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Product Name: Calumet 600 Solvent
Manufacturer: Calumet Lubricants Co. CCV
Revision Date: 08/27/2002
SECTION 01 CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
SECTION 02 COMPOSITION AND INFORMATION ON INGREDIENTS
SECTION 03 HAZARD IDENTIFICATION
SECTION 04 FIRST AID INFORMATION
SECTION 05 FIRE FIGHTING MEASURES
SECTION 06 ACCIDENTAL RELEASE MEASURES
SECTION 07 HANDLING AND STORAGE
SECTION 08 EXPOSURE CONTROLS AND PERSONAL PROTECTION
SECTION 09 PHYSICAL AND CHEMICAL PROPERTIES
SECTION 10 STABILITY AND REACTIVITY
SECTION 11 TOXICOLOGICAL INFORMATION
SECTION 12 ECOLOGICAL INFORMATION
SECTION 13 DISPOSAL CONSIDERATIONS
SECTION 14 TRANSPORTATION INFORMATION
SECTION 15 REGULATORY INFORMATION
SECTION 16 OTHER INFORMATION
Product Name: Calumet 600 Solvent
Manufacturer: Calumet Lubricants Co. CCV
Address: 1756 old hwy 7 Cotton Valley LA. 71018
Telephone: (317) 328-5660
Emergency: (800) 424-9300
Contact: Anne Goldsmith
Trade Name: Calumet 600 Solvent
Synonyms: 0610-00
Description: Petroleum Hydrocarbon Distillate
NFPA 704M漏 Rating:
Health: 1 Fire: 1 Reactivity: 0 Special:
0=Insignificant 1=Slight 2=Moderate 3=High 4=Extreme
SECTION 02 COMPOSITION AND INFORMATION ON INGREDIENTS
Chemical Ingredients (% by Weight)
Ingredient CAS Number Percent Weight
Distillates (Petroleum Straight Run Middle)64741-44-2 100 %
SECTION 03 HAZARD IDENTIFICATION
*****EMERGENCY OVERVIEW*****
* Warning: Combustible Liquid and Vapor.
* This product is a clear, hydrocarbon liquid.
* It has a solvent petroleum odor. The product floats on water.
* The Flash Point is >100 degrees F.
* Keep away from heat, sparks, and flame.
* When burned the product produces carbon monoxide and other asphyxiants during
combustion.
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* Avoid breathing vapor. Harmful if inhaled and may cause delayed lung injury.
* Aspiration hazard if swallowed - can enter lungs and cause damage.
* Use ventilation adequate to keep vapor below recommended exposure limits.
* Avoid contact with eyes, skin and clothing. Material splashed into the eyes will
irritate tissues. Gently flush material from eyes with clean water.
* Unprotected exposure to this product will cause skin dryness.
* Remove product soaked clothing and wash with mild soap. Wash thoroughly after
handling.
* As with any petroleum product, avoid mixing this product with strong oxidizers.
* This product is not listed on the NTP, IARC, OSHA, or ACGIH lists of suspected or
confirmed carcinogens.
* This product may be toxic to fish but will be toxic to birds and wildlife through
ingestion during pelage cleaning.
* This product is readily biodegradable in the presence of air and sunlight.
* Spilled material is slippery and may cause falls.
*****END OF EMERGENCY OVERVIEW*****
POTENTIAL HEALTH EFFECTS
PRIMARY ROUTE(S) OF ENTRY
Skin.
EYES
Tests on similiar materials suggest acute irritation be expected.
SKIN
Tests on similiar materials indicate acute irritation is expected to occur upon
short-term exposure, chronic dermatitis on prolonged contact.
INGESTION
ACUTE ASPIRATION HAZARD. Tests on similar materials indicate possibility of the
following symptoms: headache, nausea, drowsiness, fatigue, pneumonitis, pulmonary
adema, central nervous system depression, convulsions, and loss of consciousness.
INHALATION
Tests on similiar material indicate the possibility of the following symptoms:
headache, nasal and respiratory irritation, nausea, drowsiness, breathlessness,
fatigue, central nervous system depression, convulsions, and loss of consciousness.
CHRONIC (CANCER INFORMATION)
Prolonged and/or repeated contact with this material may produce skin irritation
and inflammation.
Carcinogen listed by : National Toxicology Program (No)
CHRONIC (CANCER INFORMATION) - Continued
I. A. R. C. (NO)
OSHA (NO)
ACGIH (NO)
This product does not require a cancer hazard warning in accordance with the OSHA
Hazard Communication Standard.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE
Personnel with pre-existing skin disorders should avoid contact with this product.
SECTION 04 FIRST AID INFORMATION
EYES
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Flush eyes immediately with water for at least 15 minutes or until irritation
subsides, occasionally lifting lower and upper lids. Get medical attention
promptly.
SKIN
Wash thoroughly with soap and water. Immediately remove contaminated clothing and
wash before reuse. If irritation or rash develops, obtain medical assistance.
Immediately remove soaked clothing.
