Material Name: JM PVC Membrane Adhesive (Water Based) Material Safety Data
Sheet ID: 3230
Section 1 - Chemical Product and Company Identification
Product Name JM PVC Membrane Adhesive (Water Based)
CAS# None Assigned
Generic Name Adhesive (Water Based)
Formula Mixture
Chemical Name: Mixture
Hazard Label ML-5113 or equivalent label
Manufacturer Information
Johns Manville Telephone: 303-978-2000 8:00AM-5:00PM M-F
Roofing Systems Group Internet Address: http://www.jm.com
P.O. Box 5108 Emergency: 800-424-9300 (Chemtrec, In English)
Denver, CO 80127 USA
Trade Names: JM PVC Membrane Adhesive (Water Based)
Section 2 - Composition / Information on Ingredients
CAS # Component Percent
Proprietary Proprietary Ingredients 83-95
108-88-3 Toluene 3-7
67-56-1 Methyl alcohol 1-5
13463-67-7 Titanium dioxide 1-5
Section 3 - Hazards Identification
Emergency Overview
APPEARANCE AND ODOR: White liquid.
Potential Health Effects
Summary
Prolonged or excessive exposures to solvent fumes can result in nausea and dizziness and central nervous system damage.
HMIS Ratings: Health = 2 Fire = 3 Reactivity = 0 PPE = B
Inhalation
Acute signs of overexposure could be headache, dizziness, nausea, upper respiratory dryness or irritation, drowsiness, mental
depression or narcosis, and difficulty in breathing.
Chronic effects of overexposure to solvent vapors could lead to permanent effects to the nervous system, body organs, or the
brain. Use with adequate ventilation.
Skin
Removal of skin oils, irritation, dermatitis, even sensitization with long overexposure.
Absorption
Can pass through skin and cause symptoms similar to those resulting from swallowing or inhalation.
Ingestion
May be harmful or fatal if swallowed.
Eyes
May cause irritation upon contact.
Primary Routes of Entry (Exposure)
Skin contact, eye contact, inhalation, ingestion.
Target Organs
Respiratory system, skin, and eye.
Medical Conditions Aggravated by Exposure
Pre-existing chronic respiratory, skin, or eye diseases or conditions.
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Material Name: JM PVC Membrane Adhesive (Water Based) Material Safety Data
Sheet ID: 3230
Section 4 - First Aid Measures
First Aid: Inhalation
Remove to fresh air. If symptoms persist contact a physician.
First Aid: Skin
Wash with soap and water. If irritation develops or persists, seek medical attention.
First Aid: Ingestion
Product is not intended to be ingested or eaten. Seek medical attention immediately.
First Aid: Eyes
Flush eyes with large amounts of water for 5-15 minutes. If irritation develops or persists, seek medical attention.
First Aid: Notes to Physician
No specific antidote. Supportive care. Treatment based on judgment of the physician in response to reactions of the patient.
Section 5 - Fire Fighting Measures
Flash Point: 140掳F
Upper Flammable Limit (UFL): 12.8 Lower Flammable Limit (LFL): 1.1
Auto Ignition: Not determined Flammability Classification: II
Rate of Burning: Not determined
General Fire Hazards
WARNING. Flammable liquid and vapor. Vapors may ignite and/or cause flash fires. Eliminate sources of ignition. Use
adequate cross-ventilation sufficient to remove odor and vapors.
Extinguishing Media
Foam, dry chemical, carbon dioxide, water spray, or fog.
Fire Fighting Equipment/Instructions
Firefighters should wear full-face, self-contained breathing apparatus and impervious protective clothing. Firefighters should
avoid inhalation of any combustion products.
Section 6 - Accidental Release Measures
Containment Procedures
Eliminate all ignition sources. Dam, mop, absorb onto sawdust or other absorbent.
Clean-Up Procedures
Transfer liquids to covered metal containers for recovery or disposal, or remove with inert absorbent. Place absorbent diking
materials in covered metal containers for disposal. Prevent contamination of sewers, steams, and groundwater with spilled
material or used absorbent.
Section 7 - Handling and Storage
Handling Procedures
Keep container closed when not in use. Use adequate ventilation to avoid breathing vapors when cover is removed.
Containers may be hazardous when empty due to product residues. Eliminate all sources of ignition.
Storage Procedures
Store at 60掳F-95掳F and out of the sun.
Section 8 - Exposure Controls / Personal Protection
Exposure Guidelines
A: General Product Information
Protective equipment should be used as necessary to prevent irritation to the eyes, skin and respiratory tract.
