MATERIAL SAFETY DATA SHEET
READ AND UNDERSTAND MATERIAL SAFETY DATA SHEET BEFORE HANDLING OR DISPOSING
OF PRODUCT
: JEFFAMINE庐 D-230
MSDS CODE AND NAME JAD230
:
DATE ISSUED 7/1/2004
DATE PRINTED : 7/1/2004
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
MATERIAL IDENTITY
MSDS CODE AND NAME
JEFFAMINE庐 D-230
JAD230
Chemical Name and/or Family or Description:
Polyoxypropylenediamine
COMPANY INFORMATION
Huntsman Petrochemical Corporation
P.O. Box 4980
The Woodlands, TX 77387-4980
TELEPHONE NUMBERS
Transportation Emergency
Company: (409) 727-0831
CHEMTREC: (800) 424-9300
Medical Emergency: (409) 722-9673 (24 Hour)
General MSDS Assistance: (281) 719-6432
Technical Information: (512) 459-6543
2. COMPOSITION AND INFORMATION ON INGREDIENTS
THE CRITERIA FOR LISTING COMPONENTS IN THE COMPOSITION SECTION ARE AS FOLLOWS: CARCINOGENS ARE LISTED WHEN
PRESENT AT 0.1 % OR GREATER; COMPONENTS WHICH ARE OTHERWISE HAZARDOUS ACCORDING TO OSHA ARE LISTED WHEN
PRESENT AT 1.0 % OR GREATER; NON-HAZARDOUS COMPONENTS ARE LISTED AT 3.0 % OR GREATER. THIS IS NOT INTENDED
TO BE COMPLETE COMPOSITIONAL DISCLOSURE. REFER TO SECTION 14 FOR APPLICABLE STATES' RIGHT TO KNOW AND
OTHER REGULATORY INFORMATION.
Product and/or Component(s) Carcinogenic According to:
NONE X
OSHA IARC NTP OTHER
Composition:
CAS Number
Chemical Name Exposure Limits Range in %
Poly(oxy(methyl-1,2-ethanediyl)),alpha-(2- 9046-10-0 100.00
aminomethylethyl)omega-(2-aminomethylethoxy)-
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JEFFAMINE庐 D-230
MSDS CODE AND NAME JAD230
:
DATE ISSUED : 7/1/2004
DATE PRINTED : 7/1/2004
COMPANY : HUNTSMAN
3. HAZARD IDENTIFICATION
EMERGENCY OVERVIEW
Appearance:
Colorless to slightly yellow liquid with a slight haze
Odor:
Ammonia-like
WARNING STATEMENT
DANGER ! CORROSIVE - CAUSES EYE AND SKIN BURNS
HARMFUL OR FATAL IF SWALLOWED
CAUSES RESPIRATORY TRACT IRRITATION AND CAN CAUSE DAMAGE
ASPIRATION HAZARD IF SWALLOWED -
CAN ENTER LUNGS AND CAUSE DAMAGE
Hazardous Material National Fire Protection
3
Health Flammability
1
Information System Association NFPA
1
Fire
3 0
(United States) (United States) Reactivity
Health
0
Reactivity
Personal protection Specific danger
POTENTIAL HEALTH EFFECTS
Primary Route of Exposure
Eye X Skin X Inhalation X Ingestion
Effects of Overexposure
Acute:
Causes irritation, experienced as pain, with excess blinking and tear production, and seen as
Eyes:
extreme redness and swelling of the eye and chemical burns of the eye. Severe eye damage
may cause blindness.
Causes severe irritation with pain, severe excess redness and swelling with chemical burns,
Skin:
blister formation, and possible tissue destruction. Other than the potential skin irritation
effects noted above, acute (short term) adverse effects are not expected from brief skin
contact; see other effects, below, and Section 11 for information regarding potential long term
effects.
