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Product Name: Hydrocal 100
Manufacturer: Calumet Lubricants Company
Revision Date: 07/12/2001
SECTION 01 CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
SECTION 02 COMPOSITION AND INFORMATION ON INGREDIENTS
SECTION 03 HAZARD IDENTIFICATION
SECTION 04 FIRST AID INFORMATION
SECTION 05 FIRE FIGHTING MEASURES
SECTION 06 ACCIDENTAL RELEASE MEASURES
SECTION 07 HANDLING AND STORAGE
SECTION 08 EXPOSURE CONTROLS AND PERSONAL PROTECTION
SECTION 09 PHYSICAL AND CHEMICAL PROPERTIES
SECTION 10 STABILITY AND REACTIVITY
SECTION 11 TOXICOLOGICAL INFORMATION
SECTION 12 ECOLOGICAL INFORMATION
SECTION 13 DISPOSAL CONSIDERATIONS
SECTION 14 TRANSPORTATION INFORMATION
SECTION 15 REGULATORY INFORMATION
SECTION 16 OTHER INFORMATION
Product Name: Hydrocal 100
Manufacturer: Calumet Lubricants Company
Address: 2780 Waterfront Pkwy E. Suite 200 Indianapolis IN 46214
Telephone: (317) 328-5660
Emergency: (800) 424-9300
Contact: Anne Goldsmith
Trade Name: Hydrocal 100
Synonyms: 1120-00
Description: Petroleum Hydrocarbon Oil
NFPA 704M漏 Rating:
Health: 0 Fire: 1 Reactivity: 0 Special:
0=Insignificant 1=Slight 2=Moderate 3=High 4=Extreme
SECTION 02 COMPOSITION AND INFORMATION ON INGREDIENTS
Chemical Ingredients (% by Weight)
Ingredient CAS Number Percent Weight
Heavy Hydrotreated Naphthenic Distillates (petroleum)64742-52-5 100.0 %
SECTION 03 HAZARD IDENTIFICATION
EMERGENCY OVERVIEW
Not expected to cause a severe emergency hazard.
POTENTIAL HEALTH EFFECTS
PRIMARY ROUTE(S) OF ENTRY
Skin.
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EYES
Tests on similar materials suggest that no eye effect be expected.
SKIN
Tests on similar materials indicate that no significant adverse health effects are
expected to occur upon short-term exposure. Prolonged or repeated skin contact may
cause skin irritation.
INGESTION
Tests on similar materials indicate no significant adverse effects expected.
Practically non-toxic.
INHALATION
Tests on similar material indicate no acute effects are expected.
CHRONIC (CANCER INFORMATION)
Prolonged and/or repeated contact with this material may produce skin
irritation and inflammation.
Carcinogen listed by: National Toxicology Program (NO)
I. A. R. C. (NO)
OSHA (NO)
ACGIH (NO)
This product does not require a cancer hazard warning in accordance with the OSHA
Hazard Communication Standard.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE
Personnel with pre-existing skin disorders should avoid contact with this product.
Health studies have shown that many petroleum hydrocarbons and synthetic
lubricants pose potential human health risks which may vary from person to person.
As a precaution, exposure to liquids, vapors, mists or fumes should be minimized.
SECTION 04 FIRST AID INFORMATION
EYES
If splashed into eyes, flush with clear water for 15 minutes or until irritation
subsides. If irritation persists, call a physician.
SKIN
In case of skin contact, remove any contaminated clothing and wash skin with soap
and water. Launder or dry-clean clothing before reuse. If product is injected into
or under the skin, or into any part of the body, regardless of the appearance of
the wound or its size, the individual should be evaluated immediately by a
physician as a surgical emergency. Even though initial symptoms from high pressure
injection may be minimal or absent, early surgical treatment within the first few
hours may significantly reduce the ultimate extent of injury. Prolonged or repeated
skin contact may cause skin irritation.
