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CHEMetrics, Inc. 24 Hour Emergency Numbers: (703) 590-9204
4295 Catlett Rd., Calverton, VA 20138 (540) 439-3860
(800) 356-3072 (540) 788-9026 Creation Date: 06/06/05 (2954-1)
Fax (540) 788-4856 E-mail technical@chemetrics.com Revision Date:
MATERIAL SAFETY DATA SHEET
I. CHEMICAL IDENTIFICATION VI. ACCIDENTAL RELEASE MEASURES
TRADE NAMES: FORMALDEHYDE Vacu-vials庐 and Activator Solutions Take up with absorbent material. Place in small containers for disposal.
VII. HANDLING AND STORAGE
KIT CATALOG NO.: K-4203
COMPONENT CATALOG NOS.: A-4201 and A-4202 Always wear eye protection when working with these ampoules.
WARNING: Do not break the tip of the ampoule unless it is completely
DESCRIPTION: Reagent ampoules and accessory solutions for the immersed in your sample. Breaking the tip in the air may cause the glass
determination of formaldehyde in water. Each Vacu-vial鈩? contains ampoule to shatter.
approximately 2 mL of liquid reagent sealed under vacuum. The bottle of A- If this product is used as directed, the user will not come in contact with or be
4201 activator solution contains approximately 3.4 grams of solid chemical. exposed to any of its chemical components.
The bottle of A-4202 activator solution contains approximately 10 mL of Wash thoroughly after handling. Avoid contact with eyes.
accessory solution. Fragile. Liquid in glass. Handle with care.
This product has a limited shelf life. Product should not be used after date
In the Vacu-vials庐: specified on refill. The shelf life can be extended by 18 months if the
NFPA RATINGS: HEALTH: 1 FLAMMABILITY: 0 REACTIVITY: 0 ampoules are refrigerated when not in use.
If product is not refrigerated, it should be stored in the dark and at room
In the Activator Solution, Catalog No. A-4201: temperature.
NFPA RATINGS: HEALTH: 2 FLAMMABILITY: 0 REACTIVITY: 1
VIII. EXPOSURE CONTROLS/PERSONAL PROTECTION
In the Activator Solution, Catalog No. A-4202:
NFPA RATINGS: HEALTH: 3 FLAMMABILITY: 0 REACTIVITY: 1
OSHA PEL: None listed
ACGIH TLV: 2 mg/m3 C Potassium Hydroxide, 0.1 mg/m3 TWA Persulfate
II. COMPOSITION/INFORMATION ON INGREDIENTS PROTECTIVE EQUIPMENT: Safety glasses, protective gloves
IX. PHYSICAL AND CHEMICAL PROPERTIES
In the Vacu-vials庐:
COMPONENT: Purpald庐
CAS NO.: 1750-12-5 PERCENT: < 1.0 In the Vacu-vials庐:
STATE: Liquid APPEARANCE: Straw or colorless ODOR: None
COMPONENT: Potassium Hydroxide SOLUBILITY IN WATER: Complete pH: 13.5
CAS NO.: 1310-58-3 PERCENT: 3.0 BOILING POINT: 105掳C MELTING POINT: 0掳C
VAPOR PRESSURE: N/A SPECIFIC GRAVITY: 1.06
COMPONENT: Deionized Water VAPOR DENSITY: N/A
CAS NO.: 7732-18-5 PERCENT: >93.0
In the Activator Solution, Catalog No. A-4201:
In the Activator Solution, Catalog No. A-4201: STATE: Crystalline, powder APPEARANCE: White
COMPONENT: Sodium Persulfate ODOR: None SOLUBILITY IN WATER: Soluble
CAS NO.: 7775-27-1 GRAMS: 3.4
In the Activator Solution, Catalog No. A-4202:
In the Activator Solution, Catalog No. A-4202: STATE: Liquid APPEARANCE: Colorless ODOR: None
COMPONENT: Potassium Hydroxide SOLUBILITY IN WATER: Miscible pH: 13 - 14
CAS NO.: 1310-58-3 PERCENT: 80.0 BOILING POINT: 1320掳C (KOH) MELTING POINT: 360掳C (KOH)
VAPOR PRESSURE: 1 mm Hg @ 719掳C (KOH)
COMPONENT: Deionized Water SPECIFIC GRAVITY: 2.0 (KOH)
CAS NO.: 7732-18-5 PERCENT: 20.0
X. STABILITY AND REACTIVITY
III. HAZARDS IDENTIFICATION INCOMPATIBILITIES: acids, bases, strong reducing agents, metals,
combustible materials, organic material
Danger! Corrosive. Causes severe burns. Harmful if swallowed. HAZARDOUS DECOMPOSITION PRODUCTS: When heated to decomposi-
ACUTE TOXICITY: Irritation, burns, headache, coughing, nausea, vomiting, tion, hydrogen gas and oxides of sodium, potassium, carbon, nitrogen and
diarrhea, eye and tissue damage, shortness of breath; symptoms may be sulfur may be emitted.
