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MSDS Material Safety Data Sheet
CAS

112-24-3

File Name: euclidchemical_com---040G_2B_U.asp
Material Safety Data Sheet




E3-G - 2 CU FT UNIT PART B
Version 1 Print Date 07/12/2007
REVISION DATE: 02/01/2006


SECTION 1 - PRODUCT IDENTIFICATION

Trade name : E3-G - 2 CU FT UNIT PART B
Product code : 040G 2B

COMPANY : Euclid Chemical Company
19218 Redwood Road
Cleveland, OH 44110
Telephone : 1-800-321-7628
Emergency Phone: : U.S. only: 1-800-255-3924
International Users Call Collect: 1-813-248-0585

Product use : Curative

SECTION 2 - HAZARDS IDENTIFICATION

Emergency Overview
Liquid. May cause slight irritation to the respiratory system. Move to fresh air. If required, artificial respiration or
administration of oxygen can be performed by trained personnel. Remove to fresh air. Get immediate medical
attention.

Acute Potential Health Effects/ Routes of Entry
Inhalation May cause slight irritation to the respiratory system.
:
Eyes Vapors or liquid may cause tearing, blurred vision, severe irritation, and possible chemical
:
burns.
Ingestion May cause gastrointestinal irritation, nausea, and vomiting. May cause chemical burns to
:
stomach, mouth, nose, and throat.
Skin May cause itching, reddening, inflammation. May cause severe burns, blistering and skin
:
damage. May cause sensitization resulting in irritation, itching and redness. May cause a
rash.

Aggravated Medical Conditions
Pre-existing eye, skin and respiratory disorders may be aggravated by exposure.

Chronic Health Effects
May cause sensitization by contact. Prolonged skin contact may cause irritation, burns or dermatitis. Repeated
overexposure to vapors and/or material may injure the liver, kidneys and respiratory system unless suitable
engineering controls and/or personal protective equipment are used. May aggravate persons sensitized to
amines. Fillers are encapsulated and not expected to be released from product under normal conditions of use.

SECTION 3 - PRODUCT COMPOSITION


Chemical Name CAS-No. Weight %
Triethylenetetramine 112-24-3 > 60.0




1/5 040G 2B
Material Safety Data Sheet




E3-G - 2 CU FT UNIT PART B
Version 1 Print Date 07/12/2007
REVISION DATE: 02/01/2006



SECTION 4 - FIRST AID MEASURES

Get immediate medical attention for any significant overexposure.

Inhalation : Move to fresh air. If required, artificial respiration or administration of oxygen can be
performed by trained personnel.Remove to fresh air. Get immediate medical
attention.
Eye contact : Flush with water for at least 15 minutes while holding eye lids apart. Get medical
attention immediately.
Skin contact : Clean area of contact thoroughly using soap and water. If irritation, rash or other
disorders develop, get medical attention immediately.
Ingestion : Do not induce vomiting unless advised by a physician. Call nearest Poison Control
Center or Physician immediately.


SECTION 5 - FIRE FIGHTING MEASURES

Flash point : 300 掳 149 掳
F, C
Method : Not available.
Lower explosion limit : Not available.
Upper explosion limit : Not available.
Autoignition temperature : Not available.
Extinguishing media : If water fog is ineffective, use carbon dioxide, dry chemical or foam.
Hazardous combustion : Carbon monoxide and carbon dioxide can form.Smoke, fumes.Nitrogen
products oxides can form.
Protective equipment for : Use accepted fire fighting techniques. Wear full firefighting protective
firefighters clothing, including self-contained breathing apparatus (SCBA).
Fire and explosion conditions : Product may ignite if heated in excess of its flash point.Vapors may
travel to sources of ignition and flashback.Vapor concentrations in
enclosed areas may ignite explosively.Empty containers may contain
ignitable vapors.


SECTION 6 - ACCIDENTAL RELEASE MEASURES

Use appropriate protective equipment. Avoid contact with material. Remove sources of ignition immediately.
Stop flow of material if safe to do so. Contain spill and keep out of water courses. Ventilate area.

SECTION 7 - HANDLING AND STORAGE

Prevent inhalation of vapor, ingestion, and contact with skin eyes and clothing. Keep container closed when
not in use. Precautions also apply to emptied containers. Do not smoke, weld, generate sparks, or use flame
near container. Do not use in confined or poorly ventilated areas. Personal protective equipment must be worn
during maintenance or repair of contaminated mixer, reactor, or other equipment. Store under dry warehouse
conditions away from heat and all ignition sources.