INGESTION
Product is practically non-toxic. Do not induce vomiting. Obtain emergency medical
attention.
INHALATION
Vapor pressure is very low. Vapor inhalation under ambient conditions is normally
not a problem. If overcome by vapor from hot product, immediately remove from
exposure and call a physician. If breathing is irregular or has stopped, start
resuscitation; administer oxygen, if available. If overexposed to oil mist, remove
from exposure until excessive oil mist condition subsides.
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SECTION 05 FIRE FIGHTING MEASURES
FLAMMABLE PROPERTIES
FLASH POINT: >320隆F >160隆C COC ASTM D92
AUTO IGNITION: >650隆F >343隆C
FLAMMABILITY CLASS: IIIB
LOWER EXPLOSIVE LIMIT (%): Not determined
UPPER EXPLOSIVE LIMIT (%): Not determined
FIRE AND EXPLOSION HAZARDS
Slightly combustible. OSHA/NFPA Class IIIB Combustible Liquid. If heated above its
flash point will release flammable vapors which can burn in the open or be
explosive in confined spaces if exposed to ignition source. Mists or sprays may be
flammable below oils normal flash point. Keep away from extreme heat or open flame.
EXTINGUISHING MEDIA
Foam, water spray (fog), dry chemical, carbon dioxide, and vaporizing liquid type
extinguishing agents mat all be suitable for extinguishing fires involving this
type of product, depending on size or potential size of fire and circumstances
related to the situation. Plan fire protection and response strategy through
consultation with local fire protection authorities or appropriate specialists.
The following procedures for this type of product are based on the recommendations
in the National Fire Protection Association's "Fire Protection Guide on Hazardous
Materials", Tenth Edition (1991):
Use water spray, dry chemical, foam or carbon dioxide to extinguish the fire. Use
water to keep fire-exposed containers cool. If a leak or spill has not ignited, use
water spray to disperse the vapors and to provide protection for persons attempting
to stop a leak. Water spray may be used to flush spills away from exposures.
Minimize breathing of gases, vapor, fumes or decomposition products. Use supplied-
air breathing equipment for enclosed or confined spaces or as otherwise needed.
DECOMPOSITION PRODUCTS UNDER FIRE CONDITIONS
Fumes, smoke, carbon monoxide, aldehydes and other decomposition products, in the
case of incomplete combustion.
SECTION 06 ACCIDENTAL RELEASE MEASURES
CLEAN WATER ACT / OIL POLLUTION ACT
This product may be classified as an oil under Section 311 of the Clean Water Act,
and under the Oil Pollution Act. Discharges or spills into or leading to surface
waters that cause a sheen must be reported to the National Response Center.
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
Recover free product. Add sand, earth, or other suitable absorbent to spill area.
Minimize skin contact. Keep product out of sewers and watercourses by diking or
impounding. Advise authorities if product has entered or may enter sewers,
watercourses, or extensive land areas.
Assure conformity with applicable governmental regulations.
SECTION 07 HANDLING AND STORAGE
HANDLING AND STORAGE PRECAUTIONS
Keep away from flames, sparks or hot surfaces. Never use a torch to cut
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or weld on or near container. Empty oil containers can contain explosive vapors.
NFPA Class IIIB storage. Wash thoroughly after handling.
WORK/HYGIENIC PRACTICES
Wash hands with soap and water before eating, drinking, smoking or use of toilet
facilities. Do not use gasoline, solvents, kerosene, or harsh abrasive skin cleaners
cleaners for washing exposed skin areas. Take a shower after work if general contact
contact occurs. Remove oil-soaked clothing and launder before reuse. Launder or
discard contaminated shoes and leather gloves.
"EMPTY" CONTAINER WARNING
"Empty" containers retain residue (liquid and/or vapor) and can be dangerous. DO NOT
NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND OR EXPOSE SUCH CONTAINERS TO
HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION; THEY MAY
EXPLODE AND CAUSE INJURY OR DEATH.
