MATERIAL SAFETY DATA SHEET
READ AND UNDERSTAND MATERIAL SAFETY DATA SHEET BEFORE HANDLING OR DISPOSING
OF PRODUCT
SURFONIC庐 L24-9
PRODUCT CODE AND NAME L249
:
ISSUE DATE : 04/01/1999
7/1/2000
MSDS CD DATE :
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
MATERIAL IDENTITY
PRODUCT CODE AND NAME
SURFONIC庐 L24-9
L249
Chemical Name and/or Family or Description:
Nonionic surfactant: alcohol ethoxylate
COMPANY INFORMATION
Huntsman Petrochemical Corporation
P.O. Box 27707
Houston, TX 77227-7707
TELEPHONE NUMBERS
Transportation Emergency
Company: (409) 727-0831
CHEMTREC: (800) 424-9300
Medical Emergency: (409) 722-9673 (24 Hour)
General MSDS Assistance: (713) 235-6432
Technical Information: (512) 459-6543
2. COMPOSITION AND INFORMATION ON INGREDIENTS
THE CRITERIA FOR LISTING COMPONENTS IN THE COMPOSITION SECTION ARE AS FOLLOWS: CARCINOGENS ARE LISTED WHEN
PRESENT AT 0.1 % OR GREATER; COMPONENTS WHICH ARE OTHERWISE HAZARDOUS ACCORDING TO OSHA ARE LISTED WHEN
PRESENT AT 1.0 % OR GREATER; NON-HAZARDOUS COMPONENTS ARE LISTED AT 3.0 % OR GREATER. THIS IS NOT INTENDED
TO BE COMPLETE COMPOSITIONAL DISCLOSURE. REFER TO SECTION 14 FOR APPLICABLE STATES' RIGHT TO KNOW AND
OTHER REGULATORY INFORMATION.
Product and/or Component(s) Carcinogenic According to:
NONE X
OSHA IARC NTP OTHER
Composition:
Chemical Name CAS Number Exposure Limits Range in %
C12-C16 synthetic alcohols and 9 moles of ethylene 68551-12-2 100
oxide
Glycol ethers (fraction of product matching EPA 3.00-9.99
definition)
THIS PRODUCT IS CONSIDERED HAZARDOUS ACCORDING TO OSHA (1910.1200).
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SURFONIC庐 L24-9
PRODUCT CODE AND NAME L249
:
ISSUE DATE : 04/01/1999
MSDS CD DATE : 7/1/2000
COMPANY : HUNTSMAN
3. HAZARD IDENTIFICATION
EMERGENCY OVERVIEW
Appearance:
Milky-white viscous liquid or semi-solid at room temperature
Odor:
Not determined
WARNING STATEMENT
WARNING ! CAUSES EYE IRRITATION
Hazardous Material National Fire Protection
3
Health Flammability
1
Information System Association NFPA
1
Fire
2 0 Reactivity
(United States) (United States) Health
0
Reactivity
Personal protection Specific danger
POTENTIAL HEALTH EFFECTS
Primary Route of Exposure
Eye X Skin X Inhalation X Ingestion
Effects of Overexposure
Acute:
Causes irritation, experienced as pain, with excess blinking and tear production, and seen as
Eyes:
marked excess redness and swelling of the eye with injury to the cornea.
Brief contact is not irritating. Prolonged contact, as with clothing wetted with material, may
Skin:
cause defatting of skin or irritation, seen as local redness with possible mild discomfort.
Other than the potential skin irritation effects noted above, acute (short term) adverse effects
are not expected from brief skin contact; see other effects, below, and Section 11 for
information regarding potential long term effects.
Vapors or mist, in excess of permissible concentrations, or in unusually high concentrations
Inhalation:
generated from spraying, heating the material or as from exposure in poorly ventilated areas
or confined spaces, may cause irritation of the nose and throat, headache, nausea, and
drowsiness.
May cause abdominal discomfort, nausea, and diarrhea.
Ingestion:
Unknown
Sensitization Properties:
Chronic:
No adverse effects have been documented in humans as a result of chronic exposure. Section 11 may contain applicable
animal data.
Medical Conditions Aggravated by Exposure:
There is no evidence that this product aggravates an existing medical condition.
Other Remarks:
None
2
SURFONIC庐 L24-9
PRODUCT CODE AND NAME L249
:
ISSUE DATE : 04/01/1999
MSDS CD DATE : 7/1/2000
COMPANY : HUNTSMAN
4. FIRST AID MEASURES
Eyes:
Immediately flush eyes with large amounts of running water for at least 15 minutes. Hold eyelids apart while flushing to rinse entire
surface of eye and lids with water. Do not attempt to neutralize with chemical agents. Obtain medical attention immediately. Continue
flushing for an additional 15 minutes if medical attention is not immediately available.
