Conservation Chemicals Consultant Ltd.
MATERIAL SAFETY DATA SHEET (MSDS)
Date of Issue: 10th May 2005
SECTION 1: name of substance/preparation and the company
Product Name: CCC Ltd Timbertect Plus range of products - standard grades, surface transport.
CCC Ltd, Unit 6, Lightburn Industrial Estate, Ulverston, Cumbria, LA12 7NE, UK.
Tel: +44 (0) 1 229 588 449, fax: + 44 (0) 1 229 588 670, email: info@conservationchemicals.co.uk
SECTION 2: composition/information on ingredients
Manufactured formulations based on hexamethylene diamine based isocyante prepolymers dissolved only in non-toxic
biodegradeable oxgenated solvents with other additives to control product behaviour.
Prepolymer of aliphatic isocyanate CAS No 28182-81-2 EU No: none-
Free isocyanate content less than 0.15% on total product (hexamethylene-1.6-diisocyanate,
CAS No 822-06-0 EU No 212-485-8).
LD50 oral, rat >5,000 mg/kg
Skin/mucous compatibility, rabbit:
skin 4 hours exposure - non-irritant
eyes - moderate reddening and slight swelling
classified as IRRITANT
50-70% of blends of ethoxyethyl propionate and methoxypropoxy acetate 100||100 % as solvent - flash point between 46 and 65
潞Celsius depending on grade
- classified as flammable when bellow 57 潞Celsius - avoid inhalation of fumes or vapour - oxygenated solvents degrade to water
and carbon dioxide)
EEP EINECS No 212-112-9 - CAS No 763-69-9; MPA EINECS No 203-603-9 ; CAS no 108-65-6
SECTION 3: Hazards identification
Irritant by inhalation; skin and eye contact.
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Flammable.
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SECTION 4: First Aid Measures
In case of inhalation: - move affected person to fresh air and seek medical attention if symptoms persist.
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In case of eye contact rinse carefully and thoroughly with water for 15 minutes with lifting of eyelids and seek medical
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attention if irritation persists.
In case of skin contact wipe off with absorbent tissue and wash with soap and water or resin removing cream before
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the product cures.
In case of irritation of respiratory tract or swallowing, do not induce vomiting - seek medical attention.
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SECTION 5: Fire Fighting Measures
Extinguishing media: CO2, foam, dry powder
In case of fire, formation of carbon monoxide, nitrogen oxide, isocyanate vapour and traces of hydrogen cyanide, particularly in
deficiency of oxygen.
Firefighters must wear self-contained breathing apparatus.
SECTION 6: Accidental Release Measures
Do not empty into drains; remove by absorbing into eg sawdust, cement, sand etc. After one hour, saturate with water and
transfer to waste container - store for several days then dispose of as waste to landfill or by incineration.
SECTION 7: Handling and Storage
Keep containers dry and in a cool well ventilated place away from sources of heat or direct sunlight.
Ensure good ventilation in the working area - exhaust ventilation is necessary if the product is sprayed.
Avoid contact with skin or eyes.
SECTION 8: Exposure Controls/Personal Protection
For exposure controls, see section 15
Wear suitable protective clothing, particularly rubber or pvc gloves, goggles, particularly if spraying or working
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overhead.
Respiratory protection is required if working in areas of low or poor ventilation and recommended in other cases - use
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Half-mask organic vapour respirator (A1) or, if spraying, full face cartridge (or air-fed) mask.
Hypersentitive persons (eg asthamatics, chronic bronchitics) should not use the product
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Keep away from foodstuffs, drinks, tobacco.
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Wash hands before breaks and at end of work
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Remove contaminated clothing immediately.
