MATERIAL SAFETY DATA SHEET
Version: 1.3
ARREST 75W Date of Issue: 04/06/2006
Date printed: 04/22/2006
1. PRODUCT AND COMPANY IDENTIFICATION
ARREST 75W
Product name :
Agricultural turf fungicide
Chemical name:
Fungicide
Use of substance/preparation:
Chemtura Canada Co./Cie
Supplier:
25 ERB STREET
Elmira, Ontario N3B 3A3 Canada
Chemtura USA Corporation
Manufacturer:
199 Benson Road
Middlebury, CT 06749 USA
866-744-3060 (Canada)
Emergency telephone
CANUTEC (24 hours) 613-996-6666
number:
For additional emergency telephone numbers see section 16 of the Safety Data
Sheet.
866-430-2775
Environmental, Health and
Safety Department:
2. COMPOSITION / INFORMATION ON INGREDIENTS
INGREDIENT % BY WEIGHT
Thiram 50
CAS# 137-26-8
Carboxin 20
CAS# 5234-68-4
Oxycarboxin 5
CAS# 5259-88-1
Free Silica (Quartz) < 0.5
CAS# 14808-60-7
WHMIS CLASSIFICATION
D2B Toxic material causing other effects.
CPR Compliance
This product has been classified with the hazard criteria of the CPR, and the MSDS contains all the information required by CPR.
3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
CAUTION!
MAY CAUSE EYE AND SKIN IRRITATION.
MAY CAUSE SKIN SENSITIZATION.
EXPOSURE CAN RESULT IN AN ADVERSE REACTION WITH THE CONSUMPTION OF ALCOHOLIC BEVERAGES.
(M)SDS# 000000034168 Page: 1 of 8
MATERIAL SAFETY DATA SHEET
Version: 1.3
ARREST 75W Date of Issue: 04/06/2006
Date printed: 04/22/2006
SEE SECTION 11 FOR INFORMATION ON CHRONIC HEALTH EFFECTS.
AVOID DISPERSION OF DUST IN AIR TO REDUCE POTENTIAL FOR DUST IGNITION/EXPLOSIONS.
CONSUMPTION OF ALCOHOL SHOULD BE AVOIDED BEFORE AND AFTER EXPOSURE.
4. FIRST AID MEASURES
Swallowing
If patient is fully conscious, give two glasses of water. Induce vomiting. Obtain medical attention immediately. Do not give milk, oily products, fat or alcohol. Do
not give anything by mouth to an unconscious person.
Inhalation
Remove to fresh air. Give artificial respiration if not breathing. Obtain medical attention.
Skin contact
Wash skin with soap and water. Remove contaminated clothing. Wash clothing before re-use. Obtain medical attention if irritation persists.
Eye contact
Immediately flush eyes with water and continue washing for at least 15 minutes. Obtain medical attention.
Notes to physician
ROUTES OF ENTRY:
Skin
Eyes
Ingestion
Inhalation
If Thiram is absorbed into the body it may affect the liver, kidneys, and central nervous system. Symptoms may include headache, insomnia, and nervous
disorders. In severe cases symptoms may include kidney pain, dizziness, loss of memory and tremors. Alcohol intolerance may result on exposure; symptoms
include flushing of the face and neck, followed by rapid heard beat, nausea, vomiting, headache and low blood pressure.
5. FIRE-FIGHTING MEASURES
Flash point: > 110 掳C
Hazardous combustion products
Burning can produce the following combustion products:
Oxides of carbon.
Oxides of nitrogen.
Oxides of sulfur.
Special fire fighting procedures
Do not discharge extinguishing waters into streams, rivers and lakes.
Special protective equipment for firefighters
Body covering protective clothing, full "turn-out" gear.
Self-contained breathing apparatus.
Extinguishing media
Suitable: Large fires:
- alcohol-type foam or universal-type foams
Small fires:
- CO2
- dry chemical
- water spray
Unsuitable: - water jets
Unusual fire and explosion hazards
Avoid dispersion of dust in air to reduce potential for dust ignition/explosions.
6. ACCIDENTAL RELEASE MEASURES
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MATERIAL SAFETY DATA SHEET
Version: 1.3
ARREST 75W Date of Issue: 04/06/2006
Date printed: 04/22/2006
Personal precautions
Wear suitable protective equipment., Avoid contact with eyes and skin.
Environmental precautions
Prevent from entering sewer system, surface water or soil.
Methods for cleaning up
Sweep up and collect in a suitable container for disposal.
Avoid dust formation.
Observe government regulations.
7. HANDLING AND STORAGE
HANDLING
Handling precautions
Do not get in eyes, on skin, on clothing., Do not swallow., Avoid dispersion of dust in air., Do not eat, drink or smoke when handling.
