Material Safety Data Sheet
EUCO 700 - 50 GAL UNIT PART B
Version 2. Print Date 08/19/2008
REVISION DATE: 08/18/2008
SECTION 1 - PRODUCT IDENTIFICATION
Trade name : EUCO 700 - 50 GAL UNIT PART B
Product code : 042A 55B
COMPANY : Euclid Chemical Company
19218 Redwood Road
Cleveland, OH 44110
Telephone : 1-800-321-7628
Emergency Phone: : U.S. only: 1-800-424-9300
International Users Call Collect: 1-703-527-3887
Product use : Curative
SECTION 2 - HAZARDS IDENTIFICATION
Emergency Overview
Gray. Liquid. May cause slight irritation to the respiratory system. Move to fresh air. If required, artificial
respiration or administration of oxygen can be performed by trained personnel.
Acute Potential Health Effects/ Routes of Entry
Inhalation May cause slight irritation to the respiratory system.
:
Eyes Vapors or liquid may cause tearing, blurred vision, severe irritation, and possible chemical
:
burns.
Ingestion May cause gastrointestinal irritation, nausea, and vomiting. May cause chemical burns to
:
stomach, mouth, nose, and throat.
Skin May cause itching, reddening, inflammation. May cause severe burns, blistering and skin
:
damage. May cause sensitization resulting in irritation, itching and redness. May cause a
rash.
Aggravated Medical Conditions
Pre-existing eye, skin and respiratory disorders may be aggravated by exposure.
Chronic Health Effects
May cause sensitization by contact. Prolonged skin contact may cause irritation, burns or dermatitis. Repeated
overexposure to vapors and/or material may injure the liver, kidneys and respiratory system unless suitable
engineering controls and/or personal protective equipment are used. May aggravate persons sensitized to
amines. Inhalation of crystalline silica (quartz) can cause cancer based on animal data, and IARC concludes
sufficient evidence in humans (Group 1). Prolonged and repeated overexposure to free crystalline silica dust
above the TLV level may cause scarring of the lungs with cough and shortness of breath. A delayed lung injury,
silicosis may result from breathing free silica. Repeated inhalation of nonyl phenol may cause lung damage.
Repeated skin contact with nonyl phenol may cause skin irritation and dermatitis. Fillers are encapsulated and
not expected to be released from product under normal conditions of use.
SECTION 3 - PRODUCT COMPOSITION
1/6 042A 55B
Material Safety Data Sheet
EUCO 700 - 50 GAL UNIT PART B
Version 2. Print Date 08/19/2008
REVISION DATE: 08/18/2008
Chemical Name CAS-No. Weight %
Mercaptan polymer NJ TSRN# 51721300-5582P 15.0 - 40.0
4-Nonylphenol 84852-15-3 15.0 - 40.0
Benzene, mono-C10-14-alkyl derivs. 68442-69-3 15.0 - 40.0
Calcium Carbonate (Limestone) 1317-65-3 15.0 - 40.0
N Amino ethyl piperazine 140-31-8 10.0 - 30.0
Benzene, C10-16-alkyl derivs. 68648-87-3 3.0 - 7.0
Crystalline Silica (Quartz)/ Silica
14808-60-7 - <1.0
Sand
SECTION 4 - FIRST AID MEASURES
Get immediate medical attention for any significant overexposure.
Inhalation : Move to fresh air. If required, artificial respiration or administration of oxygen can be
performed by trained personnel.
Eye contact : Flush with water for at least 15 minutes while holding eye lids apart. Get medical
attention immediately.
Skin contact : Clean area of contact thoroughly using soap and water. If irritation, rash or other
disorders develop, get medical attention immediately.
Ingestion : Do not induce vomiting unless advised by a physician. Call nearest Poison Control
Center or Physician immediately.
SECTION 5 - FIRE FIGHTING MEASURES
Flash point : > 200 掳 > 93 掳
F, C
Method : Setaflash Closed Cup
Lower explosion limit : Not available.
Upper explosion limit : Not available.
Autoignition temperature : Not available.
Extinguishing media : If water fog is ineffective, use carbon dioxide, dry chemical or foam.
Hazardous combustion : Carbon monoxide and carbon dioxide can form.Smoke, fumes.Nitrogen
products oxides can form.
