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MSDS Material Safety Data Sheet
CAS

57966-95-7
131807-57-3
577-11-7
110-17-8

File Name: farmchemafrica_com---MSDS_Equation_pro.asp
SAFETY DATA SHEET              according to EC directive 2001/58/EC



EQUATION庐 PRO
Version 2.0
Revision Date 18.05.2004 Ref. 130000000279

This SDS adheres to the standards and regulatory requirements of the European Community and may not meet the
regulatory requirements of other countries.

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE COMPANY/UNDERTAKING

Product information

Product name : EQUATION PRO

Synonyms : DPX-KX007 WG, Iteral, B10474623

Use of the : fungicide
Substance/Preparation

Company : Du Pont de Nemours (France) S.A.S.
Rue de L'Universit茅 137
75334 Paris
Telephone : +3333145506550
Telefax :

Emergency telephone : +44-(0)2871-861.313
number


2. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical Name CAS-No. EC-No. Classification Concentration [%]
Cymoxanil 57966-95-7 261-043-0 Xn; R22 30
R43
N; R50/53

Famoxadone 131807-57-3 N; R50/53 22,5

Sodium alkylnaphtalenesulfonate Polymer Xi; R36 3,8

Sodium Dioctyl Sulfosuccinate 577-11-7 209-406-4 Xi; R36/38 1,6

Fumaric Acid 110-17-8 203-743-0 Xi; R36 1,6

For the full text of the R phrases mentioned in this Section, see Section 16.

3. HAZARDS IDENTIFICATION

Harmful if swallowed.
Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

4. FIRST AID MEASURES

Inhalation : Move to fresh air. Oxygen or artificial respiration if needed. Consult a physician
after significant exposure.

Skin contact : Wash off immediately with soap and plenty of water while removing all
contaminated clothes and shoes. If skin irritation persists, call a physician.

Eye contact : Rinse immediately with plenty of water, also under the eyelids. If eye irritation

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SAFETY DATA SHEET according to EC directive 2001/58/EC



EQUATION庐 PRO
Version 2.0
Revision Date 18.05.2004 Ref. 130000000279

persists, consult a specialist.

Ingestion : Drink 1 or 2 glasses of water. Do not induce vomiting without medical advice.
Never give anything by mouth to an unconscious person. Call a physician
immediately.


5. FIRE-FIGHTING MEASURES

Suitable extinguishing : water spray, foam, dry powder, carbon dioxide (CO2),
media

Extinguishing media which : high volume water jet, (contamination risk),
must not be used for safety
reasons

Special protective : In the event of fire, wear self-contained breathing apparatus.
equipment for fire-fighters

Further information : (on small fires) If area is heavily exposed to fire and if conditions permit, let fire
burn itself out since water may increase the area contaminated. Cool containers
/ tanks with spray water.


6. ACCIDENTAL RELEASE MEASURES

Personal precautions : Wear personal protective equipment.

Environmental precautions : Do not flush into surface water or sanitary sewer system. Do not contaminate
surface water. Do not allow material to contaminate ground water system.

Methods for cleaning up : Clean up promptly by scoop or vacuum. Use approved industrial vacuum
cleaner for removal. Shovel into suitable container for disposal.


7. HANDLING AND STORAGE

Handling
Advice on safe handling : Provide appropriate exhaust ventilation at places where dust is formed. Avoid
dust formation.

Advice on protection : Keep away from heat and sources of ignition.
against fire and explosion


Storage
Requirements for storage : Keep containers tightly closed in a dry, cool and well-ventilated place. Store in a
areas and containers place accessible by authorized persons only. Keep out of the reach of children.

Advice on common storage : No materials to be specially mentioned.




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SAFETY DATA SHEET according to EC directive 2001/58/EC



EQUATION庐 PRO
Version 2.0
Revision Date 18.05.2004 Ref. 130000000279


8. EXPOSURE CONTROLS / PERSONAL PROTECTION


Engineering measures
Ensure adequate ventilation, especially in confined areas.

Personal protective equipment
Respiratory protection : Half mask with a particle filter P2 (EN 143).

Hand protection : Material: nitrile rubber
Glove thickness: 0,4 - 0,7 mm
Wearing time: 480 min


Eye protection : safety glasses

Skin and body protection : long sleeved clothing

Hygiene measures : Keep away from food, drink and animal feedingstuffs. Wash hands before
breaks and immediately after handling the product. When using, do not eat,
drink or smoke. Wash contaminated clothing before re-use.