Other precautions
If fine dust is formed from this product, avoid dispersion of dust in air to reduce fire and explosion hazard. Consumption of alcohol should be avoided before and
after exposure. Do not store near food, feed or fertilizers. Do not contaminate ponds, lakes, streams, or any source of water.
STORAGE
Storage requirements
Store in a cool, dry place., Store in closed original drums.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE LIMIT VALUES
Consult local authorities for acceptable provincial values.
Component Country Type Value Remark
Thiram Great Britain TWA 5 mg/m3
Great-Britain STEL 10 mg/m3
USA TLV-TWA, 1 mg/m3
ACGIH
PEL-TWA, 5.0 mg/m3
OSHA
Free Silica (Quartz) ACGIH - 0.05 mg/m3 Toxicity to reproduction/fertility: CANCER HAZARD A2
respirable dust
OSHA - 0.1 mg/m3 TWA
respirable dust
OSHA - total 0.3 mg/m3 TWA
dust
No other exposure limits have been established
PERSONAL PROTECTION
Respiratory protection
Respirator in the presence of dusts, fumes, and vapors., All respirators must be NIOSH approved.
Hand protection / protective gloves
Chemical resistant protective gloves
Eye protection
Safety glasses with side shields.
Skin protection
Wear protective clothing, such as long sleeves to minimize skin contact.
(M)SDS# 000000034168 Page: 3 of 8
MATERIAL SAFETY DATA SHEET
Version: 1.3
ARREST 75W Date of Issue: 04/06/2006
Date printed: 04/22/2006
ENGINEERING CONTROLS
Ventilation
Apply local exhaust ventilation at points of dust generation.
9. PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE
Solid
Physical state
White
Color
Faint - musty
Odor
Not available
Odor threshold
OTHER PROPERTIES
Not applicable
Boiling point
Not available
Melting point
Not available
Solidification
Not available
pH
Not available
Specific gravity (H2O=1)
Not available
Density
Vapor pressure
Not available
Solubility in water
No data available.
Solubility in organic solvents
Not available
Partitioning coefficient
Flash point
> 110 掳C
Method: Setaflash closed cup ASTM D 3828
Not available
Autoignition temperature
Not available
Upper explosion limits
Not available
Lower explosion limits
Not available
Percent volatiles
10. STABILITY AND REACTIVITY
Stability: Stable under normal conditions.
Stability - Conditions to avoid
Avoid dust formation.
Incompatible materials
Strong oxidizing agents.
Alkalis.
Acids.
Hazardous reactionsContact with strong acid can produce the following:
Carbon disulfide
(M)SDS# 000000034168 Page: 4 of 8
MATERIAL SAFETY DATA SHEET
Version: 1.3
ARREST 75W Date of Issue: 04/06/2006
Date printed: 04/22/2006
Hydrogen disulfide
Hazardous combustion products
Burning can produce the following combustion products:
Oxides of carbon.
Oxides of nitrogen.
Oxides of sulfur.
Hazardous polymerization: Will not occur.
11. TOXICOLOGICAL INFORMATION
Component data LD50 - Rat
Thiram Result: 2,600 mg/kg
Acute toxicity - Swallowing:
Component data LD50 - Rat
Carboxin Result: 2,900 mg/kg
Acute toxicity - Swallowing:
Component data NOEL - Rat
Carboxin Result: 5.5 mg/kg
Chronic toxicity - Swallowing: Exposure time: 90 d
Component data LD50 - Rat
Thiram Result: > 2,000 mg/kg
Acute toxicity - Skin absorption:
Component data LD50 - Rabbit
Carboxin Result: > 4,000 mg/kg
Acute toxicity - Skin absorption:
Component data NOEL - Rats
Carboxin Result: 30 mg/kg
Chronic toxicity - Skin absorption: Exposure time: 28 d
Component data LC50 - Rat
Thiram Result: 3.46 mg/l
Acute toxicity - Inhalation: Exposure time: 4 h
Remark: Aerosol
Component data LC50 - Rabbit
Thiram Result: 4.42 mg/l
Acute toxicity - Inhalation: Exposure time: 4 h
Component data LC50 - Rat
Carboxin Result: > 4.7 mg/l
Acute toxicity - Inhalation: Exposure time: 4 h
Component data Species: Rabbit
Thiram Remark: Not irritant
Skin irritation - Skin contact:
Component data Species: Rabbit
Carboxin Result: Not irritating
Skin irritation - Skin contact:
Component data Species: Rabbit
Thiram Classification: Irritant
(M)SDS# 000000034168 Page: 5 of 8
MATERIAL SAFETY DATA SHEET
Version: 1.3
ARREST 75W Date of Issue: 04/06/2006
Date printed: 04/22/2006
Eye irritation - Eye contact:
Component data Species: Rabbit
Carboxin Result: Mild irritation
Eye irritation - Eye contact:
Component data Species: Human
Thiram Result: Evidence of sensitization.