Do not attempt to refill or clean containers since residue is difficult to remove.
"Empty" drums should be completely drained, properly bunged and promptly returned to
to a drum reconditioner. All other containers should be disposed of in an
environmentally safe manner and in accordance with governmental regulations.
For work on tanks refer to Occupational Safety and Health Administration
regulations, ANSI Z49.1, and other governmental and industrial references pertaining
pertaining to cleaning, repairing, welding, or other contemplated operations.
SECTION 08 EXPOSURE CONTROLS AND PERSONAL PROTECTION
VENTILATION
Use local exhaust to capture vapor, mists or fumes, if necessary. Provide
ventilation sufficient to prevent exceeding recommended exposure limit or buildup
of explosive concentrations of vapor in air. No smoking, or use of flame or other
ignition sources.
EYE/FACE PROTECTION
Use safety glasses or splash goggles when eye contact may occur. Have suitable eye
wash water available.
SKIN PROTECTION
Avoid prolonged and/or repeated skin contact. If prolonged contact cannot be
avoided, wear protective impervious gloves and clothing. Acceptable materials for
gloves are polyvinyl chloride; neoprene; nitrile; polyvinyl alcohol; viton.
RESPIRATORY PROTECTION
Normally not required if adequate ventilation. If occupational exposure
limits are exceeded wear NIOSH/MSHA approved apparatus.
OTHER/GENERAL PROTECTION
If there is a likelihood of splashing, an oil resistant clothing should be worn.
Never wear oil soaked clothing. Launder or dry clean before wearing. Discard oil
soaked shoes. Affix warning labels on containers in accordance with 29 CFR
1910.1200 (Hazard Communication Standard).
CONCENTRATION
INGREDIENT NAME EXPOSURE LIMITS PERCENT BY VOLUME
-----------------------------------------------------------------------------------
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Heavy Hydrotreated Naphthenic Distillates (petroleum) 100.0
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CAS NUMBER: 64742-52-5 Exposure Limits: OIL MIST
OSHA PEL MIST 5 MG/M3 8 HRS
ACGIH TLV MIST 5 MG/M3 8 HRS
SECTION 09 PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE
Clear, pale straw to water white, viscous liquid.
ODOR
Light bland petroleum.
ODOR THRESHOLD
N.D.
BASIC PHYSICAL PROPERTIES
PHYSICAL STATE: Liquid
BOILING POINT: IBP >526 (D1160)隆F IBP >274 (D1160)隆C
MELTING POINT: -60隆F (D97) -51隆C (D97)
VAPOR PRESSURE: <0.001 mm Hg @ 20隆C
VAPOR DENSITY (AIR=1): >5
SPECIFIC GRAVITY: 0.90 Water = 1
MOLECULAR WEIGHT: 320.00
PACKING DENSITY: N/A
SOLUBILITY (H2O): negligible
PERCENT VOLATILES: nil
EVAPORATION RATE: 1000X slower than ethyl ether
pH: essentially neutral
VISCOSITY: 108.2 SUS @ 100隆F
Physical data may vary slightly to meet specifications.
SECTION 10 STABILITY AND REACTIVITY
STABILITY: Stable. Will not react violently with water.
CONDITIONS TO AVOID (STABILITY)
Sources of ignition.
INCOMPATIBLE MATERIALS
Strong oxidizers such as liquid chlorine, concentrated oxygen, sodium
hypochlorite, calcium hypochlorite, etc., as this presents a serious
explosion hazard.
HAZARDOUS DECOMPOSITION PRODUCTS
Combustion may produce carbon monoxide and other asphyxiants.
HAZARDOUS POLYMERIZATION: will not occur
SECTION 11 TOXICOLOGICAL INFORMATION
ACUTE STUDIES
Product has a low order of acute and dermal toxicity, but minute amounts aspirated
into the lungs during ingestion or vomiting may cause mild to severe pulmonary
injury and possibly death.
