MATERIAL SAFETY DATA SHEET
READ AND UNDERSTAND MATERIAL SAFETY DATA SHEET BEFORE HANDLING OR DISPOSING
OF PRODUCT
R-MER庐 II RESIN
MSDS CODE AND NAME GRADE 27
:
DATE ISSUED : 9/20/2005
9/20/2005
DATE PRINTED :
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
MATERIAL IDENTITY
MSDS CODE AND NAME
R-MER庐 II RESIN
GRADE 27
GRADE27 B
1
Chemical Name and/or Family or Description:
Chemical Name: Polystyrene thermoplastic polymer
Synonym(s): 1,3-Butadiene-Styrene copolymer
Molecular Formula: (C8H8-C4H6)X
COMPANY INFORMATION
Huntsman Corporation
P.O. Box 4980
The Woodlands, TX 77387-4980
TELEPHONE NUMBERS
Transportation Emergency
Company: (800) 328-8501
CHEMTREC: (800) 424-9300
Medical Emergency: (409) 722-9673 (24 Hour)
General MSDS Assistance: (281) 719-6432
Technical Information: (800) 972-1010
2. COMPOSITION AND INFORMATION ON INGREDIENTS
THE CRITERIA FOR LISTING COMPONENTS IN THE COMPOSITION SECTION ARE AS FOLLOWS: CARCINOGENS ARE LISTED WHEN
PRESENT AT 0.1 % OR GREATER; COMPONENTS WHICH ARE OTHERWISE HAZARDOUS ACCORDING TO OSHA ARE LISTED WHEN
PRESENT AT 1.0 % OR GREATER; NON-HAZARDOUS COMPONENTS ARE LISTED AT 3.0 % OR GREATER. THIS IS NOT INTENDED
TO BE COMPLETE COMPOSITIONAL DISCLOSURE. REFER TO SECTION 14 FOR APPLICABLE STATES' RIGHT TO KNOW AND
OTHER REGULATORY INFORMATION.
Product and/or Component(s) Carcinogenic According to:
OSHA____ IARC____ NTP____ OTHER____ NONE__X__
Composition:
Chemical Name CAS Number Exposure Limits Range in %
Benzene, ethenyl-, polymer with 1,3-butadiene 9003-55-8 >92.6
600 ppm TWA ACGIH
Pentane 109-66-0 < 7.0
1000 ppm TWA OSHA
750 ppm STEL OSHA
120 ppm TWA (Canada)
350 mg/m3 TWA (Canada)
1
R-MER庐 II RESIN
MSDS CODE AND NAME GRADE 27
:
DATE ISSUED : 9/20/2005
DATE PRINTED : 9/20/2005
COMPANY : HUNTSMAN
3. HAZARD IDENTIFICATION
EMERGENCY OVERVIEW
Appearance:
Solid, white beads
Odor:
Slight hydrocarbon odor
WARNING STATEMENT
DANGER! EXTREMELY FLAMMABLE VAPOR
VAPOR MAY CAUSE FLASH FIRE
VAPOR MAY CAUSE DIZZINESS AND DROWSINESS
VAPOR MAY CAUSE IRRITATION TO EYES AND RESPIRATORY TRACT
Hazardous Material National Fire Protection
1
Health Flammability
3
Information System Association NFPA
3
Fire
1 0
(United States) (United States) Reactivity
Health
0
Reactivity
Personal protection Specific danger
POTENTIAL HEALTH EFFECTS
Primary Route of Exposure
Eye__X__ Skin__X__ Inhalation__X__ Ingestion____
Effects of Overexposure
Acute:
Vapor may cause irritation, experienced as discomfort, with excess tear production and
Eyes:
blinking, and seen as excess redness of the eye. Product may contain residual amounts of
dust or small particulates which may cause eye irritation or abrasion experienced as mild
discomfort and slight excess redness of the eye.