Sensitization:
Component data Species: Guinea pigs
Carboxin Result: Non sensitizing.
Sensitization: Method: B眉hler-Test
Component data Species: Guinea pigs
Carboxin Result: sensitizing
Sensitization: Method: Magnusson-Kligmann-Test
MUTAGENICITY
Component (Thiram): Ames-test: no mutagenic effect
CARCINOGENICITY
Component (Thiram): No evidence of carcinogenic activity
DEVELOPMENT TOXICITY/TERATOGENICITY
Component data Species: Rat
Thiram NOAEL maternity: 7.5 mg/kg
Development toxicity/Teratogenicity:
12. ECOLOGICAL INFORMATION
Biodegradation: Value: 100 %
Remark: Readily biodegradable.
Component ecotoxicology LC50 - Rainbow trout (Oncorhynchus mykiss)
Thiram Result: 0.046 mg/l
Acute toxicity fish: Exposure time: 96 h
Component ecotoxicology LC50 - Rainbow trout (Oncorhynchus mykiss)
Thiram Result: 0.128 mg/l
Acute toxicity fish: Exposure time: 96 h
Component ecotoxicology LC50 - Bluegill (Lepomis macrochirus)
Thiram Result: 0.0445 mg/l
Acute toxicity fish: Exposure time: 96 h
Component ecotoxicology EC50 - Water flea (Daphnia magna)
Thiram Result: 0.011 mg/l
Acute toxicity to aquatic invertebrates: Exposure time: 48 h
Component ecotoxicology - Water flea (Daphnia magna)
Thiram Result: 0.021 ppm
Acute toxicity to aquatic invertebrates: Exposure time: 48 h
(M)SDS# 000000034168 Page: 6 of 8
MATERIAL SAFETY DATA SHEET
Version: 1.3
ARREST 75W Date of Issue: 04/06/2006
Date printed: 04/22/2006
13. DISPOSAL CONSIDERATIONS
Avoid discharge to sewers and natural waters., Incinerate in a furnace where permitted under appropriate Federal, State,
General:
and local regulations.
Non-cleaned packages
Empty drums should be decontaminated and either passed to an an approved drum reconditioner or destroyed., Containers that cannot be cleaned must be treated
as waste.
14. TRANSPORT INFORMATION
TDG - Canada
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
Shipping Name:
9
Class:
UN 3077
UN ID #:
III
Packing group:
IMDG Classification
Environmentally hazardous substance, solid, n.o.s.
Proper shipping name:
9
Class:
marine pollutant
Subsidiary risk:
UN 3077
UN ID #:
III
Packing group:
ICAO Classification
Environmentally hazardous substance, solid, n.o.s.
Proper shipping name:
9
Class:
UN 3077
UN ID #:
III
Packing group:
15. REGULATORY INFORMATION
WHMIS CLASSIFICATION
D2B Toxic material causing other effects.
CPR Compliance
This product has been classified with the hazard criteria of the CPR, and the MSDS contains all the information required by CPR.
CHEMICAL INVENTORY
Canada: All substances in this product are exempt from the DSL as this product is registered under the Pest
Control Products Act., PCP# 13431
16. OTHER INFORMATION
FURTHER INFORMATION
MAY BE ON THE INVENTORY LIST BUT NOT NECESSARILY REGISTERED, (Korea, China, New Zealand) CONSULT REGULATORY SPECIALIST.
(M)SDS# 000000034168 Page: 7 of 8
MATERIAL SAFETY DATA SHEET
Version: 1.3
ARREST 75W Date of Issue: 04/06/2006
Date printed: 04/22/2006
STP Standard temperature and pressure
W/W Weight/Weight
ARREST庐 is a trademark ofChemtura Canada Co./Cie
Copyright 2006 Chemtura Canada Co./Cie
THE OPINIONS EXPRESSED HEREIN ARE THOSE OF QUALIFIED EXPERTS WITHIN CHEMTURA CORPORATION. WE BELIEVE THAT THE INFORMATION CONTAINED HEREIN IS
CURRENT AS OF THE DATE OF THIS SAFETY DATA SHEET. SINCE THE USE OF THIS INFORMATION AND OF THESE OPINIONS AND THE CONDITIONS OF USE OF THIS PRODUCT
ARE NOT WITHIN THE CONTROL OF CHEMTURA CORPORATION, IT IS THE USER'S OBLIGATION TO DETERMINE THE CONDITIONS OF SAFE USE OF THE PRODUCTS.
(M)SDS# 000000034168 Page: 8 of 8
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