2/5 040G 2B
Material Safety Data Sheet




E3-G - 2 CU FT UNIT PART B
Version 1 Print Date 07/12/2007
REVISION DATE: 02/01/2006


SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION

Personal protection equipment
Respiratory protection : Wear NIOSH/MSHA approved vapor respirator with appropriate cartridge
when the vapor concentration is expected to exceed exposure limits indicated
on the MSDS. Follow manufacturer's directions for respirator use.
Hand protection : Use suitable impervious nitrile or neoprene gloves and protective apparel to
reduce exposure.
Eye protection : Wear chemical safety goggles and/or face shield to prevent eye contact. Do
not wear contact lenses. Do not touch eyes with contaminated body parts or
materials. Have eye washing facilities readily available.
Skin and body protection : Prevent contact with shoes and clothing. Use rubber apron and overshoes.
Protective measures : Inspect and replace equipment at regular intervals.Use professional judgment
in the selection, care, and use.
Engineering measures : Use only in well ventilated areas. Provide maximum ventilation in enclosed
areas.Use local exhaust when the general ventilation is inadequate.

Exposure Limits
No known components with exposure limits.



SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES

Form : Liquid
Odor : Amine
pH : Not available.
Vapour pressure : Not available.
Vapor density : Heavier than air
Melting point/range : Not available.
Freezing point : Not available.
Boiling point/range : 530.6 掳 277 掳
F, C
Water solubility : Negligible
Specific Gravity : 0.99
% Volatile Weight : 0.0 %


SECTION 10 - REACTIVITY / STABILITY

Substances to avoid : Oxidizing agents.Epoxies.Isocyanates.Acids.
Stability : Material is stable under normal storage, handling, and use.
Hazardous polymerization : Will not occur under normal conditions.



3/5 040G 2B
Material Safety Data Sheet




E3-G - 2 CU FT UNIT PART B
Version 1 Print Date 07/12/2007
REVISION DATE: 02/01/2006



SECTION 11 - TOXICOLOGICAL INFORMATION

No Data Available


SECTION 12 - ECOLOGICAL INFORMATION

No Data Available


SECTION 13 - DISPOSAL CONSIDERATIONS

Disposal Method : Subject to hazardous waste treatment, storage, and disposal requirements under
RCRA. Recycle or incinerate waste at EPA approved facility or dispose of in
compliance with federal, state and local regulations.


SECTION 14 - TRANSPORTATION / SHIPPING DATA

TDG / DOT Shipping Description:
CORROSIVE LIQUID, N.O.S. (Contains Triethylene tetramine), 8, UN1760, PG II


SECTION 15 - REGULATORY INFORMATION

North American Inventories:
All components are listed or exempt from the TSCA inventory.
This product or its components are listed on, or exempt from the Canadian Domestic Substances List.

U.S. Federal Regulations:
:
SARA 313 Components None present or none present in regulated quantities.

SARA 311/312 Hazards : Acute Health Hazard

OSHA Hazardous Components :
Triethylenetetramine 112-24-3

OSHA Status: Considered : Corrosive
hazardous based on the
following criteria:

OSHA Flammability : IIIB

Regulatory VOC (less water and : 0 g/l
exempt solvent)
VOC Method 310 : 0%

U.S. State Regulations:
MASS RTK Components : Triethylenetetramine 112-24-3

Penn RTK Components : Triethylenetetramine 112-24-3


4/5 040G 2B
Material Safety Data Sheet




E3-G - 2 CU FT UNIT PART B
Version 1 Print Date 07/12/2007
REVISION DATE: 02/01/2006


NJ RTK Components : Triethylenetetramine 112-24-3

Chemicals known to the State of California to cause cancer birth defects and/or other reproductive harm:
None known.


SECTION 16 - OTHER INFORMATION

HMIS Rating :
Health 2 0 = Minimum
1 = Slight
Flammability 1
2 = Moderate
Reactivity 0
3 = Serious
PPE
4 = Severe

Further information:
For Industrial Use Only. Keep out of Reach of Children. The hazard information herein is offered solely for the
consideration of the user, subject to their own investigation of compliance with applicable regulations, including
the safe use of the product under every foreseeable condition.

Prepared by: Rich Mikol

Legend
ACGIH - American Conference of Governmental Hygienists PEL - Permissible Exposure Limit
CERCLA - Comprehensive Environmental Response, Compensation, and
RCRA - Resource Conservation and Recovery Act
Liability Act
DOT - Department of Transportation RTK - Right To Know
DSL - Domestic Substance List SARA - Superfund Amendments and Reauthorization Act
EPA - Environmental Protection Agency STEL - Short Term Exposure Limit
HMIS - Hazardous Materials Information System TLV - Threshold Limit Value
IARC - International Agency for Research on Cancer TSCA - Toxic Substances Control Act
MSHA - Mine Safety Health Administration TWA - Time Weighted Average
NDSL - Non-Domestic Substance List V - Volume
NIOSH - National Institute for Occupational Safety and Health VOC - Volatile Organic Compound
WHMIS - Workplace Hazardous Materials Information
NTP - National Toxicology Program
System
OSHA - Occupational Safety and Health Administration




5/5 040G 2B

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