Protective equipment for : Use accepted fire fighting techniques. Wear full firefighting protective
firefighters clothing, including self-contained breathing apparatus (SCBA).
Fire and explosion conditions : Product may ignite if heated in excess of its flash point.Vapors may
travel to sources of ignition and flashback.Vapor concentrations in
enclosed areas may ignite explosively.Empty containers may contain
ignitable vapors.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
Use appropriate protective equipment. Avoid contact with material. Remove sources of ignition immediately.
Stop flow of material if safe to do so. Contain spill and keep out of water courses. Ventilate area.
2/6 042A 55B
Material Safety Data Sheet
EUCO 700 - 50 GAL UNIT PART B
Version 2. Print Date 08/19/2008
REVISION DATE: 08/18/2008
SECTION 7 - HANDLING AND STORAGE
Prevent inhalation of vapor, ingestion, and contact with skin eyes and clothing. Keep container closed when
not in use. Precautions also apply to emptied containers. Do not smoke, weld, generate sparks, or use flame
near container. Do not use in confined or poorly ventilated areas. Personal protective equipment must be worn
during maintenance or repair of contaminated mixer, reactor, or other equipment. Store under dry warehouse
conditions away from heat and all ignition sources.
SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
Personal protection equipment
Respiratory protection : Wear NIOSH/MSHA approved vapor respirator with appropriate cartridge
when the vapor concentration is expected to exceed exposure limits indicated
on the MSDS. Follow manufacturer's directions for respirator use.
Hand protection : Use suitable impervious nitrile or neoprene gloves and protective apparel to
reduce exposure.
Eye protection : Wear chemical safety goggles and/or face shield to prevent eye contact. Do
not wear contact lenses. Do not touch eyes with contaminated body parts or
materials. Have eye washing facilities readily available.
Skin and body protection : Prevent contact with shoes and clothing. Use rubber apron and overshoes.
Protective measures : Inspect and replace equipment at regular intervals.Use professional judgment
in the selection, care, and use.
Engineering measures : Use only in well ventilated areas. Provide maximum ventilation in enclosed
areas.Use local exhaust when the general ventilation is inadequate.
Exposure Limits
Chemical Name CAS Number Regulation Limit Form
Calcium Carbonate 1317-65-3 OSHA PEL: 5 mg/m3 Respirable fraction.
(Limestone) OSHA PEL: 15 mg/m3 Total dust.
ACGIH TWA: 3 mg/m3 Respirable particles.
ACGIH TWA: 10 mg/m3 Inhalable particles.
OSHA TWA: 15 mg/m3 Total dust.
OSHA TWA: 5 mg/m3 Respirable fraction.
Crystalline Silica (Quartz)/ 14808-60-7 OSHA TWA: 0.1 mg/m3 Respirable.
Silica Sand OSHA TWA: 0.3 mg/m3 Total dust.
OSHA PEL: 15 mg/m3 Total dust.
OSHA PEL: 5 mg/m3 Respirable fraction.
ACGIH TWA: 0.025 mg/m3 Respirable fraction.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
Form : Liquid
Color : Gray
3/6 042A 55B
Material Safety Data Sheet
EUCO 700 - 50 GAL UNIT PART B
Version 2. Print Date 08/19/2008
REVISION DATE: 08/18/2008
Odor : Mild mercaptan odor
pH : 8-9
Vapour pressure : Not available.
Vapor density : Heavier than air
Melting point/range : Not available.
Freezing point : Not available.
Boiling point/range : Not available.
Water solubility : Negligible
Specific Gravity : 1.2
% Volatile Weight : 25.9 %
SECTION 10 - REACTIVITY / STABILITY
Substances to avoid : Oxidizing agents.Epoxies.Isocyanates.Acids.
Stability : Material is stable under normal storage, handling, and use.
Hazardous polymerization : Will not occur under normal conditions.
SECTION 11 - TOXICOLOGICAL INFORMATION
No Data Available
SECTION 12 - ECOLOGICAL INFORMATION
No Data Available
SECTION 13 - DISPOSAL CONSIDERATIONS
Disposal Method : Subject to hazardous waste treatment, storage, and disposal requirements under
RCRA. Recycle or incinerate waste at EPA approved facility or dispose of in
compliance with federal, state and local regulations.
