===================== Product Identification =====================
MSDS NAME:SUPPLEMENTAL COOLANT ADDITIVE
Status Code:A
MSDS Number: CLNYC
=== Responsible Party ===
Company:BETZDEARBORN INC
Address:4636 SOMERTON ROAD
City:TREVOSE
State:PA
ZIP:19053
Country:US
Info Phone Num:215-355-3300
Emergency Phone Num:800-877-1940
CAGE:1CWF7
=== Contractor Identification ===
Company:BETZDEARBORN INC
Address:4636 SOMERTON ROAD
Box:City:TREVOSE
State:PA
ZIP:19053
Country:US
Phone:215-355-3300
CAGE:1CWF7
============= Composition/Information on Ingredients =============
Name:SODIUM NITRITE
CAS:7632-00-0
RTECS #:RA1225000
Minumum % Wt:2.
Maxumum % Wt:5.
OSHA PEL:NOT DETERMINED
ACGIH TLV:NOT DETERMINED
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS
Name:BORIC ACID, DISODIUM SALT, PENTAHYDRATE
CAS:12179-04-3
RTECS #:VZ2540000
OSHA PEL:NOT DETERMINED
ACGIH TLV:1 MG/M3
Name:SODIUM METASILICATE, PENTAHYDRATE
CAS:10213-79-3
OSHA PEL:NOT DETERMINED
ACGIH TLV:NOT DETERMINED
Name:SODIUM NITRATE
CAS:7631-99-4
RTECS #:WC5600000
Minumum % Wt:2.
Maxumum % Wt:5.
OSHA PEL:NOT DETERMINED
ACGIH TLV:NOT DETERMINED
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50: ORAL RAT: >1,000 MG/KG (ESTIMATED)
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EMERGENCY OVERVIEW: WARNING: MAY CAUSE
SLIGHT IRRITATION TO SKIN. SEVERE IRRITANT TO EYES. MISTS/AEROSOLS
MAY CAUSE IRRITATION TO UPPER RESPIRATORY TRACT. ACUTE SKIN
EFFECTS: SKIN: PRIMARY ROUTE OF EX POSURE; MAY CAUSE SLIGHT
IRRITATION TO THE SKIN. ACUTE EYE EFFECTS: SEVERE IRRITANT TO THE
EYES. ACUTE RESPIRATORY EFFECTS: MISTS/AEROSOLS MAY CAUSE
IRRITATION TO UPPER RESPIRATORY TRACT. INGESTION EF FECTS: MAY
CAUSE GASTROINTESTIONAL IRRITATION. TARGET ORGANS: PROLONGED OR
REPEATED EXPOSURES MAY CAUSE CNS DEPRESSION AND/OR TOXICITY TO THE
KIDNEY AND BLOOD. SYMPTOMS OF EXPOSURE: MAY CAUSE REDNESS OR
ITCHING OF SKIN, (OVEREXPOSURE)
Explanation of Carcinogenicity:NO COMPONENT IS CONSIDERED TO BE A
CARCINOGEN BY THE NATIONAL TOXICOLOGY PROGRAM, THE INTERNATIONAL
AGENCY FOR RESEARCH ON CANCER, OR THE OCCUPATIONAL SAFETY AND
HEALTH ADMINISTRATION AT OSHA THRESHOL DS FOR CARCINOGENS.
Effects of Overexposure:HEALTH HAZARDS ACUTE AND CHRONIC (CON'T):
IRRITATION AND/OR TEARING OF EYES (DIRECT CONTACT). INGREDIENTS
HAZARDS: SODIUM NITRITE: OXIDIZER; TOXIC (BY INGESTION); POTENTIAL
BLOOD TOXIN. BORIC ACID, D ISODIUM SALT, PENTAHYDTATE: IRRITANT
(ABRADED SKIN); SLIGHT IRRITANT (RESPIRATORY). SODIUM METASILICATE,
PENTAHYDRATE: CORROSIVE (EYES, SKIN, AND RESPIRATORY); POTENTIAL
KIDNEY TOXIN. SODIUM NITRATE: OXIDIZER; POTENTIAL BLOOD TOXIN.
Medical Cond Aggravated by Exposure:NOT KNOWN.
