===================== Product Identification =====================
MSDS NAME:IRON (II) SULFIDE, S80015, I150500, S80016MF
Status Code:A
MSDS Number: CLNYM
=== Responsible Party ===
Company:FISHER SCIENTIFIC
Address:1 REAGENT LANE
City:FAIRLAWN
State:NJ
ZIP:07410
Info Phone Num:201-796-7100
Emergency Phone Num:201-796-7100
Resp. Party Other MSDS Num.:09875
Chemtrec Ind/Phone:(800)424-9300
CAGE:DO274
=== Contractor Identification ===
Company:FISHER SCIENTIFIC
Address:1 REAGENT LANE
Box:City:FAIRLAWN
State:NJ
ZIP:07410
Country:US
Phone:201-796-7100
CAGE:DO274
============= Composition/Information on Ingredients =============
Name:IRON (II) SULFIDE. (EINECS # 215-268-6)
CAS:1317-37-9
= Wt:100.
Other REC Limits:NIOSH: 1 MG/M3
OSHA PEL:NONE LISTED
ACGIH TLV:1 MG/M3 AS FE
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50/LC50: NOT AVAILABLE.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EMERGENCY OVERVIEW: CAUTION! THE
TOXICOLOGICAL PROPERTIES OF THIS MATERIAL HAVE NOT BEEN FULLY
INVESTIGATGED. MAY CAUSE IRRITATION. POTENTIAL TARGET ORGANS: NONE.
HEALTH EFFECTS: EYE: DUST MAY CAUSE MECHANICAL IRRITATION. SKIN:
MAY CAUSE SKIN IRRITATION. INGESTION: MAY CAUSE IRRITATION OF THE
DIGESTIVE TRACT. THE TOXICOLOGICAL PROPERTIES OF THIS SUBSTANCE
HAVE NOT BEEN FULLY INVESTIGATED. INHALAT ION: MAY CAUSE
RESPIRATORY TRACT IRRITATION. CHRONIC: NOT AVAILABLE.
Explanation of Carcinogenicity:CARCINOGENICITY: IRON (II) SULFIDE: NOT
LISTED BY ACGIH, IARC, NIOSH, NTP OR OSHA.
======================= First Aid Measures =======================
Eyes: FLUSH EYES WITH PLENTY OF WATER FOR FOR AT LEAST 15
MINUTES, OCCASIONALLY LIFTING UPPER/LOWER EYELIDS. GET MEDICAL AID.
SKIN: FLUSH SKIN WITH PLENTY OF SOAP AND WATER FOR AT LEAST 15
MINUTES WHI LE REMOVING CONTAMININATED CLOTHING AND SHOES. GET
MEDICAL AID IF IRRITATION DEVELOPS OR PERSISTS. INGESTION: IF
VICTIM IS CONSCIOUS AND ALERT, GIVE 2-4 CUPFULS OF MILK OR WATER.
NEVER GIVE ANYTHING B Y MOUTH TO AN UNCONSCIOUS PERSON. GET MEDICAL
AID. INHALATION: REMOVE FROM EXPOSURE TO FRESH AIR IMMEDIATELY. IF
NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS
DIFFICULT, GIVE OXYGEN. GET MEDICAL AID (SPILL RELEASE PROCEDURES)
===================== Fire Fighting Measures =====================
Lower Limits:NOT AVAIL
Upper Limits:NOT AVAIL
Extinguishing Media:FOR SMALL FIRES, USE WATER SPRAY, DRY CHEMICAL,
CARBON DIOXIDE OR CHEMICAL FOAM.
Fire Fighting Procedures:AS IN ANY FIRE, WEAR A SELF-CONTAINED
BREATHING APPARATUS IN PRESSURE-DEMAND, NIOSH (APPROVED OR
EQUIVALENT), AND FULL PROTECTIVE GEAR.
Unusual Fire/Explosion Hazard:N/P. AUTOIGNITION TEMPERATURE:
NOT APPLICABLE. NFPA RATING: NOT PUBLISHED
================== Accidental Release Measures ==================
Spill Release Procedures:VACUUM OR SWEEP UP MATERIAL AND PLACE INTO A
SUITABLE DISPOSAL CONTAINER. AVOID GENERATING DUSTY CONDITIONS.