Vapors or mist, especially as generated from heating the material or as from exposure in
Inhalation:
poorly ventilated areas or confined spaces, are irritating and cause nasal discharge,
coughing, and discomfort in nose and throat. Prolonged or repeated overexposure may
result in lung damage.
Causes burning of mouth, throat, and stomach with abdominal and chest pain, nausea,
Ingestion:
vomiting, diarrhea, thirst, weakness, and collapse. Aspiration may occur during swallowing
or vomiting, resulting in lung damage.
This product is not expected to be a human skin sensitizer based on animal data.
Sensitization Properties:
Chronic:
Repeated skin contact may cause a persistent irritation or dermatitis. Repeated inhalation may cause lung damage.
Medical Conditions Aggravated by Exposure:
Skin contact may aggravate an existing dermatitis (skin condition). Overexposure to vapor, dust or mist may aggravate
existing respiratory conditions, such as asthma, bronchitis, and inflammatory or fibrotic respiratory disease.
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JEFFAMINE庐 D-230
MSDS CODE AND NAME JAD230
:
DATE ISSUED : 7/1/2004
DATE PRINTED : 7/1/2004
COMPANY : HUNTSMAN
Other Remarks:
This product contains one or more amines which may produce temporary and reversible hazy or blurred vision. Symptoms
disappear when exposure is terminated.
4. FIRST AID MEASURES
Eyes:
Immediately flush eyes with large amounts of running water for at least 15 minutes. Hold eyelids apart while flushing to rinse entire
surface of eye and lids with water. Do not attempt to neutralize with chemical agents. Obtain medical attention immediately. Continue
flushing for an additional 15 minutes if medical attention is not immediately available.
Skin:
Immediately remove contaminated clothing and shoes. Under a safety shower, flush skin thoroughly with large amounts of running
water for at least 15 minutes. Do not attempt to neutralize with chemical agents. Get medical attention immediately. Discard or
decontaminate clothing and shoes before reuse.
Ingestion:
If person is conscious and can swallow, immediately give two glasses of water (16 oz.), but do not induce vomiting. This material is
corrosive. If vomiting occurs, give fluids again. Have a physician determine if condition of patient will permit induction of vomiting or
evacuation of stomach. Do not give anything by mouth to an unconscious or convulsing person.
Inhalation:
If inhaled, remove to fresh air. If not breathing or in respiratory distress, clear person's airway and start artificial respiration. With a
physician's advice, give supplemental oxygen using a bag-valve mask or manually triggered oxygen supply.
Other Instructions:
Swallowing of this corrosive material may result in severe ulceration, inflammation, and possible perforation of the upper alimentary
tract, with hemorrhage and fluid loss. Aspiration of this product during induced emesis can result in severe lung injury. If evacuation of
stomach is necessary, use method least likely to cause aspiration, such as gastric lavage after endotracheal intubation. Contact a
Poison Control Center for additional treatment information.
5. FIRE-FIGHTING MEASURES
Ignition Temperature - AIT (degrees C):
Not determined.
Flash Point (degrees C):
121.1 (250掳F) (PMCC)
Flammable Limits % (Lower-Upper):
Lower: Not determined.
Upper: Not determined.
Recommended Fire Extinguishing Agents And Special Procedures:
Use water spray, dry chemical, foam or carbon dioxide to extinguish flames. Use water spray to cool fire-exposed containers. Water
or foam may cause frothing.
Unusual or Explosive Hazards:
None
Special Protective Equipment for Firefighters:
Wear special chemical protective clothing and positive pressure self-contained breathing apparatus. Approach fire from upwind to
avoid hazardous vapors and toxic decomposition products. Decontaminate or discard any clothing that may contain chemical
residues.
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JEFFAMINE庐 D-230
MSDS CODE AND NAME JAD230
:
DATE ISSUED : 7/1/2004
DATE PRINTED : 7/1/2004
COMPANY : HUNTSMAN
6. ACCIDENTAL RELEASE MEASURES (Transportation Spills: CHEMTREC (800)424-9300)
Procedures in Case of Accidental Release, Breakage or Leakage:
Ventilate area. Avoid breathing vapor. Wear appropriate personal protective equipment, including appropriate respiratory protection.