Protective measures : All chemical protective clothing should be visually inspected prior to use.
Clothing and gloves should be replaced in case of chemical or physical damage
or if contaminated.


9. PHYSICAL AND CHEMICAL PROPERTIES


Form : solid, dry flowable water dispersible granules,

Colour : brown,

pH : 5 - 7 at 10 g/l ( 20 掳C), Method: CIPAC MT 75

Flash point : not applicable

Oxidizing properties : The product has been shown not to be oxidising in a test following Directive
67/548/EEC (Method A17, oxidising properties).

Explosive properties : Not explosive

Bulk density : 580 kg/m3

Solubility/qualitative : dispersible


10. STABILITY AND REACTIVITY

Materials to avoid : humid air, water,

Hazardous decomposition : Carbon oxides, nitrogen oxides (NOx),


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SAFETY DATA SHEET according to EC directive 2001/58/EC



EQUATION庐 PRO
Version 2.0
Revision Date 18.05.2004 Ref. 130000000279

products

Hazardous reactions : No decomposition if stored and applied as directed.


11. TOXICOLOGICAL INFORMATION

Acute oral toxicity : LD50/rat : 1 333 mg/kg

Acute inhalation toxicity : no data available

Acute dermal toxicity : LD50/rabbit : > 5 000 mg/kg

Skin irritation : rabbit
No skin irritation

Eye irritation : rabbit
No eye irritation

Sensitization : Maximisation Test (GPMT) guinea pig Animaltest did not cause sensitization by
skin contact.


12. ECOLOGICAL INFORMATION

Elimination information (persistence and degradability)

Biodegradability : no data available


Ecotoxicity effects
Toxicity to fish : LC50/96 h/Rainbow trout: 0,038 mg/l


Toxicity to fish : LC50/96 h/Rainbow trout: 0,040 mg/l


Toxicity to algae : EC50/72 h/selenastrum capricornutum: 0,011 mg/l


Aquatic toxicity : EC50/48 h/Daphnia: 0,054 mg/l
Method:




13. DISPOSAL CONSIDERATIONS

Product : In accordance with local and national regulations. Must be incinerated in a
suitable incineration plant holding a permit delivered by the competent
authorities. Do not contaminate ponds, waterways or ditches with chemical or
used container.

Contaminated packaging : Do not re-use empty containers.


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SAFETY DATA SHEET according to EC directive 2001/58/EC



EQUATION庐 PRO
Version 2.0
Revision Date 18.05.2004 Ref. 130000000279


14. TRANSPORT INFORMATION

ADR
Class: 9
Packaging group: III
Classification Code: M7
HI No:: 90
UN-No: 3077
Labelling No.: 9
Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (contains
Famoxadone, Cymoxanil)

IATA_C
Class: 9
Packaging group: III
UN-No: 3077
Labelling No.: 9MI
Proper shipping name: Environmentally hazardous substance, solid, n.o.s. (contains Famoxadone,
Cymoxanil)

IMDG
Class: 9
Packaging group: III
UN-No: 3077
Labelling No.: 9
Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (contains
Famoxadone, Cymoxanil)



15. REGULATORY INFORMATION

Labelling according to EEC Directive
Symbol(s) : Xn Harmful
N Dangerous for the environment


Hazardous components: Famoxadone
Cymoxanil

R-phrase(s) : R22 Harmful if swallowed.
R50/53 Very toxic to aquatic organisms, may cause long-term
adverse effects in the aquatic environment.


S-phrase(s) : S35 This material and its container must be disposed of in a safe
way.
S46 If swallowed, seek medical advice immediately and show this
container or label.
S57 Use appropriate containment to avoid environmental
contamination.


Exceptional labelling of : To avoid risks to man and the environment, comply with the instructions for use.

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Print date: 2004 - 08 - 31
SAFETY DATA SHEET according to EC directive 2001/58/EC



EQUATION庐 PRO
Version 2.0
Revision Date 18.05.2004 Ref. 130000000279

special preparations

Sensitising components contains:
- Cymoxanil
May produce an allergic reaction.


16. OTHER INFORMATION

Text of R phrases mentioned in Section 2
R22 Harmful if swallowed.
R36 Irritating to eyes.
R36/38 Irritating to eyes and skin.
R43 May cause sensitization by skin contact.
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.



The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at
the date of its publication. The information given is designed only as a guidance for safe handling, use, processing,
storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The
information relates only to the specific material designated and may not be valid for such material used in
combination with any other materials or in any process, unless specified in the text.




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