MATERIAL SAFETY DATA SHEET
S00856
01 00
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Section 1 -- PRODUCT AND COMPANY IDENTIFICATION
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PRODUCT NUMBER HMIS CODES
Health 3
S00856 Flammability 4
Reactivity 0
PRODUCT NAME
SPRAYON* Insect Repellent II
MANUFACTURER'S NAME EMERGENCY TELEPHONE NO.
THE SHERWIN-WILLIAMS COMPANY (216) 566-2917
Consumer Group - Industrial
Cleveland, OH 44115
DATE OF PREPARATION INFORMATION TELEPHONE NO.
08-AUG-03 (800) 251-2486
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Section 2 -- COMPOSITION/INFORMATION ON INGREDIENTS
% by WT CAS No. INGREDIENT UNITS VAPOR PRESSURE
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6 74-98-6 Propane
ACGIH TLV 2500 ppm 760 mm
OSHA PEL 1000 ppm
14 106-97-8 Butane
ACGIH TLV 800 ppm 760 mm
OSHA PEL 800 ppm
45 67-63-0 2-Propanol
ACGIH TLV 400 ppm 33 mm
ACGIH TLV 500 ppm STEL
OSHA PEL 400 ppm
OSHA PEL 500 ppm STEL
3 136-45-8 Dipropyl Isocinchomeronate
ACGIH TLV Not Available
OSHA PEL Not Available
25 134-62-3 Diethyltoluamide
ACGIH TLV Not Available
OSHA PEL Not Available
5 Proprietary n-Octyl Bicycloheptene Dicarboximide
ACGIH TLV Not Available
OSHA PEL Not Available
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Section 3 -- HAZARDS IDENTIFICATION
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ROUTES OF EXPOSURE
INHALATION of vapor or spray mist.
EYE or SKIN contact with the product, vapor or spray mist.
EFFECTS OF OVEREXPOSURE
EYES: Irritation.
SKIN: Prolonged or repeated exposure may cause irritation.
INHALATION: Irritation of the upper respiratory system.
May cause nervous system depression. Extreme overexposure may result in
unconsciousness and possibly death.
Continued on page 2
S00856 page 2
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SIGNS AND SYMPTOMS OF OVEREXPOSURE
Headache, dizziness, nausea, and loss of coordination are indications of
excessive exposure to vapors or spray mists.
Redness and itching or burning sensation may indicate eye or excessive
skin exposure.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE
Prolonged or frequent repeated skin contact may cause allergic reactions
in some individuals.
CANCER INFORMATION
For complete discussion of toxicology data refer to Section 11.
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Section 4 -- FIRST AID MEASURES
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EYES: Flush eyes with large amounts of water for 15 minutes.
Get medical attention.
SKIN: Wash affected area thoroughly with soap and water.
Remove contaminated clothing and launder before re-use.
INHALATION: If affected, remove from exposure. Restore breathing.
Keep warm and quiet.
INGESTION: Do not induce vomiting.
Get medical attention immediately.
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Section 5 -- FIRE FIGHTING MEASURES
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FLASH POINT LEL UEL
Propellant < 0 F 1.9 12.7
EXTINGUISHING MEDIA
Carbon Dioxide, Dry Chemical, Foam
UNUSUAL FIRE AND EXPLOSION HAZARDS
Containers may explode when exposed to extreme heat.
Application to hot surfaces requires special precautions.
During emergency conditions overexposure to decomposition products may
cause a health hazard. Symptoms may not be immediately apparent. Obtain
medical attention.
SPECIAL FIRE FIGHTING PROCEDURES
Full protective equipment including self-contained breathing apparatus
should be used.
Water spray may be ineffective. If water is used, fog nozzles are
preferable. Water may be used to cool closed containers to prevent
pressure build-up and possible autoignition or explosion when exposed to
extreme heat.
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Section 6 -- ACCIDENTAL RELEASE MEASURES
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STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
Remove all sources of ignition. Ventilate the area.
Remove with inert absorbent.
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Section 7 -- HANDLING AND STORAGE
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ENVIRONMENTAL HAZARDS
This product is toxic to fish and aquatic invertebrates. Do not apply
directly to water.
STORAGE CATEGORY
Not Available
Continued on page 3
S00856 page 3
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PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE
Keep away from heat, sparks, and open flame. Vapors will accumulate
readily and may ignite explosively.
During use and until all vapors are gone: Keep area ventilated - Do not
smoke - Extinguish all flames, pilot lights, and heaters - Turn off stoves,
electric tools and appliances, and any other sources of ignition.
Consult NFPA Code. Use approved Bonding and Grounding procedures.
Contents under pressure. Do not puncture, incinerate, or expose to
temperature above 120F. Heat from sunlight, radiators, stoves, hot water,
and other heat sources could cause container to burst. Do not take
internally. Keep out of the reach of children.
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Section 8 -- EXPOSURE CONTROLS/PERSONAL PROTECTION
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PRECAUTIONS TO BE TAKEN IN USE
Use only with adequate ventilation.