INGESTION
CALL PHYSICIAN IMMEDIATELY. Do not induce vomiting except at the instruction of a
physician. Never give anything by mouth to an unconscious person.
INHALATION
Remove patient to fresh air and consult a physician. If breathing is difficult,
give oxygen. If not breathing give artifical respiration.
SECTION 05 FIRE FIGHTING MEASURES
FLAMMABLE PROPERTIES
FLASH POINT: >275掳F >135掳C Open Cup ASTM D92
AUTOIGNITION: >490掳F >254掳C
FLAMMABILITY CLASS: IIIB
LOWER EXPLOSIVE LIMIT (%): 0.7 %
UPPER EXPLOSIVE LIMIT (%): 6.0 %
FIRE AND EXPLOSION HAZARD
Material is combustible.
EXTINGUISHING MEDIA
Dry Chemical, carbon dioxide, and foam. CAUTION: Water stream may spread fire.
FIRE FIGHTING INSTRUCTIONS
Use water spray only to cool containers exposed to flames. Do not enter enclosed or
a confined work space without proper protective equipment. Fire fighting personnel
should wear respiratory protection (positive pressure if available). If leak or
spill has not ignited, use water spray to disperse the vapors.
Products of combustion include fumes, smoke and carbon monoxide.
SECTION 06 ACCIDENTAL RELEASE MEASURES
NOTIFICATION PROCEDURES: Notify emergency response personnel. Evacuate area and
remove ignition sources. Build dike to contain flow. Remove free liquid. Shut off
ignition source. Report spills as required to appropriate authorities. U. S. Coast
Guard regulations require immediate reporting of spills that could reach any
waterway including intermittent dry creeks. Report spill to Coast Guard toll free
number (800) 424-8802. In case of accident or road spill notify CHEMTREC (800) 424-
9300.
PROCEDURES IF MATERIAL IS RELEASED OR SPILLED: Absorb on inert material. Shovel up
and dispose of at an appropriate waste disposal facility in accordance with current
applicable laws and regulations, and product characteristics at time of disposal.
ENVIRONMENTAL PRECAUTIONS: Prevent spills from entering storm sewers or drains and
contact with soil.
PERSONAL PRECAUTIONS: See Section 8
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SECTION 07 HANDLING AND STORAGE
HANDLING AND STORAGE PRECAUTIONS
Store as OSHA Class IIIB combustible liquid. Keep away from flames, sparks or hot
surfaces. Never use a torch to cut or weld on or near container. Empty oil
containers can contain explosive vapors. Wash thoroughly after handling. Do not
store with strong oxidizers.
STORAGE PRECAUTIONS
Empty containers retain product residue (liquid and vapor) and can be dangerous.
Storage Temperature: ambient
Storage Pressure: atmospheric
WORK/HYGIENIC PRACTICES
Wash hands with soap and water before eating, drinking, smoking or use of toilet
facilities. Take a shower after work if general contact occurs. Remove oil-soaked
clothing and launder before reuse. Launder or discard contaminated shoes and
leather gloves.
SECTION 08 EXPOSURE CONTROLS AND PERSONAL PROTECTION
ENGINEERING CONTROLS
Use adequate ventilation to keep oil mists of this material below applicable
standard(s). See Section on occupational exposure limits.
EYE/FACE PROTECTION
Safety glasses, splash goggles, or face shield as appropriate. Have suitable eye
water wash available.
SKIN PROTECTION
Avoid prolonged and/or repeated skin contact. If prolonged contact cannot be
avoided, wear protective impervious gloves and clothing. Acceptable materials for
gloves are neoprene; nitrile; viton.
OTHER/GENERAL PROTECTION
If there is a likelihood of splashing, an oil resistant clothing should be worn.
Never wear oil soaked clothing. Launder or dry clean before wearing. Discard oil
soaked shoes. Affix warning labels on containers in accordance with 29 CFR
1910.1200 (Hazard Communication Standard).
Loading, unloading, tank gauging, etc., remain upwind. Request assistance of safety
and industrial hygiene personnel to determine air concentrations.
INGREDIENT NAME, CAS #, EXPOSURE LIMITS, PERCENT BY VOLUME
------------------------------------------------------ ----------------------------
-------
Straight Run Middle Distillate, CAS NUMBER: 64741-44-2, Exposure Limits: OIL MIST
OSHA PEL MIST 5 MG/M3 8 HRS ACGIH TLV MIST 5 MG/M3 8 HRS, 100%
SECTION 09 PHYSICAL AND CHEMICAL PROPERTIES
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APPEARANCE
Clear, pale straw to water white, non掳viscous liquid.
ODOR
Light bland petroleum.
ODOR THRESHOLD
N.D.
BASIC PHYSICAL PROPERTIES
PHYSICAL STATE: Liquid
BOILING POINT: IBP >500掳F IBP >260掳C
MELTING POINT: N/A掳F N/A掳C
VAPOR PRESSURE: 0.000367 psia @ 68掳F
VAPOR DENSITY (AIR=1): 8
SPECIFIC GRAVITY @ 60掳F(water=1): 0.816
MOLECULAR WEIGHT: 237.00
SOLUBILITY (H2O): negligible in water
PERCENT VOLATILES: 100
VISCOSITY: 3.5 cst @40掳C
Physical data may vary slightly to meet specifications.
