MATERIAL SAFETY DATA SHEET
03630
01 00
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Section 1 鈭掆垝 PRODUCT AND COMPANY IDENTIFICATION
鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭?
PRODUCT NUMBER HMIS CODES
Health 2
03630 Flammability 4
Reactivity 0
PRODUCT NAME
KRYLON* Industrial QUIK鈭扢ARK* Water鈭払ased Inverted Marking Paint
(Fluorescent), Safety Green
MANUFACTURER鈥橲 NAME EMERGENCY TELEPHONE NO.
THE SHERWIN鈭扺ILLIAMS COMPANY (216) 566鈭?2917
Diversified Brands
Cleveland, OH 44115
DATE OF PREPARATION INFORMATION TELEPHONE NO.
30鈭扟UL鈭?05 (800) 247鈭?3266
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Section 2 鈭掆垝 COMPOSITION/INFORMATION ON INGREDIENTS
% by WT CAS No. INGREDIENT UNITS VAPOR PRESSURE
鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭?
14 74鈭?98鈭?6 Propane
ACGIH TLV 2500 ppm 760 mm
OSHA PEL 1000 ppm
6 106鈭?97鈭?8 Butane
ACGIH TLV 800 ppm 760 mm
OSHA PEL 800 ppm
14 64742鈭?89鈭?8 Lt. Aliphatic Hydrocarbon Solvent
ACGIH TLV 100 ppm 53 mm
OSHA PEL 100 ppm
2 64742鈭?89鈭?8 V. M. & P. Naphtha
ACGIH TLV 300 ppm 12 mm
OSHA PEL 300 ppm
OSHA PEL 400 ppm STEL
16 108鈭?88鈭?3 Toluene
ACGIH TLV 50 ppm (Skin) 22 mm
OSHA PEL 100 ppm (Skin)
OSHA PEL 150 ppm (Skin) STEL
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Section 3 鈭掆垝 HAZARDS IDENTIFICATION
鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭?
ROUTES OF EXPOSURE
INHALATION of vapor or spray mist.
EYE or SKIN contact with the product, vapor or spray mist.
EFFECTS OF OVEREXPOSURE
EYES: Irritation.
SKIN: Prolonged or repeated exposure may cause irritation.
INHALATION: Irritation of the upper respiratory system.
May cause nervous system depression. Extreme overexposure may result in
unconsciousness and possibly death.
Continued on page 2
03630 page 2
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SIGNS AND SYMPTOMS OF OVEREXPOSURE
Headache, dizziness, nausea, and loss of coordination are indications of
excessive exposure to vapors or spray mists.
Redness and itching or burning sensation may indicate eye or excessive
skin exposure.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE
None generally recognized.
CANCER INFORMATION
For complete discussion of toxicology data refer to Section 11.
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Section 4 鈭掆垝 FIRST AID MEASURES
鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭?
EYES: Flush eyes with large amounts of water for 15 minutes.
Get medical attention.
SKIN: Wash affected area thoroughly with soap and water.
Remove contaminated clothing and launder before re鈭抲se.
INHALATION: If affected, remove from exposure. Restore breathing.
Keep warm and quiet.
INGESTION: Do not induce vomiting.
Get medical attention immediately.
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Section 5 鈭掆垝 FIRE FIGHTING MEASURES
鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭?
FLASH POINT LEL UEL
Propellant < 0 F 0.9 9.5
EXTINGUISHING MEDIA
Carbon Dioxide, Dry Chemical, Alcohol Foam
UNUSUAL FIRE AND EXPLOSION HAZARDS
Closed containers may explode (due to the build鈭抲p of pressure) when
exposed to extreme heat.
Application to hot surfaces requires special precautions.
During emergency conditions overexposure to decomposition products may
cause a health hazard. Symptoms may not be immediately apparent. Obtain
medical attention.
SPECIAL FIRE FIGHTING PROCEDURES
Full protective equipment including self鈭抍ontained breathing apparatus
should be used.
Water spray may be ineffective. If water is used, fog nozzles are
preferable. Water may be used to cool closed containers to prevent
pressure build鈭抲p and possible autoignition or explosion when exposed to
extreme heat.
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Section 6 鈭掆垝 ACCIDENTAL RELEASE MEASURES
鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭?
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
Remove all sources of ignition. Ventilate the area.
Remove with inert absorbent.
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Section 7 鈭掆垝 HANDLING AND STORAGE
鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭?
STORAGE CATEGORY
Not Available
Continued on page 3
03630 page 3
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PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE
Keep away from heat, sparks, and open flame. Vapors will accumulate
readily and may ignite explosively.
During use and until all vapors are gone: Keep area ventilated 鈭? Do not
smoke 鈭? Extinguish all flames, pilot lights, and heaters 鈭? Turn off stoves,
electric tools and appliances, and any other sources of ignition.
Consult NFPA Code. Use approved Bonding and Grounding procedures.
Contents under pressure. Do not puncture, incinerate, or expose to
temperature above 120F. Heat from sunlight, radiators, stoves, hot water,
and other heat sources could cause container to burst. Do not take
internally. Keep out of the reach of children.
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Section 8 鈭掆垝 EXPOSURE CONTROLS/PERSONAL PROTECTION
鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭?
PRECAUTIONS TO BE TAKEN IN USE
Use only with adequate ventilation.
Avoid contact with skin and eyes. Avoid breathing vapor and spray mist.