Skin:
Wash skin with plenty of soap and water for several minutes. Get medical attention if skin irritation develops or persists.
Ingestion:
If patient is conscious and can swallow, give two glasses of water (16 oz.) Induce vomiting as directed by medical personnel. Do not
induce vomiting or give anything by mouth to an unconscious or convulsing person.
Inhalation:
If irritation, headache, nausea, or drowsiness occurs, remove to fresh air. Get medical attention if breathing becomes difficult or
respiratory irritation persists.
Other Instructions:
None
5. FIRE-FIGHTING MEASURES
Ignition Temperature - AIT (degrees C):
Not determined.
Flash Point (degrees C):
162.8 ( 325 F ) (PMCC)
Flammable Limits % (Lower-Upper):
Lower: Not Determined
Upper: Not Determined
Recommended Fire Extinguishing Agents And Special Procedures:
Use water spray, dry chemical, foam, or carbon dioxide to extinguish flames. Use water spray to cool fire-exposed containers. Water
or foam may cause frothing.
Unusual or Explosive Hazards:
None
Special Protective Equipment for Firefighters:
Wear full protective clothing and positive pressure breathing apparatus. Approach fire from upwind to avoid hazardous vapors and
toxic decomposition products.
6. ACCIDENTAL RELEASE MEASURES (Transportation Spills: CHEMTREC (800)424-9300)
Procedures in Case of Accidental Release, Breakage or Leakage:
Ventilate area. Avoid breathing vapor. Wear appropriate personal protective equipment, including appropriate respiratory protection.
Contain spill if possible. Wipe up or absorb on suitable material and shovel up. Prevent entry into sewers and waterways. Avoid
contact with skin, eyes or clothing.
3
SURFONIC庐 L24-9
PRODUCT CODE AND NAME L249
:
ISSUE DATE : 04/01/1999
MSDS CD DATE : 7/1/2000
COMPANY : HUNTSMAN
7. HANDLING AND STORAGE
Precautions to be Taken in
Handling:
Minimum feasible handling temperatures should be maintained. Eye wash should be available nearby when this product is handled or
used.
Storage:
Periods of exposure to high temperatures should be minimized. Water contamination should be avoided.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Protective Equipment (Type)
Eye/Face Protection:
Avoid eye contact. Chemical type goggles with face shield must be worn. Do not wear contact lenses.
Skin Protection:
Workers should wash exposed skin several times daily with soap and water. Soiled work clothing should be laundered or dry-cleaned.
Respiratory Protection:
Airborne concentrations should be kept to lowest levels possible. If vapor, mist or dust is generated and the occupational
exposure limit of the product, or any component of the product, is exceeded, use appropriate NIOSH or MSHA approved air
purifying or air supplied respirator after determining the airborne concentration of the contaminant. Air supplied respirators
should always be worn when airborne concentration of the contaminant or oxygen content is unknown.
Ventilation:
Local exhaust ventilation recommended if generating vapor, dust, or mist. If exhaust ventilation is not available or inadequate, use
MSHA or NIOSH approved respirator as appropriate.
Exposure Limit for the Total Product:
None established for product.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance:
Milky-white viscous liquid or semi-solid at room temperature
Odor:
Not determined
Boiling Point (degrees C):
Not determined.
Melting/Freezing Point (degrees C):
15.5 - 23.9 ( 60 - 75 F )
Specific Gravity (water=1):
.994
pH:
Not determined.
Vapor Pressure:
Not determined.
4
SURFONIC庐 L24-9
PRODUCT CODE AND NAME L249
:
ISSUE DATE : 04/01/1999
MSDS CD DATE : 7/1/2000
COMPANY : HUNTSMAN
Viscosity:
Not applicable.
VOC Content:
1% by ASTM D 2369
Vapor Density (Air=1):
19
Solubility in Water (%):
>10
Other:
None
10. STABILITY AND REACTIVITY
This Material Reacts Violently With:
None of these X
Air Water Heat Strong Oxidizers Others
Comments:
None
Products Evolved When Subjected to Heat or Combustion:
Toxic levels of carbon monoxide, carbon dioxide, irritating aldehydes and ketones may be formed on burning. Heating in air may
produce irritating aldehydes, acids, and ketones.
Hazardous Polymerizations:
DO NOT OCCUR
11. TOXICOLOGICAL INFORMATION
TOXICOLOGICAL INFORMATION (ANIMAL TOXICITY DATA)
Oral:
LD50 2.14 g/kg (rat) slightly toxic
Inhalation:
Not determined.