======================= First Aid Measures =======================
First Aid:SKIN CONTACT: REMOVE CONTAMINATED CLOTHING. WASH EXPOSED AREA
WITH A LARGE QUANTITY OF SOAP SOLUTION OR WATER FOR 15 MINUTES. EYE
CONTACT: IMMEDIATELY FLUSH EYES WITH WATER FOR 15 MINUTES.
IMMEDIATELY CONTACT A PHYSICIAN FOR ADDITIONAL TREATMENT.
INHALATION: REMOVE VICTIM FROM CONTAMINATED AREA TO FRESH AIR.
APPLY APPROPRIATE FIRST AID TREATMENT AS NECESSARY. INGESTION: DO
NOT FEED ANYTHING BY MOU TH TO AN UNCONSCIOUS OR CONVULSIVE VICTIM.
DO NOT INDUCE VOMITING. IMMEDIATELY CONTACT PHYSICIAN. DILUTE
CONTENTS OF STOMACH USING 3-4 GLASSES OF MILK OR WATER.
===================== Fire Fighting Measures =====================
Flash Point Method:PMCC
Flash Point:>93.3C, 200.F
Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE, FOAM OR WATER.
Fire Fighting Procedures:WEAR NIOSH APPROVED SELF-CONTAINED BREATHING
APPARATUS AND FULL PROTECTIVE EQUIPMENT . FIRE FIGHTERS SHOULD WEAR
POSITIVE PRESSURE SELF-CONTAINED BREATHING APPARATUS (FACE-PIECE
TYPE) AND FULL PROTECTIVE EQUIPMENT.
Unusual Fire/Explosion Hazard:N/P. THERMAL DECOMPOSITION (DESTRUCTIVE
FIRES) YIELDS ELEMENTAL OXIDES. MISCELLANEOUS: CORROSIVE TO
ALUMINUM, RQ, UN3266; EMERGENCY RESPONSE GUIDE #154.
================== Accidental Release Measures ==================
Spill Release Procedures:VENTILATE AREA. USE SPECIFIED PROTECTIVE
EQUIPMENT. CONTAIN & ABSORB ON ABSORBENT MATERIAL. PLACE IN WASTE
DISPOSAL CONTAINER. FLUSH AREA WITH WATER. WET AREA MAY BE
SLIPPERY. SPREAD SAND/GRIT. WATER CONTAMINATED WITH THIS PRODUCT
MAY BE SENT TO A SANITARY SEWER TREATMENT FACILITY, IN ACCORDANCE
WITH ANY LOCAL AGREEMENT, A PERMITTED WASTE TREATMENT FACILITY OR
DISCHARGED (OTHER PRECAUTION)
====================== Handling and Storage ======================
Handling and Storage Precautions:HANDLING: CONTAINS AN OXIDIZER. AVOID
ALL CONTACT WITH REDUCING AGENTS, OILS, GREASES, ORGANICS AND
ACIDS. DO NOT ALLOW TO DRY. STORAGE: KEEP CONTAINERS CLOSED WHEN
NOT IN USE. USE APPROVED CONTAINERS ONLY. DO NOT FREEZE. IF
FROZEN, THAW AND MIX COMPLETELY PRIOR TO USE.
Other Precautions:N/P. SPILL/RELEASE PROCEDURE (CON'T): UNDER A PERMIT.
PRODUCT AS IS - INCINERATE OR LAND DISPOSE IN AN APPROVED LANDFILL.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:A RESPIRATORY PROGRAM THAT MEETS OSHA'S 29 CFR
1910.134 & ANSI Z88.2 REQUIREMENTS MUST BE FOLLOWED WHENEVER
WORKPLACE CONDITIONS WARRANT RESPIRATOR USE. USE AIR PURIFYING
RESPIRATORS WITHIN USE LIMITA TIONS ASSOCIATED WITH EQUIPMENT OR
ELSE USE SUPPLIED-AIR RESPIRATORS. IF AIR PURIFYING RESPIRATOR USE
IS APPROPRIATE, USE A RESPIRATOR WITH DUST/MIST FILTERS.
Ventilation:ADEQUATE VENTILATION TO MAINTAIN AIR CONTAMINANTS BELOW
EXPOSURE LIMITS.
Protective Gloves:NEOPRENE GLOVES. WASH OFF AFTER EACH USE. REPLACE AS
NECESSARY.
