Sartomer Company
Material Safety Data Sheet
Product: Sarbox SB405 Revised Date: 01-17-2005
MSDS ID: S-000774 Replaces Date: 03-06-2000
01. GENERAL INFORMATION
Sartomer Company, Inc.
Oaklands Corporate Center
502 Thomas Jones Way
Exton, Pennsylvania 19341
Emergency phone numbers:
800/424-9300 (CHEMTREC)
610/692-8401 (Sartomer Co., Inc.)
Product information:
610/363-4100
GENERIC NAME
Aromatic acid acrylate half ester blend
DOT PROPER SHIPPING NAME UN/NA NUMBER
Resin Solution UN 1866
DOT HAZARD CLASS/DIVISION PACKING GROUP
3, Flammable Liquid III
02. SUMMARY OF HAZARDS
WARNING
PHYSICAL HAZARDS: Combustible liquid and vapor
Unstable (reactive) upon depletion of inhibitor
ACUTE HEALTH EFFECTS: Slight eye irritant
(SHORT-TERM) Not a skin irritant based on available data
Suspect skin sensitization hazard
Suspect skin absorption hazard
Suspect respiratory tract irritation hazard
May be slightly toxic by inhalation
Suspect ingestion hazard
CHRONIC HEALTH EFFECTS: No chronic health effects information is available
for this product as a whole. See Supplement section
of MSDS for information on product's components.
03. COMPONENTS
COMPONENT NAME CAS NUMBER % COMPOSITION (BY WT.)
Aromatic acid acrylate half ester Not Assigned AP 66-69
PM Acetate; 1-methoxy-2-propanol
acetate (PMA) 108-65-6 AP 30
2-Hydroxyethyl acrylate (HEA) 818-61-1 AP 1-4
04. PHYSICAL AND CHEMICAL DATA
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Sartomer Company
Material Safety Data Sheet
Product: Sarbox SB405 Revised Date: 01-17-2005
MSDS ID: S-000774 Replaces Date: 03-06-2000
BOILING POINT pH
PMA: 150C/302F AP 6
FREEZING POINT DRY POINT
N/DA N/AP
SPECIFIC GRAVITY (H20=1 at 39.2F) VOLATILE CHARACTERISTICS
N/DA AP 30%
VISCOSITY UNITS, TEMP. (Brookfield) SOLUBILITY IN WATER
AP 510 cps at 60C/140F AP 30%
VAPOR PRESSURE STABILITY
PMA: 3.7 mm Hg at 20C/68F Stable
VAPOR SP GR (AIR=1 at 60 - 90F) HAZARDOUS POLYMERIZATION
PMA: 4.6 May occur
APPEARANCE AND ODOR
Clear liquid with acrylic odor
CONDITIONS AND MATERIALS TO AVOID
Heat, sparks, open flames, or other ignition sources
High temperatures, localized heat sources (ie, drum or band heaters),
oxidizing conditions, freezing conditions, direct sunlight, ultraviolet
radiation, inert gas blanketing;
Strong oxidizers, strong reducers, free radical initiators, inert gases,
oxygen scavengers
HAZARDOUS DECOMPOSITION PRODUCTS
Acrid smoke-fumes/carbon monoxide/carbon dioxide and perhaps other toxic
vapors may be released during a fire involving this product.
Peroxides may also form during a fire involving this product.
05. OCCUPATIONAL EXPOSURE LIMITS
SUBSTANCE SOURCE TYPE VALUE TIME
PMA AIHA WEEL* TWA 100 ppm 8 hours
HEA Manufacturer TWA 1 ppm 8 hours
Recommendations STEL 3 ppm 15 minutes
*WEEL = Workplace Environmental Exposure Level
06. FIRE AND EXPLOSION
FLASH POINT METHOD=(PMCC) AUTOIGNITION TEMP. METHOD=ASTM E 659-78
AP 43C/109F PMA: 354C/670F
FLAMMABLE LIMITS (% VOLUME IN AIR)
LOWER: PMA, 1.3 at 78C/173F UPPER: PMA, 13.1 at 139C/283F
FIRE AND EXPLOSION HAZARDS
When heated above flash point, releases vapors. When mixed with air and
exposed to ignition source, vapors can burn in open or explode if confined.
