MATERIAL SAFETY DATA SHEET 1 of 2
12435 INSECT REPELLENT HD AEROSOL
DEGIL SAFETY PRODUCTS 681 ROWNTREE DAIRY ROAD PH. 905-856-1511
www.degilsafety.com WOODBRIDGE, ON CANADA L4L 5T9 FAX. 905-856-1694
SECTION ONE PRODUCT IDENTIFICATION
TRADE NAME CROC BLOC HEAVY DUTY INSECT REPELLENT AEROSOL UPC CODE
CHEMICAL FAMILY N,N-DIETHYL m-TOLUAMIDE (DEET)
PRODUCT USE INSECTICIDE Packaging
MOLECULAR WEIGHT NOT APPLICABLE 24 CANS / CASE
FORMULA NOT APPLICABLE
CNFC SECTION 3 3.5 LEVEL 3
NFPA CODE 30B LEVEL 3
T.D.G. CLASS ORM-D CONSUMER COMMODITY
WHMIS CLASSIFICATION NOT APPLICABLE
HMIS RATING: FLAMMABILITY 4 SEVERE HAZARD
HMIS RATING: HEALTH 2 MODERATE HAZARD
HMIS RATING: REACTIVITY 0 MINIMAL HAZARD
SECTION TWO COMPOSITION / INFORMATION INGREDIENTS
Hazardous Ingredients % T.L.V. C.A.S. # LD/50, Route, Species LC/50, Route, Species
N,N-DIETHYL m-TOLUAMIDE 28.5 N/A 134-62-3 2000 mg/kg ORAL - RAT 5950 mg/kg INHAL - RAT
ISOPROPANOL 30 - 60 400ppm 67-63-0 >4720mg/kg ORAL - RAT 12000ppm (8hr) INHAL - RAT
ISOBUTANE 30-Oct N/A 75-28-5 NOT AVAILABLE 142500 ppm (4hr) INHAL - MOUSE
PROPANE 1-5 1000ppm 74-98-6 NOT AVAILABLE NOT AVAILABLE
SECTION THREE PHYSICAL DATA
PHYSICAL STATE AEROSOL
APPEARANCE CLEAR - COLOURLESS
ODOR ALCOHOL
ODOR THRESHOLD NOT AVAILABLE
BOILING POINT (掳 C)(CONC) 83
EVAPORATION RATE GREATER THAN 1
VAPOUR PRESSURE (PSIG) AEROSOL 40 - 50 @ 20掳 C
VAPOUR DENSITY (AIR=1) GREATER THAN 1
AEROSOL % VOC (w/w) 79 - 80
AEROSOL % VOLATILE 79 - 80
SOLUBILITY IN WATER NOT AVAILABLE
pH NOT APPLICABLE
SPECIFIC GRAVITY (LIQUID) 0.83 - 0.87
SPECIFIC GRAVITY (AEROSOL) 0.75 - 0.79
COEFFICIENT OF WATER/OIL DIST NOT AVAILABLE
FREEZING POINT: (掳 C) NOT AVAILABLE
SECTION FOUR FIRE & EXPLOSION HAZARD DATA
AEROSOL FLAME PROJECTION > 45cm
FLASHBACK NOT APPLICABLE
FLAMMABILITY EXTREMELY FLAMMABLE
IF YES, UNDER WHICH CONDITIONS EXCESSIVE HEAT, SPARKS AND OPEN FLAME
AUTO IGNITION TEMPERATURE (掳 C) NOT AVAILABLE
EXTINGUISHING MEDIA CARBON DIOXIDE, DRY CHEMICAL, FOAM
UPPER FLAMMABLE LIMIT 12.0 (% BY VOLUME)
LOWER FLAMMABLE LIMIT 1.9 (% BY VOLUME)
EXPLOSION DATA
SENSITIVITY TO STATIC DISCHARGE NOT APPLICABLE
SENSITIVITY TO IMPACT NOT APPLICABLE
HAZARDOUS COMBUSTION
PRODUCTS HYDROCARBON FUMES AND SMOKE, CARBON MONOXIDE WHERE
COMBUSTION IS INCOMPLETE.
FLASH POINT (掳 C) TAG CLOSED 14 CUP
(CONCENTRATE)
SPECIAL PROCEDURES WATER FROM FOGGING NOZZLES MAY BE USED TO COOL CLOSED CONTAINERS
TO PREVENT BUILD UP IF EXPOSED TO EXTREME TEMPERATURES. FULL
PROTECTIVE EQUIPMENT INCLUDING SELF CONTAINED BREATHING APPARATUS
SHOULD BE WORN IN A FIRE INVOLVING THIS MATERIAL.