Dermal:
LD50 > 2.00 g/kg (rabbit) practically non-toxic
IRRITATION INDEX, ESTIMATION OF IRRITATION (SPECIES)
Skin:
(Draize) .34 /8.0 (rabbit) no appreciable effect
Eyes:
(Draize) 42.00 /110 (rabbit) severely irritating
Sensitization:
Not determined.
Other:
This product may contain residual (less than 100 ppm) concentrations of ethylene oxide. Ethylene oxide causes tumors in
laboratory animals.
5
SURFONIC庐 L24-9
PRODUCT CODE AND NAME L249
:
ISSUE DATE : 04/01/1999
MSDS CD DATE : 7/1/2000
COMPANY : HUNTSMAN
12. DISPOSAL CONSIDERATIONS:
Waste Disposal Methods:
This product has been evaluated for RCRA characteristics and does not meet the criteria of a hazardous waste if discarded in its
purchased form. Under RCRA, it is the responsibility of the user of the product to determine at the time of disposal, whether the
product meets RCRA criteria for hazardous waste. This is because product uses, transformations, mixtures, processes, etc. may
render the resulting materials hazardous.
Remarks:
None
13. TRANSPORT INFORMATION
Transportation
DOT:
Proper Shipping Name:
Environmentally Hazardous Substances, liquid, N.O.S. (alcohol, C12-C16, poly (1-6) ethoxylate)
Hazard Class:
9
Identification Number:
UN 3082
Packing Group:
III
Label Required:
Class 9 + marine pollutant mark
Depending on container size, spills of this product may require reporting under SARA 304 and/or CERCLA 102(A) regulations.
Please refer to Sections 2 and 14 of MSDS for composition and component RQ information.
IMDG
Proper Shipping Name:
Environmentally Hazardous Substances, liquid, N.O.S. (alcohol, C12-C16, poly (1-6) ethoxylate)
Hazard Class
9
Identification Number
UN 3082
Packing Group
III
Label Required
Class 9 + marine pollutant mark
ICAO
Proper Shipping Name:
Environmentally Hazardous Substances, liquid, N.O.S. (alcohol, C12-C16, poly (1-6) ethoxylate)
Hazard Class
9
Identification Number
UN 3082
Packing Group
III
Label Required
6
SURFONIC庐 L24-9
PRODUCT CODE AND NAME L249
:
ISSUE DATE : 04/01/1999
MSDS CD DATE : 7/1/2000
COMPANY : HUNTSMAN
Class 9 + marine pollutant mark
TDG
Proper Shipping Name:
Not regulated
Hazard Class:
Not regulated
Identification Number:
Not regulated
Label Required:
Not regulated
14. REGULATORY INFORMATION
Federal Regulations:
SARA Title III:
Section 302/304 Extremely Hazardous Substances
Chemical Name CAS Number Range in % TPQ RQ
Residual ethylene oxide (typical) 75-21-8 0.001 1000 10
Section 311 Hazardous Categorization:
Acute X Chronic Fire Pressure Reactive N/A
Section 313 Toxic Chemical
Chemical Name CAS Number Concentration
None.
CERCLA 102(a)/DOT Hazardous Substances:
Chemical Name CAS Number Range in % RQ
Glycol ethers (fraction of product matching EPA definition) 3.00-9.99 1
Residual ethylene oxide (typical) 75-21-8 0.001 10
States Right-to-Know Regulations:
Chemical Name State Right-to-know
None.
State list: CT (Connecticut), FL (Florida), IL (Illinois), MI (Michigan), LA (Louisiana), MA
(Massachusetts), NJ (New Jersey), PA (Pennsylvania), RI (Rhode Island)
California Prop. 65:
The following detectable components of this product are substances, or belong to classes of substances, known to the State of
California to cause cancer and/or reproductive toxicity.
Chemical Name CAS Number
Residual ethylene oxide (typical) 75-21-8
INTERNATIONAL REGULATIONS:
TSCA Inventory Status:
This product, or its components, are listed on or are exempt from the the Toxic Substance Control Act (TSCA) Chemical
Substance Inventory.
WHMIS Classification:
Class D, Div 2, Subdiv B: Irritant
Canadian Inventory Status:
7
SURFONIC庐 L24-9
PRODUCT CODE AND NAME L249
:
ISSUE DATE : 04/01/1999
MSDS CD DATE : 7/1/2000
COMPANY : HUNTSMAN
This product, or its components, are listed on or are exempt from the Canadian Domestic Substance List (DSL).
EINECS Inventory Status:
Not determined
Australian Inventory Status:
This product, or its components, are listed on or are exempt from the Australian Inventory of Chemical Substances (AICS).
Japan Inventory Status:
Not determined
15. ENVIRONMENTAL INFORMATION
Aquatic Toxicity:
Not determined.