Wash hands after using.
This coating may contain materials classified as nuisance particulates
(listed "as Dust" in Section 2) which may be present at hazardous levels
only during sanding or abrading of the dried film. If no specific dusts
are listed in Section 2, the applicable limits for nuisance dusts are ACGIH
TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3
(total dust), 5 mg/m3 (respirable fraction).
VENTILATION
Local exhaust preferable. General exhaust acceptable if the exposure to
materials in Section 2 is maintained below applicable exposure limits.
Refer to OSHA Standards 1910.94, 1910.107, 1910.108.
RESPIRATORY PROTECTION
If personal exposure cannot be controlled below applicable limits by
ventilation, wear a properly fitted organic vapor/particulate respirator
approved by NIOSH/MSHA for protection against materials in Section 2.
When sanding or abrading the dried film, wear a dust/mist respirator
approved by NIOSH/MSHA for dust which may be generated from this product,
underlying paint, or the abrasive.
PROTECTIVE GLOVES
None required for normal application of aerosol products where minimal
skin contact is expected. For long or repeated contact, wear chemical
resistant gloves.
EYE PROTECTION
Wear safety spectacles with unperforated sideshields.
OTHER PRECAUTIONS
Intentional misuse by deliberately concentrating and inhaling the
contents can be harmful or fatal.
Continued on page 4
03630 page 4
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Section 9 鈭掆垝 PHYSICAL AND CHEMICAL PROPERTIES
鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭?
PRODUCT WEIGHT 6.66 lb/gal 798 g/l
SPECIFIC GRAVITY 0.80
BOILING POINT <0 鈭? 325 F <鈭?18 鈭? 162 C
MELTING POINT Not Available
VOLATILE VOLUME 92 %
EVAPORATION RATE Faster than ether
VAPOR DENSITY Heavier than air
SOLUBILITY IN WATER N.A.
pH 7.0
VOLATILE ORGANIC COMPOUNDS (VOC Theoretical)
Volatile Weight 54.55 % Less Water and Federally Exempt Solvents
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Section 10 鈭掆垝 STABILITY AND REACTIVITY
鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭?
STABILITY 鈭掆垝 Stable
CONDITIONS TO AVOID
None known.
INCOMPATIBILITY
None known.
HAZARDOUS DECOMPOSITION PRODUCTS
By fire: Carbon Dioxide, Carbon Monoxide
HAZARDOUS POLYMERIZATION
Will not occur
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Section 11 鈭掆垝 TOXICOLOGICAL INFORMATION
鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭?
CHRONIC HEALTH HAZARDS
No ingredient in this product is an IARC, NTP or OSHA listed carcinogen.
Prolonged overexposure to solvent ingredients in Section 2 may cause
adverse effects to the liver, urinary, cardiovascular and reproductive
systems.
Reports have associated repeated and prolonged overexposure to solvents
with permanent brain and nervous system damage.
鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭?
TOXICOLOGY DATA
CAS No. Ingredient Name
鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭?
74鈭?98鈭?6 Propane
LC50 RAT 4HR Not Available
LD50 RAT Not Available
106鈭?97鈭?8 Butane
LC50 RAT 4HR Not Available
LD50 RAT Not Available
64742鈭?89鈭?8 Lt. Aliphatic Hydrocarbon Solvent
LC50 RAT 4HR Not Available
LD50 RAT Not Available
64742鈭?89鈭?8 V. M. & P. Naphtha
LC50 RAT 4HR Not Available
LD50 RAT Not Available
108鈭?88鈭?3 Toluene
LC50 RAT 4HR 4000 ppm
LD50 RAT 5000 mg/kg
Continued on page 5
03630 page 5
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Section 12 鈭掆垝 ECOLOGICAL INFORMATION
鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭?
ECOTOXICOLOGICAL INFORMATION
No data available.
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Section 13 鈭掆垝 DISPOSAL CONSIDERATIONS
鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭?
WASTE DISPOSAL METHOD
Waste from this product may be hazardous as defined under the Resource
Conservation and Recovery Act (RCRA) 40 CFR 261.
Waste must be tested for ignitability to determine the applicable EPA
hazardous waste numbers.
Do not incinerate. Depressurize container. Dispose of in accordance
with Federal, State/Provincial, and Local regulations regarding pollution.
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Section 14 鈭掆垝 TRANSPORT INFORMATION
鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭?
No data available.
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Section 15 鈭掆垝 REGULATORY INFORMATION
鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭?
SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION
CAS No. CHEMICAL/COMPOUND % by WT % Element
鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭?
108鈭?88鈭?3 Toluene 16
CALIFORNIA PROPOSITION 65
WARNING: This product contains chemicals known to the State of
California to cause cancer and birth defects or other reproductive harm.
TSCA CERTIFICATION
All chemicals in this product are listed, or are exempt from listing,
on the TSCA Inventory.
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Section 16 鈭掆垝 OTHER INFORMATION
鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭?
This product has been classified in accordance with the hazard criteria
of the Canadian Controlled Products Regulations (CPR) and the MSDS contains
all of the information required by the CPR.
The above information pertains to this product as currently formulated,
and is based on the information available at this time. Addition of
reducers or other additives to this product may substantially alter the
composition and hazards of the product. Since conditions of use are
outside our control, we make no warranties, express or implied, and assume
no liability in connection with any use of this information.
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