Product may contain residual amounts of dust or small particulates that may cause skin
Skin:
irritation or abrasion experienced as local redness with possible mild discomfort.
Vapors or mist may cause irritation of the nose and throat. Inhalation may cause dizziness,
Inhalation:
drowsiness, euphoria, loss of coordination, disorientation, headache, nausea, and vomiting.
In poorly ventilated areas or confined spaces, unconsciousness and asphyxiation may result.
Prolonged or repeated overexposure may result in the absorption of potentially harmful
amounts of material.
Dust may cause irritation of the nose and throat. Overexposure to high concentrations of
dust may cause respiratory irritation, experienced as coughing and difficulty breathing.
If more than several mouthfuls are swallowed, abdominal discomfort, nausea, and diarrhea
Ingestion:
may occur.
Unknown
Sensitization Properties:
Chronic:
Prolonged or repeated inhalation of dust or particulates may impair lung function or cause lung damage.
Medical Conditions Aggravated by Exposure:
Overexposure to vapor, dust or mist may aggravate existing respiratory conditions, such as asthma, bronchitis, and
inflammatory or fibrotic respiratory disease.
2
R-MER庐 II RESIN
MSDS CODE AND NAME GRADE 27
:
DATE ISSUED : 9/20/2005
DATE PRINTED : 9/20/2005
COMPANY : HUNTSMAN
Other Remarks:
None
4. FIRST AID MEASURES
Eyes:
Flush eyes with plenty of water for several minutes. Remove larger particulates from the eye as one would any foreign object.
Get medical attention if eye irritation persists or particulates are difficult to remove from the eye.
Skin:
Wash skin with plenty of soap and water for several minutes. Get medical attention if skin irritation develops or persists.
Ingestion:
If more than several mouthfuls of this material are swallowed, give two glasses of water (16 oz.). Get medical attention.
Inhalation:
If inhaled, remove to fresh air. If not breathing, clear person's airway and give artificial respiration. If breathing is difficult,
qualified medical personnel may administer oxygen. Get medical attention immediately.
Other Instructions:
None.
5. FIRE-FIGHTING MEASURES
Ignition Temperature - AIT (degrees C):
260 (500 F) for Pentane
471 (880 F) by ASTM D-1929 Expanded polystyrene
Flash Point (degrees C):
-40 (-40 F) CC for Pentane
Flammable Limits % (Lower-Upper):
Lower: 1.5 for Pentane
Upper: 7.8 for Pentane
Recommended Fire Extinguishing Agents And Special Procedures:
Water may be ineffective on flames but should be used to cool fire-exposed containers and provide protection for persons
attempting to stop the leak. Use water spray, dry chemical, foam or carbon dioxide to extinguish flames.
Unusual or Explosive Hazards:
Danger! Extremely flammable materials may release vapors that travel long distances, ignite, and flash back. Containers may
explode in a fire. Do not expose to heat, sparks, flame, static, or other sources of ignition. When handling, use non-sparking
tool, ground and bond all containers.
Explosive air-vapor mixtures may form. Fire gives off dense black smoke and acid gasses. Electrostatic discharge can be a
source of ignition due to accumulated pentane vapors exceeding the L.E.L. (lower explosive limit) of 1.5% (15,000 ppm).
Pentane vapors may be emitted from newly opened containers or when the product is heated. If ignited, there could be a very
high rate of flame propagation.
"NO SMOKING - NO MATCHES - NO LIGHTERS - NO WELDING" rules should be enforced.
Special Protective Equipment for Firefighters:
Wear full protective clothing and positive pressure breathing apparatus.