Vapors may be heavier than air. May travel long distances along ground
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Sartomer Company
Material Safety Data Sheet
Product: Sarbox SB405 Revised Date: 01-17-2005
MSDS ID: S-000774 Replaces Date: 03-06-2000
before igniting/flashing back to vapor source. Fine sprays/mists may be
combustible at temperatures below normal flash point.
High temperatures, inhibitor depletion, accidental impurities, or exposure to
radiation or oxidizers may cause spontaneous polymerizing reaction generating
heat/pressure. Closed containers may rupture or explode during runaway
polymerization.
Peroxides may also form during a fire or explosion involving this product.
EXTINGUISHING MEDIA
Dry chemical
CO2
Water spray
Foam
Water fog
SPECIAL FIREFIGHTING PROCEDURES
Do not enter fire area without proper protection. See Section 4 -
decomposition products possible. Fight fire from safe distance/protected
location. Heat/impurities may increase temperature/build pressure/rupture
closed containers, spreading fire, increasing risk of burns/injuries. Water
may be ineffective in firefighting due to low solubility. Use water
spray/fog for cooling. Pressure relief system may plug with solids,
increasing risk of overpressure. Notify authorities if liquid enters
sewer/public waters.
07. HEALTH HAZARDS
ROUTES OF EXPOSURE
INHALATION -- PRIMARY ROUTE
Overexposure may cause irritation to the respiratory tract and to other
mucous membranes.
Excessive concentrations may cause nervous system depression, headache, and
weakness leading to unconsciousness.
EYE CONTACT -- PRIMARY ROUTE
May cause minor eye irritation. Symptoms may include excessive tearing,
blinking and redness.
SKIN ABSORPTION -- PRIMARY ROUTE
Although no appropriate human or animal health effects data are known to
exist, this material is expected to be a health hazard by skin absorption.
May be extremely harmful if absorbed through the skin.
SKIN IRRITATION -- PRIMARY ROUTE
This material is not expected to cause skin irritation based on available
test data.
Although no appropriate human or animal health effects data is known to
exist, this material may cause an allergic skin reaction (sensitization) in
susceptible individuals upon repeated exposure.
INGESTION
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Sartomer Company
Material Safety Data Sheet
Product: Sarbox SB405 Revised Date: 01-17-2005
MSDS ID: S-000774 Replaces Date: 03-06-2000
Although no appropriate human or animal health effects data are known to
exist, this material is expected to be an ingestion hazard.
May be extremely harmful if ingested in large amounts.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE
This material or its emissions may induce an allergic or sensitization
reaction and thereby aggravate systemic disease.
08. PROTECTIVE EQUIPMENT / CONTROL MEASURES
RESPIRATORY PROTECTION
If exposure exceeds the occupational exposure limit, use NIOSH/MSHA approved
respiratory protection equipment as specified in the NIOSH/OSHA 1981
occupational health guidelines for chemical hazards.
If this material is handled at elevated temperature or under mist forming
conditions, NIOSH/MSHA approved respiratory protection equipment should be
used.
EYE PROTECTION
Eye protection such as chemical splash goggles and/or face shield must be
worn when possibility exists for eye contact due to splashing or spraying
liquid, airborne particles, or vapor. Contact lenses should not be worn.
SKIN PROTECTION
This material is not expected to cause skin irritation based on available test
data. However, skin contact should be avoided to prevent skin sensitization.
Wear gloves and protective clothing as needed and practice good personal
hygiene. Wash hands and other areas of exposed skin with mild soap and water
before eating, drinking, smoking and when leaving work.
ENGINEERING CONTROLS
Use only where ventilation can control exposures to within exposure
standard(s). Special attention should be given to low areas/pits where
flammable vapors can accumulate.