Avoid contact with skin and eyes. Avoid breathing vapor and spray mist.
Wash hands after using.
VENTILATION
Local exhaust preferable. General exhaust acceptable if the exposure to
materials in Section 2 is maintained below applicable exposure limits.
Refer to OSHA Standards 1910.94, 1910.107, 1910.108.
RESPIRATORY PROTECTION
If personal exposure cannot be controlled below applicable limits by
ventilation, wear a properly fitted organic vapor/particulate respirator
approved by NIOSH/MSHA for protection against materials in Section 2.
PROTECTIVE GLOVES
None required for normal application of aerosol products where minimal
skin contact is expected. For long or repeated contact, wear chemical
resistant gloves.
Wear gloves which are recommended by glove supplier for protection
against materials in Section 2.
EYE PROTECTION
Wear safety spectacles with unperforated sideshields.
OTHER PRECAUTIONS
Do not spray to contact food, feedstuffs or water supplies. Thoroughly
wash dishes and food-handling utensils contaminated with this product.
Remove pets and cover fish bowls before spraying.
Do not contaminate water, food or feed by storage or disposal. Do not
store near heat or open flame. Store in cool area away from children.
It is a violation of Federal law to use this product in a manner
inconsistent with its labeling. Read entire label.
Intentional misuse by deliberately concentrating and inhaling the
contents can be harmful or fatal.
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Section 9 -- PHYSICAL AND CHEMICAL PROPERTIES
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PRODUCT WEIGHT 6.53 lb/gal 782 g/l
SPECIFIC GRAVITY 0.79
BOILING POINT <0 - 181 F <-18 - 82 C
MELTING POINT Not Available
VOLATILE VOLUME 73 %
EVAPORATION RATE Faster than ether
VAPOR DENSITY Heavier than air
SOLUBILITY IN WATER N.A.
VOLATILE ORGANIC COMPOUNDS (VOC Theoretical)
Volatile Weight 65.00 % Less Water and Federally Exempt Solvents
Continued on page 4
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Section 10 -- STABILITY AND REACTIVITY
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STABILITY -- Stable
CONDITIONS TO AVOID
None known.
INCOMPATIBILITY
None known.
HAZARDOUS DECOMPOSITION PRODUCTS
By fire: Carbon Dioxide, Carbon Monoxide
HAZARDOUS POLYMERIZATION
Will not occur
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Section 11 -- TOXICOLOGICAL INFORMATION
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CHRONIC HEALTH HAZARDS
No ingredient in this product is an IARC, NTP or OSHA listed carcinogen.
Reports have associated repeated and prolonged overexposure to solvents
with permanent brain and nervous system damage.
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TOXICOLOGY DATA
CAS No. Ingredient Name
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74-98-6 Propane
LC50 RAT 4HR Not Available
LD50 RAT Not Available
106-97-8 Butane
LC50 RAT 4HR Not Available
LD50 RAT Not Available
67-63-0 2-Propanol
LC50 RAT 4HR Not Available
LD50 RAT 5045 mg/kg
136-45-8 Dipropyl Isocinchomeronate
LC50 RAT 4HR Not Available
LD50 RAT 5230 mg/kg
134-62-3 Diethyltoluamide
LC50 RAT 4HR Not Available
LD50 RAT 1950 mg/kg
Proprietary n-Octyl Bicycloheptene Dicarboximi
LC50 RAT 4HR Not Available
LD50 RAT 2800 mg/kg
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Section 12 -- ECOLOGICAL INFORMATION
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ECOTOXICOLOGICAL INFORMATION
No data available.
Continued on page 5
S00856 page 5
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Section 13 -- DISPOSAL CONSIDERATIONS
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WASTE DISPOSAL METHOD
Waste from this product may be hazardous as defined under the Resource
Conservation and Recovery Act (RCRA) 40 CFR 261.
Waste must be tested for ignitability to determine the applicable EPA
hazardous waste numbers.
Do not incinerate. Depressurize container. Dispose of in accordance
with Federal, State/Provincial, and Local regulations regarding pollution.
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Section 14 -- TRANSPORT INFORMATION
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No data available.
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Section 15 -- REGULATORY INFORMATION
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SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION
CAS No. CHEMICAL/COMPOUND % by WT % Element
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136-45-8 Dipropyl Isocinchomeronate 3
CALIFORNIA PROPOSITION 65
WARNING: This product contains a chemical known to the State of
California to cause cancer.
TSCA CERTIFICATION
All chemicals in this product are listed, or are exempt from listing,
on the TSCA Inventory.
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Section 16 -- OTHER INFORMATION
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This product has been classified in accordance with the hazard criteria
of the CPR and the MSDS contains all of the information required by the
CPR.
The above information pertains to this product as currently formulated,
and is based on the information available at this time. Addition of
reducers or other additives to this product may substantially alter the
composition and hazards of the product. Since conditions of use are
outside our control, we make no warranties, express or implied, and assume
no liability in connection with any use of this information.
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