Contain spill if possible. Wipe up or absorb on suitable material and shovel up. Prevent entry into sewers and waterways. Avoid
contact with skin, eyes or clothing.
7. HANDLING AND STORAGE
Precautions to be Taken in
Handling:
Minimum feasible handling temperatures should be maintained. Eye wash and safety shower should be available nearby when this
product is handled or used.
Storage:
Periods of exposure to high temperatures should be minimized. Water contamination should be avoided. If stored above 100掳F, a
nitrogen atmosphere is recommended.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Protective Equipment (Type)
Eye/Face Protection:
Avoid eye contact. Chemical type goggles with face shield must be worn. Do not wear contact lenses.
Skin Protection:
Protective clothing such as coveralls or lab coats should be worn. Launder or dry-clean when soiled. Gloves resistant to chemicals
and petroleum distillates required. When handling large quantities, impervious suits, gloves, and rubber boots must be worn.
Remove and dry-clean or launder clothing soaked or soiled with this material before reuse. Dry cleaning of contaminated clothing may
be more effective than normal laundering. Inform individuals responsible for cleaning of potential hazards associated with handling
contaminated clothing.
Respiratory Protection:
Airborne concentrations should be kept to lowest levels possible. If vapor, mist or dust is generated and the occupational exposure
limit of the product, or any component of the product, is exceeded, use appropriate NIOSH approved air purifying or air supplied
respirator after determining the airborne concentration of the contaminant. Air supplied respirators should always be worn when
airborne concentration of the contaminant or oxygen content is unknown.
Ventilation:
Local exhaust ventilation recommended if generating vapor, dust, or mist. If exhaust ventilation is not available or inadequate, use
NIOSH approved respirator as appropriate.
Exposure Limit for the Total Product:
None established for product.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance:
Colorless to slightly yellow liquid with a slight haze
Odor:
Ammonia-like
Boiling Point (degrees C):
260 (500掳F)
Melting/Freezing Point (degrees C):
Not determined.
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JEFFAMINE庐 D-230
MSDS CODE AND NAME JAD230
:
DATE ISSUED : 7/1/2004
DATE PRINTED : 7/1/2004
COMPANY : HUNTSMAN
Specific Gravity (water=1):
0.948 @ 20/20掳C
pH:
11.7 (5% aqueous)
Vapor Pressure:
1 mmHg at 100掳C (212掳F)
Viscosity:
9.5 cSt at 25掳C (77掳F)
VOC Content:
25% by ASTM D 2369
Vapor Density (Air=1):
>1
Solubility in Water (%):
>10
Other:
None
10. STABILITY AND REACTIVITY
This Material Reacts Violently With:
Others X
Air Water Heat Strong Oxidizers None of these
Comments:
This material reacts violently with acids.
Products Evolved When Subjected to Heat or Combustion:
Toxic levels of ammonia, combustion products of nitrogen, carbon monoxide, carbon dioxide, irritating aldehydes and ketones may be
formed on burning in a limited air supply.
Hazardous Polymerizations:
DO NOT OCCUR
11. TOXICOLOGICAL INFORMATION
TOXICOLOGICAL INFORMATION (ANIMAL TOXICITY DATA)
Oral:
LD50 2.88 g/kg (rat) slightly toxic
Dermal:
LD50 2.98 g/kg (rabbit) practically non-toxic
Inhalation:
Not determined.