OTHER HYGIENIC PRACTICES
Emergency eye wash fountains and safety showers should be available in the
immediate vicinity of any potential exposure.
OTHER WORK PRACTICES
Use good personal hygiene practices. Wash hands before eating, drinking,
smoking, or using toilet facilities. Promptly remove soiled clothing/wash
thoroughly before reuse. Shower after work using plenty of soap and water.
09. EMERGENCY AND FIRST AID
INHALATION
If overcome by exposure, remove victim to fresh air immediately. Give oxygen
or artificial respiration as needed. Obtain emergency medical attention.
Prompt action is essential.
EYE CONTACT
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Sartomer Company
Material Safety Data Sheet
Product: Sarbox SB405 Revised Date: 01-17-2005
MSDS ID: S-000774 Replaces Date: 03-06-2000
In case of eye contact, immediately rinse with clean water for 20-30 minutes.
Retract eyelids often. Obtain emergency medical attention if pain, blinking,
tears or redness persist.
SKIN CONTACT
Remove contaminated clothing as needed. Wash skin thoroughly with mild
soap/water. Flush with lukewarm water for 15 minutes. If sticky, use waterless
cleaner first.
INGESTION
If swallowed, give lukewarm water (pint) if victim completely conscious/
alert. Do not induce vomiting/risk of damage to lungs exceeds poisoning risk.
Obtain emergency medical attention.
EMERGENCY MEDICAL TREATMENT PROCEDURES
Note to physician: First aid treatment for ingestion of the minor component
of this product, according to the component's manufacturer, is immediate
evacuation of stomach contents.
10. SPILL AND DISPOSAL
PRECAUTIONS IF MATERIAL IS SPILLED OR RELEASED
Release can cause fire/explosion. May polymerize/release heat/gases.
Extinguish all ignition sources. Blanket with firefighting foam. Impound/
recover large land spill; soak up small spill. On water, contain/minimize
dispersion/collect. Report per regulatory requirements.
WASTE DISPOSAL METHODS
When discarded in its purchased form, this product is a RCRA hazardous waste
because it exhibits the characteristic of ignitability as defined in 40 CFR
261, Subpart C. However, it is the responsibility of the generator to
determine at the time of disposal whether the product meets the criteria of
hazardous waste. Comply with all applicable federal, state and local
regulations. Disposal options include fuel blending or incinerating. Assure
emissions comply with applicable regulations. Dilute aqueous waste may
biodegrade; avoid overloading/poisoning plant biomass. Assure effluent
complies with applicable regulations.
11. ADDITIONAL PRECAUTIONS
HANDLING AND STORAGE PROCEDURES
Unless inhibited, product can polymerize, raising temperature and pressure,
possibly rupturing container. Check inhibitor content often, adding to bulk
liquid if needed. Do not blanket or mix with oxygen-free gas as it renders
inhibitor ineffective. Do not store at/below 32F -- inhibitor can separate
as a solid. If frozen, warm and remix material gently (< 90F). Prevent
moisture contact. Prevent contamination by foreign materials and limit
storage time. Store in tightly closed, properly vented containers away from:
heat, sparks, open flame, strong oxidizers, radiation and other initiators.
Store drums with bung in up position. Carefully vent internal pressure
before removing closure. Containers must be grounded before beginning
transfer. Use only non-sparking tools. Electrical equipment should conform
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Sartomer Company
Material Safety Data Sheet
Product: Sarbox SB405 Revised Date: 01-17-2005
MSDS ID: S-000774 Replaces Date: 03-06-2000
to National Electric Code. Handle "empty" containers with care/vapor residue
may be flammable.
If peroxide formation is suspected, do not move container. Addition of water
will lessen peroxide formation.
DECONTAMINATION PROCEDURES
Follow standard plant procedures or supervisor's instructions for
decontamination operations.