Eye Protection:ANSI APPROVED CHEMICAL SAFETY GOGGLES AND FULL
FACESHIELD .
Other Protective Equipment:EYEWASH AND DELUGE SHOWER MEETING ANSI
DESIGN CRITERIA . USE PROTECTIVE EQUIPMENT IN ACCORDANCE WITH 29CFR
1910 SUBPART 1.
Supplemental Safety and Health
N/P.
================== Physical/Chemical Properties ==================
Melt/Freeze Pt:=-7.6C, 18.F
M.P/F.P Text:FREEZE POINT.
Vapor Pres:APPROXIMATELY 18.0 MM HG.
Vapor Density:<1.0 AIR=1
Spec Gravity:1.121 (@ 70F, 21C).
pH:APPROX 12 AS IS
Viscosity:8 CPS @ 70F, 21C.
Evaporation Rate & Reference:< 1.00 (ETHER=1).
Solubility in Water:100%
Appearance and Odor:RED-PURPLE LIQUID. SLIGHT ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
MAY REACT WITH STRONG OXIDIZERS.
Stability Condition to Avoid:STABLE UNDER NORMAL STORAGE CONDITIONS.
BETZDEARBORN INTERNAL PUMPOUT/CLEANOUT CATEGORIES: "B".
Hazardous Decomposition Products:THERMAL DECOMPOSITION (DESTRUCTIVE
FIRES) YIELDS ELEMENTAL OXIDES.
=================== Toxicological Information ===================
Toxicological Information:ORAL LD50 RAT: >1,000 MG/KG (NOTE - ESTIMATED
VALUE). DERMAL LD50 RABBIT: >2,000 MG/KG (NOTE - ESTIMATED VALUE).
===================== Ecological Information =====================
Ecological:AQUATIC TOXICOLOGY: NO DATA AVAILABLE. BIODEGRADATION: COD
(MM/GM): 52 CALCULATED. TOC (MM/GM): 11 CALCULATED. BOD-5 (MG/GM):
0 CALCULATED. BOD-28 (MG/GM): 1 CALCULATED.
==================== Disposal Considerations ====================
Waste Disposal Methods:IFTHIS UNDILUTED PRODUCT IS DISCARDED AS A
WASTE, THE U.S. RCRA HAZARDOUS WASTE IDENTIFICATION NUMBER IS: NOT
APPLICABLE. PLEASE BE ADVISED; HOWEVER, STATE & LOCAL REQUIREMENTS
FOR WASTE DISPOSAL MAY BE MORE RESTRICTIVE OR OTHERWISE DIFFERENT
FROM FEDERAL REGULATIONS. CONSULT STATE & LOCAL REGULATI ONS
REGARDING PROPER DISPOSAL OF THIS MATERIAL.
=================== MSDS Transport Information ===================
Transport Information:DOT HAZARD: CORROSIVE TO ALUMINUM, RQ. UN/NA
NUMBER: UN3266. DOT EMERGENCY RESPONSE GUIDE#: 154.
===================== Regulatory Information =====================
SARA Title III Information:SECTION 312 HAZARD CLASS: IMMEDIATE (ACUTE);
DELAYED (CHRONIC). SECTION 302 CHEMICALS: NO REGULATED CONSTITUENT
PRESENT AT OSHA THRESHOLDS. SECTION 313 CHEMICALS: 7632-00-0,
SODIUM NITRITE, 2.0-5.0%. 7631-99-4, SODIUM NITRATE, 2.0-5.0%.
Federal Regulatory Information:TSCA: ALL COMPONENTS OF THIS PRODUCT ARE
LISTED IN THE TSCA INVENTORY. CERCLA AND/OR SARA REPORTABLE
QUANTITY (RQ): 219 GALLONS DUE TO SODIUM NITRITE.
State Regulatory Information:CALIFORNIA SAFE DRINKING WATER AND TOXIC
ENFORCEMENT ACT (PROPOSITION 65) CHEMICALS PRESENT: NO REGULATED
CONSTITUENT PRESENT AT OSHA THRESHOLDS. MICHIGAN REGULATORY
INFORMATION: NO REGULATED CONSTIT UENT PRESENT AT OSHA THRESHOLDS.
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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