IRRITATION INDEX, ESTIMATION OF IRRITATION (SPECIES)
Eyes:
(Draize) Believed to be > 80.00 - 110.00 /110 (rabbit) extremely irritating
Skin:
(Draize) Believed to be > 6.50 - 8.00 /8.0 (rabbit) corrosive
Sensitization:
(Buehler) Negative - skin (guinea pig)
Other:
None
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JEFFAMINE庐 D-230
MSDS CODE AND NAME JAD230
:
DATE ISSUED : 7/1/2004
DATE PRINTED : 7/1/2004
COMPANY : HUNTSMAN
12. DISPOSAL CONSIDERATIONS:
Waste Disposal Methods:
This product has been evaluated for RCRA characteristics and does not meet the criteria of a hazardous waste if discarded in its
purchased form. Under RCRA, it is the responsibility of the user of the product to determine at the time of disposal, whether the
product meets RCRA criteria for hazardous waste. This is because product uses, transformations, mixtures, processes, etc. may
render the resulting materials hazardous.
Remarks:
None
13. TRANSPORT INFORMATION
Transportation
DOT:
Proper Shipping Name:
Amines, liquid, corrosive, n.o.s. (polyoxypropylene diamine)
Hazard Class:
Class 8: Corrosive material
Identification Number:
UN2735
Packing Group:
III
Label Required:
Class 8: Corrosive
IMDG
Proper Shipping Name:
AMINES, LIQUID, CORROSIVE, N.O.S. (polyoxypropylene diamine)
Hazard Class
Class 8
Identification Number
UN2735
Packing Group
III
Label Required
Class 8 - Corrosive substances
ICAO
Proper Shipping Name:
Amines, liquid, corrosive, n.o.s. (polyoxypropylene diamine)
Hazard Class
Class 8
Identification Number
UN2735
Packing Group
III
Label Required
Class 8 - Corrosive
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JEFFAMINE庐 D-230
MSDS CODE AND NAME JAD230
:
DATE ISSUED : 7/1/2004
DATE PRINTED : 7/1/2004
COMPANY : HUNTSMAN
TDG
Proper Shipping Name:
Corrosive liquid, n.o.s. (polyoxypropylene diamine)
Hazard Class:
8
Identification Number:
UN1760
Packing Group:
III
Label Required:
Corrosive
14. REGULATORY INFORMATION
Federal Regulations:
SARA Title III:
Section 302/304 Extremely Hazardous Substances
Chemical Name CAS Number Range in % TPQ RQ
None.
Section 311 Hazardous Categorization:
Acute X Chronic Fire Pressure Reactive N/A
Section 313 Toxic Chemical
CAS Number
Chemical Name Concentration
None.
CERCLA 102(a)/DOT Hazardous Substances:
Chemical Name CAS Number Range in % RQ
None.
States Right-to-Know Regulations:
Chemical Name State Right-to-know
None.
California Prop. 65:
The following detectable components of this product are substances, or belong to classes of substances, known to the State of
California to cause cancer and/or reproductive toxicity.
Chemical Name CAS Number
None.
INTERNATIONAL REGULATIONS:
TSCA Inventory Status:
This product, or its components, are listed on or are exempt from the Toxic Substance Control Act (TSCA) Chemical Substance
Inventory.
WHMIS Classification:
Class E: Corrosive
Canadian Inventory Status:
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JEFFAMINE庐 D-230
MSDS CODE AND NAME JAD230
:
DATE ISSUED : 7/1/2004
DATE PRINTED : 7/1/2004
COMPANY : HUNTSMAN
This product, or its components, are listed on or are exempt from the Canadian Domestic Substance List (DSL).
EINECS Inventory Status:
This product, or its components, are listed on or are exempt from the European Inventory of Existing Chemical Substances (EINECS) or
the European List of Notified Chemical Substances (ELINCS).
Australian Inventory Status:
This product, or its components, are listed on or are exempt from the Australian Inventory of Chemical Substances (AICS).
Japan Inventory Status:
This product, or its components, are listed on or are exempt from the Japan Ministry of International Trade and Industry (MITI) inventory.
15. ENVIRONMENTAL INFORMATION
Aquatic Toxicity:
Not determined.
Mobility:
Not determined.