12. LABEL INFORMATION
USE STATEMENT
FOR INDUSTRIAL USE ONLY
SIGNAL WORD
WARNING
PHYSICAL HAZARDS
COMBUSTIBLE LIQUID AND VAPOR
UNSTABLE (REACTIVE) UPON LOSS OF INHIBITOR
HEALTH HAZARDS
MAY BE HARMFUL IF INHALED, INGESTED OR ABSORBED THROUGH SKIN
MAY CAUSE RESPIRATORY TRACT IRRITATION
MAY CAUSE ALLERGIC SKIN REACTION
PRECAUTIONARY MEASURES
DO NOT HANDLE NEAR HEAT, SPARKS, OR OPEN FLAME.
AVOID OXIDIZING AGENTS.
HAZARDOUS POLYMERIZATION MAY OCCUR UPON DEPLETION OF INHIBITOR.
USE ONLY WITH ADEQUATE VENTILATION/PERSONAL PROTECTION.
AVOID BREATHING VAPORS/MISTS.
AVOID CONTACT WITH EYES, SKIN AND CLOTHING.
DO NOT TASTE OR SWALLOW.
WASH THOROUGHLY AFTER HANDLING.
KEEP CONTAINER CLOSED WHEN NOT IN USE.
BEFORE USING, READ MATERIAL SAFETY DATA SHEET (MSDS).
13. SUPPLEMENT
NPCA HMIS RATING
Health 2
Flammability 2
Reactivity 2
Personal protection See Section 8 of MSDS.
CHRONIC HEALTH EFFECTS INFORMATION:
No chronic health effects information is available for this product as a
whole. However, an 11 day inhalation study with PMA in male rats showed no
observed effects (NOEL) at 300 ppm. The lowest observed effect level (LOEL)
in this study was 1000 ppm (target organ: kidney). In addition, an 11 day
inhalation study with PMA in mice and female rats showed no observed effects
(NOEL) at 3000 ppm (the highest concentration tested).
Neurotoxic effects, including peripheral nerve damage, were seen in a 13 week
Date Printed: 05-25-2005 Page: 6 of 7
Sartomer Company
Material Safety Data Sheet
Product: Sarbox SB405 Revised Date: 01-17-2005
MSDS ID: S-000774 Replaces Date: 03-06-2000
animal study with HEA, the minor component of this product. In addition,
prolonged or repeated exposures to HEA may cause liver or kidney damage
according to several references.
REGULATORY INFORMATION
TSCA STATUS
TSCA status: All components of this product are listed, or excluded from
listing, on the United States Environmental Protection Agency Toxic Substances
Control Act (TSCA) inventory.
CALIFORNIA PROPOSITION 65
California Proposition 65 Information: This product contains, or may contain,
trace quantities of a substance(s) known to the state of California to cause
cancer and/or reproductive toxicity.
This material contains an inhibitor (HQ, MEHQ, etc.) at <1%. The type and
amount meet product specifications. Contact a company representative for
exact concentrations and details on inhibitor level maintenance.
INTERNATIONAL STATUS
Australia (AICS):
Canada (DSL):
China (CECS): included on inventory
Europe (EINECS):
Japan (ENCS): not included on inventory
Korea (ECL):
Philippines (PICCS):
*Note - qualifiers and codes used in this MSDS
EQ = Equal; AP = Approximately; LT = Less Than; GT = Greater Than;
TR = Trace; UK = Unknown; N/AP = Not Applicable; N/P = No Applicable
Information Found; N/DA = No Data Available
14. DISCLAIMERS
Some of the information presented and conclusions drawn herein are from
sources other than direct test data on the product itself. The information in
this MSDS was obtained from sources which we believe are reliable. However,
the information is provided without any warranty, express or implied,
regarding its correctness. The conditions or methods of handling, storage, use
and disposal of the product are beyond our control and may be beyond our
knowledge. For this and other reasons, we do not assume responsibility and
expressly disclaim liability for loss, damage or expense arising out of or in
any way connected with the handling, storage, use or disposal of the product.
This MSDS was prepared and is to be used only for this product. If the
product is used as a component in another product, this MSDS information may
not be applicable. This MSDS has been prepared in accordance with the
requirements of the OSHA Hazard Communication Standard (29 CFR 1910.1200).
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