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SECTION 9: Physical Properties
Form mobile to low viscosity liquids
Colour clear to opalescent, depending on grade
Odour fruity solvent odour
Freezing point n/a
Initial Boiling point 155-160 潞C
Density approx 0.97-1.02 (DIN 53217)
Vapour Pressure 3mbar at 20潞C
Viscosity approx 275mPa-s at 25 潞C
Solubility in water immiscible - reacts as described in Section 10
pH value n/a
Flash Point 46 - 65 潞C (DIN 51758) depending on grade
Ignition Temperature not determined
Explosion Limits 1-8%
SECTION 10: Stability and Reactivity
Hazardous decompositition products: no hazardous decomposition products when stored and handled correctly.
Hazardous reactions: exothermic reaction with strong oxidising reagents.
SECTION 11: Toxicological Information
Acute toxicity
LD50 oral, rat: more than 5000mg/kg
Skin and mucous compatibilty, rabbit:
skin 4 hours - slight reddening, very slight superficical cauterisation
eyes - slight reddening
for further information, contact the manufacturer
Special properties/effects:
over-exposure, especially during spraying operations without the necessary precautions, entails the risk of concentration-
dependent irritating effects on eyes, nose, throat and u/l rt. Delayed apearance of these effects is likely and development of
hypersensititivity is possible.
Hypersenstitive persons may suffer from these effects even at low concentrations.
Prolonged contact with the skin may cause defatting, reddening and irritation effects
SECTION 12: Environmental Information
Do not allow to escape into drains, sewers, waterways - components may be harmful to aquatic life.
Bio-accumulation potential is high due to low biodegradation rates of some non-volatile components.
SECTION 13: Disposal Considerations
May be incinerated in suitable facility provided local regulations are observed.
Empty containers may be disposed of as refuse after any residue has dried or is neutralised with a mixture of water and
ammonia; after this procedure, remove hazard labels.
SECTION 14: Transport Information
UN No 1263
Packing Group (Standard grades) III
ADR/RID class 31(c)
IMO Class 3
ICAO/IATA Class 3
IMO Shipping name Paint or related substance, flash point over 23C, less than 57C: flammable
IATA Shipping name Paint, nos, FP over 23C
ADR/RID Shipping Name 1263 Paint or related substance, flash point over 23C, less than 57C: flammable
Other Information N/A
Marine Pollutant yes
SECTION 15: Regulatory Information
(applicable to liquid uncured material only)
labelling as required by Chemicals (Hazard Information and Packaging for Supply) Amendment Regulations and corresponding
EU directives:
Symbol: Xi hazard description: Irritant
R10 flammable for grades where fp is less than 57潞C.
R21 irritating on inhalation.
R42/43 may cause sensitisation by inhalation and skin contact.
S24/25 avoid contact with skin and eyes.
S26 in case of contact with eyes, rinse immediately with plenty of water and
seek medical advice.
S51 ensure good ventilation/use only in well ventilated areas.
Occupational exposure limit:
Maximum exposure limit - HMDI 8 hour 0.02/mg/m3
15 min stel 0.07mg/m3
these products 8 hour 0.08mg/m3
15 min stel 0.2mg/m3 measured as NCO
EEP (CAS No 763-69-9) LT Exp (8 hrs) 50ppm ST Exp (15min) 100ppm
Effects of Overexposure irritation of nose, throat and eyes on prolonged
exposure in poor ventilation; irritating to eyes on
prolonged contact with vapour.
May be irritating to skin on prolonged contact.
May cause sensitisation in some persons.
SECTION 16: Other information
For use in the protection and coating stone, wood and other construction materials
All personnel involved in the use or handling of this product should be adequately informed and trained in handling of the material
and use of protective measures and should read and understand this data sheet.
This data sheet should be read in conjunction with the technical information/data sheet for the product
The information given herein is based on current knowledge and experience and its purpose is to describe the product in terms of
its safety requirements; the data does not signify any warranty with regard to the products properties or performance.
Date of issue - original February 1997, latest revision February 1998, November 2000, May 2001, June 2002, June 2003, May
2004, May 2005.
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