EYE EFFECTS
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Product contacting the eyes may cause eye irritation.
SKIN EFFECTS
Prolonged or repeated skin contact with this product tends to remove skin oils,
possibly leading to irritation and dermatitis; however, based on human experience
and available toxicological data, this product is judged to be neither a "corrosive"
"corrosive" nor an "irritant" by OSHA criteria.
ACUTE ORAL EFFECTS
Product has a low order of acute and dermal toxicity, but minute amounts aspirated
into the lungs during ingestion or vomiting may cause mild to severe pulmonary
injury and possibly death.
ACUTE INHALATION EFFECTS
Product has a low order of acute and dermal toxicity, but minute amounts aspirated
into the lungs during ingestion or vomiting may cause mild to severe pulmonary
injury and possibly death.
In accordance with the current OSHA Hazard Communication Standard criteria, this
product does not require a cancer hazard warning. This is because the product is
formulated from base stocks which are severely hydrotreated, severely solvent
extracted, and/or processed by mild hydrotreatment and extraction. Alternatively, it
it may consist of components not otherwise affected by IARC criteria, such as
atmospheric distillates or synthetically derived materials, and as such is not
characterized by current IARC classification criteria.
SECTION 12 ECOLOGICAL INFORMATION
No specific ecological data are available for this product. Please refer to section
6 for information regarding accidental releases and section 15 for regulatory
reporting requirements.
SECTION 13 DISPOSAL CONSIDERATIONS
Follow federal, state and local regulations. Not a RCRA hazardous waste if
uncontaminated. If "used", RCRA criteria must be determined. Do not flush to
drain/storm sewer. Contract to authorized disposal service. If permitted
incineration may be practical. Recommend recycling.
RCRA INFORMATION
Not a RCRA hazardous waste if uncontaminated.
SECTION 14 TRANSPORTATION INFORMATION
PROPER SHIPPING NAME: Not regulated by DOT
HAZARD CLASS: Not applicable
DOT IDENTIFICATION NUMBER: N/A
DOT SHIPPING LABEL: Not regulated by DOT
SECTION 15 REGULATORY INFORMATION
U.S. FEDERAL REGULATORY INFORMATION
SARA 302 Threshold Planning Quantity: NOT APPLICABLE
SARA 304 Reportable Quantity : NOT APPLICABLE
SARA 311 Categories: Immediate (Acute) Health Effects --N
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Delayed (Chronic) Health Effects --Y
Fire Hazard --N
Sudden Release of Pressure Hazard--N
Reactivity Hazard --N
EPA/TSCA Inventory: The components of this product are listed on the EPA/TSCA
inventory of chemicals.
EPA Hazard Classification Code: NOT APPLICABLE
Comprehensive Environmental Response, Compensation and Liability Act
(CERCLA): No chemicals in this product are subject to the reporting
requirements of CERCLA.
SARA TITLE III - SECTION 313 SUPPLIER NOTIFICATION
No chemicals in this product exceed the De Minimus reporting level
established by SARA Title III, Section 313 and 40 CFR 372.
EUROPEAN (ECC) REGULATORY INFORMATION
This product is listed on the European Inventory of Existing Commercial
Substances.
CANADIAN REGULATORY INFORMATION
This product is listed on the Canadian (DSL) Domestic Substances List.
WHMIS Classification: NOT CONTROLLED
SECTION 16 OTHER INFORMATION
DISCLAIMER OF EXPRESSED AND IMPLIED WARRANTIES
The information contained herein is based upon data believed to be reliable and
reflects our best professional judgment. Although reasonable care has been taken in
the preparation of this document, we extend no warranties and make no
representations as to the accuracy or completeness of the information contained
therein and assume no responsibility regarding the suitability of this information
for the user's intended purpose or for the consequence of its use. Each individual
should make a determination as to the suitability of the information for his/her
particular purpose(s).
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