SECTION 10 STABILITY AND REACTIVITY
STABILITY: Stable under normal conditions
CONDITIONS TO AVOID (STABILITY)
Sources of ignition.
INCOMPATIBLE MATERIALS
Strong oxidizers.
HAZARDOUS DECOMPOSITION PRODUCTS
Incomplete combustion may produce carbon monoxide and other asphyxiants.
HAZARDOUS POLYMERIZATION: will not occur
SECTION 11 TOXICOLOGICAL INFORMATION
ACUTE STUDIES
EYE EFFECTS
Slight irritation on contact.
SKIN EFFECTS
May cause irritation or dermatitis with prolonged and repeated contact.
ACUTE ORAL EFFECTS
Tests on similar materials indicate an order of acute oral toxicity.
ACUTE INHALATION EFFECTS
Acute toxicity expected on inhalation.
This product is not listed as carcinogenic or a potential carcinogen by the
National Toxicology Program, by the I.A.R.C. monographs or by OSHA. Therefore, if
the precautions outlined in this
bulletin are followed to minimize repeated or prolonged skin contact which could
cause irritation, these oils should pose no carcinogenic hazard to humans.
Prolonged repeated skin contact with low viscosity materials may defat the skin
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resulting in possible irritation and dermatitis. Nevertheless, good industrial
hygienic practices are recommended.
SECTION 12 ECOLOGICAL INFORMATION
If applied to leaves, this product may kill grasses and small plants by interfering
with transpiration and respiration. This product is not toxic to fish but may coat
gill structures resulting in suffocation if spilled in shallow, running water.
Product may be moderately toxic to amphibians by preventing dermal respiration.
This product may cause gastrointestinal distress to birds and mammals through
ingestion during pelage grooming.
This product is rapidly biodegradable. Biodegradation is possible within 90 to 120
days in aerobic environments at temperatures above 70o F (21o C).
SECTION 13 DISPOSAL CONSIDERATIONS
Product as supplied does not meet the characteristics of a hazardous waste as
defined in 40 CFR 261.21-24. If mixed with other products, waste mixture must be
characterized. DO NOT dispose of this product in drains or storm sewers. DO NOT
dispose of this product in a landfill without prior solidification. Waste product
should be recycled. Consider waste brokering.
SECTION 14 TRANSPORTATION INFORMATION
PROPER SHIPPING NAME: Not regulated by DOT
HAZARD CLASS: Not applicable
DOT IDENTIFICATION NUMBER: N/A
DOT SHIPPING LABEL: Not regulated by DOT
SECTION 15 REGULATORY INFORMATION
U.S. FEDERAL REGULATORY INFORMATION
SARA 302 Threshold Planning Quantity: NOT APPLICABLE
SARA 304 Reportable Quantity: NOT APPLICABLE
SARA TITLE III - Section 311/312 Hazard classes:
路 Immediate/Acute Health Effects: no
路 Delayed/Chronic Health Effects: yes
路 Fire Hazard: no
路 Sudden Release of Pressure Hazard: no
路 Reactivity Hazard: no
EPA/TSCA Inventory: The components of this product are listed on the
EPA/TSCA inventory of chemicals.
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SARA TITLE III - Section 313 Supplier notification:
The following chemicals are subject to the reporting requirements of Section 313 of
Title III of the Superfund Amendments and reauthorization Act of 1986 and 40 CFR
Part 372: none
Comprehensive Environmental Response, Compensation and Liability Act (CERCLA): No
chemicals in this product are subject to the reporting requirements of CERCLA
Section 101(14)(F). When this product is used in a mixture, or as an ingredient in
another product, or in a manufacturing operation, the petroleum exclusion may
terminate and an accidental spill may require reporting to the National Response
Center.
CANADIAN REGULATORY INFORMATION
The components of this product are/are not listed on the Canadian (DSL) Domestic
Substances List.
EUROPEAN (ECC) REGULATORY INFORMATION
The components of this product are/are not listed on the European Inventory of
Existing Commercial Substances. EINECS#
SECTION 16 OTHER INFORMATION
SUPERCEDES MSDS DATED: 7/31/02
Revised: 8/27/02
Section changed vapor pressure
DISCLAIMER OF EXPRESSED AND IMPLIED WARRANTIES
The information contained herein is based upon data available to us, and reflects
our best professional judgement. However, no warranty of merchantability, fitness
for any use, or other warranty is expressed or implied regarding the accuracy of
such data, the results to be obtained from the use thereof, or that any such use
does not infringe any patent. Since the information contained herein may be applied
under conditions of use beyond our control and with which we may be unfamiliar, we
do not assume any responsibility for the results of such application. This
information is furnished upon the condition that the person receiving it shall make
his own determination of the suitability of the material for his particular
purpose.
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