B: Component Exposure Limits
Toluene (108-88-3)
ACGIH: 50 ppm TWA
Skin - potential significant contribution to overall exposure by the cutaneous route
OSHA: 100 ppm TWA; 375 mg/m3 TWA
150 ppm STEL; 560 mg/m3 STEL
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Material Name: JM PVC Membrane Adhesive (Water Based) Material Safety Data
Sheet ID: 3230
Methyl alcohol (67-56-1)
ACGIH: 200 ppm TWA
250 ppm STEL
Skin - potential significant contribution to overall exposure by the cutaneous route
OSHA: 200 ppm TWA; 260 mg/m3 TWA
250 ppm STEL; 325 mg/m3 STEL
Prevent or reduce skin absorption
Titanium dioxide (13463-67-7)
ACGIH: 10 mg/m3 TWA
OSHA: 10 mg/m3 TWA (total dust)
PERSONAL PROTECTIVE EQUIPMENT
Personal Protective Equipment: Eyes/Face
Safety glasses with sideshields, chemical goggles are recommended.
Personal Protective Equipment: Skin
Wear impervious clothing, boots and gloves to prevent skin contact.
Personal Protective Equipment: Respiratory
If workplace exposure limit of product is exceeded, a NIOSH/MSHA approved air supplied respirator is advised in absence of
proper environmental controls.
Ventilation
Local exhaust ventilation should be provided at areas of use to remove gases & vapors from work area. General dilution
ventilation should be provided as necessary to keep gases & vapors below the applicable exposure limits and guidelines. The
need for ventilation systems should be evaluated by a professional industrial hygienist, while the design of specific ventilation
systems should be conducted by a professional engineer.
Personal Protective Equipment: General
No additional information available.
Section 9 - Physical & Chemical Properties
Appearance: White
Physical State: pH:
liquid/emulsion 6.0
Boiling Point: Melting Point:
148掳F-232掳F Not applicable
Freezing Point: Specific Gravity:
Not determined 1.078
VOC: Evaporation Rate:
151.5 g/L Faster than n-Butyl Acetate
Section 10 - Chemical Stability & Reactivity Information
Chemical Stability
This is a stable material.
Chemical Stability: Conditions to Avoid
Fire, sparks, static electricity
Incompatibility
Strong oxidizing agents, strong acids and bases.
Hazardous Decomposition
Carbon monoxide, carbon dioxide
Hazardous Polymerization
Will not occur.
Section 11 - Toxicological Information
Acute Toxicity
A: General Product Information
No additional information available.
B: Component Analysis - LD50/LC50
Toluene (108-88-3)
Inhalation LC50 Rat: 12.5 mg/L/4H; Inhalation LC50 Rat: >26700 ppm/1H; Oral LD50 Rat: 636 mg/kg; Dermal LD50 Rabbit:
8390 mg/kg
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Material Name: JM PVC Membrane Adhesive (Water Based) Material Safety Data
Sheet ID: 3230
Methyl alcohol (67-56-1)
Inhalation LC50 Rat: 83.2 mg/L/4H; Inhalation LC50 Rat: 64000 ppm/4H; Oral LD50 Rat: 5628 mg/kg; Dermal LD50 Rabbit:
15800 mg/kg
Titanium dioxide (13463-67-7)
Oral LD50 Rat: >10000 mg/kg
Carcinogenicity
A: General Product Information
No additional information available.
B: Component Carcinogenicity
Toluene (108-88-3)
ACGIH: A4 - Not Classifiable as a Human Carcinogen
IARC: Group 3 - Not Classifiable (IARC Monograph 71 [1999], Monograph 47 [1989])
Titanium dioxide (13463-67-7)
ACGIH: A4 - Not Classifiable as a Human Carcinogen
IARC: Group 2B - Possibly Carcinogenic to Humans (IARC Monograph 93 posted, Monograph 47
[1989])
Section 12 - Ecological Information
Ecotoxicity
A: General Product Information
No data available for this product.
B: Component Analysis - Ecotoxicity - Aquatic Toxicity
Toluene (108-88-3)
96 Hr LC50 Pimephales promelas: 25 mg/L [flow-through] (1 day old); 96 Hr LC50 Oncorhynchus mykiss: 24.0 mg/L [static];
96 Hr LC50 Lepomis macrochirus: 24.0 mg/L [static]; 96 Hr LC50 Lepomis macrochirus: 13 mg/L [static]
96 Hr EC50 Selenastrum capricornutum: >433 mg/L
30 min EC50 Photobacterium phosphoreum: 19.7 mg/L
48 Hr EC50 water flea: 11.3 mg/L; 48 Hr EC50 water flea: 310 mg/L; 48 Hr EC50 Daphnia magna: 11.3 mg/L
Methyl alcohol (67-56-1)
96 Hr LC50 Pimephales promelas: 29400 mg/L [flow-through] (28 days old); 96 Hr LC50 Oncorhynchus mykiss: 13 mg/L
(fingerling)
5 min EC50 Photobacterium phosphoreum: 43000 mg/L; 15 min EC50 Photobacterium phosphoreum: 40000 mg/L; 25 min
EC50 Photobacterium phosphoreum: 39000 mg/L
Section 13 - Disposal Considerations
US EPA Waste Number & Descriptions
A: General Product Information
Product waste is classified as hazardous under Resource Conservation and Recovery Act (RCRA) regulations at 40 CFR 261.