delayed Stable under normal conditions.
CHRONIC TOXICITY: Irritation, allergic reactions, sensitization, dermatitis,
XI. TOXICOLOGICAL INFORMATION
conjunctivitis, destructive effect on tissues
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Allergies and eye,
skin, and respiratory disorders CARCINOGENIC STATUS: None
No other data available at this time.
IV. FIRST AID MEASURES
XII. ECOLOGICAL INFORMATION
EYE AND SKIN CONTACT: Immediately flush eyes and skin with water for
15 minutes. No data available.
INGESTION: Do not induce vomiting. If victim is conscious and alert, give 2-4
XIII. DISPOSAL CONSIDERATIONS
cupfuls of milk or water. Never give anything by mouth to an unconscious
person. Seek medical attention.
INHALATION: Remove individual to fresh air. Dispose of in a manner consistent with Federal, State, and Local Regulations.
V. FIRE FIGHTING MEASURES XIV. TRANSPORT INFORMATION
FLASH POINT: 180 掳C AUTOIGNITION POINT: N/A U.S. DOT: 49 CFR, 173.4 Exceptions for Small Quantities
FLAMMABILITY LIMITS: UPPER: N/A LOWER: N/A IATA: Dangerous Goods in Excepted Quantities
EXTINGUISHING MEDIA: Water spray Hazard Class: 8 ID: UN 1760 GROUP: II
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CHEMetrics, Inc. 24 Hour Emergency Numbers: (703) 590-9204
4295 Catlett Rd., Calverton, VA 20138 (540) 439-3860
(800) 356-3072 (540) 788-9026 Creation Date: 06/06/05 (2954-1)
Fax (540) 788-4856 E-mail technical@chemetrics.com Revision Date:
XV. REGULATORY INFORMATION
EUROPEAN INFORMATION:
EU Symbols: C - CORROSIVE, Xn - HARMFUL, O - OXIDIZING
Risk Phrases: Causes severe burns. Harmful if swallowed. May cause
sensitization by inhalation and skin contact. Contact with combustible material
may cause fire.
Safety Phrases: Keep away from combustible materials. Avoid contact with
skin and eyes. Wear suitable protective clothing, gloves, and eye/face
protection. In case of contact with skin or eyes, rinse immediately with plenty
of water and seek medical advice. In case of accident or if you feel unwell,
seek medical advice immediately (show the label where possible).
CANADIAN INFORMATION:
WHMIS Classification: C, D2A, D1B, D2B, E
All chemical components of this product are listed on Canada鈥檚 DSL or NDSL.
U.S. INFORMATION:
All chemical components of this product are listed on the TSCA Inventory.
XVI. OTHER INFORMATION
THE ABOVE INFORMATION IS BELIEVED TO BE ACCURATE AND REPRESENTS THE BEST
INFORMATION CURRENTLY AVAILABLE TO US. ALL PRODUCTS ARE OFFERED IN
ACCORDANCE WITH THE MANUFACTURER'S CURRENT PRODUCTION SPECIFICATIONS
AND ARE INTENDED SOLELY FOR USE IN ANALYTICAL TESTING. THE MANUFACTURER
SHALL IN NO EVENT BE LIABLE FOR ANY INJURY, LOSS OR DAMAGE RESULTING FROM
THE HANDLING, USE OR MISUSE OF THESE PRODUCTS.
Vacu-vials庐 is a registered trademark of CHEMetrics, Inc.
Purpald庐 is a registered trademark of Aldrich Chemical Company.
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