
COMPONENTS HAVE CERCLA REPORTABLE QUANTITIES,ETHYL
ACETATE(141-78-6)
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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