FIRST AID (CONT): IF COUGH, OTHER SYMPTOMS APPEAR. NOTES TO
PHYSICIAN: TREAT SYMPT OMATICALLY. ANTIDOTE: NONE REPORTED.
====================== Handling and Storage ======================
Handling and Storage Precautions:HANDLING: USE WITH ADEQUATE
VENTILATION. AVOID CONTACT WITH SKIN AND EYES. AVOID INGESTION AND
INHALATION. STORAGE: STORE IN A COOL, DRY, WELL-VENTILATED AREA
AWAY FROM INCOMPATIBLE SUBSTANCES.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:FOLLOW THE OSHA RESPIRATOR REGULATIONS FOUND IN
29CFR 1910.134 OR EUROPEAN STANDARD EN 149. ALWAYS USE A NIOSH OR
EUROPEAN STANDARD EN 149 APPROVED RESPIRATOR WHEN NECESSARY.
Ventilation:USE ADEQUATE VENTILATION TO KEEP AIRBORNE CONCENTRATIONS
LOW. EXPOSURE LIMITS: IRON (II) SULFIDE, AS FE: 1MG/M3 TWA, 1MG/M3
NIOSH, OSHA-FINAL PELS - NONE LISTED
Protective Gloves:WEAR APPROPRIATE (IMPERVIOUS - FPN) PROTECTIVE GLOVES
TO PREVENT SKIN EXPOSURE.
Eye Protection:WEAR APPROPRIATE PROTECTIVE EYEGLASSES OR (SUPPLEMENTAL
SAFETY AND HEALTH)
Other Protective Equipment:EYEWASH AND DELUGE SHOWER MEETING ANSI
DESIGN CRITERIA . CLOTHING: WEAR APPROPRIATE PROTECTIVE CLOTHING
TO PREVENT SKIN EXPOSURE.
Supplemental Safety and Health
EYE PROTECTION (CONT): CHEMICAL SAFETY GOGGLES AS DESCRIBED BY OSHA'S
EYE AND FACE PROTECTION REGULATIONS IN 29 CFR 1910.133 OR EUROPEAN
STANDARD EN 166.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:DECOMPOSES
Melt/Freeze Pt:=1194.C, ######F
Decomp Temp:Decomp Text:NOT AVAILABLE
Vapor Density:NOT AVAIL.
Spec Gravity:4.84
pH:NOT AVAILABLE
Solubility in Water:INSOLUBLE IN WATER
Appearance and Odor:GRAY TO BROWN BLACK SOLID. ODOR: NONE REPORTED.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG ACIDS.
Stability Condition to Avoid:MOISTURE, EXPOSURE TO AIR, STRONG
OXIDANTS. STABLE UNDER NORMAL TEMPERATURES AND PRESSURES.
Hazardous Decomposition Products:OXIDES OF SULFUR, HYDROGEN SULFIDE.
=================== Toxicological Information ===================
Toxicological Information:RTECS#: CAS# 1317-37-9 UNLISTED.
EPIDEMIOLOGY: NO DATA AVAILABLE. TERATOGENICITY: NO DATA
AVAILABLE. REPRODUCTIVE EFFECTS: NO DATA AVAILABLE.
NEUROTOXICITY: NO DATA AVAILABLE. MUTAGENICITY: NO DA TA
AVAILABLE. OTHER STUDIES: NO DATA AVAILABLE. EXPOSURE
LIMITS: CHEMICAL NAME: IRON (II) SULFIDE. ACGIH: AS FE: 1 MG/M3
TWA (LISTED UNDER IRON SALTS (SOLUBLE)). NIOSH: 1 MG/M3 TWA
(LISTED U NDER IRON SALTS (SOLUBLE)). OSHA - FINAL PEL'S: NONE
LISTED. OSHA VACATED PEL'S: AS FE: 1 MG/M3 TWA (LISTED UNDER IRON
SALTS (SOLUBLE)).