3
R-MER庐 II RESIN
MSDS CODE AND NAME GRADE 27
:
DATE ISSUED : 9/20/2005
DATE PRINTED : 9/20/2005
COMPANY : HUNTSMAN
6. ACCIDENTAL RELEASE MEASURES (Transportation Spills: CHEMTREC (800)424-9300)
Procedures in Case of Accidental Release, Breakage or Leakage:
Avoid the generation of dust clouds. Place in appropriate containers for disposal or recycle. Avoid breathing dust. Pressure
demand air supplied respirators should always be worn when the airborne concentration of the contaminant or oxygen is
unknown. Otherwise, wear respiratory protection and other personal protective equipment as appropriate for the potential
exposure hazard. Wear gloves, goggles, and protective clothing to avoid contact with eyes, skin, or clothing. Use vacuuming
or sweeping compound for clean-up. Do not dry sweep or use methods which increase dusting. Prevent entry into sewers and
waterways.
7. HANDLING AND STORAGE
Precautions to be Taken in
Handling:
Use spark-proof tools. Material may be at elevated temperatures and/or pressures. Exercise care when opening bleeders
and sampling ports.
Storage:
Ground and bond shipping container, transfer line, and receiving container. Keep away from heat, sparks, flame, and other
sources of ignition.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Protective Equipment (Type)
Eye/Face Protection:
Avoid eye contact. Chemical type goggles should be worn. Do not wear contact lenses.
Skin Protection:
Workers should wash exposed skin several times daily with soap and water. Soiled work clothing should be laundered or
dry-cleaned.
Respiratory Protection:
Airborne concentrations should be kept to lowest levels possible. If vapor, mist or dust is generated and the occupational
exposure limit of the product, or any component of the product, is exceeded, use appropriate NIOSH or MSHA approved air
purifying or air supplied respirator after determining the airborne concentration of the contaminant. Air supplied respirators
should always be worn when airborne concentration of the contaminant or oxygen content is unknown.
Ventilation:
Use explosion-proof equipment to maintain adequate ventilation to meet occupational exposure limits, if applicable (see
below), prevent accumulation of explosive air-gas mixtures, and avoid significant oxygen displacement. Oxygen levels should
be at least 19.5% in confined spaces or other work areas (OSHA value).
Exposure Limit for the Total Product:
None established for product; refer to Section 2 for component exposure limits.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance:
Solid, white beads
Odor:
Slight hydrocarbon odor
4
R-MER庐 II RESIN
MSDS CODE AND NAME GRADE 27
:
DATE ISSUED : 9/20/2005
DATE PRINTED : 9/20/2005
COMPANY : HUNTSMAN
Boiling Point (degrees C):
Not applicable
Melting/Freezing Point (degrees C):
Softens and expands at 93.3-101.7 C (200-215 F)
Specific Gravity (water=1):
Depending on bulk density of the product, the material may float on top of water.
pH:
Not applicable.
Vapor Pressure:
Negligible
Viscosity:
Not applicable
VOC Content:
Not determined.
Vapor Density (Air=1):
>1
Solubility in Water (%):
< 0.1
Other:
None
10. STABILITY AND REACTIVITY
This Material Reacts Violently With:
Air____ Water____ Heat__X__ Strong Oxidizers__X__ Others____ None of these____
Comments:
None
Products Evolved When Subjected to Heat or Combustion:
Toxic levels of carbon monoxide, carbon dioxide, irritating aldehydes and ketones.
Hazardous Polymerizations:
DO NOT OCCUR
11. TOXICOLOGICAL INFORMATION
TOXICOLOGICAL INFORMATION (ANIMAL TOXICITY DATA)
Oral:
LD50 Believed to be > 5.00 g/kg (rat) practically non-toxic
Inhalation:
Not determined.
Dermal:
LD50 Believed to be > 2.00 g/kg (rabbit) practically non-toxic
IRRITATION INDEX, ESTIMATION OF IRRITATION (SPECIES)
5
R-MER庐 II RESIN
MSDS CODE AND NAME GRADE 27
:
DATE ISSUED : 9/20/2005
DATE PRINTED : 9/20/2005
COMPANY : HUNTSMAN
Skin:
(Draize) Believed to be > .50 - 3.00 /8.0 (rabbit) slightly irritating
Eyes:
(Draize) Believed to be > 15.00 - 25.00 /110 (rabbit) slightly irritating
Sensitization:
Not determined.