5/2/20064:35 PM ITEM# 12435 DEGIL SAFETY PRODUCTS
MATERIAL SAFETY DATA SHEET 2 of 2
12435 INSECT REPELLENT HD AEROSOL
SECTION FIVE STABILITY AND REACTIVITY
HAZARDOUS PRODUCTS OF
DECOMPOSITION HYDROCARBON FUMES AND SMOKE. CARBON MONOXIDE WHERE
COMBUSTION IS INCOMPLETE
CHEMICAL STABILITY YES
UNDER NORMAL CONDITIONS
COMPATABILITY WITH OTHER
SUBSTANCES - NO, WHICH ONES? STRONG OXIDIZING AGENTS
REACTIVITY CONDITIONS? NOT APPLICABLE
SECTION SIX HEALTH DATA
ROUTE OF ENTRY
INGESTION MAY CAUSE HEADACHE, NAUSEA, VOMITING & WEAKNESS
INHALATION INHALATION OF SOLVENTS MAY CAUSE IRRITATION. PROPELLENT IS SIMPLE ASPHYXIANT
EYE CONTACT MAY CAUSE IRRITATION
SKIN CONTACT MAY CAUSE IRRITATION
EFFECTS OF ACUTE EXPOSURE DIZZINESS, NAUSEA, IRRITATION TO SKIN & EYES
EFFECTS OF CHRONIC EXPOSURE SOLVENTS MAY CAUSE DEFATTING DERMATITIS
EXPOSURE LIMIT OF MATERIAL SEE SECTION TWO
CARCINOGENICITY OF MATERIAL THE INGREDIENTS OF THIS PRODUCT ARE NOT LISTED AS
CARCINOGENS BY NTP, (NATIONAL TOXICOLOGY PROGRAM), NOT
REGULATED AS CARCINOGENS BY OSHA, (OCCUPATIONAL SAFETY
AND HEALTH ADMINISTRATION), AND HAVE NOT BEEN EVALUATED BY
IARC, (INTERNATIONAL AGENCY FOR RESEARCH ON CANCER), NOR
BYACGIH (AMERICAN CONFERENCE OF GOVERNMENTAL
INDUSTRIAL HYGIENISTS).
REPRODUCTIVE EFFECTS NO INFORMATION IS AVAILABLE AND NO ADVERSE RESPRODUCTIVE
EFFECTS ARE ANTICIPATED.
IRRITANCY OF MATERIAL SLIGHT
TERATOGENICITY NO INFORMATION IS AVAILABLE AND NO ADVERSE TERATOGENICITY
EFFECTS ARE ANTICIPATED.
MUTAGENICITY NO INFORMATION IS AVAILABLE AND NO ADVERSE MUTAGENIC
EFFECTS ARE ANTICIPATED.
SYNERGISTIC MATERIALS NONE KNOWN
SECTION SEVEN EXPOSURE CONTROLS/PERSONAL PROTECTION
GLOVES CHEMICAL RESISTANT GLOVES
RESPIRATORY IF USED INDOORS ON A CONTINUOUS BASIS, USE OF A CARTRIDGE TYPE
RESPIRATOR (NIOSH/MSHA TC-23C OR EQUIVALENT) IS RECOMMENDED.
EYE SAFETY GLASSES
ENGINEERING CONTROLS VENTILATION - LOCAL (MECHANICAL IF INDOORS ON A CONTINUOUS BASIS)
FOOTWEAR NOT NORMALLY REQUIRED
OTHER NOT REQUIRED
SECTION EIGHT HANDLING AND STORAGE
LEAK / SPILL REMOVE ALL SOURCES OF IGNITION, USE AN INERT ABSORBENT MATERIAL AND NON -
SPARKING TOOLS. AVOID BREATHING FUMES, VENTILATE AREA
STORAGE NEEDS KEEP AWAY FROM HEAT, SPARKS, AND OPEN FLAMS
HANDLING PROCEDURES AND STORE IN A COOL, WELL VENTILATED AREA NOT TO EXCEED 50 DEG C.
EQUIPMENT
SHIPPING INSTRUCTIONS SEE SECTION ONE TDG CLASSIFICATION
WASTE DISPOSAL DO NOT PUNCTURE OR INCINERATE PACKAGES EVEN WHEN EMPTY. DISPOSE OF IN
ACCORDANCE WITH LOCAL, PROVINCIAL AND FEDERAL REGULATIONS
SECTION NINE FIRST AID MEASURES
EMERGENCY FIRST AID IN CASE OF EYE CONTACT, FLUSH IMMEDIATELY WITH PLENTY OF
PROCEDURE WATER FOR AT LEAST 15 MINUTES AND GET MEDICAL ATTENTION. FOR
SKIN, WASH THOROUGHLY WITH SOAP AND WATER. IF AFFECTED BY
INHALATION OF VAPOUR OR SPRAY MIST, REMOVE TO FRESH AIR. IF
SWALLOWED; DO NOT INDUCE VOMITING, GET MEDICAL ATTENTION.
SECTION TEN ADDITIONAL INFORMATION
This document has been prepared using data from sources considered technically reliable.
It does not constitute a warranty, express or implied, as to the accuracy of the information
contained herein. Actual conditions of use and handling are beyond seller's control.
User is responsible to evaluate all available information when using product for any
particular use and to comply with all Federal, State, Provincial and local laws and
regulations.
Prepared By: Maureen Kayum 1-800-332-1810 REVIEWED MAY 2/2006
5/2/20064:35 PM ITEM# 12435 DEGIL SAFETY PRODUCTS
|