Persistence and Biodegradability:
Not determined.
Potential to Bioaccumulate:
Not determined.
Remarks:
None
16. OTHER INFORMATION 7/1/2004
None
Date Issued: 7/1/2004.
THE INFORMATION IN THIS DATA SHEET IS PROVIDED INDEPENDENTLY OF ANY SALE OF THE PRODUCT. IT IS PROVIDED FOR THE PURPOSE OF HAZARD
COMMUNICATION AS PART OF HUNTSMAN鈥橲 PRODUCT SAFETY PROGRAM. IT IS INTENDED ONLY AS A GUIDE TO THE APPROPRIATE PRECAUTIONARY
HANDLING OF THE PRODUCT BY A PROPERLY TRAINED PERSON. YOU ARE ENCOURAGED AND REQUESTED TO ADVISE THOSE WHO MAY COME IN
CONTACT WITH SUCH PRODUCTS OF THE INFORMATION CONTAINED HEREIN. THE DATA RELATES ONLY TO THE SPECIFIC PRODUCT DESIGNATED, AND
DOES NOT RELATE TO USE OF THE PRODUCT IN COMBINATION WITH ANY OTHER MATERIAL OR USE OF THE PRODUCT IN ANY PROCESS. THE DATA IS
NOT INTENDED TO CONSTITUTE PERFORMANCE INFORMATION CONCERNING THE PRODUCT. NO EXPRESS WARRANTY, OR IMPLIED WARRANTY OF
MERCHANTABILITY FOR FITNESS FOR A PARTICULAR PURPOSE IS MADE WITH RESPECT TO THE PRODUCT, ITS COMPOSITION, ITS SAFETY OR THE
INFORMATION CONTAINED IN THIS DATA SHEET.
TO DETERMINE THE APPLICABILITY OR THE EFFECTS OF ANY LAW OR REGULATION WITH RESPECT TO THE PRODUCT, THE USER SHOULD CONSULT A
LEGAL ADVISOR OR THE APPROPRIATE GOVERNMENT AGENCY. HUNTSMAN DOES NOT UNDERTAKE TO FURNISH ADVICE ON SUCH MATTERS.
CURRENT DATA SHEETS ARE AVAILABLE FOR ALL HUNTSMAN PRODUCTS. YOU ARE URGED TO OBTAIN DATA SHEETS FOR ALL HUNTSMAN
PRODUCTS YOU BUY, USE OR DISTRIBUTE BY CALLING (281) 719-6432 OR DIRECTING YOUR INQUIRIES TO:
HUNTSMAN
MANAGER, PRODUCT SAFETY
P.O. BOX 4980
THE WOODLANDS, TX 77387-4980
NO PERSON OR ORGANIZATION EXCEPT A DULY AUTHORIZED HUNTSMAN EMPLOYEE IS AUTHORIZED TO PROVIDE OR MAKE AVAILABLE DATA SHEETS
FOR HUNTSMAN PRODUCTS. DATA SHEETS FROM UNAUTHORIZED SOURCES MAY CONTAIN INFORMATION THAT IS NO LONGER CURRENT OR
ACCURATE. NO PART OF THIS DATA SHEET MAY BE REPRODUCED OR TRANSMITTED IN ANY FORM, OR BY ANY MEANS, WITHOUT PERMISSION IN
WRITING FROM HUNTSMAN. ALL REQUESTS FOR PERMISSION TO REPRODUCE MATERIAL FROM THIS DATA SHEET SHOULD BE DIRECTED TO
HUNTSMAN, MANAGER, PRODUCT SAFETY AT THE ABOVE ADDRESS.
COPYRIGHT 漏 BY HUNTSMAN CORPORATION. ALL RIGHTS RESERVED.
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JEFFAMINE庐 D-230
MSDS CODE AND NAME JAD230
:
DATE ISSUED : 7/1/2004
DATE PRINTED : 7/1/2004
COMPANY : HUNTSMAN
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