Other:
Product may contain dust or particulates that may cause eye irritation or abrasion.
12. DISPOSAL CONSIDERATIONS:
Waste Disposal Methods:
This material should be disposed of in accordance with local, state and federal regulations.
Remarks:
Do not allow to enter drains or sewers.
13. TRANSPORT INFORMATION
Transportation
DOT:
Proper Shipping Name:
Polymeric beads, expandable
Hazard Class:
9
Identification Number:
UN 2211
Packing Group:
III
Label Required:
Class 9
IMDG
Proper Shipping Name:
Polymeric beads, expandable
Hazard Class
9
Identification Number
UN 2211
Packing Group
III
Label Required
Class 9 (See Section 16 for additional information)
ICAO
Proper Shipping Name:
6
R-MER庐 II RESIN
MSDS CODE AND NAME GRADE 27
:
DATE ISSUED : 9/20/2005
DATE PRINTED : 9/20/2005
COMPANY : HUNTSMAN
Polymeric beads, expandable
Hazard Class
9
Identification Number
UN 2211
Packing Group
III
Label Required
Class 9 (See Section 16 for additional information)
TDG
Proper Shipping Name:
Polymeric beads, expandable
Hazard Class:
9
Identification Number:
UN 2211
Label Required:
Class 9 (per UN recommendations, black vertical stripes)
14. REGULATORY INFORMATION
Federal Regulations:
SARA Title III:
Section 302/304 Extremely Hazardous Substances
Chemical Name CAS Number Range in % TPQ RQ
None.
Section 311 Hazardous Categorization:
Acute__X__ Chronic__X__ Fire__X__ Pressure____ Reactive____ N/A____
Section 313 Toxic Chemical
Chemical Name CAS Number Concentration
None.
CERCLA 102(a)/DOT Hazardous Substances:
Chemical Name CAS Number Range in % RQ
None.
States Right-to-Know Regulations:
Chemical Name State Right-to-know
Pentane FL, MA, MN, NJ, PA, RI
California Prop. 65:
The following detectable components of this product are substances, or belong to classes of substances, known to the State of
California to cause cancer and/or reproductive toxicity.
Chemical Name CAS Number
None.
INTERNATIONAL REGULATIONS:
7
R-MER庐 II RESIN
MSDS CODE AND NAME GRADE 27
:
DATE ISSUED : 9/20/2005
DATE PRINTED : 9/20/2005
COMPANY : HUNTSMAN
TSCA Inventory Status:
This product, or its components, are listed on, or are exempt from the Toxic Substance Control Act (TSCA) Chemical Substance
Inventory.
WHMIS Classification:
Not determined.
Canadian Inventory Status:
This product, or its components, are listed on or are exempt from the Canadian Domestic Substance List (DSL).
EINECS Inventory Status:
This product, or its components, are listed on or are exempt from the European Inventory of Existing Chemical Substances
(EINECS) or the European List of Notified Chemical Substances (ELINCS).
Australian Inventory Status:
This product, or its components, are listed on or are exempt from the Australian Inventory of Chemical Substances (AICS).
Japan Inventory Status:
This product, or its components, are listed on or are exempt from the Japanese Ministry of International Trade and Industry (MITI)
inventory.
15. ENVIRONMENTAL INFORMATION
Aquatic Toxicity:
Not applicable.
Mobility:
Not applicable.
Persistence and Biodegradability:
This product is expected to persist in the environment.
Potential to Bioaccumulate:
Not applicable.
Remarks:
Sewer/waterways obstruction; fish may eat beads and obstruct their digestive tract.