SECTION 14 - TRANSPORTATION / SHIPPING DATA
TDG / DOT Shipping Description:
NOT REGULATED
SECTION 15 - REGULATORY INFORMATION
North American Inventories:
All components are listed or exempt from the TSCA inventory.
This product or its components are listed on, or exempt from the Canadian Domestic Substances List.
4/6 042A 55B
Material Safety Data Sheet
EUCO 700 - 50 GAL UNIT PART B
Version 2. Print Date 08/19/2008
REVISION DATE: 08/18/2008
U.S. Federal Regulations:
SARA 313 Components None present or none present in regulated quantities.
:
SARA 311/312 Hazards : Acute Health Hazard
Chronic Health Hazard
OSHA Hazardous Components :
Calcium Carbonate (Limestone) 1317-65-3
Crystalline Silica (Quartz)/ Silica Sand 14808-60-7
OSHA Status: Considered : Irritant
hazardous based on the Carcinogen
following criteria:
OSHA Flammability : Not Regulated
When appropriately mixed with the other part, product has a VOC less water and exempt solvent of:
0 g/l
Chemical is listed as an IARC, NTP, OSHA, or ACGIH Carcinogen:
Crystalline Silica (Quartz)/ Silica Sand 14808-60-7
U.S. State Regulations:
MASS RTK Components : Calcium Carbonate (Limestone) 1317-65-3
N Amino ethyl piperazine 140-31-8
Crystalline Silica (Quartz)/ Silica Sand 14808-60-7
Penn RTK Components : Mercaptan polymer NJ TSRN# 51721300-5582P
4-Nonylphenol 84852-15-3
Benzene, mono-C10-14-alkyl derivs. 68442-69-3
Calcium Carbonate (Limestone) 1317-65-3
N Amino ethyl piperazine 140-31-8
Benzene, C10-16-alkyl derivs. 68648-87-3
NJ RTK Components : Mercaptan polymer NJ TSRN# 51721300-5582P
4-Nonylphenol 84852-15-3
Benzene, mono-C10-14-alkyl derivs. 68442-69-3
Calcium Carbonate (Limestone) 1317-65-3
N Amino ethyl piperazine 140-31-8
Crystalline Silica (Quartz)/ Silica Sand 14808-60-7
WARNING! Contains chemicals known to the State of California to cause cancer, birth defects and/or other
reproductive harm:
14808-60-7 Crystalline Silica (Quartz)/ Silica Sand
5/6 042A 55B
Material Safety Data Sheet
EUCO 700 - 50 GAL UNIT PART B
Version 2. Print Date 08/19/2008
REVISION DATE: 08/18/2008
SECTION 16 - OTHER INFORMATION
HMIS Rating :
Health 3 0 = Minimum
1 = Slight
Flammability 1
2 = Moderate
Reactivity 1
3 = Serious
PPE
4 = Severe
Further information:
For Industrial Use Only. Keep out of Reach of Children. The hazard information herein is offered solely for the
consideration of the user, subject to their own investigation of compliance with applicable regulations, including
the safe use of the product under every foreseeable condition.
Prepared by: Rich Mikol
Legend
ACGIH - American Conference of Governmental Hygienists PEL - Permissible Exposure Limit
CERCLA - Comprehensive Environmental Response, Compensation, and
RCRA - Resource Conservation and Recovery Act
Liability Act
DOT - Department of Transportation RTK - Right To Know
DSL - Domestic Substance List SARA - Superfund Amendments and Reauthorization Act
EPA - Environmental Protection Agency STEL - Short Term Exposure Limit
HMIS - Hazardous Materials Information System TLV - Threshold Limit Value
IARC - International Agency for Research on Cancer TSCA - Toxic Substances Control Act
MSHA - Mine Safety Health Administration TWA - Time Weighted Average
NDSL - Non-Domestic Substance List V - Volume
NIOSH - National Institute for Occupational Safety and Health VOC - Volatile Organic Compound
WHMIS - Workplace Hazardous Materials Information
NTP - National Toxicology Program
System
OSHA - Occupational Safety and Health Administration
6/6 042A 55B
|