Dispose of material in accordance with federal, state, and local regulations in a hazardous waste facility. If you are unsure of
the regulations, contact your local Public Health Department, or the local office of the Environmental Protection Agency (EPA).
B: Component Waste Numbers
Toluene (108-88-3)
RCRA: waste number U220
Methyl alcohol (67-56-1)
RCRA: waste number U154 (Ignitable waste)
Disposal Instructions
Dispose of waste material according to Local, State, Federal, and Provincial Environmental Regulations.
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Material Name: JM PVC Membrane Adhesive (Water Based) Material Safety Data
Sheet ID: 3230
Section 14 - Transportation Information
International Transportation Regulations
DOT: Adhesive NEC. Excepted per 49 CFR 173.150(f).
IATA: UN1133, Adhesives, 3, PG III
FLAMMABLE LIQUID label required
Inner packagings must not exceed 10 L (2.6 gal) each (depending on the type of inner packaging used) and the outer package
may not exceed 60 L (15.8 gal). A UN single package is limited to 60 L (15.8 gal).
IMDG: UN1133, Adhesives, 3, PG III
FLAMMABLE LIQUID label required
Section 15 - Regulatory Information
US Federal Regulations
A: General Product Information
SARA 311 Status. The following SARA 311 designations apply to this product: Immediate (acute) health hazard. Delayed
(chronic) health hazard. Fire hazard.
B: Component Analysis
This material contains one or more of the following chemicals required to be identified under SARA Section 302 (40 CFR 355
Appendix A), SARA Section 313 (40 CFR 372.65) and/or CERCLA (40 CFR 302.4).
Toluene (108-88-3)
SARA 313: 1.0 % de minimis concentration
CERCLA: 1000 lb final RQ; 454 kg final RQ
Methyl alcohol (67-56-1)
SARA 313: 1.0 % de minimis concentration
CERCLA: 5000 lb final RQ; 2270 kg final RQ
State Regulations
A: General Product Information
Other state regulations may apply. Check individual state requirements.
B: Component Analysis - State
The following components appear on one or more of the following state hazardous substances lists:
Component CAS # CA FL MA MN NJ PA
Toluene 108-88-3 Yes No Yes Yes Yes Yes
Methyl alcohol 67-56-1 Yes No Yes Yes Yes Yes
Titanium dioxide 13463-67-7 No No Yes Yes Yes Yes
The following statement(s) are provided under the California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65):
WARNING! This product contains a chemical known to the state of California to cause reproductive/developmental effects.
Component CAS #
Toluene 108-88-3
A: TSCA Status
This product and its components are listed on the TSCA 8(b) inventory.
None of the components listed in this product are listed on the TSCA Export Notification 12(b) list.
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Material Name: JM PVC Membrane Adhesive (Water Based) Material Safety Data
Sheet ID: 3230
B: Component Analysis - Inventory
Component CAS # TSCA DSL EINECS
Toluene 108-88-3 Yes Yes Yes
Methyl alcohol 67-56-1 Yes Yes Yes
Titanium dioxide 13463-67-7 Yes Yes Yes
Component Analysis - WHMIS IDL
The following components are identified under the Canadian Hazardous Products Act Ingredient Disclosure List:
Component CAS # Minimum Concentration
Toluene 108-88-3 1%
Methyl alcohol 67-56-1 1%
Section 16 - Other Information
Other Information
Prepared for:
Johns Manville
Roofing Systems Group
P. O. Box 5108
Denver, CO USA 80217-5108
Prepared by:
Johns Manville Technical Center
P.O. Box 625005
Littleton, CO USA 80162-5005
The information herein is presented in good faith and believed to be accurate as of the effective date given. However, no
warranty, expressed or implied, is given. It is the buyer's responsibility to ensure that its activities comply with Federal, State or
provincial, and local laws.
Date MSDS # Reason
02/20/06 3230-1.0000 New MSDS authoring system.
02/08/07 3230-1.0001 Regulatory update. Minor edits throughout.
This is the end of MSDS # 3230
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