16. OTHER INFORMATION 9/20/2005
European, ADR regulations require additional marking (see item 2912) "Keep Away From Any Source of Ignition." Vessel carriers request
marking warning "No Smoking or Open Flame" on box doors.
Date Issued: 9/20/2005.
THE INFORMATION IN THIS DATA SHEET IS PROVIDED INDEPENDENTLY OF ANY SALE OF THE PRODUCT. IT IS PROVIDED
FOR THE PURPOSE OF HAZARD COMMUNICATION AS PART OF HUNTSMAN鈥橲 PRODUCT SAFETY PROGRAM. IT IS
INTENDED ONLY AS A GUIDE TO THE APPROPRIATE PRECAUTIONARY HANDLING OF THE PRODUCT BY A PROPERLY
TRAINED PERSON. YOU ARE ENCOURAGED AND REQUESTED TO ADVISE THOSE WHO MAY COME IN CONTACT WITH
SUCH PRODUCTS OF THE INFORMATION CONTAINED HEREIN. THE DATA RELATES ONLY TO THE SPECIFIC PRODUCT
DESIGNATED, AND DOES NOT RELATE TO USE OF THE PRODUCT IN COMBINATION WITH ANY OTHER MATERIAL OR USE
OF THE PRODUCT IN ANY PROCESS. THE DATA IS NOT INTENDED TO CONSTITUTE PERFORMANCE INFORMATION
CONCERNING THE PRODUCT. NO EXPRESS WARRANTY, OR IMPLIED WARRANTY OF MERCHANTABILITY FOR FITNESS
FOR A PARTICULAR PURPOSE IS MADE WITH RESPECT TO THE PRODUCT, ITS COMPOSITION, ITS SAFETY OR THE
INFORMATION CONTAINED IN THIS DATA SHEET.
8
R-MER庐 II RESIN
MSDS CODE AND NAME GRADE 27
:
DATE ISSUED : 9/20/2005
DATE PRINTED : 9/20/2005
COMPANY : HUNTSMAN
TO DETERMINE THE APPLICABILITY OR THE EFFECTS OF ANY LAW OR REGULATION WITH RESPECT TO THE PRODUCT,
THE USER SHOULD CONSULT A LEGAL ADVISOR OR THE APPROPRIATE GOVERNMENT AGENCY. HUNTSMAN DOES NOT
UNDERTAKE TO FURNISH ADVICE ON SUCH MATTERS.
CURRENT DATA SHEETS ARE AVAILABLE FOR ALL HUNTSMAN PRODUCTS. YOU ARE URGED TO OBTAIN DATA SHEETS
FOR ALL HUNTSMAN PRODUCTS YOU BUY, USE OR DISTRIBUTE BY CALLING (281) 719-6432 OR DIRECTING YOUR
INQUIRIES TO:
HUNTSMAN
MANAGER, PRODUCT SAFETY
P.O. BOX 4980
THE WOODLANDS, TX 77387-4980
NO PERSON OR ORGANIZATION EXCEPT A DULY AUTHORIZED HUNTSMAN EMPLOYEE IS AUTHORIZED TO PROVIDE OR
MAKE AVAILABLE DATA SHEETS FOR HUNTSMAN PRODUCTS. DATA SHEETS FROM UNAUTHORIZED SOURCES MAY
CONTAIN INFORMATION THAT IS NO LONGER CURRENT OR ACCURATE. NO PART OF THIS DATA SHEET MAY BE
REPRODUCED OR TRANSMITTED IN ANY FORM, OR BY ANY MEANS, WITHOUT PERMISSION IN WRITING FROM
HUNTSMAN. ALL REQUESTS FOR PERMISSION TO REPRODUCE MATERIAL FROM THIS DATA SHEET SHOULD BE
DIRECTED TO HUNTSMAN, MANAGER, PRODUCT SAFETY AT THE ABOVE ADDRESS.
COPYRIGHT 漏 BY HUNTSMAN CORPORATION. ALL RIGHTS RESERVED.
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