===================== Ecological Information =====================
Ecological:ECOTOXICITY: NOT AVAILABLE. ENVIRONMENTAL FATE: NOT
AVAILABLE. PHYSICAL / CHEMICAL: NOT AVAILABLE. OTHER: NOT
AVAILABLE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN A MANNER CONSISTENT WITH FEDERAL,
STATE AND LOCAL REGULATIONS. RCRA P-SERIES: NONE LISTED. RCRA
U-SERIES: NONE LISTED.
=================== MSDS Transport Information ===================
Transport Information:US DOT: NO INFORMATION AVAILABLE. IMO: NOT
REGULATED AS A HAZARDOUS MATERIAL. IATA: NOT REGULATED AS A
HAZARDOUS MATERIAL. RID / ADR: NOT REGULATED AS A HAZARDOUS
MATERIAL. CANADIAN TDG: NO INF ORMATION AVAILABLE.
===================== Regulatory Information =====================
SARA Title III Information:SECTION 302 (RQ): NONE OF THE CHEMICALS IN
THIS MATERIAL HAVE AN RQ. SECTION 302 (TPQ): NONE OF THE
CHEMICALS IN THIS PRODUCT HAVE A TPQ. SECTION 313: NO CHEMICALS
ARE REPORTABLE UNDER SECTION 313 . FEDERAL REGULATORY
(CONT): DEPLETORS. THIS MATERIAL DOES NOT CONTAIN ANY CLASS 2
OZONE DEPLETORS. CLEAN WATER ACT: NONE OF THE CHEMICALS IN THIS
PRODUCT ARE LISTED AS HAZARDOUS SUBSTANCES UNDER THE CWA. NONE OF
THE CHEMICALS IN THIS PRODUCT ARE LISTED AS PRIORITY POLLUTANTS
UNDER THE CWA. NONE OF THE CHEMICALS IN THIS PRODUCT ARE LISTED AS
TOXIC POLLUTANTS UNDER THE CWA.
Federal Regulatory Information:TSCA: CAS# 1317-37-9 IS LISTED ON THE
TSCA INVENTORY. HEALTH & SAFETY REPORTING LIST: NONE OF THE
CHEMICALS ARE ON THE HEALTH & SAFETY REPORTING LIST. CHEMICAL TEST
RULES: NONE OF THE CHEMICALS IN T HIS PRODUCT ARE UNDER A CHEMICAL
TEST RULE. SECTION 12B: NONE OF THE CHEMICALS ARE LISTED UNDER
TSCA SECTION 12B. TSCA SIGNIFICANT NEW USE RULE: NONE OF THE
CHEMICALS IN THIS MATERIAL HAVE A SNUR UN DER TSCA. OSHA: NONE
OF THE CHEMICALS IN THIS PRODUCT ARE CONSIDERED HIGHLY HAZARDOUS BY
OSHA. CLEAN AIR ACT: THIS MATERIAL DOES NOT CONTAIN ANY
HAZARDOUS AIR POLLUTANTS. THIS MATERIAL DOES NOT CONTAIN ANY CLASS
1 OZONE (SARA III)
State Regulatory Information:IRON (II) SULFIDE CAN BE FOUND ON THE
FOLLOWING STATE RIGHT TO KNOW LISTS: CALIFORNIA (LISTED IRON SALTS
(SOLUBLE), PENNSYLVANIA, (LISTED AS IRON SALTS (SOLUBLE),
MASSACHUSETTS (LISTED IRON SALTS SOLU BLE). CALIFORNIA NO
SIGNIFICANT RISK LEVEL. NONE OF THE CHEMICALS IN THIS PRODUCT ARE
LISTED. EUROPEAN / INTERNATIONAL REGULATIONS: EUROPEAN
LABELING IN ACCORDANCE WITH EC DIRECTIVES: HAZARD SY MBOLS: XN.
RISK PHRASES: R 32 CONTACT WITH ACIDS LIBERATES VERY TOXIC GAS.
SAFETY PHRASES: N/P. WGK (WATER DANGER / PROTECTION): CAS #
1317-37-9: NO INFORMATION AVAILABLE. CANADA: CAS # 1317-37-9 IS
LISTED ON (OTHER INFORMATION)
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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