Mobility:
Not determined.
Persistence and Biodegradability:
Not determined.
Potential to Bioaccumulate:
Not determined.
Remarks:
None
16. OTHER INFORMATION 04/01/1999
Ethoxylated products may contain residual amounts of ethylene oxide (EO) which can accumulate in the container headspace and
be released into the ambient environment. This process is enhanced when the product is agitated, as during tank car loading and
unloading, and blending operations. Ethylene oxide causes tumors in laboratory animals. The Occupational Safety and Health
Administration (OSHA) Permissible Exposure Level (PEL) for EO is 1 ppm for an eight-hour time weighted average exposure. The
standard regulates occupational exposure to EO from all sources, including products containing residual EO. It is the responsibility
of the employer to comply with OSHA ethylene oxide standard (29 CFR 1910.1047).
Supercedes: 2/12/1997 The following section has been revised: 13
Print Date: 06/09/2000
THE INFORMATION IN THIS DATA SHEET IS PROVIDED INDEPENDENTLY OF ANY SALE OF THE PRODUCT. IT IS PROVIDED
FOR THE PURPOSE OF HAZARD COMMUNICATION AS PART OF HUNTSMAN鈥橲 PRODUCT SAFETY PROGRAM. IT IS INTENDED
ONLY AS A GUIDE TO THE APPROPRIATE PRECAUTIONARY HANDLING OF THE PRODUCT BY A PROPERLY TRAINED PERSON.
YOU ARE ENCOURAGED AND REQUESTED TO ADVISE THOSE WHO MAY COME IN CONTACT WITH SUCH PRODUCTS OF THE
INFORMATION CONTAINED HEREIN. THE DATA RELATES ONLY TO THE SPECIFIC PRODUCT DESIGNATED, AND DOES NOT
RELATE TO USE OF THE PRODUCT IN COMBINATION WITH ANY OTHER MATERIAL OR USE OF THE PRODUCT IN ANY
PROCESS. THE DATA IS NOT INTENDED TO CONSTITUTE PERFORMANCE INFORMATION CONCERNING THE PRODUCT. NO
EXPRESS WARRANTY, OR IMPLIED WARRANTY OF MERCHANTABILITY FOR FITNESS FOR A PARTICULAR PURPOSE IS MADE
WITH RESPECT TO THE PRODUCT, ITS COMPOSITION, ITS SAFETY OR THE INFORMATION CONTAINED IN THIS DATA SHEET.
TO DETERMINE THE APPLICABILITY OR THE EFFECTS OF ANY LAW OR REGULATION WITH RESPECT TO THE PRODUCT,
THE USER SHOULD CONSULT A LEGAL ADVISOR OR THE APPROPRIATE GOVERNMENT AGENCY. HUNTSMAN DOES NOT
UNDERTAKE TO FURNISH ADVICE ON SUCH MATTERS.
CURRENT DATA SHEETS ARE AVAILABLE FOR ALL HUNTSMAN PRODUCTS. YOU ARE URGED TO OBTAIN DATA SHEETS FOR
ALL HUNTSMAN PRODUCTS YOU BUY, USE OR DISTRIBUTE BY CALLING (713) 235-6432 OR DIRECTING YOUR INQUIRIES TO:
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SURFONIC庐 L24-9
PRODUCT CODE AND NAME L249
:
ISSUE DATE : 04/01/1999
MSDS CD DATE : 7/1/2000
COMPANY : HUNTSMAN
HUNTSMAN
COORDINATOR, PRODUCT SAFETY
P.O. Box 27707
HOUSTON, TX 77227-7707
NO PERSON OR ORGANIZATION EXCEPT A DULY AUTHORIZED HUNTSMAN EMPLOYEE IS AUTHORIZED TO PROVIDE OR
MAKE AVAILABLE DATA SHEETS FOR HUNTSMAN PRODUCTS. DATA SHEETS FROM UNAUTHORIZED SOURCES MAY
CONTAIN INFORMATION THAT IS NO LONGER CURRENT OR ACCURATE. NO PART OF THIS DATA SHEET MAY BE
REPRODUCED OR TRANSMITTED IN ANY FORM, OR BY ANY MEANS, WITHOUT PERMISSION IN WRITING FROM HUNTSMAN.
ALL REQUESTS FOR PERMISSION TO REPRODUCE MATERIAL FROM THIS DATA SHEET SHOULD BE DIRECTED TO
HUNTSMAN, COORDINATOR, PRODUCT SAFETY AT THE ABOVE ADDRESS.
COPYRIGHT 漏 1999 BY HUNTSMAN CORPORATION. ALL RIGHTS RESERVED.
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